CN106567267A - Water-based pigment digital ink-jet textile printing ink and preparation and use methods thereof - Google Patents
Water-based pigment digital ink-jet textile printing ink and preparation and use methods thereof Download PDFInfo
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- CN106567267A CN106567267A CN201610991294.8A CN201610991294A CN106567267A CN 106567267 A CN106567267 A CN 106567267A CN 201610991294 A CN201610991294 A CN 201610991294A CN 106567267 A CN106567267 A CN 106567267A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0023—Digital printing methods characterised by the inks used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/0041—Digital printing on surfaces other than ordinary paper
- B41M5/0047—Digital printing on surfaces other than ordinary paper by ink-jet printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5264—Macromolecular compounds obtained otherwise than by reactions involving only unsaturated carbon-to-carbon bonds
- D06P1/5285—Polyurethanes; Polyurea; Polyguanides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention provides a water-based pigment digital ink-jet textile printing ink and preparation and use methods thereof. The water-based pigment digital ink-jet textile printing ink is characterized by containing a pigment color paste, a nano composite adhesive and deionized water, wherein the nano composite adhesive comprises a polyurethane emulsion, an organic fluorine modified polyacrylate nano emulsion and another polyacrylate emulsion. With use of the nano composite adhesive, the problem of low water washing fastness of a water-based pigment ink-jet printing ink on a printing fabric is solved emphatically, and a new solution is provided for industrialized application of the water-based pigment ink-jet printing ink in the field of fabric digital ink-jet printing.
Description
Technical field
The present invention relates to a kind of aqueous pigment digital ink-jet printing in textiles ink and preparation method thereof, while being related to the ink
The ink-jet printed method on fabric of water.
Background technology
Traditional silk screen, ROTARY SCREAM PRINTING operating procedure complexity are tediously long, and it is various to meet high-quality, small lot, style
Change, personalized requirement, and digital ink-jet printed technology has broken away from Conventional decal color separation, plate-making, the analog form of system net, has
Easy to operate, pollution-free, low energy consumption, the clear superiority of high repayment, to textile printing and dyeing industry unprecedented opportunity to develop is brought.
Digital ink-jet printed is that required decalcomania is input in digital form in computer, is edited through the scanning of computer color separation in printing
After process, in the digital inkjet printing machine through computer controls, directly printing ink is accurately ejected on fabric, is printed
Go out various required color patterns.Digital ink-jet printed ink is the important consumptive material of digit printing, and the property of digit printing ink
Printing quality can be directly influenced, the digital ink-jet printed ink of presently used fabric is contaminated mainly based on dye ink
There are shortcomings in material ink：(1) dye ink does not have versatility.Different fabrics needs different types of dye ink
Stamp requirement can be met, due to changing ink cleaning sprayer and pipeline are needed, cause operation cumbersome；(2) complex manufacturing,
There is certain environmental pollution.Needed to pre-process fabric before ink-jet printed, it is ink-jet printed after need to enter fabric promoting the circulation of qi steaming
Fixation, washing remove the post processing such as loose colour, and technique is complex, and energy consumption is higher.Fabric post-processing stages generally require many
Secondary washing could remove the dyestuff not being securely held, because certain environmental pollution can be caused；(3) light fastness is poor.One
As dyestuff be all low-molecular-weight water-soluble dye, easily decompose under illumination condition, cause fade discoloration, affect PRINTED FABRIC product
Matter.
The disadvantages mentioned above of dye ink hinders the popularization of digital ink-jet printed technology, therefore exploitation is avoided that dye ink
The task of the novel ink-jet printing ink of shortcoming is extremely urgent, and pigment ink-jetting printing ink comes into existence as the situation requires.Pigment jetting prints
Flower ink, in the film forming mechanism of fabric face, the pigment without compatibility and reactivity is sticked on fabric based on adhesive,
Again through bakeing the surface for making pigmentation and being firmly secured to fabric, so as to give the gorgeous color of fabric and abundant figure
Case.Pigment ink-jetting printing ink can be common to various fabrics, such as cotton, hair, silk, cotton synthetic fibre, dacron and blend fabric, in spray
Fabric variety is converted during ink-printed need not change ink and cleaning sprayer and pipeline, and ink wastes less, hardly dirty
Dye environment.In addition, the process is simple of pigment ink-jetting printing ink, without post processing and washing process, water-saving, power saving, low energy consumption.
But the advantage that therefore pigment ink-jetting printing ink is used for textile ink-jet stamp is it will be apparent that at present the technology is present still
An open question：Fail to find suitable textile binding agent, so as to cause ink-jet printed product washing fastness low.
