CN106189410A - A kind of fabric acrylic acid ester emulsion coating - Google Patents

A kind of fabric acrylic acid ester emulsion coating Download PDF

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Publication number
CN106189410A
CN106189410A CN201610600881.XA CN201610600881A CN106189410A CN 106189410 A CN106189410 A CN 106189410A CN 201610600881 A CN201610600881 A CN 201610600881A CN 106189410 A CN106189410 A CN 106189410A
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parts
acrylic acid
ester emulsion
emulsion coating
acid ester
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CN201610600881.XA
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Chinese (zh)
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董荣琴
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Individual
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Priority to CN201610600881.XA priority Critical patent/CN106189410A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Inorganic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of fabric acrylic acid ester emulsion coating; it is made up of deionized water, ammonia, styrene, acrylic acid 2 Octyl Nitrite, fatty alcohol, sodium sulfite, phthalic anhydride, acetic acid, phthalocyanine blue ketone, phosphoric acid and essence; protect for textile surface; gloss 91 95%; decorative surface is good; water-tolerant, fastness to washing is high, no color differnece；Pencil hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；Solidification 60min drying time 20, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, and good mechanical property is skin friendly, can increase substantially antibiotic property and the mildew resistance of textile product.

Description

A kind of fabric acrylic acid ester emulsion coating
Technical field
The present invention relates to textile material surface acrylic acid ester emulsion coating, particularly relate to a kind of fabric acrylic acid Ester emulsion coatings.
Background technology
Original meaning of weaving is taken from spinning and the general name weaved cotton cloth, but is as continuous of weaving knowledge hierarchy and subject system Exhibition and perfect, particularly non-woven textile material and three-dimensional is composite braided etc. after technology produces, present weaving has been not only Traditional hand spinning and weaving cotton cloth, also includes nonwoven fabric technology, Modern three-dimensional knitting skill, modern electrostatic nanometer net-forming technology etc. The clothing produced are used, industry is used, decorative textile product.So, modern textile refers to many chis of a kind of fiber or fiber assembly Degree structure process technology.The weaving of ancient Chinese and printing technology have the longest history, as far back as primitive society period, ancient People, for the change of acclimatization, has understood and has gathered materials on the spot, utilize natural resources as weaving and printing and dyeing raw material, and manufacture Simple Handicraft Textile instrument.Until today, clothing, air bag and the curtain carpet in daily life is all weaving and printing and dyeing The product of technology.
Industry growth rate glides even atrophy, and enterprise is in the urgent need to seeking transition in the industry, and following industry faces shuffles.Enterprise Industry faces several aspect problem transition: first: improve environmental protection concept.Energy-saving and emission-reduction are future developing trends, and textile industry height is dirty Dye and not environmentally problem are endured to the fullest extent and are denounced, and it is unfavorable to form industry development, and environmental pollution becomes industry development bottleneck.Secondly, promote Brand image, improves brand recognition and market share.3rd, expand Sales Channel, since 2012, although industry is low Fan, but on line, network selling still prevails, and has significantly played its power.4th, strengthen cost control, such as the research and development of new raw material Utilize, re-establish market competition advantage.5th, exploitation variation, differentiated products, meet the market demand, break away from industry The state that product homogeneity is serious.
Ancient Chinese can be divided into coloring earth and vegetable colour for the material of coloring, wherein main with the latter for ancient times Dyestuff.Coloring earth coloring is the surface being allowed to adhere to fabric by bonding agent, but color is met deionized water and the most easily come off. Vegetable colour is quite different, when contaminating processed, its pigment molecular be by with fabric fibre affinity and change the color of fiber, institute color Though washing through Exposure to Sunlight deionization, equal difficult drop-off or seldom come off.
The mineral and plant dyestuff that ancient times are commonly used is the most numerous, the dyeing that ancients create according to different dye characteristics Technique is in respect of direct dye, mordant dyeing, reduction dye, resist printing, chromatography dye etc..The multiformity of dye species and process makes print ancient times The chromatograph of dye industry is the abundantest, and see record in ancient books just has hundreds of kind, particularly separates clearly in a kind of tone Tens kinds of advancing colours, this needs expertly to grasp the combination of various dyestuff, formula and change process conditions and can reach.
