CN106188762A - A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material and preparation method thereof - Google Patents
A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material and preparation method thereof Download PDFInfo
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- CN106188762A CN106188762A CN201610599866.8A CN201610599866A CN106188762A CN 106188762 A CN106188762 A CN 106188762A CN 201610599866 A CN201610599866 A CN 201610599866A CN 106188762 A CN106188762 A CN 106188762A
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- Prior art keywords
- optical cable
- outdoor
- cable sheath
- resistance
- resistant building
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B6/00—Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
- G02B6/44—Mechanical structures for providing tensile strength and external protection for fibres, e.g. optical transmission cables
- G02B6/4401—Optical cables
- G02B6/4429—Means specially adapted for strengthening or protecting the cables
- G02B6/443—Protective covering
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Insulated Conductors (AREA)
Abstract
The invention discloses a kind of for outdoor UV resistance ageing-resistant building optical cable sheath material, it is to be prepared by the raw material of following weight parts: Low Density Polyethylene 80 100, methyl phenyl silicone resin 35, magnesium hydroxide 46, sericite in powder 46, tetraethyl orthosilicate 0.5 1, VTES 1.5 2.5, triphenyl phosphate 35, propylgallate 0.01 0.015, dibutyl phthalate 0.5 1, antioxidant 1010 0.3 0.5, nano-cerium oxide 0.5 1, BTA 0.3 0.5.The Cable jacket materials of the present invention has excellent mechanical performance and fire resistance concurrently, and stretch-proof, bending resistance are good, and have good UV resistance ageing resistace, adapt to Exposure to Sunlight condition, are suitably applied building outdoor optical cable sheath field.
Description
Technical field
The present invention relates to optical fiber jacket field of material technology, particularly relate to a kind of for the outdoor ageing-resistant building of UV resistance
Optical cable sheath material and preparation method thereof.
Background technology
Along with the development of telecommunications, the use of optical cable is more and more universal, and this proposes also to the structure of optical cable and performance
New requirement.Particularly domestic premises optical cable is as obtaining the product greatly developed in recent years, and demand is huge, Communication ray used
Cable is close with the safety and health issue concerns of people, therefore requires higher to the fire retardant performance of optical cable.The most conventional
Cable jacket mainly uses common polythene material, and not only case hardness is not enough, easily produce abrasion, and flame-proof environmental protection performance
, there is great potential safety hazard in difference.
For improving the fire protecting performance of optical cable, promote its safety in utilization, often in polyethylene, add bittern-free flame-proof material such as
Magnesium hydroxide is to reach flame retardant effect.But the substantial amounts of mineral-filled decline causing macromolecular material mechanical performance, serious shadow
Ring its serviceability.CN201010293614 discloses a kind of Halogen, presses down cigarette, the preparation method of flame retardant type plastic optical fiber sheath,
Use two-step method that flame retardant of magnesium hydroxide is carried out surface modification, by promoting the affinity reduction of fire retardant and base polyethylene
Add the fire retardant impact on the mechanical property of materials.But this method is to the mechanical performance of sheath material, especially bendability
Energy, tensile property etc. are improved limited, and still there is wearability, the situation of anti-flammability deficiency, it is difficult to meet domestic premises light
The demand of cable wiring.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that one has good fire retardant performance and machine concurrently
UV resistance ageing-resistant building optical cable sheath material for outdoor of tool performance and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material, it is to be prepared by the raw material of following weight parts:
Low Density Polyethylene 80-100, methyl phenyl silicone resin 3-5, magnesium hydroxide 4-6, sericite in powder 4-6, tetraethyl orthosilicate
0.5-1, VTES 1.5-2.5, triphenyl phosphate 3-5, propylgallate 0.01-0.015, O-phthalic
Dibutyl phthalate 0.5-1, antioxidant 1010 0.3-0.5, nano-cerium oxide 0.5-1, BTA 0.3-0.5.
A kind of preparation method for outdoor UV resistance ageing-resistant building optical cable sheath material, comprises the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added mixing roll 50-60 DEG C jointly high
Speed is blended 10-15min, is subsequently adding 100-110 DEG C of high speed of dibutyl phthalate and 5-10min is blended, finally in 165-185
DEG C extruding pelletization, obtains modified poly ethylene base material；
(2) mix all with dehydrated alcohol by weight 1:2-1:3 after VTES and tetraethyl orthosilicate being mixed
Even obtaining mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10-1/15 stirs, and adds mixed liquor weight 1-
50-60 DEG C of the water of 1.5 times stirring 0.5-1h, is adjusted to neutrality by pH after cooling, add magnesium hydroxide, sericite in powder, nano oxidized
Cerium stirring 2-4h, filters, is dried, grinds uniformly, obtain modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10-15min with triphenyl phosphate,
It is subsequently adding remaining raw material and 10-20min is blended at a high speed, carry out extruding pelletization finally by double screw extruder in 180-220 DEG C,
Obtain for outdoor UV resistance ageing-resistant building optical cable sheath material.
