Supermolecule nursing agent, circulation water for heating Zero discharging system and using method
Technical field
The present invention relates to chemical technology field, particularly relate to a kind of supermolecule nursing agent, circulation water for heating Zero discharging system
And using method.
Background technology
At present, city central heating is carried out widely, and the hot water that thermo-power station produces is delivered to each family by heating network
Each family.And right, the recirculated water that the heating system in city uses is easy to corrosion and scaling, the dirt of heating network be mainly rust,
Incrustation scale, rust deposite, incrustation scale etc. be attached to metal surface, because its thermal resistance is tens times of metal even hundreds of times, can have a strong impact on
Heat exchange.In order to prevent boiler heat supplying pipe network fouling corrosion in prior art, in heating system, generally add phosphate, phosphoric acid
The Main Function of salt is the fouling preventing hot water, and therefore the environment at phosphate place is generally faintly acid, joins hot-water heating system
After, equipment is had certain corrosion;Meanwhile, the equipment of heating system, pipeline are chronically at work in hot environment environment, and temperature is the highest
In 55 DEG C, existing corrosion inhibiter is not had substantially to the effect of inhibition.China Patent No. 201610010686.1 discloses one
Kind heating system augmentation of heat transfer agent, and disclose the concrete component of coolant, wherein, the cleaned chilled water that is mixed in of fouling flows over
Cheng Zhong, the fine graphite powder in nursing agent is for lubricating the fouling in chilled water, it is to avoid flow the most smooth.But, make actual
During with, owing to using fine graphite powder cannot be dissolved in water, fine graphite powder easily covers and is being formed with the cold of fouling
The metal surface of matchmaker's water system, fouling is covered by fine graphite powder and causes nursing agent cannot clear up fouling fast and effectively,
Thus complete supermolecule protecting film cannot be formed in the metal surface of chilled-water system, cause Central air-conditioner refrigerant water system
Cleaning efficiency and effect are poor.How to design a kind of circulation water for heating system clean efficiency and the more preferable additive of effect is this
Bright technical problem to be solved.
Summary of the invention
The technical problem to be solved is: provide a kind of supermolecule nursing agent, circulation water for heating Zero discharging system
And using method, by adding supermolecule nursing agent in circulation water for heating, it is achieved reduce recirculated water and produce fouling and reduce system
System extent of corrosion, reaches to reduce the effect of sewage discharge, improves cleaning efficiency and cleaning effect.
The technical scheme that the present invention provides is, a kind of supermolecule nursing agent, including following components in percentage by weight: alkyl
Benzene sulfonic acid sodium salt 7%~10%, sodium polyacrylate 10%~12%, dodecyl dimethyl benzyl ammonium chloride 5%~6%, alkanolamide 2%
~2.5%, fatty alcohol-polyoxyethylene ether 4.5%~6%, cyanoacetic acid 4%~5%, phenylpropyl alcohol triazole 1%~1.5%, sodium tripolyphosphate
2%~3%, sodium silicate 2%-2.5%, tertiary sodium phosphate 1%-1.5%, ethylene glycol 2% ~ 3%, pyridoxine hydrochloride 1% ~ 1.5%, disodium hydrogen phosphate
2%~2.5%, surplus is water.
Further, also include: many polyethylene glycol oxides nonyl 2, 2-Oxydiphenol 3%~6%, para-totuidine 4%~5%, ethylenediamine triacetic acid
1%-1.5%。
Further, also include: silicon potassium acid 2%-3%, polyacrylic acid 2%-2.5%, dodecyl dimethyl benzyl ammonium chloride
Disodium hydrogen phosphate 0.5%-1%, dihydroxy ethyl high-carbon fatty acid amide 0.5%-1%, alkyl benzene sulphonate 0.3%-0.8%, dimethyl benzene sulphur
Acid sodium 1.2%-1.5%.
The present invention also provides for a kind of circulation water for heating Zero discharging system, and including heating system, described heating system includes even
Circulating pump, heat exchanger, water knockout drum, user side radiator and the water collector being connected together, also includes scale remover water tank and liquid medicine pump,
Described scale remover water tank is connected with the water inlet of described circulating pump by described liquid medicine pump, is contained with in described scale remover water tank
State supermolecule nursing agent.