In Chinese textile industry Eleventh Five-Year Development Plan outline, propose fabrics for industrial use based on scientific and technical innovation using as Giving priority to of textile industry, this provides huge motive power for this industrial expansion undoubtedly.China be textile production and The big country of outlet, china textile industry self is through development for many years, and competitive advantage is fairly obvious, possesses the most most complete Industrial chain, the highest process mating deionization level, the self regulation energy of the industry cluster ground reply market risk of numerous prosperities Power constantly strengthens, and keeps sane developing steps to provide solid guarantee to industry.
Printing and dyeing assistant is the auxiliary agent used during textile printing and dyeing, it is possible to increase stamp and the effect of dyeing Really, it includes printing assistant and dyeing assistant, printing assistant have thickening agent, binding agent, cross linking agent, emulsifying agent, dispersant and its His printing assistant etc..
The yield of China's chemical fibre, from 280.19 ten thousand tons of 1994, develops into 1161.37 ten thousand tons of 2003, newly fine Dimensions such as ppt and pla etc. are the most under development.Along with country cancels for adapting to textile exports quota, and the New Measure taked goes out Platform, and encourage the outlet of high added value textile and clothing, the demand of textile auxiliary will increase accordingly.China's dye in 2005 Material, organic pigment yield amount to 79.7 ten thousand tons, increase by 7.4% on a year-on-year basis, also push away while meeting domestic textile demand Move textile industry development.Last year, China's dyestuff total volume of import and export 29.59 ten thousand tons, increase by 1.61% on a year-on-year basis；Organic pigment enters The total volume of exports 14.59 ten thousand tons, increases by 5.12% on a year-on-year basis, and this Dou Shi China develops the important opportunity of textile auxiliary further.But, We are seeing that printing and dyeing assistant also should objectively recognize the weak point of existence while flourish.
Along with social city, technicalization, the development of hommization, a kind of decorative surface of design is good, levelability, pigment profit Moist, antibiotic property and the good weaving acrylic acid ester emulsion coating of mildew resistance, to meet the market demand, be very important.
Summary of the invention
Solve the technical problem that:
The application for existing weaving surface acrylic ester emulsion coatings dicoration, levelability, antibiotic property, mildew resistance and The technical problem of pigment wettability difference, it is provided that a kind of fabric acrylic acid ester emulsion coating.
Technical scheme:
A kind of fabric acrylic acid ester emulsion coating, raw materials by weight portion proportioning is as follows: deionized water 100 parts, Ammonia 10-30 part, styrene 10-30 part, acrylic acid-2-ethyl caproite 15-35 part, fatty alcohol 0.1-0.5 part, sodium sulfite 0.05-0.45 part, phthalic anhydride 5-45 part, acetic acid 10-30 part, phthalocyanine blue 1-5 part, phosphoric acid 3-7 part, essence 0.5-2.5 Part.
As a preferred technical solution of the present invention: the raw material of described weaving acrylic acid ester emulsion coating is by weight Number proportioning is as follows: deionized water 100 parts, ammonia 15-25 part, styrene 15-25 part, acrylic acid-2-ethyl caproite 20-30 part, Fatty alcohol 0.2-0.4 part, sodium sulfite 0.15-0.35 part, phthalic anhydride 15-35 part, acetic acid 15-25 part, phthalocyanine blue 2-4 part, phosphatase 24-6 parts, essence 1-2 part.
As a preferred technical solution of the present invention: the raw material of described weaving acrylic acid ester emulsion coating is by weight Number proportioning is as follows: deionized water 100 parts, ammonia 15 parts, styrene 15 parts, acrylic acid-2-ethyl caproite 20 parts, fatty alcohol 0.2 Part, sodium sulfite 0.15 part, phthalic anhydride 15 parts, acetic acid 15 parts, phthalocyanine blue 2 parts, phosphatase 24 part, 1 part of essence.
As a preferred technical solution of the present invention: the raw material of described weaving acrylic acid ester emulsion coating is by weight Number proportioning is as follows: deionized water 100 parts, ammonia 25 parts, styrene 25 parts, acrylic acid-2-ethyl caproite 30 parts, fatty alcohol 0.4 Part, sodium sulfite 0.35 part, phthalic anhydride 35 parts, acetic acid 25 parts, phthalocyanine blue 4 parts, phosphoric acid 6 parts, 2 parts of essence.
As a preferred technical solution of the present invention: the raw material of described weaving acrylic acid ester emulsion coating is by weight Number proportioning is as follows: deionized water 100 parts, ammonia 20 parts, styrene 20 parts, acrylic acid-2-ethyl caproite 25 parts, fatty alcohol 0.3 Part, sodium sulfite 0.25 part, phthalic anhydride 25 parts, acetic acid 20 parts, phthalocyanine blue 3 parts, phosphoric acid 5 parts, 1.5 parts of essence.
Beneficial effect:
