CN106189264A - A kind of cable resistance oil silicone rubber material - Google Patents
A kind of cable resistance oil silicone rubber material Download PDFInfo
- Publication number
- CN106189264A CN106189264A CN201610717214.XA CN201610717214A CN106189264A CN 106189264 A CN106189264 A CN 106189264A CN 201610717214 A CN201610717214 A CN 201610717214A CN 106189264 A CN106189264 A CN 106189264A
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- China
- Prior art keywords
- parts
- silicone rubber
- cable resistance
- resistance oil
- rubber material
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The invention discloses a kind of cable resistance oil silicone rubber material, the raw material of following weight portion prepare: nitrile silicone rubber 80 90 parts, polyethylene 45 55 parts, polyurethane 12 20 parts, bamboo fibre 10 14 parts, aluminium hydroxide 38 parts, polymethylene carbonic ester 58 parts, ethylene glycol 28 parts, sodium hexameta phosphate 14 parts, ethylene propylene diene rubber 12 20 parts, dimethylformamide 6 10 parts, 14 20 parts of sn-bi alloy powder, nitrile rubber 58 parts, pine tar 5 10 parts, γ glycidyl ether oxygen propyl trimethoxy silicane 7 11 parts, tricalcium phosphate 28 parts.The cable resistance oil silicone rubber strength of materials prepared by the present invention is high, has excellent mechanical property, and all shows splendid in terms of resistance to mineral oil and fuel oil resistance, has broad application prospects.
Description
Technical field
The invention belongs to polymeric material field, be specifically related to a kind of cable resistance oil silicone rubber material.
Background technology
Cable is made up of conductor and the outsourcing insulating protective layer of one or more mutually insulated, by electric power or information at one
It is transferred to the wire at another.Along with the gradually development of cable industry, cable is used for the various aspects of people's life.Electric wire electricity
Cable industry is that the second largest industry that China is only second to automobile industry, product variety Service Efficiency and domestic market occupation rate all exceed
90%.Worldwide, China's electric wire gross output value has exceeded the U.S., becomes the first big electric wire in the world and produces
State.Along with China's wires and cables industry high speed development, creation of new enterprise quantity constantly rises, and industry overall technology level obtains greatly
Width improves.China's economic growth continuously and healthily, provides the huge market space for cable products, strong the luring of Chinese market
Puzzled power so that the world all focuses on Chinese market sight, in the decades that reform and opening-up is short, cable manufacturing industry institute of China shape
The huge production capacity become allows the world regard with special esteem.Along with China electric power industry, data communication industry, urban track traffic industry, vapour
The continuous expansion of the industry sizes such as car industry and shipbuilding, also will increase rapidly the demand of electric wire, following electric wire industry
Also has huge development potentiality.In November, 2008, China is reply world financial crisis, and government decided puts into 4 trillion yuan and pulls
Domestic demand, wherein has about more than 40% for urban and rural power grids construction and upgrading.Whole nation wires and cables industry has had again good city
Field opportunity, various places electric wire enterprise seizes the opportunity, and meets new round urban and rural power grids construction and upgrading.Silicone rubber is former by silicon, oxygen
Son formed main chain, side chain is carbon-containing group, consumption maximum be side chain be the silicone rubber of ethylene.Silicone rubber is mainly used in aviation work
The aspects such as industry, electrical industry, food industry and health care industry.In numerous synthetic rubber, silicone rubber is wherein outstanding
Person.It has tasteless nontoxic, is not afraid of high temperature and resists the feature of severe cold, silicone rubber can-60 DEG C (or lower temperatures) to+
Life-time service at 250 DEG C (or higher temperature).Silicone rubber also has good electrical insulating property, oxytolerant ageing resistance, fast light anti-ageing
The property changed and mildew resistance, chemical stability etc..Therefore be widely used in make cable outsourcing insulating protective layer, but silicone rubber
Oil resistant, solvent resistance be not good enough, have impact on its range.The most how overcoming the deficiencies in the prior art is current this area skill
The problem that art personnel need solution badly.
Summary of the invention
It is an object of the invention to provide a kind of cable resistance oil silicone rubber material.