The present invention also provides for the using method of a kind of circulation water for heating Zero discharging system, uses above-mentioned circulation water for heating zero-emission
Place system;Being first in the case of water running for heating system, described using method includes that pattern one, described pattern one have
Body is: filling the supermolecule nursing agent of the first metering while heating system filling recirculated water, heating system is properly functioning
During, at interval of the time of setting, in heating system, again supplement the supermolecule nursing agent of filling the second metering;Wherein, follow
The adding amount of ring water is L, and the adding amount of the first metering of supermolecule nursing agent is 0.01 ~ 0.02L, the second of supermolecule nursing agent
The adding amount of metering is 0.003 ~ 0.007 L.
Further, for the heating system run, and the recirculated water in heating system has been detected by existing fouling
In the case of, described using method also includes pattern two, and described pattern two particularly as follows: fill the oversubscription of the 3rd metering to heating system
Sub-nursing agent, after heating system runs the setting time, if recirculated water becomes translucent dark brown liquid, then maintains heat supply system
System continues to run with, if recirculated water is still turbid liquid, the most again to the supermolecule nursing of heating system filling the 4th metering
Agent, after heating system runs the setting time, empties the recirculated water in heating system, and the mode according still further to pattern one is grasped
Make;Wherein, the adding amount of the 3rd metering of supermolecule nursing agent is 0.03 ~ 0.04L, adding of the 4th metering of supermolecule nursing agent
Fluence is 0.04 ~ 0.06 L.
Compared with prior art, advantages of the present invention and good effect are: the supermolecule nursing agent of present invention offer, heat supply
Recirculated water Zero discharging system and using method, by supermolecule nursing agent add sodium polyacrylate can alkalescence and in highly concentrated
Running non-scaling under demagnification number, meanwhile, sodium alkyl benzene sulfonate is by the crystallite of the salts such as the calcium carbonate in recirculated water, calcium sulfate or mud
Sand is dispersed in water and does not precipitates, thus reaches scale inhibition purpose, and dodecyl dimethyl benzyl ammonium chloride has wide spectrum, efficient
Sterilization algae removal ability also coordinates phenylpropyl alcohol triazole to have the strongest corrosion inhibiting ability, can protect the metal of heating network be not corroded and
Corrosion, and alkanolamide has good washing force and water stabilization effect, it is possible to effectively clean out on heating network shape
The fouling become, after by dirt removals such as the various rust deposites of metal surface, grease, dirts, fatty alcohol-polyoxyethylene ether coordinates cyanogen
Guanidine-acetic acid has catalytic action, accelerates the components such as tertiary sodium phosphate, sodium silicate, sodium polyacrylate and coordinates to assemble, and being combined into complexity has
The polymer of tissue, forms one layer of Supermolecular film and reaches to delay the effect of fouling in metal surface;It is essential that employing ethylene glycol
Coordinating disodium hydrogen phosphate to substitute insoluble graphite powder with pyridoxine hydrochloride, disodium hydrogen phosphate is dissolved in water insoluble in alcohol, and second
Glycol and pyridoxine hydrochloride are the most soluble in water to form the liquid with lubrication, and the fouling being mixed in chilled water can be smooth and easy
Flowing, by adding supermolecule nursing agent in circulation water for heating, it is achieved reduce recirculated water and produce fouling also to reduce system rotten
Degree of corrosion, reaches to reduce the effect of sewage discharge, reaches zero burn into zero fouling, the effect of zero blowdown.
Accompanying drawing explanation
In order to be illustrated more clearly that the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
In having technology to describe, the required accompanying drawing used is briefly described, it should be apparent that, the accompanying drawing in describing below is this
Some bright embodiments, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to
Other accompanying drawing is obtained according to these accompanying drawings.
Fig. 1 is the use state reference map of circulation water for heating Zero discharging system of the present invention.
