CN106188761A - A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material and preparation method thereof - Google Patents
A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material and preparation method thereof Download PDFInfo
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- CN106188761A CN106188761A CN201610599857.9A CN201610599857A CN106188761A CN 106188761 A CN106188761 A CN 106188761A CN 201610599857 A CN201610599857 A CN 201610599857A CN 106188761 A CN106188761 A CN 106188761A
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- nanometer boron
- boron fibre
- optical cable
- cable sheath
- strength degree
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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Abstract
The invention discloses a kind of nanometer boron fibre modified high-strength degree building optical cable sheath material, it is to be prepared by the raw material of following weight parts: Low Density Polyethylene 80 100, methyl phenyl silicone resin 35, acrylonitrile butadient styrene 35, magnesium hydroxide 46, tetraethyl orthosilicate 0.5 1, VTES 1.5 2.5, triphenyl phosphate 35, nanometer boron fibre 12, glass fiber powder 24, antioxidant 1010 0.3 0.5, dimethicone 0.5 1, erucyl amide 0.5 1.The Cable jacket materials of the present invention has excellent mechanical performance and fire resistance concurrently, and stretch-proof, bending resistance are good, and have high intensity, and wearability, good stability are suitably applied building cable jacket field.
Description
Technical field
The present invention relates to optical fiber jacket field of material technology, particularly relate to a kind of nanometer boron fibre modified high-strength degree building light
Cable sheath material and preparation method thereof.
Background technology
Along with the development of telecommunications, the use of optical cable is more and more universal, and this proposes also to the structure of optical cable and performance
New requirement.Particularly domestic premises optical cable is as obtaining the product greatly developed in recent years, and demand is huge, Communication ray used
Cable is close with the safety and health issue concerns of people, therefore requires higher to the fire retardant performance of optical cable.The most conventional
Cable jacket mainly uses common polythene material, and not only case hardness is not enough, easily produce abrasion, and flame-proof environmental protection performance
, there is great potential safety hazard in difference.
For improving the fire protecting performance of optical cable, promote its safety in utilization, often in polyethylene, add bittern-free flame-proof material such as
Magnesium hydroxide is to reach flame retardant effect.But the substantial amounts of mineral-filled decline causing macromolecular material mechanical performance, serious shadow
Ring its serviceability.CN201010293614 discloses a kind of Halogen, presses down cigarette, the preparation method of flame retardant type plastic optical fiber sheath,
Use two-step method that flame retardant of magnesium hydroxide is carried out surface modification, by promoting the affinity reduction of fire retardant and base polyethylene
Add the fire retardant impact on the mechanical property of materials.But this method is to the mechanical performance of sheath material, especially bendability
Energy, tensile property etc. are improved limited, and still there is wearability, the situation of anti-flammability deficiency, it is difficult to meet domestic premises light
The demand of cable wiring.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that one has good fire retardant performance and machine concurrently
Nanometer boron fibre modified high-strength degree building optical cable sheath material of tool performance and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material, it is to be prepared by the raw material of following weight parts:
Low Density Polyethylene 80-100, methyl phenyl silicone resin 3-5, acrylonitrile-butadiene-styrene copolymer 3-5, hydroxide
Magnesium 4-6, tetraethyl orthosilicate 0.5-1, VTES 1.5-2.5, triphenyl phosphate 3-5, nanometer boron fibre 1-2,
Glass fiber powder 2-4, antioxidant 1010 0.3-0.5, dimethicone 0.5-1, erucyl amide 0.5-1.
The preparation method of a kind of nanometer boron fibre modified high-strength degree building optical cable sheath material, comprises the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added mixing roll 50-60 DEG C jointly high
Speed is blended 10-15min, is subsequently adding acrylonitrile-butadiene-styrene copolymer and 120-140 DEG C of high speed of erucyl amide is blended
5-10min, finally in 165-185 DEG C of extruding pelletization, obtains modified poly ethylene base material；
(2) mix all with dehydrated alcohol by weight 1:2-1:3 after VTES and tetraethyl orthosilicate being mixed
Even obtaining mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10-1/15 stirs, and adds mixed liquor weight 1-
50-60 DEG C of the water of 1.5 times stirring 0.5-1h, is adjusted to pH neutrality, adds magnesium hydroxide, glass fiber powder, nanometer boron after cooling
Fiber stirring 2-4h, filters, is dried, grinds uniformly, obtain modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10-15min with triphenyl phosphate,
It is subsequently adding remaining raw material and 10-20min is blended at a high speed, carry out extruding pelletization finally by double screw extruder in 180-220 DEG C,
Obtain nanometer boron fibre modified high-strength degree building optical cable sheath material.
The invention have the advantage that
One aspect of the present invention utilizes methyl phenyl silicone resin, acrylonitrile-butadiene-styrene copolymer to low-density polyethylene
It is modified that body resin carries out melt blending, thus improves the anti-flammability of matrix resin, pliability and the compatibility with filler；On the one hand
Magnesium hydroxide, glass fiber powder, nanometer boron fibre powder body are carried out vinyl polysiloxane coating modification, powder body can be improved
Toughness and fire resistance, can improve again the binding ability of powder body and matrix resin by graft reaction, promotes the mechanicalness of material
Energy and stability.By the coordination potentiation of above material, and with remaining raw material carry out compounding so as to get cable jacket
Material has excellent mechanical performance and fire resistance concurrently, and stretch-proof, bending resistance are good, and have high intensity, wearability, stable
Property is good, is suitably applied building cable jacket field.