At present, the adhesive for being applied to textile coating stamp is typically polyacrylate or polyaminoester emulsion, and they
Modified resin, wherein polyacrylate adhesive with it is relatively broad.Polyacrylate dispersion fabric face into
The film transparency is good, stronger to the adhesive capacity of fiber, and with preferable resistance to water, weatherability and mechanical property, but there is hand
The shortcomings of sense is easier to hard, hot sticky cold crisp.Aqueous polyurethane emulsion it is good into film dynamic performance, with higher elasticity and good
Permeability, and heat-resisting, cold-resistant, resistance to bent mill, feel particularly soft, fastness to wet rubbing and smoothness it is good, epithelium is not tacky, does not adsorb
Dust.As long as traditional coating printing adhesive size not network blocking, and come if use as ink-jet printed adhesive, tradition
Not enough, particle diameter is too big for coating printing adhesive emulsion stability, easily the expensive piezo jets of blocking, thus cannot be used for ink-jet
Stamp.The ink-jet printed requirement to adhesive is：(1) emulsion particle diameter can stably and not breakdown of emulsion under nanoscale, high and low temperature；
(2) emulsion film forming is firm and elastic good, and cementitiousness is strong, and washing fastness is high；(3) film forming is soft, not tacky.
Have with regard to the most representational patent of aqueous pigment type ink-jet ink containing polyacrylate dispersion
US7338988, US70301175, but the ink-jet ink in these patents is mainly for the plastic film material such as PP, PVC, PU
Coloring, the vitrification point of polyacrylate dispersion used is above room temperature, hard film formed on ground, it is clear that
May not apply to soft fabric.Domestic room width is completed et al. to carboxylic acid-based copolymer in aqueous pigment ink-jet printing ink
The dual-use function of pigment hyper-dispersant and textile binding agent is played simultaneously, but carboxylic acid-based copolymer comes from hyper-dispersant angle
See, due to lacking single-point or multiple spot pigment anchoring group, and solvent free chain, therefore Jing polyocarboxy acid type copolymerization in macromolecular chain
The pigment stability of thing hyper-dispersant will not be satisfactory；From from the perspective of textile binding agent, carboxylic acid-based copolymer oversubscription
Powder content is less, although esterification occurs with cellulosic fabric, but hardly reacts with the chemical ＆ blended fabric such as terylene, nylon,
Therefore bonding effect is not ideal enough.Patent CN101100815 is added to crosslinking agent in pigment ink-jetting printing ink, to improve
Dry, fastness to wet rubbing, but effect is still not ideal enough, fastness to wet rubbing only has 2-3 levels, dry fastness 3-4 levels, and actually face
If crosslinking agent presence in material type ink-jet printing ink, then all may at any time in the transport of ink or storing process
Reaction is crosslinked, causes the storage stability of ink bad, and print fluency and serious problems also occur.Patent
CN1583898 employs self-crosslinking acrylic ester resin as plant adhesive, the results show：Fabric face after stamp
Crosslinked polyacrylate film is relatively hard and crisp, easily comes off from fabric after dry state or hygrometric state friction, and washing fastness is reduced to 2
Level.E.I.Du Pont Company in recent years disclosed patent WO2005/071026, WO2009/076386, WO2009/137747 having
, used as the adhesive of ink-jet printing ink, but the washing fastness of fabric still will not be high for the polyaminoester emulsion of cross-linked structure,
WO2009/137753 adds in the ink the polyaminoester emulsion adhesive with cross-linked structure and crosslinking agent simultaneously, and in ink
The crosslinking agent of presence easily causes the crosslinking of ink polyurethane in transport or storing process, cause ink storage stability,
Print fluency bad.
The content of the invention
The present invention is directed to the less-than-ideal problem of current aqueous pigment ink-jet printing ink washing fastness on fabric, there is provided
A kind of good aqueous pigment ink-jet printing ink of washing fastness and its preparation and application, in the ink-jet printing ink simultaneously
Containing two kinds of polyacrylate dispersions and a kind of polyaminoester emulsion as nanocomposite adhesive, the organic fluorine richness of one of which
Polyacrylate dispersion particle diameter is higher in nanoscale, emulsion particle internal crosslinking degree, in fabric face film forming due to crosslinking not
Generation breakdown of emulsion film forming, still with the fractions distribution of hydrophobic nanometre particle by another kind of polyacrylate dispersion and polyaminoester emulsion
In the laminated film of formation.It is good that the nano effect that this well-designed nanostructured is showed has can film
Hydrophobicity performance.The granules of pigments being scattered in film is difficult to be come off from fabric, and adhesive force is preferable, the washing of ink-jet printed fabric
Fastness obtains larger raising, and soft.Aqueous pigment ink-jet printing ink system containing above-mentioned nanocomposite adhesive
Standby process is simple, with good storage stability and printing fluency, and compared with dye-type ink-jet printing ink, can
Omit pre-treatment and the aftertreatment technology of fabric.
