CN106186428A - A kind of Pb-Zn deposits beneficiation wastewater treatment method and processing means thereof - Google Patents

A kind of Pb-Zn deposits beneficiation wastewater treatment method and processing means thereof Download PDF

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Publication number
CN106186428A
CN106186428A CN201610674491.7A CN201610674491A CN106186428A CN 106186428 A CN106186428 A CN 106186428A CN 201610674491 A CN201610674491 A CN 201610674491A CN 106186428 A CN106186428 A CN 106186428A
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Prior art keywords
tank
pond
pipeline
collecting
sand
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Pending
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CN201610674491.7A
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Chinese (zh)
Inventor
曾亚
王思亮
梁松苗
梁永红
唐文延
梁龙
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Vontron Technology Co Ltd
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Vontron Technology Co Ltd
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Priority to CN201610674491.7A priority Critical patent/CN106186428A/en
Publication of CN106186428A publication Critical patent/CN106186428A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • C02F1/5245Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)

Abstract

The present invention relates to technical field of waste water processing, especially a kind of Pb-Zn deposits beneficiation wastewater treatment method and processing means thereof, by the structure of device is configured, make device realize chemical precipitation to be coupled accurately with membrane processing method, realize chemical precipitation and process coupling processing Pb-Zn deposits beneficiation wastewater with film, the acidity caused during simultaneously overcoming chemical precipitation is not suitable for, and causes the defect that film processing unit is impaired, reduces the cost processing Pb-Zn deposits beneficiation wastewater.