The invention have the advantage that
One aspect of the present invention utilizes methyl phenyl silicone resin that low-density polyethylene body resin carries out melt blending modification, thus
Improve the anti-flammability of matrix resin, pliability and the compatibility with filler；On the one hand to magnesium hydroxide, sericite in powder, nano oxygen
Change cerium powder body and carry out vinyl polysiloxane coating modification, toughness and the fire resistance of powder body can be improved, again can be by grafting
Reaction improves the binding ability of powder body and matrix resin, promotes mechanical performance and the stability of material.Association by above material
Adjust potentiation, and with remaining raw material carry out compounding so as to get Cable jacket materials have excellent mechanical performance and resistance concurrently
Combustion performance, stretch-proof, bending resistance are good, and have good UV resistance ageing resistace, adapt to Exposure to Sunlight condition, and being suitable for should
For building outdoor optical cable sheath field.
Detailed description of the invention
A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material, by the component raw material of following weight (kg)
It is prepared from:
Low Density Polyethylene 80, methyl phenyl silicone resin 3, magnesium hydroxide 4, sericite in powder 4, tetraethyl orthosilicate 0.5, vinyl three
Ethoxysilane 1.5, triphenyl phosphate 3, propylgallate 0.01, dibutyl phthalate 0.5, antioxidant 1010
0.3, nano-cerium oxide 0.5, BTA 0.3.
Wherein methyl phenyl silicone resin model uses DC-994.
A kind of preparation method for outdoor UV resistance ageing-resistant building optical cable sheath material, comprises the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added jointly 50 DEG C of high speeds of mixing roll
10min is blended, is subsequently adding 100 DEG C of high speeds of dibutyl phthalate and 5min is blended, finally in 165-185 DEG C of extruding pelletization,
Obtain modified poly ethylene base material；
(2) mix homogeneously with dehydrated alcohol by weight 1:2 after VTES and tetraethyl orthosilicate being mixed and obtain
To mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10 stirs, and 50 DEG C of the water adding mixed liquor weight 1 times stirs
Mix 0.5h, after cooling, pH is adjusted to neutrality, add magnesium hydroxide, sericite in powder, nano-cerium oxide stirring 2h, filter, be dried, grind
Mill uniformly, obtains modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10min with triphenyl phosphate, so
Remaining raw material of rear addition is blended at a high speed 10min, carries out extruding pelletization finally by double screw extruder in 180-220 DEG C, to obtain final product
For outdoor UV resistance ageing-resistant building optical cable sheath material.
Through inspection, above-mentioned prepared sheath material oxygen index (OI) is 32.4%, and elongation at break is 155.6%, and hot strength is
15.3MPa。
Claims (2)
1. the UV resistance ageing-resistant building optical cable sheath material for outdoor, it is characterised in that it is by following weight
The raw material of part prepares:
Low Density Polyethylene 80-100, methyl phenyl silicone resin 3-5, magnesium hydroxide 4-6, sericite in powder 4-6, tetraethyl orthosilicate
0.5-1, VTES 1.5-2.5, triphenyl phosphate 3-5, propylgallate 0.01-0.015, O-phthalic
Dibutyl phthalate 0.5-1, antioxidant 1010 0.3-0.5, nano-cerium oxide 0.5-1, BTA 0.3-0.5.
A kind of preparation side for outdoor UV resistance ageing-resistant building optical cable sheath material the most according to claim 1
Method, it is characterised in that comprise the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added mixing roll 50-60 DEG C jointly high
Speed is blended 10-15min, is subsequently adding 100-110 DEG C of high speed of dibutyl phthalate and 5-10min is blended, finally in 165-185
DEG C extruding pelletization, obtains modified poly ethylene base material；
(2) mix all with dehydrated alcohol by weight 1:2-1:3 after VTES and tetraethyl orthosilicate being mixed
Even obtaining mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10-1/15 stirs, and adds mixed liquor weight 1-
50-60 DEG C of the water of 1.5 times stirring 0.5-1h, is adjusted to neutrality by pH after cooling, add magnesium hydroxide, sericite in powder, nano oxidized
Cerium stirring 2-4h, filters, is dried, grinds uniformly, obtain modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10-15min with triphenyl phosphate,
It is subsequently adding remaining raw material and 10-20min is blended at a high speed, carry out extruding pelletization finally by double screw extruder in 180-220 DEG C,
Obtain for outdoor UV resistance ageing-resistant building optical cable sheath material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610599866.8A CN106188762A (en) | 2016-07-28 | 2016-07-28 | A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610599866.8A CN106188762A (en) | 2016-07-28 | 2016-07-28 | A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106188762A true CN106188762A (en) | 2016-12-07 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610599866.8A Pending CN106188762A (en) | 2016-07-28 | 2016-07-28 | A kind of for outdoor UV resistance ageing-resistant building optical cable sheath material and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109276A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Weather-proof polyolefin wire cable material and preparation method thereof |
-
2016
- 2016-07-28 CN CN201610599866.8A patent/CN106188762A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109276A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Weather-proof polyolefin wire cable material and preparation method thereof |
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Application publication date: 20161207 |