To achieve these goals, the invention provides a kind of cable resistance oil silicone rubber material, by following weight portion
Raw material prepares: nitrile silicone rubber 80-90 part, polyethylene 45-55 part, polyurethane 12-20 part, bamboo fibre 10-14 part, aluminium hydroxide 3-
8 parts, polymethylene carbonic ester 5-8 part, ethylene glycol 2-8 part, sodium hexameta phosphate 1-4 part, ethylene propylene diene rubber 12-20 part, diformazan
Base Methanamide 6-10 part, sn-bi alloy powder 14-20 part, nitrile rubber 5-8 part, pine tar 5-10 part, γ-glycidyl ether oxygen third
Base trimethoxy silane 7-11 part, tricalcium phosphate 2-8 part.
Also include butanol 3-6 part.
Also include anhydrous Lithium chloride 10-20 part.
Also include sodium carboxymethyl cellulose 5-10 part.
Its preparation method is: first each component is joined in vacuum kneader or banbury after mix homogeneously, then passes through
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by mill.
The method have the advantages that the cable resistance oil silicone rubber strength of materials prepared by the present invention is high, have excellent
Good mechanical property, and all show splendid in terms of resistance to mineral oil and fuel oil resistance, have broad application prospects.
Detailed description of the invention
The following stated is only the preferred embodiments of the present invention, is not limited to the present invention, although with reference to aforementioned reality
Executing example to be described in detail the present invention, for a person skilled in the art, it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or wherein portion of techniques feature is carried out equivalent.All essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Embodiment 1
A kind of cable resistance oil silicone rubber material of the present embodiment, is prepared by the raw material of following weight portion: nitrile silicone rubber 90
Part, polyethylene 55 parts, polyurethane 20 parts, bamboo fibre 14 parts, aluminium hydroxide 8 parts, polymethylene carbonic ester 8 parts, ethylene glycol 8 parts,
Sodium hexameta phosphate 4 parts, ethylene propylene diene rubber 20 parts, dimethylformamide 10 parts, 20 parts of sn-bi alloy powder, nitrile rubber 8 parts, pine
10 parts of tar, γ-glycidyl ether oxygen propyl trimethoxy silicane 11 parts, tricalcium phosphate 8 parts, 6 parts of butanol.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 2
A kind of cable resistance oil silicone rubber material of the present embodiment, is prepared by the raw material of following weight portion: nitrile silicone rubber 80
Part, polyethylene 45 parts, polyurethane 12 parts, bamboo fibre 10 parts, aluminium hydroxide 3 parts, polymethylene carbonic ester 5 parts, ethylene glycol 2 parts,
Sodium hexameta phosphate 1 part, ethylene propylene diene rubber 12 parts, dimethylformamide 6 parts, 14 parts of sn-bi alloy powder, nitrile rubber 5 parts, pine
5 parts of tar, γ-glycidyl ether oxygen propyl trimethoxy silicane 7 parts, tricalcium phosphate 2 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 3
A kind of cable resistance oil silicone rubber material of the present embodiment, is prepared by the raw material of following weight portion: nitrile silicone rubber 80
Part, polyethylene 45 parts, polyurethane 12 parts, bamboo fibre 10 parts, aluminium hydroxide 3 parts, polymethylene carbonic ester 5 parts, ethylene glycol 2 parts,
Sodium hexameta phosphate 1 part, ethylene propylene diene rubber 12 parts, dimethylformamide 6 parts, 14 parts of sn-bi alloy powder, nitrile rubber 5 parts, pine
5 parts of tar, γ-glycidyl ether oxygen propyl trimethoxy silicane 7 parts, tricalcium phosphate 2 parts, 3 parts of butanol, anhydrous Lithium chloride 10
Part.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Embodiment 4
A kind of cable resistance oil silicone rubber material of the present embodiment, is prepared by the raw material of following weight portion: nitrile silicone rubber 90
Part, polyethylene 55 parts, polyurethane 20 parts, bamboo fibre 14 parts, aluminium hydroxide 8 parts, polymethylene carbonic ester 8 parts, ethylene glycol 8 parts,
Sodium hexameta phosphate 4 parts, ethylene propylene diene rubber 20 parts, dimethylformamide 10 parts, 20 parts of sn-bi alloy powder, nitrile rubber 8 parts, pine
10 parts of tar, γ-glycidyl ether oxygen propyl trimethoxy silicane 11 parts, tricalcium phosphate 8 parts, 6 parts of butanol, anhydrous Lithium chloride 20
Part, sodium carboxymethyl cellulose 10 parts.
Preparation method is: first join in vacuum kneader or banbury after mix homogeneously by each component, then by opening
Synthetic rubber molding, the mould finally put in vulcanizer by molded rubber are vulcanized by refining machine.