In order to solve above-mentioned technical problem, following technical scheme is present invention employs：
A kind of aqueous pigment digital ink-jet printing in textiles ink, it is characterised in that comprising dispersible pigment color paste, nano combined viscous
Mixture and deionized water, described nanocomposite adhesive includes polyaminoester emulsion, Organic fluoride modified polyacrylate nano-emulsion
Liquid and another kind of polyacrylate dispersion.
Preferably, described Organic fluoride modified polyacrylate nanoemulsions do not occur after textile ink-jet stamp breakdown of emulsion into
Film, is formed with the fractions distribution of hydrophobicity nano-particle in described polyaminoester emulsion and another kind of polyacrylate dispersion
In laminated film.
Preferably, the synthetic method of described Organic fluoride modified polyacrylate nanoemulsions includes：By 10-15 weight portions
Methyl methacrylate (MMA), 2-4 weight parts of methacrylic acid hexafluoro butyl ester (HFBM), 0.1-1 parts by weight Emulsifier, 0.1-1
Weight portion ethylene glycol dimethacrylate is added in 15-25 weight portion water, and stirring, pre-emulsification 25-35min obtains monomer
Pre-emulsion；Then, the pre-emulsion of 25-35 weight parts monomers is added in reaction vessel, is warming up to 75-85 DEG C, added
2-5 weight portions concentration is the initiator potassium persulfate aqueous solution of 0.7%-0.9%, reacts 25-35min, then 4-8 weight portions is dense
Spend is the initiator potassium persulfate aqueous solution of 0.7%-0.9% and the pre-emulsion of remaining monomer while being added dropwise to reaction vessel
In, react 1-3h, that is, required Organic fluoride modified polyacrylate nanoemulsions are obtained, particle diameter is 40-70nm.
It is highly preferred that described emulsifying agent by disappear worried 465 and lauryl sodium sulfate SDS with mass ratio 1: 0.5-1.5
Mix.
It is highly preferred that described emulsifying agent by disappear worried 465 and lauryl sodium sulfate SDS with the mixing of mass ratio 1: 1
Into.
Preferably, described nanocomposite adhesive is by polyaminoester emulsion 10%-50% and Organic fluoride modified polyacrylic acid
Ester nanoemulsions 10%-50% and another kind polyacrylate dispersion 10%-50% are composited；Described polyaminoester emulsion
For MK-119, PU328-9K, PU628-9K, BY-6336 or BY-6337；Another kind of polyacrylate dispersion is BD-4838, BD-
4895th, QY-001, QY-003 or QY-004.
Preferably, described aqueous pigment digital ink-jet printing in textiles ink also includes surfactant, NMF, pH
At least one of conditioning agent and antiseptic.
Preferably, described aqueous pigment digital ink-jet printing in textiles ink is by dispersible pigment color paste 5.0-25.0%, surface
Activating agent 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, NMF 5.0-35.0%, pH adjusting agent 0.5-2.0%,
The deionized water composition of antiseptic 0.1-0.5% and surplus.
Preferably, described surfactant is：BYK-125, BYK-140, benzalkonium chloride, lauryl sodium sulfate, ten
Dialkyl benzene sulfonic acids sodium, α-sodium olefin sulfonate, Disodium sulfosuccinate, alkyl polyoxyethylene ether ammonium sulfate, dibutyl naphthalenesulfonic acid
In sodium, OPEO, triton x-100, laurate alkanolamide, this Pan 20, this Pan 60, this Pan 80 and Tween 80
One kind.
Preferably, described NMF is 2-Pyrrolidone, METHYLPYRROLIDONE, octyl-pyrrolidone, second two
Alcohol, diethylene glycol, triethylene glycol, TEG, glycerine, 1,2-PD, 1,3-PD, methyl propanediol, ethyl hydroxyl
Base propane diols, a contracting propane diols, two contracting propane diols, 1,2- butanediols, BDO, BT, 1,5-PD,
Tert-pentyl alcohol, pentaerythrite, 2- methyl -2,4- pentanediols are cyclohexanol, 1,2- hexylene glycols, 2 methyl cyclohexanol, heptandiol, just pungent
One or more in alcohol, polyethylene glycol (PEG) 200, PEG-400 and PEG-800.
