CN106349714A - Anti-tear silicone rubber material for cable - Google Patents
Anti-tear silicone rubber material for cable Download PDFInfo
- Publication number
- CN106349714A CN106349714A CN201610714695.9A CN201610714695A CN106349714A CN 106349714 A CN106349714 A CN 106349714A CN 201610714695 A CN201610714695 A CN 201610714695A CN 106349714 A CN106349714 A CN 106349714A
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- Prior art keywords
- parts
- cable
- silicone rubber
- rubber material
- tear
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
- C08L83/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses an anti-tear silicone rubber material for a cable. The anti-tear silicone rubber material for the cable is prepared from the following raw materials in parts by weight: 80 to 100 parts of fluorinated silicone rubber, 60 to 75 parts of aliphatic series of aromatic copolyester, 4 to 16 parts of polypropylene, 1 to 4 parts of sodium hexametaphosphate, 2 to 6 parts of maleic anhydride, 8 to 10 parts of dicumyl peroxide, 3 to 6 parts of tricalcium phosphate, 5 to 8 parts of nitrile rubber, 5 to 10 parts of pine tar, 5 to 10 parts of sodium carboxymethylcellulose, 3 to 5 parts of nano-zinc oxide, 10 to 18 parts of methyl tridiacetylmonoxime silane, 12 to 18 parts of alumina fiber, 2 to 8 parts of vinyl triethoxy silane, and 30 to 40 parts of water. The anti-tear silicone rubber material for the cable provided by the invention has excellent temperature resistance and tear resistance, small anti-compression deformation, less production cost, and favorable economic benefit.
Description
Technical field
The invention belongs to polymeric material field is and in particular to a kind of cable anti tear silastic material.
Background technology
Cable is made up of the conductor of one or more mutually insulated and outsourcing insulating protective layer, by electric power or information at one
It is transferred to the wire at another place.With the gradually development of cable industry, cable is used for the various aspects of people's life.Electric wire electricity
Cable industry is the second largest industry that China is only second to automobile industry, and product variety Service Efficiency and domestic market occupation rate all exceed
90%.Worldwide, the Chinese electric wire gross output value exceedes the U.S., becomes the first big electric wire in the world and produces
State.Along with Chinese wires and cables industry high speed development, creation of new enterprise quantity constantly rises, and industry overall technology level obtains greatly
Width improves.China's economic growth continuously and healthily, is that cable products provide the huge market space, strong the luring of Chinese market
Puzzled power so that the world all focuses on Chinese market sight, in the short decades of reforming and opening up to the outside world, Chinese cable manufacturing industry institute shape
The huge production capacity becoming allows the world to regard with special esteem.With China electric power industry, data communication industry, urban track traffic industry, vapour
The continuous expansion of the industry size such as car industry and shipbuilding, also will increase rapidly to the demand of electric wire, following electric wire industry
Also has huge development potentiality.In November, 2008, China is reply world financial crisis, and government decided puts into 4 trillion yuan and pulls
Domestic demand, wherein has about more than 40% for urban and rural power grids construction and upgrading.National wires and cables industry has good city again
Field opportunity, various places electric wire enterprise seizes the opportunity, and meets new round urban and rural power grids construction and upgrading.Silicone rubber is former by silicon, oxygen
Son forms main chain, and side chain is carbon-containing group, and consumption maximum is the silicone rubber that side chain is ethylene.Silicone rubber is mainly used in aviation work
The aspects such as industry, electrical industry, food industry and health care industry.In numerous synthetic rubber, silicone rubber is wherein outstanding
Person.It has tasteless nontoxic, is not afraid of high temperature and resists the feature of severe cold, silicone rubber can -60 DEG C (or lower temperatures) to+
Life-time service at 250 DEG C (or higher temperature).Silicone rubber also has good electrical insulating property, oxytolerant ageing resistance, fast light anti-ageing
The property changed and mildew resistance, chemical stability etc..Therefore it is widely used in making the insulating protective layer of cable outsourcing, but silicone rubber
The mechanical performance such as anti tear poor, its physical and mechanical properties, not as good as most of synthetic rubber, have impact on its use at normal temperatures.
Therefore how to overcome the problem that the deficiencies in the prior art are current those skilled in the art's urgent need to resolves.
Content of the invention
It is an object of the invention to provide a kind of cable anti tear silastic material.
To achieve these goals, the invention provides a kind of cable anti tear silastic material, by following weight portion
Raw material be obtained: fluorosioloxane rubber 80-100 part, aliphatic aromatic copolyesters 60-75 part, polypropylene 4-16 part, sodium hexameta phosphate
1-4 part, maleic anhydride 2-6 part, cumyl peroxide 8-10 part, tricalcium phosphate 3-6 part, nitrile rubber 5-8 part, pine tar 5-
10 parts, sodium carboxymethyl cellulose 5-10 part, nano zine oxide 3-5 part, methyl tributanoximo silane 10-18 part, aluminium oxide fine
Dimension 12-18 part, VTES 2-8 part, water 30-40 part.