Detailed description of the invention
A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material, by the component raw material system of following weight (kg)
For forming:
Low Density Polyethylene 80, methyl phenyl silicone resin 3, acrylonitrile-butadiene-styrene copolymer 3, magnesium hydroxide 4, positive silicon
Acetoacetic ester 0.5, VTES 1.5, triphenyl phosphate 3, nanometer boron fibre 1, glass fiber powder 2, antioxidant
1010 0.3, dimethicone 0.5, erucyl amide 0.5.
Wherein methyl phenyl silicone resin model uses DC-994.
The preparation method of a kind of nanometer boron fibre modified high-strength degree building optical cable sheath material, comprises the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added jointly 50 DEG C of high speeds of mixing roll
10min is blended, is subsequently adding acrylonitrile-butadiene-styrene copolymer and 120 DEG C of high speeds of erucyl amide are blended 5min, finally
In 165-185 DEG C of extruding pelletization, obtain modified poly ethylene base material；
(2) mix homogeneously with dehydrated alcohol by weight 1:2 after VTES and tetraethyl orthosilicate being mixed and obtain
To mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10 stirs, and 50 DEG C of the water adding mixed liquor weight 1 times stirs
Mix 0.5h, after cooling, pH is adjusted to neutrality, add magnesium hydroxide, glass fiber powder, nanometer boron fibre stirring 2h, filter, be dried,
Grind uniformly, obtain modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10min with triphenyl phosphate, so
Remaining raw material of rear addition is blended at a high speed 10min, carries out extruding pelletization finally by double screw extruder in 180-220 DEG C, to obtain final product
Nanometer boron fibre modified high-strength degree building optical cable sheath material.
Through inspection, above-mentioned prepared sheath material oxygen index (OI) is 31.3%, and elongation at break is 191.2%, and hot strength is
18.9MPa。
Claims (2)
1. a nanometer boron fibre modified high-strength degree building optical cable sheath material, it is characterised in that it is by following weight parts
Raw material prepare:
Low Density Polyethylene 80-100, methyl phenyl silicone resin 3-5, acrylonitrile-butadiene-styrene copolymer 3-5, hydroxide
Magnesium 4-6, tetraethyl orthosilicate 0.5-1, VTES 1.5-2.5, triphenyl phosphate 3-5, nanometer boron fibre 1-2,
Glass fiber powder 2-4, antioxidant 1010 0.3-0.5, dimethicone 0.5-1, erucyl amide 0.5-1.
The preparation side of a kind of nanometer boron fibre modified high-strength degree building optical cable sheath material the most according to claim 1
Method, it is characterised in that comprise the following steps:
(1) weigh raw material by weight, first Low Density Polyethylene and methyl phenyl silicone resin are added mixing roll 50-60 DEG C jointly high
Speed is blended 10-15min, is subsequently adding acrylonitrile-butadiene-styrene copolymer and 120-140 DEG C of high speed of erucyl amide is blended
5-10min, finally in 165-185 DEG C of extruding pelletization, obtains modified poly ethylene base material；
(2) mix all with dehydrated alcohol by weight 1:2-1:3 after VTES and tetraethyl orthosilicate being mixed
Even obtaining mixed liquor, the glacial acetic acid being subsequently adding mixed liquor weight 1/10-1/15 stirs, and adds mixed liquor weight 1-
50-60 DEG C of the water of 1.5 times stirring 0.5-1h, is adjusted to pH neutrality, adds magnesium hydroxide, glass fiber powder, nanometer boron after cooling
Fiber stirring 2-4h, filters, is dried, grinds uniformly, obtain modified powder；
(3) first the modified powder in (2), the modified poly ethylene base material in (1) are blended at a high speed 10-15min with triphenyl phosphate,
It is subsequently adding remaining raw material and 10-20min is blended at a high speed, carry out extruding pelletization finally by double screw extruder in 180-220 DEG C,
Obtain nanometer boron fibre modified high-strength degree building optical cable sheath material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610599857.9A CN106188761A (en) | 2016-07-28 | 2016-07-28 | A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material and preparation method thereof |
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| CN201610599857.9A CN106188761A (en) | 2016-07-28 | 2016-07-28 | A kind of nanometer boron fibre modified high-strength degree building optical cable sheath material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117164956A (en) * | 2023-09-13 | 2023-12-05 | 尤尼梅特电线电缆(苏州)有限公司 | Filler for cable and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109276A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Weather-proof polyolefin wire cable material and preparation method thereof |
-
2016
- 2016-07-28 CN CN201610599857.9A patent/CN106188761A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104109276A (en) * | 2014-06-23 | 2014-10-22 | 安徽荣玖光纤通信科技有限公司 | Weather-proof polyolefin wire cable material and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN117164956A (en) * | 2023-09-13 | 2023-12-05 | 尤尼梅特电线电缆(苏州)有限公司 | Filler for cable and preparation method thereof |
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Application publication date: 20161207 |
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