Claims (4)
1. a cable resistance oil silicone rubber material, it is characterised in that prepared by the raw material of following weight portion: nitrile silicone rubber 80-90
Part, polyethylene 45-55 part, polyurethane 12-20 part, bamboo fibre 10-14 part, aluminium hydroxide 3-8 part, polymethylene carbonic ester 5-8
Part, ethylene glycol 2-8 part, sodium hexameta phosphate 1-4 part, ethylene propylene diene rubber 12-20 part, dimethylformamide 6-10 part, stannum bismuth close
Bronze 14-20 part, nitrile rubber 5-8 part, pine tar 5-10 part, γ-glycidyl ether oxygen propyl trimethoxy silicane 7-11 part,
Tricalcium phosphate 2-8 part.
A kind of cable resistance oil silicone rubber material the most according to claim 1, it is characterised in that: also include butanol 3-6 part.
A kind of cable resistance oil silicone rubber material the most according to claim 1, it is characterised in that: also include anhydrous Lithium chloride
10-20 part.
A kind of cable resistance oil silicone rubber material the most according to claim 1, it is characterised in that: also include carboxymethyl cellulose
Element sodium 5-10 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610717214.XA CN106189264A (en) | 2016-08-23 | 2016-08-23 | A kind of cable resistance oil silicone rubber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610717214.XA CN106189264A (en) | 2016-08-23 | 2016-08-23 | A kind of cable resistance oil silicone rubber material |
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| Publication Number | Publication Date |
|---|---|
| CN106189264A true CN106189264A (en) | 2016-12-07 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610717214.XA Withdrawn CN106189264A (en) | 2016-08-23 | 2016-08-23 | A kind of cable resistance oil silicone rubber material |
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| CN (1) | CN106189264A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383892A (en) * | 2017-07-31 | 2017-11-24 | 铜陵市铜都特种线缆有限公司 | A kind of gopher protected cable sheath material |
| CN107674405A (en) * | 2017-09-15 | 2018-02-09 | 安徽伙伴电气有限公司 | A kind of good photovoltaic cable of low-cost flame-retardant heat endurance |
| CN108276685A (en) * | 2017-12-29 | 2018-07-13 | 安徽天星电缆科技有限公司 | A kind of high tensile torsion cable for robot arm material |
| CN111849046A (en) * | 2020-07-31 | 2020-10-30 | 上海蓝昊电气江苏有限公司 | Semiconductive external shielding material for high-temperature-resistant cable |
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| CN102585386A (en) * | 2012-01-10 | 2012-07-18 | 湖北拓普聚合体科技有限公司 | 155 DEG C high-strength, oil-resistant and flame-retardant polyolefin high-speed extruded thin-wall material and preparation method thereof |
| CN103642114A (en) * | 2013-12-26 | 2014-03-19 | 河南省聚友塑料有限公司 | 150-DEG C high-strength high-electric-property oil-resistant irradiation crosslinking halogen-free flame retardant environment-friendly polyolefin cable material and production method thereof |
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| CN102585386A (en) * | 2012-01-10 | 2012-07-18 | 湖北拓普聚合体科技有限公司 | 155 DEG C high-strength, oil-resistant and flame-retardant polyolefin high-speed extruded thin-wall material and preparation method thereof |
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| CN105419017A (en) * | 2015-12-07 | 2016-03-23 | 湖北洋田塑料制品有限公司 | High-temperature-oil-resistant thermoplastic elastomer and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383892A (en) * | 2017-07-31 | 2017-11-24 | 铜陵市铜都特种线缆有限公司 | A kind of gopher protected cable sheath material |
| CN107674405A (en) * | 2017-09-15 | 2018-02-09 | 安徽伙伴电气有限公司 | A kind of good photovoltaic cable of low-cost flame-retardant heat endurance |
| CN108276685A (en) * | 2017-12-29 | 2018-07-13 | 安徽天星电缆科技有限公司 | A kind of high tensile torsion cable for robot arm material |
| CN111849046A (en) * | 2020-07-31 | 2020-10-30 | 上海蓝昊电气江苏有限公司 | Semiconductive external shielding material for high-temperature-resistant cable |
| CN111849046B (en) * | 2020-07-31 | 2022-05-06 | 上海蓝昊电气江苏有限公司 | Semiconductive external shielding material for high-temperature-resistant cable |
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Application publication date: 20161207 |