Also include glycyrrhizic acid dipotassium 6-10 part.
Also include glycerol 5-15 part.
Also include nano-calcium carbonate 1-5 part.
Its preparation method is: first each component is added to after mix homogeneously in vacuum kneader or banbury, then passes through
Molded rubber, by synthetic rubber molding, is finally put in the mould in vulcanizer and is vulcanized by mill.
The method have the advantages that the cable anti tear silastic material heat resistance, anti-that the present invention provides
Tear resistance is extremely excellent, and resistance to compression compression deformation is little, and production cost is few, has good economic benefit.
Specific embodiment
Described below is only the preferred embodiments of the present invention, is not limited to the present invention, although with reference to aforementioned reality
Apply example the present invention has been described in detail, for a person skilled in the art, it still can be to aforementioned each enforcement
Technical scheme described in example is modified, or carries out equivalent to wherein some technical characteristics.All essences in the present invention
Within god and principle, any modification, equivalent substitution and improvement made etc., should be included within the scope of the present invention.
Embodiment 1
A kind of cable anti tear silastic material of the present embodiment, is obtained by the raw material of following weight portion: fluorosioloxane rubber
80 parts, 60 parts of aliphatic aromatic copolyesters, 4 parts of polypropylene, 1 part of sodium hexameta phosphate, 2 parts of maleic anhydride, peroxidating diisopropyl
8 parts of benzene, 3 parts of tricalcium phosphate, 5 parts of nitrile rubber, 5 parts of pine tar, 5 parts of sodium carboxymethyl cellulose, 3 parts of nano zine oxide, methyl
10 parts of tributanoximo silane, 12 parts of alumina fibre, 2 parts of VTES, 30 parts of water.
Preparation method is: is first added to after mix homogeneously in vacuum kneader or banbury by each component, then passes through to open
Molded rubber, by synthetic rubber molding, is finally put in the mould in vulcanizer and is vulcanized by mill.
Embodiment 2
A kind of cable anti tear silastic material of the present embodiment, is obtained by the raw material of following weight portion: fluorosioloxane rubber
100 parts, 75 parts of aliphatic aromatic copolyesters, 16 parts of polypropylene, 4 parts of sodium hexameta phosphate, 6 parts of maleic anhydride, peroxidating two different
10 parts of propyl benzene, 6 parts of tricalcium phosphate, 8 parts of nitrile rubber, 10 parts of pine tar, 10 parts of sodium carboxymethyl cellulose, 5 parts of nano zine oxide,
18 parts of methyl tributanoximo silane, 18 parts of alumina fibre, 8 parts of VTES, 40 parts of water, glycyrrhizic acid dipotassium
10 parts.
Preparation method is: is first added to after mix homogeneously in vacuum kneader or banbury by each component, then passes through to open
Molded rubber, by synthetic rubber molding, is finally put in the mould in vulcanizer and is vulcanized by mill.
Embodiment 3
A kind of cable anti tear silastic material of the present embodiment, is obtained by the raw material of following weight portion: fluorosioloxane rubber
80 parts, 60 parts of aliphatic aromatic copolyesters, 4 parts of polypropylene, 1 part of sodium hexameta phosphate, 2 parts of maleic anhydride, peroxidating diisopropyl
8 parts of benzene, 3 parts of tricalcium phosphate, 5 parts of nitrile rubber, 5 parts of pine tar, 5 parts of sodium carboxymethyl cellulose, 3 parts of nano zine oxide, methyl
10 parts of tributanoximo silane, 12 parts of alumina fibre, 2 parts of VTES, 30 parts of water, 6 parts of glycyrrhizic acid dipotassium,
5 parts of glycerol.
Preparation method is: is first added to after mix homogeneously in vacuum kneader or banbury by each component, then passes through to open
Molded rubber, by synthetic rubber molding, is finally put in the mould in vulcanizer and is vulcanized by mill.
Embodiment 4
A kind of cable anti tear silastic material of the present embodiment, is obtained by the raw material of following weight portion: fluorosioloxane rubber
100 parts, 75 parts of aliphatic aromatic copolyesters, 16 parts of polypropylene, 4 parts of sodium hexameta phosphate, 6 parts of maleic anhydride, peroxidating two different
10 parts of propyl benzene, 6 parts of tricalcium phosphate, 8 parts of nitrile rubber, 10 parts of pine tar, 10 parts of sodium carboxymethyl cellulose, 5 parts of nano zine oxide,
18 parts of methyl tributanoximo silane, 18 parts of alumina fibre, 8 parts of VTES, 40 parts of water, glycyrrhizic acid dipotassium
10 parts, 15 parts of glycerol, 5 parts of nano-calcium carbonate.
Preparation method is: is first added to after mix homogeneously in vacuum kneader or banbury by each component, then passes through to open
Molded rubber, by synthetic rubber molding, is finally put in the mould in vulcanizer and is vulcanized by mill.
