CN106175346A - A kind of heat storing and heat preserving water tumbler - Google Patents

A kind of heat storing and heat preserving water tumbler Download PDF

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Publication number
CN106175346A
CN106175346A CN201610601363.XA CN201610601363A CN106175346A CN 106175346 A CN106175346 A CN 106175346A CN 201610601363 A CN201610601363 A CN 201610601363A CN 106175346 A CN106175346 A CN 106175346A
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CN
China
Prior art keywords
heat
water
water tumbler
cup
wall
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Application number
CN201610601363.XA
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Chinese (zh)
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CN106175346B (en
Inventor
胡军
王祯
王甜甜
何世军
郑茂盛
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Northwest University
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Northwest University
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Priority to CN201610601363.XA priority Critical patent/CN106175346B/en
Publication of CN106175346A publication Critical patent/CN106175346A/en
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Publication of CN106175346B publication Critical patent/CN106175346B/en
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    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/22Drinking vessels or saucers used for table service
    • A47G19/2205Drinking glasses or vessels
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G19/00Table service
    • A47G19/22Drinking vessels or saucers used for table service
    • A47G19/2288Drinking vessels or saucers used for table service with means for keeping liquid cool or hot

Abstract

The invention provides a kind of heat storing and heat preserving water tumbler, including cup, and be spirally connected the bowl cover covered with described cup, described cup includes inner and outer wall, has a mezzanine space between described inwall and described outer wall;Described inwall is stainless steel, and described outer wall is the lucite that heat conductivity is less than 0.2W/ (m.K);It is provided with phase change heat storage material in described mezzanine space.The insulating cup that the present invention provides, simple in construction, easy to use, use the jacket structure of rustless steel and lucite, the two mezzanine space arranges phase change heat storage material, can realize the water in water tumbler is carried out thermostatic control, the temperature retention time making this water water in the cup is greatly prolonged, and during heating, do not have the situation of water temperature over-high, it is finally reached the purpose of long-time temperature control insulation, allows people drink warm water at any time.