Preferably, described pH adjusting agent is in ammoniacal liquor, monoethanolamine, ethylene glycol amine, triethanolamine and methylethanolamine
One kind.
Preferably, described antiseptic is SilvDurTMET antiseptics, HR-25 fabric antimicrobial finishing agents, GOOD NICE and
One kind in AEM5772-5 antimildew and antibacterial agents.
Preferably, viscosity of the described aqueous pigment digital ink-jet printing in textiles ink at 25 DEG C of temperature is 2.0-
10.0cP, surface tension is 20-60mN/m, and pH value is 7-9.
Present invention also offers the preparation method of above-mentioned aqueous pigment digital ink-jet printing in textiles ink, its feature exists
In, including：
The first step：First in proportion by surfactant 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, moisturizing
Agent 5.0-35.0%, pH adjusting agent 0.5-2.0% and antiseptic 0.1-0.5% are added in the deionized water of surplus, are subsequently used
Homogenizer stirs 40-100min with the rotating speed of 2000-4500rad/min so as to become uniform dicyandiamide solution；
Second step：Dispersible pigment color paste 5.0-25.0% is added in above-mentioned dicyandiamide solution, with homogenizer with 1000-
The rotating speed stirring 20-60min of 3000rad/min so as to become uniform ink dispersion；
3rd step：By the filtering with microporous membrane that obtained ink dispersion aperture is 0.2-1.0 μm, obtain final product aqueous
Pigment digital ink-jet printing in textiles ink.
Present invention also offers being sprayed in various fabrics using above-mentioned aqueous pigment digital ink-jet printing in textiles ink
Ink-printed method, it is characterised in that include：By the weaving of blue, red, yellow, black (C, M, Y, K) four primaries aqueous pigment digital ink-jet
Product printing ink is respectively charged in large-scale ink-jet decorating machine print cartridge, by the control of ink-jet printed software, by required color
Print on fabric with pattern；Then the fabric after will be ink-jet printed, with 120-160 DEG C of temperature, bakees solid in hot baked machine
Color 4-6min.
Compared with prior art, the invention has the beneficial effects as follows：
1st, washing fastness is very good.Contain a kind of polyacrylate of homemade organic fluorine richness in the ink-jet printing ink
Emulsion particle diameter is higher in nanoscale, emulsion particle internal crosslinking degree, in fabric face film forming due to crosslinking do not occur breakdown of emulsion into
Film, it is still compound what is formed by another kind of polyacrylate dispersion and polyaminoester emulsion with the fractions distribution of hydrophobic nanometre particle
In film.The nano effect that this well-designed nanostructured is showed can be that film has good hydrophobicity performance.
The granules of pigments being scattered in film is difficult to be come off from fabric, and preferably, the washing fastness of ink-jet printed fabric is obtained adhesive force
Greatly improve, and do not affect fabric feeling, be industry of the aqueous pigment ink-jet printing ink in the digital ink-jet printed field of fabric
Change application and provide new solution.
2nd, ink-jet printed process is simple, without the need for pre-processing to fabric before stamp, without carrying out to fabric after stamp
Decatize, washing etc. are post-processed；
3rd, there is versatility to different types of fabric.Different types of ink will not be needed because fabric types are different；
4th, environmental pollution is little.Due to drop on demand ink jet stamp, not there are problems that the waste of pigment.Fabric after stamp is not required to
Washing removes loose colour, reduces quantity of wastewater effluent；
5th, energy consumption is low；
6th, print performance is good.Print that fluency is good, storage stability is good, the group's high precision, the lovely luster that print, especially
It is with good washing fastness.
Specific embodiment
With reference to specific embodiment, the present invention is expanded on further.It should be understood that these embodiments are merely to illustrate the present invention
Rather than restriction the scope of the present invention.In addition, it is to be understood that after the content for having read instruction of the present invention, people in the art
Member can make various changes or modifications to the present invention, and these equivalent form of values equally fall within the application appended claims and limited
Scope.
Each percentage in the present invention, if no special instructions, is mass percent.
It is public that CMYK four primaries dispersible pigment color pastes described in various embodiments of the present invention are purchased from Cabot (China) limited investment
Department, wherein the average grain diameter of pigment particles is between 80-150nm.