Description

A kind of Pb-Zn deposits beneficiation wastewater treatment method and processing means thereof
Technical field
The present invention relates to technical field of waste water processing, especially a kind of Pb-Zn deposits beneficiation wastewater treatment method and process dress thereof Put.
Background technology
At present in ore dressing processing procedure, substantial amounts of waste water will be produced, cause substantial amounts of mine wastewater to enter water body Basin so that mine ore dressing contaminated wastewater environment.Particularly with in Pb-Zn deposits ore dressing process, it contains substantial amounts of metallic element, Such as Zn, Cd, Pb, As etc., after these metallic elements flow in environment, easily cause environmental pollution, and due to the character of raw ore, Causing in ore dressing process, mineral water clay content is bigger so that the pulp density in ore dressing water is the most unstable, causes in beneficiation wastewater One-tenth be grouped into the most unstable, cause substantial amounts of heavy metal element along with loss, cause the pollution of the high degree of environment.
In prior art, although for the process of mine ore dressing waste water, there is substantial amounts of investigative technique, but mostly use Be physics sedimentation after, directly filter, or use the method such as chemical precipitation to process, and for the waste water of Pb-Zn deposits ore dressing In, it contains substantial amounts of heavy metal element, and during using said method to process, the response rate still making water is relatively low, And processing procedure easily reveals in the environment, cause the pollution of environment.
Along with the fast development of film industry, film have also been obtained in field of waste water treatment and develops faster, and achieves Great breakthrough, but in prior art, the technology using film to process for Pb-Zn deposits beneficiation wastewater is the most relatively fewer, and also There are no to process to be coupled with film by chemical treatment and process the report of Pb-Zn deposits beneficiation wastewater.
In consideration of it, this researcher is studied for Pb-Zn deposits beneficiation wastewater, carry out at recovery for Pb-Zn deposits beneficiation wastewater Reason utilizes, it is provided that a kind of new approaches.
Summary of the invention
In order to solve above-mentioned technical problem present in prior art, the present invention provides a kind of Pb-Zn deposits beneficiation wastewater to process Method and processing means thereof.
It is achieved particular by techniques below scheme:
A kind of Pb-Zn deposits beneficiation wastewater processing means, including collecting-tank (1), the rain being connected by pipeline with collecting-tank (1) Pond (2), the reaction tank (16) being connected by pipeline with collecting-tank (1), the distribution reservoir being connected by pipeline with reaction tank (16) (15), the sedimentation tank (14) being connected by pipeline with distribution reservoir (15), the port of export of sedimentation tank (14) be divided into sludge outlet end and Liquid outlet end;Be connected by pipeline with sludge outlet end is sludge concentration tank (4), and sludge concentration tank (4) passes through conveyer belt Connect is filter press (5);Be connected by pipeline with liquid outlet end is primiparity pond (13), with primiparity pond (14) Connected by pipeline is sand filter (7), and be connected by pipeline with sand filter (7) is film processing unit (8), film processing unit (8) respectively connected concentrated solution collecting pit (10) and reuse pool (9).
Described sand filter (7), it first passes through pipeline and connects pH regulator pond, then passes through pipeline junctional membrane processing unit (8).
Described pH regulator pond is deposited pond (6) and is connected with buffer agent.
Described sand filter (7) connects with sand-washing water pond (12).
Described pH regulator pond connects with emergency lagoon (11).
Described reaction tank (16) connects with flocculant storage tank (3).
A kind of Pb-Zn deposits beneficiation wastewater treatment method, comprises the following steps:
1) by wastewater collection in collecting-tank (1), and add rainwater and be diluted to its suspension;
2) entering in reaction tank, and be added thereto to flocculant, addition is the 0.01%~0.02% of wastewater quality, stirs Mix mix homogeneously;
3) enter in distribution reservoir, add the clear water accounting for wastewater quality 10-20%, stir;
4) enter in sedimentation tank, staticly settle, and precipitating sludge is sent in sludge concentration tank concentrate, and will concentrate after Dry slag is placed in filter pressing in filter press and processes;Precipitation supernatant is sent into primiparity pond, then the water in primiparity pond is passed through Sand filter sand filtration processes, and is 6-8 by adjusting pH value in water pH regulator pond more out in sand filter or adjusts without pH value After, it is directly entered film processing unit and carries out membrane filtration process, concentrated solution is sent into concentrated solution collecting pit, drainage is sent into recycle-water Chi Zhong,.
Described flocculant is polyaluminium sulfate and Calx, the mixture of sodium hydroxide, and mixing quality ratio is for 1:0.3: 0.6。
Described concentrated solution is back in collecting-tank;Described regulation pH is to use buffer agent regulation;Described buffer agent For the mixture of potassium dihydrogen phosphate Yu sodium sulfite, mixing ratio is 1:0.3;Described pH regulator pond is connected with emergency lagoon, emergent Pond forms closed circuit with collecting-tank;After described sand filter carries out sand filtration, and it being carried out washed-out sand process, washed-out sand water returns collection Pool circulating processes;Described sludge concentration tank, the liquid formed after its sludge condensation returns collecting-tank circular treatment;Described Filter press, the liquid obtained after filter pressing returns circular treatment in collecting-tank.
Compared with prior art, the technique effect of the present invention is embodied in:
By the structure of device is configured so that device realizes chemical precipitation and obtains coupling accurately with membrane processing method Close, it is achieved chemical precipitation processes coupling processing Pb-Zn deposits beneficiation wastewater, the acid caused during simultaneously overcoming chemical precipitation with film Degree is not suitable for, and causes the defect that film processing unit is impaired, reduces the cost processing Pb-Zn deposits beneficiation wastewater.
The invention control by processing method so that the emission index of waste water significantly reduces so that give up in many places Water obtains circulating reflux and processes, so that particle or precipitation or the material such as adhesion or absorption obtain pretreatment, keeps away Exempt to enter film processing unit after stain diaphragm, extend the service life of film processing unit, it is to avoid reverse osmosis in film processing unit Permeable system wrecks, and reduces processing cost.
In the invention, when reclaiming Pb-Zn deposits beneficiation wastewater, the Water Sproading rate in its disposable waste water reaches To more than 75%, effectively raise the recycling of Pb-Zn deposits beneficiation wastewater, decrease the Pb-Zn deposits ore dressing water containing heavy metal Directly discharge, reduces environmental pollution rate.
The process technique of the invention is simple, and flow process is short, easy and simple to handle, and cost is relatively low.
Accompanying drawing explanation
Fig. 1 is assembly of the invention structural representation.
1-collecting-tank 2-stormwater tank 3-flocculant storage tank 4-sludge concentration tank 5-filter press 6-buffer agent is deposited Put pond 7-sand filter 8-film processing unit 9-reuse pool 10-dope collecting pit 11-emergency lagoon 12-sand-washing water pond 13- Primiparity pond 14-sedimentation tank 15-distribution reservoir 16-reaction tank.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme is further limited, but claimed Scope is not only limited to description.
Embodiment
As it is shown in figure 1, a kind of Pb-Zn deposits beneficiation wastewater processing means, including collecting-tank 1, with collecting-tank 1 by pipeline even The stormwater tank 2 connect, the reaction tank 16 being connected by pipeline with collecting-tank 1, the distribution reservoir 15 being connected by pipeline with reaction tank 16, The sedimentation tank 14 being connected by pipeline with distribution reservoir 15, the port of export of sedimentation tank 14 is divided into sludge outlet end and liquid outlet end; Be connected by pipeline with sludge outlet end is sludge concentration tank 4, and what sludge concentration tank 4 was connected by conveyer belt is filter press Machine 5;Be connected by pipeline with liquid outlet end is primiparity pond 13, and be connected by pipeline with primiparity pond 14 is sand filter 7, be connected by pipeline with sand filter 7 is film processing unit 8, and film processing unit 8 respectively connected concentrated solution collecting pit 10 He Reuse pool 9.
In certain embodiments, described sand filter 7, it is first passed through pipeline and connects pH regulator pond, then is connected by pipeline Film processing unit 8.Realize the pH value of the water entering film processing unit is controlled and is adjusted, it is to avoid membrane component is damaged by pH, Extend the service life of film processing unit, reduce cost.
In certain embodiments, described pH regulator pond is deposited pond 6 and is connected with buffer agent.By using buffer agent to adjust PH value, it is achieved the accurate control to pH value, it is to avoid chemicals addition control controls the improper defect causing pH value accommodative excess, reduces behaviour Make difficulty.
In certain embodiments, described sand filter 7 connects with sand-washing water pond 12.The water that washed-out sand processes can be received After collection, circulating reflux is to collecting-tank, it is to avoid the generation of new pollutant effluents.
In certain embodiments, described pH regulator pond connects with emergency lagoon 11.Can be prevented effectively from pH regulator process In, after causing pH value accommodative excess, it is difficult to carry out the process of next step, and then force the operation of stop device, it is possible to effectively carry The operational efficiency of high device.
In certain embodiments, described reaction tank 16 connects with flocculant storage tank 3.
Use said apparatus to carry out Pb-Zn deposits beneficiation wastewater treatment method, comprise the following steps:
1) by wastewater collection in collecting-tank 1, and add rainwater and be diluted to its suspension;
2) entering in reaction tank, and be added thereto to flocculant, addition is the 0.01%~0.02% of wastewater quality, stirs Mix mix homogeneously;
3) enter in distribution reservoir, add the clear water accounting for wastewater quality 10-20%, stir;
4) enter in sedimentation tank, staticly settle, and precipitating sludge is sent in sludge concentration tank concentrate, and will concentrate after Dry slag is placed in filter pressing in filter press and processes;Precipitation supernatant is sent into primiparity pond, then the water in primiparity pond is passed through Sand filter sand filtration processes, and is 6-8 by adjusting pH value in water pH regulator pond more out in sand filter or adjusts without pH value After, it is directly entered film processing unit and carries out membrane filtration process, concentrated solution is sent into concentrated solution collecting pit, drainage is sent into recycle-water Chi Zhong,.
Described flocculant is polyaluminium sulfate and Calx, the mixture of sodium hydroxide, and mixing quality ratio is for 1:0.3: 0.6。
Described concentrated solution is back in collecting-tank;Described regulation pH is to use buffer agent regulation;Described buffer agent For the mixture of potassium dihydrogen phosphate Yu sodium sulfite, mixing ratio is 1:0.3;Described pH regulator pond is connected with emergency lagoon, emergent Pond forms closed circuit with collecting-tank;After described sand filter carries out sand filtration, and it being carried out washed-out sand process, washed-out sand water returns collection Pool circulating processes;Described sludge concentration tank, the liquid formed after its sludge condensation returns collecting-tank circular treatment;Described Filter press, the liquid obtained after filter pressing returns circular treatment in collecting-tank.