Claims (4)
1. a kind of cable anti tear silastic material is it is characterised in that be obtained by the raw material of following weight portion: fluorosioloxane rubber 80-
100 parts, aliphatic aromatic copolyesters 60-75 part, polypropylene 4-16 part, sodium hexameta phosphate 1-4 part, maleic anhydride 2-6 part, mistake
Oxidation diisopropylbenzene (DIPB) 8-10 part, tricalcium phosphate 3-6 part, nitrile rubber 5-8 part, pine tar 5-10 part, sodium carboxymethyl cellulose 5-
10 parts, nano zine oxide 3-5 part, methyl tributanoximo silane 10-18 part, alumina fibre 12-18 part, vinyl three ethoxy
Base silane 2-8 part, water 30-40 part.
2. a kind of cable anti tear silastic material according to claim 1 it is characterised in that: also include glycyrrhizic acid two
Potassium 6-10 part.
3. a kind of cable anti tear silastic material according to claim 1 it is characterised in that: also include glycerol 5-15
Part.
4. a kind of cable anti tear silastic material according to claim 1 it is characterised in that: also include nano-calcium carbonate
Calcium 1-5 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714695.9A CN106349714A (en) | 2016-08-23 | 2016-08-23 | Anti-tear silicone rubber material for cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610714695.9A CN106349714A (en) | 2016-08-23 | 2016-08-23 | Anti-tear silicone rubber material for cable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106349714A true CN106349714A (en) | 2017-01-25 |
Family
ID=57844027
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610714695.9A Withdrawn CN106349714A (en) | 2016-08-23 | 2016-08-23 | Anti-tear silicone rubber material for cable |
Country Status (1)
| Country | Link |
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| CN (1) | CN106349714A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325562A (en) * | 2017-08-04 | 2017-11-07 | 安徽远征电缆科技有限公司 | A kind of cable flame-proof silicon rubber |
| CN107507671A (en) * | 2017-08-09 | 2017-12-22 | 安徽杰奥电气有限公司 | A kind of cable tear-proof fiber braiding layer |
| CN108129720A (en) * | 2017-12-25 | 2018-06-08 | 洛阳名力科技开发有限公司 | Cable material |
| CN110229527A (en) * | 2019-06-24 | 2019-09-13 | 安徽华泰电缆有限公司 | A kind of anti-aging cable material of high temperature resistant and preparation method thereof |
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| CN103992654A (en) * | 2014-04-22 | 2014-08-20 | 天长市富信电子有限公司 | Cold-resistant power line sheath material and preparing method thereof |
| CN104177838A (en) * | 2014-08-11 | 2014-12-03 | 无锡市华美电缆有限公司 | Fluorosilicone rubber cable material for coal mine cable and preparation method of cable material |
| CN104312059A (en) * | 2014-09-30 | 2015-01-28 | 安徽华峰电缆集团有限公司 | High-performance modified fluororubber cable sheath material |
| CN104312060A (en) * | 2014-09-30 | 2015-01-28 | 安徽华峰电缆集团有限公司 | Cold-resisting oil-resisting modified fluorine rubber cable sheath material |
| CN105368054A (en) * | 2015-12-07 | 2016-03-02 | 无锡市华美电缆有限公司 | Silicone rubber for electric wires and cables |
-
2016
- 2016-08-23 CN CN201610714695.9A patent/CN106349714A/en not_active Withdrawn
Patent Citations (5)
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| CN103992654A (en) * | 2014-04-22 | 2014-08-20 | 天长市富信电子有限公司 | Cold-resistant power line sheath material and preparing method thereof |
| CN104177838A (en) * | 2014-08-11 | 2014-12-03 | 无锡市华美电缆有限公司 | Fluorosilicone rubber cable material for coal mine cable and preparation method of cable material |
| CN104312059A (en) * | 2014-09-30 | 2015-01-28 | 安徽华峰电缆集团有限公司 | High-performance modified fluororubber cable sheath material |
| CN104312060A (en) * | 2014-09-30 | 2015-01-28 | 安徽华峰电缆集团有限公司 | Cold-resisting oil-resisting modified fluorine rubber cable sheath material |
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Non-Patent Citations (1)
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| 李远才，等: "《铸造造型材料使用手册》", 30 June 2015, 机械工业出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325562A (en) * | 2017-08-04 | 2017-11-07 | 安徽远征电缆科技有限公司 | A kind of cable flame-proof silicon rubber |
| CN107507671A (en) * | 2017-08-09 | 2017-12-22 | 安徽杰奥电气有限公司 | A kind of cable tear-proof fiber braiding layer |
| CN108129720A (en) * | 2017-12-25 | 2018-06-08 | 洛阳名力科技开发有限公司 | Cable material |
| CN110229527A (en) * | 2019-06-24 | 2019-09-13 | 安徽华泰电缆有限公司 | A kind of anti-aging cable material of high temperature resistant and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20170125 |
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| WW01 | Invention patent application withdrawn after publication |