The polyaminoester emulsion MK-119 of the present invention is purchased from Guangzhou to believe Chemical Co., Ltd., PU328-9K, PU628-9K
Zhong Fang auxiliary reagent factories of Tai Xin cities are purchased from, BY-6336 or BY-6337 is purchased from Dongguan City Yi Bao resins Co., Ltd；Polyacrylic acid
Ester emulsion BD-4838, BD-4895 is purchased from Shanghai Baidao Chemical Co., Ltd., QY-001, QY-003 and QY-004 and is purchased from east
Tabernaemontanus bulrush whole world resin Industrial Co., Ltd..
The SilvDur of the present inventionTMET antiseptics are purchased from Shanghai Runhe Nanometer Material Technology Co., Ltd, HR-25 fabrics
Antibacterial finishing agent is purchased from Shanghai Juan Rui Chemical Co., Ltd.s, and GOOD NICE and AEM5772-5 antimildew and antibacterial agents are purchased from good we
Think anti-biotic material Co., Ltd.
Surfactant B YK-125, BYK-140 of the present invention is purchased from Bi Ke auxiliary agents (Shanghai) Co., Ltd..
Embodiment 1
A kind of blue water-based pigment digital ink-jet printing in textiles ink, its formula is as shown in table 1.
The blue water-based pigment digital ink-jet printing in textiles ink set of table 1：
Wherein, the synthetic method of described Organic fluoride modified polyacrylate nanoemulsions is：By 12.3g methacrylic acids
Methyl esters (MMA), 2.7g Hexafluorobutyl mathacrylates (HFBM), 0.6g emulsifying agents are (by the worried 465, lauryl sodium sulfate that disappears
SDS is mixed with mass ratio 1: 1), 0.5g ethylene glycol dimethacrylates be added in 20g water, it is high with 2500rpm rotating speeds
Speed stirring, pre-emulsification 30min obtains the pre-emulsion of monomer.Then, the pre-emulsion of 30g monomers is added in three-necked bottle, is heated up
To 80 DEG C, the 4g initiator potassium persulfate aqueous solution (concentration 0.82%) is added, react 30min.Again 6g is drawn with dropping funel
Simultaneously, slowly (10 drops/min) are added dropwise to send out the pre-emulsion of agent persulfate aqueous solution (concentration 0.82%) and remaining monomer
In three-necked bottle, 2h is reacted, that is, obtain required Organic fluoride modified polyacrylate nanoemulsions, particle diameter (Malvern laser particle
Instrument Nano-S90 is tested) it is 40-70nm.Described Organic fluoride modified polyacrylate nanoemulsions after textile ink-jet stamp not
Generation breakdown of emulsion film forming, with the fractions distribution of hydrophobicity nano-particle in described polyaminoester emulsion and another kind of polyacrylate
In the laminated film that emulsion is formed.
The preparation method of described blue water-based pigment digital ink-jet printing in textiles ink is：By listed in table 1
Each component fill a prescription, first by surfactant, nanocomposite adhesive, NMF, pH adjusting agent and antiseptic be added to from
In sub- water, subsequently 80min is stirred with the rotating speed of 2000-4500rad/min with homogenizer so as to become uniform solvent body
System；In again blue pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) being added to into above-mentioned dicyandiamide solution, with a high speed
Mixer stirs 30min with the rotating speed of 2000rad/min so as to become uniform ink dispersion；Finally will be obtained
Ink dispersion aperture is 0.5 μm of filtering with microporous membrane, obtains final product blue water-based pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the Blue inkjet printing ink at 25 DEG C：Surface tension 32.98mN/m is (by BZY-2 full application of brake tables
Face tensiometer is measured), viscosity 3.08cP (takes out cylinder flow graph to measure) together by R/S-CC, and pH value 8.2 (is surveyed by Ph-20 pen types pH
Examination instrument is measured).Jing high temperature (70 DEG C) and low temperature (0 DEG C) weatherability are measured：The Blue inkjet printing ink storage stability is good.
Ink-jet printed test on dacron draws：Blue ink printing fluency is good, and group is bright in colour pure,
Line edge is sharp keen, and washing fastness is high.The feel of dacron is without significant change before and after ink-jet printed.
Washing fastness method of testing：A methods of inspection test in GB GBT 3921-2008.
(1) sample：Size prints for the blue water-based pigment digital ink-jet textile of employing the present embodiment of 100mm × 40mm
Flower ink adopts the dacron of the ink-jet printed technique stamp of conventional digital, adjacent fabric (meet the cotton of GB GB/T6151, gather
Ester fabric) it is equivalently-sized, sample is sandwiched between two adjacent fabrics, it is composite sample along minor face suture.
(2) instrument：Color fastness to washing testing machine, model SW-12All Wenzhou Darong Textile Instrument Co., Ltd.).