Detailed description of the invention
For making the purpose of the embodiment of the present invention, technical scheme and advantage clearer, below in conjunction with the embodiment of the present invention
In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is
The a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art
The every other embodiment obtained under not making creative work premise, broadly falls into the scope of protection of the invention.
The present invention provides a kind of supermolecule nursing agent for circulation water for heating, and this supermolecule nursing agent includes following heavy
The component of amount percentage ratio: sodium alkyl benzene sulfonate 7%~10%, sodium polyacrylate 10%~12%, dodecyl dimethyl Benzylmagnesium chloride
Ammonium 5%~6%, alkanolamide 2%~2.5%, fatty alcohol-polyoxyethylene ether 4.5%~6%, cyanoacetic acid 4%~5%, phenylpropyl alcohol triazole
1%~1.5%, sodium tripolyphosphate 2%~3%, sodium silicate 2%-2.5%, tertiary sodium phosphate 1%-1.5%, ethylene glycol 2% ~ 3%, hydrochloric acid pyrrole are trembled
Alcohol 1% ~ 1.5%, disodium hydrogen phosphate 2%~2.5%, surplus is water.
Specifically, by dodecyl dimethyl benzyl ammonium chloride in supermolecule nursing agent coordinate polyacrylic acid, three
The rust on polyphosphate sodium scavenging system surface, incrustation scale carry out adsorbing and decomposing.1-hydroxy ethylidene-1,1-diphosphonic acid ensures that medicament is in heat supply system
Cleaning scale removal more efficiently under the condition of high temperature of system.Meanwhile, the catalysis of cyanoacetic acid is coordinated to make at fatty alcohol-polyoxyethylene ether
Under with, it is possible to the components such as acceleration tertiary sodium phosphate, sodium silicate, sodium polyacrylate are worked in coordination with and played Supramolecular self assembly effect, by metal
After the dirt removals such as the various rust in surface, incrustation scale, dirt, form one layer of Supermolecular film in metal surface, reach corrosion-mitigation scale-inhibition
Effect.Owing to corrosion scale inhibition performance is all close to 0%, heating system need not carry out especially blowdown, close to zero blowdown.This heating cycle
Easily and effectively, and scale remover scale removal inhibition when high temperature is unaffected for water cleaning method.It is essential that use ethylene glycol and hydrochloric acid
Pyridoxol coordinates disodium hydrogen phosphate to substitute insoluble graphite powder, and disodium hydrogen phosphate is dissolved in water insoluble in alcohol, and ethylene glycol and
Pyridoxine hydrochloride is the most soluble in water to form the liquid with lubrication, and the fouling being mixed in chilled water can be flowed smoothly
Dynamic.
Further, supermolecule nursing agent also includes: many polyethylene glycol oxides nonyl 2, 2-Oxydiphenol 3%~6%, para-totuidine 4%~5%,
Ethylenediamine triacetic acid 1%-1.5%.Concrete, many polyethylene glycol oxides nonyl 2, 2-Oxydiphenol of increase can possess good after reacting with para-totuidine
Good chemical stability, not only tolerates high temperature, also has preferable cooperative effect, to many tools such as metal ion such as calcium, magnesium, copper etc.