Compared to the prior art a kind of weaving acrylic acid ester emulsion coating of the present invention use above technical scheme, tool There is techniques below effect: 1, protecting for textile surface, gloss 91-95%, decorative surface is good, water-tolerant, fastness to washing Height, no color differnece；2, pencil hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect Feel；3, solidification 20-60min drying time, bond strength is high, and levelability and pigment wettability are excellent, good permeability, and wide spectrum resists Bacterium；4, adhesive force is strong, and good mechanical property is skin friendly, can increase substantially antibiotic property and the mildew resistance of textile product, Ke Yiguang Current material is replaced in the general production not division of history into periods.
Detailed description of the invention
Embodiment 1:
Proportioning by weight weighs deionized water 100 parts, ammonia 10 parts, styrene 10 parts, acrylic acid-2-ethyl caproite 15 parts, fatty alcohol 0.1 part, sodium sulfite 0.05 part, phthalic anhydride 5 parts, acetic acid 10 parts, phthalocyanine blue 1 part, phosphoric acid 3 parts, 0.5 part of essence.To be uniformly mixed, after grinding machine for grinding, filter and package.
Protecting for textile surface, gloss 91%, decorative surface is good, water-tolerant, and fastness to washing is high, no color differnece；Lead Hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；When solidification is dried Between 60min, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, mechanical performance Good, skin friendly, antibiotic property and the mildew resistance of textile product can be increased substantially.
Embodiment 2:
Proportioning by weight weighs deionized water 100 parts, ammonia 30 parts, styrene 30 parts, acrylic acid-2-ethyl caproite 35 parts, fatty alcohol 0.5 part, sodium sulfite 0.45 part, phthalic anhydride 45 parts, acetic acid 30 parts, phthalocyanine blue 5 parts, phosphoric acid 7 Part, 2.5 parts of essence.To be uniformly mixed, after grinding machine for grinding, filter and package.
Protecting for textile surface, gloss 92%, decorative surface is good, water-tolerant, and fastness to washing is high, no color differnece；Lead Hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；When solidification is dried Between 50min, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, mechanical performance Good, skin friendly, antibiotic property and the mildew resistance of textile product can be increased substantially.
Embodiment 3:
Proportioning by weight weighs deionized water 100 parts, ammonia 15 parts, styrene 15 parts, acrylic acid-2-ethyl caproite 20 parts, fatty alcohol 0.2 part, sodium sulfite 0.15 part, phthalic anhydride 15 parts, acetic acid 15 parts, phthalocyanine blue 2 parts, phosphatase 24 Part, 1 part of essence.To be uniformly mixed, after grinding machine for grinding, filter and package.
Protecting for textile surface, gloss 93%, decorative surface is good, water-tolerant, and fastness to washing is high, no color differnece；Lead Hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；When solidification is dried Between 40min, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, mechanical performance Good, skin friendly, antibiotic property and the mildew resistance of textile product can be increased substantially.
Embodiment 4:
Proportioning by weight weighs deionized water 100 parts, ammonia 25 parts, styrene 25 parts, acrylic acid-2-ethyl caproite 30 parts, fatty alcohol 0.4 part, sodium sulfite 0.35 part, phthalic anhydride 35 parts, acetic acid 25 parts, phthalocyanine blue 4 parts, phosphoric acid 6 Part, 2 parts of essence.To be uniformly mixed, after grinding machine for grinding, filter and package.
Protecting for textile surface, gloss 94%, decorative surface is good, water-tolerant, and fastness to washing is high, no color differnece；Lead Hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；When solidification is dried Between 30min, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, mechanical performance Good, skin friendly, antibiotic property and the mildew resistance of textile product can be increased substantially.
Embodiment 5:
Proportioning by weight weighs deionized water 100 parts, ammonia 20 parts, styrene 20 parts, acrylic acid-2-ethyl caproite 25 parts, fatty alcohol 0.3 part, sodium sulfite 0.25 part, phthalic anhydride 25 parts, acetic acid 20 parts, phthalocyanine blue 3 parts, phosphoric acid 5 Part, 1.5 parts of essence.To be uniformly mixed, after grinding machine for grinding, filter and package.
Protecting for textile surface, gloss 95%, decorative surface is good, water-tolerant, and fastness to washing is high, no color differnece；Lead Hardness is F, has and fabulous sucks ionized water uniformity, can prevent pit and shrinkage cavity phenomenon, not affect feel；When solidification is dried Between 20min, bond strength is high, and levelability and pigment wettability are excellent, good permeability, broad-spectrum antiseptic；Adhesive force is strong, mechanical performance Good, skin friendly, antibiotic property and the mildew resistance of textile product can be increased substantially.
All components in above example all can be commercially available.
Above-described embodiment is only intended to be illustrated present disclosure rather than limit, therefore with the present invention's Any change in implication that claims are suitable and scope, is all considered as being included within the scope of the claims.