Claims (9)

1. a Pb-Zn deposits beneficiation wastewater processing means, it is characterised in that include collecting-tank (1), passes through pipeline with collecting-tank (1) The stormwater tank (2) connected, the reaction tank (16) being connected by pipeline with collecting-tank (1), it is connected by pipeline with reaction tank (16) Distribution reservoir (15), the sedimentation tank (14) being connected by pipeline with distribution reservoir (15), the port of export of sedimentation tank (14) is divided into mud The port of export and liquid outlet end;Be connected by pipeline with sludge outlet end is sludge concentration tank (4), and sludge concentration tank (4) leads to Cross conveyer belt connection is filter press (5);Be connected by pipeline with liquid outlet end is primiparity pond (13), with primiparity What pond (14) was connected by pipeline is sand filter (7), and be connected by pipeline with sand filter (7) is film processing unit (8), film Processing unit (8) respectively connected concentrated solution collecting pit (10) and reuse pool (9).
2. Pb-Zn deposits beneficiation wastewater processing means as claimed in claim 1, it is characterised in that described sand filter (7), it is first PH regulator pond is connected by pipeline, then by pipeline junctional membrane processing unit (8).
3. Pb-Zn deposits beneficiation wastewater processing means as claimed in claim 2, it is characterised in that described pH regulator pond and buffering Pond (6) connection is deposited in agent.
4. Pb-Zn deposits beneficiation wastewater processing means as claimed in claim 1 or 2, it is characterised in that described sand filter (7) with Sand-washing water pond (12) connects.
5. as claimed in claim 2 or claim 3 Pb-Zn deposits beneficiation wastewater processing means, it is characterised in that described pH regulator pond with Emergency lagoon (11) connects.
6. Pb-Zn deposits beneficiation wastewater processing means as claimed in claim 1, it is characterised in that described reaction tank (16) and wadding Solidifying agent storage tank (3) connection.
7. a Pb-Zn deposits beneficiation wastewater treatment method, it is characterised in that comprise the following steps:
1) by wastewater collection in collecting-tank (1), and add rainwater and be diluted to its suspension;
2) entering in reaction tank, and be added thereto to flocculant, addition is the 0.01%~0.02% of wastewater quality, and stirring is mixed Close uniformly;
3) enter in distribution reservoir, add the clear water accounting for wastewater quality 10-20%, stir;
4) enter in sedimentation tank, staticly settle, and precipitating sludge is sent in sludge concentration tank concentrate, and will concentrate after dry slag It is placed in filter pressing in filter press to process;Precipitation supernatant is sent into primiparity pond, then by the water in primiparity pond through sand filtration Device sand filtration processes, and will adjust after pH value is 6-8 or adjusts without pH value in water pH regulator pond more out in sand filter, directly Tap into and carry out membrane filtration process into film processing unit, concentrated solution is sent into concentrated solution collecting pit, drainage is sent in reuse pool, ?.
8. Pb-Zn deposits beneficiation wastewater treatment method as claimed in claim 7, it is characterised in that described flocculant is polymerised sulphur Acid aluminum and Calx, the mixture of sodium hydroxide, mixing quality ratio is for 1:0.3:0.6.
9. Pb-Zn deposits beneficiation wastewater treatment method as claimed in claim 7, it is characterised in that described concentrated solution is back to collection In pond;Described regulation pH is to use buffer agent regulation;Described buffer agent is the mixing of potassium dihydrogen phosphate and sodium sulfite Thing, mixing ratio is 1:0.3;Described pH regulator pond is connected with emergency lagoon, and emergency lagoon forms closed circuit with collecting-tank;Described After sand filter carries out sand filtration, and it being carried out washed-out sand process, washed-out sand water returns collecting-tank circular treatment;Described sludge condensation Pond, the liquid formed after its sludge condensation returns collecting-tank circular treatment;Described filter press, the liquid obtained after filter pressing Body returns circular treatment in collecting-tank.
CN201610674491.7A 2016-08-16 2016-08-16 A kind of Pb-Zn deposits beneficiation wastewater treatment method and processing means thereof Pending CN106186428A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107721007A (en) * 2017-08-14 2018-02-23 内蒙古森泰企业咨询有限公司 Lead-zinc sulfide ore mine wastewater step-by-step processing and sub-prime utilize technique
CN108218108A (en) * 2017-12-22 2018-06-29 天津顺兴捷科技有限责任公司 A kind of domestic sewage treatment process
CN109231638A (en) * 2018-11-24 2019-01-18 江苏卓博环保科技有限公司 Lead-zinc beneficiation wastewater treatment for reuse devices and methods therefor
CN109437448A (en) * 2018-11-24 2019-03-08 江苏卓博环保科技有限公司 Pb-Zn deposits beneficiation wastewater treatment for reuse devices and methods therefor

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CN104973714A (en) * 2015-06-23 2015-10-14 广西冶金研究院 Deep purification and recycling method for waste water containing heavy metal ions
CN205115118U (en) * 2015-10-15 2016-03-30 深圳市迈德希环保科技有限公司 Heavy metal sewage treatment system

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US20140251914A1 (en) * 2013-03-07 2014-09-11 Brandon Ryan Ball Method for treating acid mine drainage
CN104973714A (en) * 2015-06-23 2015-10-14 广西冶金研究院 Deep purification and recycling method for waste water containing heavy metal ions
CN205115118U (en) * 2015-10-15 2016-03-30 深圳市迈德希环保科技有限公司 Heavy metal sewage treatment system

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107721007A (en) * 2017-08-14 2018-02-23 内蒙古森泰企业咨询有限公司 Lead-zinc sulfide ore mine wastewater step-by-step processing and sub-prime utilize technique
CN108218108A (en) * 2017-12-22 2018-06-29 天津顺兴捷科技有限责任公司 A kind of domestic sewage treatment process
CN109231638A (en) * 2018-11-24 2019-01-18 江苏卓博环保科技有限公司 Lead-zinc beneficiation wastewater treatment for reuse devices and methods therefor
CN109437448A (en) * 2018-11-24 2019-03-08 江苏卓博环保科技有限公司 Pb-Zn deposits beneficiation wastewater treatment for reuse devices and methods therefor
CN109231638B (en) * 2018-11-24 2023-10-24 江苏卓博环保科技有限公司 Lead zinc oxide ore dressing wastewater treatment and recycling device and method thereof

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Application publication date: 20161207