(3) soap lye：Soap, in terms of dry weight, contained humidity is less than 5%, and free alkali is (with Na2CO3Meter)≤0.3%, dissociate
Alkali (in terms of NaOH)≤0.1%, total fat composition >=850g/Kg prepares soap fatty acid mixed congealing point≤30 DEG C, iodine number≤50,
Without fluorescent whitening agent.Soap lye is prepared according to the concentration containing 5g soap in 1L water (tertiary effluent meets GB/T6682).
(4) test：In (550 ± 50) mL stainless steel cups that composite sample is put in color fastness to washing testing machine, in cup
It is put into and the soap lye that Composite sample mass ratio is 50: 1.Stainless steel cup is sealed, then along radius be 45mm, rotating speed be 40r/min
Rotated, 40 DEG C of stirring 30min of temperature.Sample is taken out in off-test, is cleaned twice with cold tertiary effluent, then in flowing cool water
Middle flushing 10min, squeezes and removes moisture.Launch composite sample, sample and stickers lining is only connected by a suture, be suspended on not higher than 60
DEG C environment in be dried.The discoloration of sample is evaluated with discoloration gray scale (GB 250), with staining gray scale (GB
251) staining of adjacent fabric is evaluated.
Washing fastness changes colour and 5 grades of staining grade totally, and 5 grades are optimum, evaluates the change colour gradation of sample into 4-5 levels, staining
For 4-5 levels.
Embodiment 2
A kind of red aqueous pigment digital ink-jet printing in textiles ink, its formula is as shown in table 2.
The red aqueous pigment digital ink-jet printing in textiles ink set of table 2：
The synthetic method of described Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.
The preparation method of described red aqueous pigment digital ink-jet printing in textiles ink is：By listed in table 2
Each component fill a prescription, first by surfactant, nanocomposite adhesive, NMF, pH adjusting agent and antiseptic be added to from
In sub- water, subsequently 80min is stirred with the rotating speed of 2000-4500rad/min with homogenizer so as to become uniform solvent body
System；In again red pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) being added to into above-mentioned dicyandiamide solution, with a high speed
Mixer stirs 30min with the rotating speed of 2000rad/min so as to become uniform ink dispersion；Finally will be obtained
Ink dispersion aperture is 0.5 μm of filtering with microporous membrane, obtains final product red aqueous pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the red ink-jet printing ink at 25 DEG C：Surface tension 33.89mN/m is (by BZY-2 full application of brake tables
Face tensiometer is measured), viscosity 3.12cP (takes out cylinder flow graph to measure) together by R/S-CC, and pH value 8.3 (is surveyed by Ph-20 pen types pH
Examination instrument is measured).Jing high temperature (70 DEG C) and low temperature (0 DEG C) weatherability are measured：The red ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron draws：Red ink printing fluency is good, and group is bright in colour pure,
Line edge is sharp keen.The feel of dacron is without significant change before and after ink-jet printed.Surveyed using the washing fastness described in embodiment 1
Method for testing, evaluates the change colour gradation of sample into 4-5 levels, and staining is 4-5 levels.
Embodiment 3
A kind of yellow aqueous pigment digital ink-jet printing in textiles ink, its formula is as shown in table 3.
The yellow aqueous pigment digital ink-jet printing in textiles ink set of table 3：
The synthetic method of described Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.Described is organic
There is no breakdown of emulsion film forming in fluorine richness polyacrylate nanoemulsions, after textile ink-jet stamp with the form of hydrophobicity nano-particle
In the laminated film that polyaminoester emulsion and another kind of polyacrylate dispersion described in being distributed in is formed.
The preparation method of described yellow aqueous pigment digital ink-jet printing in textiles ink is：By listed in table 2
Each component fill a prescription, first by surfactant, nanocomposite adhesive, NMF, pH adjusting agent and antiseptic be added to from
In sub- water, subsequently 80min is stirred with the rotating speed of 2000-4500rad/min with homogenizer so as to become uniform solvent body
System；In again yellow uitramarine mill base (being purchased from Cabot (China) Investment Co., Ltd) being added to into above-mentioned dicyandiamide solution, with a high speed
Mixer stirs 30min with the rotating speed of 2000rad/min so as to become uniform ink dispersion；Finally will be obtained
Ink dispersion aperture is 0.5 μm of filtering with microporous membrane, obtains final product yellow aqueous pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the yellow ink-jet printing ink at 25 DEG C：Surface tension 34.01mN/m is (by BZY-2 full application of brake tables
Face tensiometer is measured), viscosity 3.11cP (takes out cylinder flow graph to measure) together by R/S-CC, and pH value 8.1 (is surveyed by Ph-20 pen types pH
Examination instrument is measured).Jing high temperature (70 DEG C) and low temperature (0 DEG C) weatherability are measured：The yellow ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron draws：Yellow ink printing fluency is good, and group is bright in colour pure,
Line edge is sharp keen.The feel of dacron is without significant change before and after ink-jet printed.Surveyed using the washing fastness described in embodiment 1
Method for testing, evaluates the change colour gradation of sample into 4-5 levels, and staining is 4-5 levels.