Claims (5)

1. a fabric acrylic acid ester emulsion coating, it is characterised in that described weaving acrylic acid ester emulsion coating Raw materials by weight portion proportioning is as follows: deionized water 100 parts, ammonia 10-30 part, styrene 10-30 part, acrylic acid-2-ethyl Own ester 15-35 part, fatty alcohol 0.1-0.5 part, sodium sulfite 0.05-0.45 part, phthalic anhydride 5-45 part, acetic acid 10- 30 parts, phthalocyanine blue 1-5 part, phosphoric acid 3-7 part, essence 0.5-2.5 part.
A kind of fabric acrylic acid ester emulsion coating the most according to claim 1, it is characterised in that described weaving is used The raw materials by weight portion proportioning of acrylic acid ester emulsion coating is as follows: deionized water 100 parts, ammonia 15-25 part, styrene 15- 25 parts, acrylic acid-2-ethyl caproite 20-30 part, fatty alcohol 0.2-0.4 part, sodium sulfite 0.15-0.35 part, O-phthalic Anhydride 15-35 part, acetic acid 15-25 part, phthalocyanine blue 2-4 part, phosphatase 24-6 parts, essence 1-2 part.
A kind of fabric acrylic acid ester emulsion coating the most according to claim 1, it is characterised in that described weaving is used The raw materials by weight portion proportioning of acrylic acid ester emulsion coating is as follows: deionized water 100 parts, ammonia 15 parts, styrene 15 parts, and third Olefin(e) acid-2-Octyl Nitrite 20 parts, fatty alcohol 0.2 part, sodium sulfite 0.15 part, phthalic anhydride 15 parts, acetic acid 15 parts, phthalein Blue 2 parts of cyanines, phosphatase 24 part, 1 part of essence.
A kind of fabric acrylic acid ester emulsion coating the most according to claim 1, it is characterised in that: described weaving is used The raw materials by weight portion proportioning of acrylic acid ester emulsion coating is as follows: deionized water 100 parts, ammonia 25 parts, styrene 25 parts, and third Olefin(e) acid-2-Octyl Nitrite 30 parts, fatty alcohol 0.4 part, sodium sulfite 0.35 part, phthalic anhydride 35 parts, acetic acid 25 parts, phthalein Blue 4 parts of cyanines, phosphoric acid 6 parts, 2 parts of essence.
A kind of fabric acrylic acid ester emulsion coating the most according to claim 1, it is characterised in that: described weaving is used The raw materials by weight portion proportioning of acrylic acid ester emulsion coating is as follows: deionized water 100 parts, ammonia 20 parts, styrene 20 parts, and third Olefin(e) acid-2-Octyl Nitrite 25 parts, fatty alcohol 0.3 part, sodium sulfite 0.25 part, phthalic anhydride 25 parts, acetic acid 20 parts, phthalein Blue 3 parts of cyanines, phosphoric acid 5 parts, 1.5 parts of essence.
CN201610600881.XA 2016-07-27 2016-07-27 A kind of fabric acrylic acid ester emulsion coating Pending CN106189410A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898762A (en) * 2013-03-19 2014-07-02 常州纺织服装职业技术学院 Size for textile sizing and preparation method of size
CN104846643A (en) * 2015-05-21 2015-08-19 青岛德翕拓创高新技术有限公司 High-efficiency environment-friendly textile sizing agent

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103898762A (en) * 2013-03-19 2014-07-02 常州纺织服装职业技术学院 Size for textile sizing and preparation method of size
CN104846643A (en) * 2015-05-21 2015-08-19 青岛德翕拓创高新技术有限公司 High-efficiency environment-friendly textile sizing agent

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