There is the sequestering power of excellence, be more beneficial for scale remover scale removal corrosion inhibition when high temperature, improve its ant-scaling performance gentle erosion energy
Power;And the ethylenediamine triacetic acid increased can with tertiary sodium phosphate and sodium silicate cooperate to circulation water for heating formed enclosed follow
Dirt in circulation road carries out adsorbing, bond and decomposing, thus without waste discharge, additionally it is possible to stop the dissolved oxygen in water and gold
Metal surface contact corrosion metal, reaches relevant device zero burn into zero fouling and the purpose of zero blowdown in heating system.Preferably,
Supermolecule nursing agent also includes: silicon potassium acid 2%-3%, polyacrylic acid 2%-2.5%, dodecyl dimethyl benzyl ammonium chloride phosphoric acid hydrogen
Disodium 0.5%-1%, dihydroxy ethyl high-carbon fatty acid amide 0.5%-1%, alkyl benzene sulphonate 0.3%-0.8%, acid dimethyl sodium
1.2%-1.5%.Concrete, the acid of silicon potassium and polyacrylic acid can form stable compound with the metal ion in circulation water for heating,
Calcium carbonate in water and calcium hydroxide there is excellent decomposition, such that it is able to more effectively decompose formation on heating network
Fouling, meanwhile, is also beneficial to slow down the formation of fouling;And dodecyl dimethyl benzyl ammonium chloride disodium hydrogen phosphate, dihydroxy second
The effect that base high-carbon fatty acid amide, alkyl benzene sulphonate, acid dimethyl sodium are collaborative by further playing component, is more beneficial for
Realize Supramolecular self assembly, meet the effect reaching to delay fouling under hot environment at metal surface one layer of Supermolecular film of formation.
As it is shown in figure 1, the present embodiment circulation water for heating Zero discharging system, including existing heating system, heating system one
As include the circulating pump 1, heat exchanger 2, water knockout drum 3, user side radiator 4 and the water collector 5 that link together, recirculated water is in circulation
Pump 1, heat exchanger 2, water knockout drum 3, user side radiator 4 and water collector 5 circulate, the present embodiment heating cycle water zero discharge
System also includes scale remover water tank 6 and liquid medicine pump 7, and scale remover water tank 6 is contained with above-mentioned supermolecule nursing agent, below carries out concrete
Using method explanation:
In actual use, for the new heating system used, then use pattern one, i.e. to heating system filling circulation
The supermolecule nursing agent of the first metering is filled, in heating system normal course of operation, at interval of the time of setting, again while water
The supermolecule nursing agent of filling the second metering is supplemented in heating system;Wherein, the adding amount of recirculated water is L, and supermolecule is nursed
The adding amount of the first metering of agent is 0.01 ~ 0.02L, and the adding amount of the second metering of supermolecule nursing agent is 0.003 ~ 0.007
L。
In actual use, in the heating system run, because there being the situation of fouling inside it,
Then use pattern two, i.e. to the supermolecule nursing agent of heating system filling the 3rd metering, after heating system runs the setting time, as
Really recirculated water becomes translucent dark brown liquid, then maintain heating system to continue to run with, if recirculated water is still dirty solution
Body, the most again to the supermolecule nursing agent of heating system filling the 4th metering, after heating system runs the setting time, by heat supply system
Recirculated water emptying in system, the mode according still further to pattern one operates;Wherein, the filling of the 3rd metering of supermolecule nursing agent
Amount is 0.03 ~ 0.04L, and the adding amount of the 4th metering of supermolecule nursing agent is 0.04 ~ 0.06 L.
Illustrating, the heating system accepting certain community processes engineering.This District Heating System is possessed the water yield and is about 400m
, heating system is because having used, and there is slight corrosion and scaling phenomenon inside.According to possessing the water yield 3% adds circulation water for heating
Supermolecule nursing agent, dosage is 12m, and within 4 days, Posterior circle water is translucent dark brown, is not required to change water dosing, allows medicament with following
Ring water continues to run with.Medicament forms one layer of form compact and stable Supermolecular film in metal surface according to supramolecular self assembly effect,
Assembling during film forming, can be by the rusty stain of metal surface, incrustation scale, calcium dirt etc. is broken to be dissipated, dissolve, simultaneously because Supermolecular film
According to dirty effect, can effectively stop dirt adhere to, protect metal not to be corroded, be not required to individually carry out blowdown, make circulation water for heating
Reach almost zero burn into zero fouling, zero blowdown.
Last it is noted that above example is only in order to illustrate technical scheme, it is not intended to limit;Although
With reference to previous embodiment, the present invention is described in detail, it will be understood by those within the art that: it still may be used
So that the technical scheme described in foregoing embodiments to be modified, or wherein portion of techniques feature is carried out equivalent;
And these amendment or replace, do not make appropriate technical solution essence depart from various embodiments of the present invention technical scheme spirit and
Scope.