Embodiment 4
A kind of black water pigment digital ink-jet printing in textiles ink, its formula is as shown in table 4.
The black water pigment digital ink-jet printing in textiles ink set of table 4：
The synthetic method of described Organic fluoride modified polyacrylate nanoemulsions is same as Example 1.Described is organic
There is no breakdown of emulsion film forming in fluorine richness polyacrylate nanoemulsions, after textile ink-jet stamp with the form of hydrophobicity nano-particle
In the laminated film that polyaminoester emulsion and another kind of polyacrylate dispersion described in being distributed in is formed.
The preparation method of described black water pigment digital ink-jet printing in textiles ink is：By listed in table 2
Each component fill a prescription, first by surfactant, nanocomposite adhesive, NMF, pH adjusting agent and antiseptic be added to from
In sub- water, subsequently 80min is stirred with the rotating speed of 2000-4500rad/min with homogenizer so as to become uniform solvent body
System；In again black pigment mill base (being purchased from Cabot (China) Investment Co., Ltd) being added to into above-mentioned dicyandiamide solution, with a high speed
Mixer stirs 30min with the rotating speed of 2000rad/min so as to become uniform ink dispersion；Finally will be obtained
Ink dispersion aperture is 0.5 μm of filtering with microporous membrane, obtains final product black water pigment digital ink-jet printing in textiles ink
Water.
The physical and chemical indexes of the black ink-jet printing ink at 25 DEG C：Surface tension 31.67mN/m is (by BZY-2 full application of brake tables
Face tensiometer is measured), viscosity 3.05cP (takes out cylinder flow graph to measure) together by R/S-CC, and pH value 8.3 (is surveyed by Ph-20 pen types pH
Examination instrument is measured).Jing high temperature (70 DEG C) and low temperature (0 DEG C) weatherability are measured：The black ink-jet printing ink storage stability is good.
Ink-jet printed test on dacron draws：Black ink printing fluency is good, and group is bright in colour pure,
Line edge is sharp keen.The feel of dacron is without significant change before and after ink-jet printed.Surveyed using the washing fastness described in embodiment 1
Method for testing, evaluates the change colour gradation of sample into 4-5 levels, and staining is 4-5 levels.
Application examples
By obtained blue, red, yellow, black (C, M, Y, K) four primaries aqueous pigment digital ink-jet textile print in embodiment 1-4
Flower ink is respectively charged in large-scale ink-jet decorating machine print cartridge, by the control of ink-jet printed software, by required color and figure
Case is printed on dacron；Then the fabric after will be ink-jet printed, with 140 DEG C of temperature, bakees fixation in hot baked machine
5min.
Claims (10)
1. a kind of aqueous pigment digital ink-jet printing in textiles ink, it is characterised in that comprising dispersible pigment color paste, nano combined bonding
Agent and deionized water, described nanocomposite adhesive includes polyaminoester emulsion, Organic fluoride modified polyacrylate nanoemulsions
And another kind of polyacrylate dispersion.
2. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that described Organic fluoride
There is no breakdown of emulsion film forming in modified polyacrylate nanoemulsions, after textile ink-jet stamp with the form of hydrophobicity nano-particle point
In the laminated film that polyaminoester emulsion and another kind of polyacrylate dispersion described in being distributed in is formed.
3. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that described Organic fluoride
The synthetic method of modified polyacrylate nanoemulsions includes：By 10-15 parts by weight of methylmethacrylate, 2-4 weight portion first
Base hexafluorobutyl acrylate, 0-1 parts by weight Emulsifier, 0-1 weight portion ethylene glycol dimethacrylates are added to 15-25 weight
In part water, stirring, pre-emulsification 25-35min obtains the pre-emulsion of monomer；Then, the pre-emulsion of 25-35 weight parts monomers is added
Enter in reaction vessel, be warming up to 75-85 DEG C, add the initiator potassium persulfate that 2-5 weight portions concentration is 0.7%-0.9%
The aqueous solution, reacts 25-35min, then by 4-8 weight portions concentration is for the initiator potassium persulfate aqueous solution of 0.7%-0.9% and remains
The pre-emulsion of remaining monomer is added dropwise in reaction vessel simultaneously, reacts 1-3h, that is, obtain required Organic fluoride modified polypropene
Acid esters nanoemulsions, particle diameter is 40-70nm.
4. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 3, it is characterised in that described emulsifying agent
By disappear worried 465 and lauryl sodium sulfate SDS mixed with mass ratio 1: 1.
5. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that described nanometer is answered
Adhesive is closed by polyaminoester emulsion 10%-50% and Organic fluoride modified polyacrylate nanoemulsions 10%-50% and another
Plant polyacrylate dispersion 10%-50% to be composited；Described polyaminoester emulsion be MK-119, PU328-9K, PU628-9K,
BY-6336 or BY-6337；Another kind of polyacrylate dispersion is BD-4838, BD-4895, QY-001, QY-003 or QY-004.
6. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that described aqueous number
Code ink-jet printing sublimation ink is by dispersible pigment color paste 5.0-25.0%, surfactant 0.2-2.0%, nanocomposite adhesive
The deionized water of 5.0-15.0%, NMF 5.0-35.0%, pH adjusting agent 0.5-2.0%, antiseptic 0.1-0.5% and surplus
Composition.
7. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that live on described surface
Property agent is：BYK-125, BYK-140, benzalkonium chloride, lauryl sodium sulfate, neopelex, α-sodium olefin sulfonate,
Disodium sulfosuccinate, alkyl polyoxyethylene ether ammonium sulfate, nekal, OPEO, Qula lead to X-
100th, one kind in laurate alkanolamide, this Pan 20, this Pan 60, this Pan 80 and Tween 80；Described NMF is 2- pyrroles
Alkanone, METHYLPYRROLIDONE, octyl-pyrrolidone, ethylene glycol, diethylene glycol, triethylene glycol, TEG, the third three
Alcohol, 1,2-PD, 1,3-PD, methyl propanediol, ethyl hydroxy propane diols, a contracting propane diols, two contracting propane diols, 1,2-
Butanediol, BDO, BT, 1,5-PD, tert-pentyl alcohol, pentaerythrite, 2- methyl -2,4- pentanediols,
In cyclohexanol, 1,2- hexylene glycols, 2 methyl cyclohexanol, heptandiol, n-octyl alcohol, polyethylene glycol 200, PEG-400 and PEG-800
One or more；Described pH adjusting agent is in ammoniacal liquor, monoethanolamine, ethylene glycol amine, triethanolamine and methylethanolamine
Kind；Described antiseptic is SilvDurTMET antiseptics, HR-25 fabric antimicrobial finishing agents, GOOD NICE and AEM5772-5 prevent
One kind in mould antiseptic.
8. aqueous pigment digital ink-jet printing in textiles ink as claimed in claim 1, it is characterised in that described aqueous number
Viscosity of the code ink-jet printing sublimation ink at 25 DEG C of temperature is 2.0-10.0cP, and surface tension is 20-60mN/m, and pH value is
7-9。
9. the preparation method of the aqueous pigment digital ink-jet printing in textiles ink any one of claim 1-8, it is special
Levy and be, including：
The first step：First in proportion by surfactant 0.2-2.0%, nanocomposite adhesive 5.0-15.0%, NMF
5.0-35.0%, pH adjusting agent 0.5-2.0% and antiseptic 0.1-0.5% are added in the deionized water of surplus, subsequently with height
Fast mixer stirs 40-100min with the rotating speed of 2000-4500rad/min so as to become uniform dicyandiamide solution；
Second step：Dispersible pigment color paste 5.0-25.0% is added in above-mentioned dicyandiamide solution, with homogenizer with 1000-
The rotating speed stirring 20-60min of 3000rad/min so as to become uniform ink dispersion；
3rd step：By the filtering with microporous membrane that obtained ink dispersion aperture is 0.2-1.0 μm, aqueous pigment is obtained final product
Digital ink-jet printing in textiles ink.
10. the aqueous pigment digital ink-jet printing in textiles ink any one of claim 1-8 sprays in various fabrics
Ink-printed method, it is characterised in that include：By blue, red, yellow, black four primaries aqueous pigment digital ink-jet printing in textiles ink
Water is respectively charged in large-scale ink-jet decorating machine print cartridge, by the control of ink-jet printed software, required color and pattern is beaten
Print on fabric；Then the fabric after will be ink-jet printed, with 120-160 DEG C of temperature, bakees fixation 4-6min in hot baked machine
.
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