Description

A kind of heat storing and heat preserving water tumbler
Technical field
The present invention relates to articles for daily use field, be specifically related to a kind of heat storing and heat preserving water tumbler based on phase change heat storage material.
Background technology
Along with the progress of science and technology, rhythm of life is gradually accelerated, and the time becomes more and more valuable.When people use equipped with boiled water Conventional vacuum cup time, the when of wanting summer to drink water, water temperature is the highest, can find again thermos cup mistake standing time when that winter drinking Long water temperature step-down, water temperature does not always reach the ideal temperature oneself wanted.Conventional vacuum cup is used to wait what boiled water gradually cooled off Process is very long.If the water that conventional vacuum cup dries in the air is the coolest, summer is not bad, and winter can only reheat, and that loses time is same Time again it cannot be guaranteed that drink warm water.At this moment people are just badly in need of a kind of water carrying out temperature control the water tumbler that can be incubated for a long time.Vertical See insulating cup the most on the market and generally utilize insulation material and heat insulation vacuum layer, although this water tumbler has insulation to hot water Effect, but owing to the heat conductivity of material is fixing, heat is always transmitted to mental retardation by high energy in addition, and the lost of its heat is Unidirectional, heat consume is persistently occurring so that it is can not ensure that the temperature stabilization of water water in the cup is at 45-55 DEG C for a long time.Cause This, exploitation one can carry out thermostatically controlled water tumbler to water and be very important.
Summary of the invention
For deficiency of the prior art, the present invention provides a kind of heat storing and heat preserving water tumbler based on phase change heat storage material, should Water tumbler simple in construction, is possible not only to insulation, can also freeze or heats simultaneously, make water tumbler reach well to protect in suitable temperature Temp effect.This is equivalent to enclosing last layer thermal source or low-temperature receiver around the water in water tumbler, and water the most slightly cools off, thermal source around Will provide heat, once water temperature over-high for water, phase change heat storage material around will absorb too high water temperature, finally ensures water Temperature long-time stable in the temperature suitably drunk, allow busy people drink water convenient, it is not necessary to because the discomfort of water temperature And it is worried.
The heat storing and heat preserving water tumbler that the present invention provides, including cup, and is spirally connected the bowl cover covered with described cup, its feature Being, described cup includes inner and outer wall, has a mezzanine space, described inwall and institute between described inwall and described outer wall State outer wall in top sealing engagement;
Described inwall is stainless steel, and described outer wall is the lucite that heat conductivity is less than 0.2W/ (m.K);Described Phase change heat storage material it is provided with in mezzanine space.
Preferably, the main component of described phase change heat storage material is Na2S2O3.5H2O crystal.
It is highly preferred that described phase change heat storage material is by Na2S2O3.5H2O crystal, nucleator and thickening agent composition, Qi Zhongcheng The addition of core agent is Na2S2O3.5H2The 0.5-2% of O crystal mass, the addition of described thickening agent is Na2S2O3.5H2O crystal The 4-5% of quality.
It is highly preferred that described nucleator is MgCl2.6H2O crystal, described thickening agent is carboxymethyl cellulose.
Preferably, the heat conductivity of described lucite is 0.1-0.18W/ (m.K).
Aluminium foil is posted in the outer wall side being preferably located in described mezzanine space, and described aluminium foil inside face is silver color, outside Face is black.
Preferably, the thickness of described mezzanine space is 6mm-8mm.
Preferably, the addition of described phase change heat storage material is 700-740g:1000mL with the proportionate relationship of cup volume.
Preferably, described outer wall is all or local carries out frosted process.
The heat storing and heat preserving water tumbler that the present invention provides has the advantages that
(1) simple in construction, easy to use, use the jacket structure of rustless steel and lucite, the two mezzanine space sets Put phase change heat storage material, can realize the water in water tumbler is carried out thermostatic control, make the temperature retention time of this water water in the cup be greatly prolonged, And during heating, do not have the situation of water temperature over-high, it is finally reached the purpose of long-time temperature control insulation, allows people drink temperature at any time Water;
(2) to compare plastic material drinking-water safer for rustless steel, and this kind of accumulation of heat water tumbler is applicable to various crowd, is also simultaneously Drink water and save the plenty of time;
(3) suit processing, one layer of minimizing difficulty of processing of one layer of set, processing simplicity are used;
(4) water tumbler outer wall (lucite) surface is carried out all or local frosted processes, and prevents hands from slipping out.
Accompanying drawing explanation
The sectional view of a kind of heat storing and heat preserving water tumbler that Fig. 1 provides for the embodiment of the present invention;
Detailed description of the invention
In order to make those skilled in the art be more fully understood that, technical scheme can be practiced, below in conjunction with specifically The invention will be further described for embodiment, but illustrated embodiment is not as a limitation of the invention.
A kind of heat storing and heat preserving water tumbler, concrete as it is shown in figure 1, include cup, and the bowl cover covered that is spirally connected with cup, cup Including inwall 101 and outer wall 102, there is between inwall 101 and outer wall 102 mezzanine space;Inwall 101 is stainless steel, Outer wall 102 is less than the lucite of 0.2W/ (m.K) for heat conductivity;Phase change heat storage material 103 it is provided with in described mezzanine space, Inwall 101 and outer wall 102 carry out jacket layer sealing, sealing engagement at top lucite.
Preferably, the main component of above-mentioned phase change heat storage material 103 is Na2S2O3.5H2O crystal, specifically by Na2S2O3.5H2O crystal, nucleator and thickening agent composition, wherein the addition of nucleator is Na2S2O3.5H2O crystal mass 0.5-2%, the addition of thickening agent is Na2S2O3.5H2The 4-5% of O crystal mass.
Preferably, above-mentioned nucleator is MgCl2.6H2O crystal, thickening agent is carboxymethyl cellulose.
Above-mentioned heat storing and heat preserving water tumbler uses the jacket structure of rustless steel inwall 101 and lucite outer wall 102, and its interlayer is empty The above-mentioned phase change heat storage material 103 of interior placement.Wherein Na2S2O3.5H2O crystal is the main of inorganic hydrous salt phase transition heat-storing material Composition, inorganic hydrous salt phase transition material has bigger heat of fusion and fixing fusing point (really inorganic hydrated salt abjection knot The temperature of brilliant water), the water of crystallization of abjection makes salt melt and absorb heat, and inverse process occurs during cooling, absorb aqueous water and heat release again Generate inorganic hydrated salt structure.Wherein Na2S2O3.5H2The melting temperature of O crystal is 48 DEG C, when the temperature of water water in the cup is more than 48 DEG C time, too high water temperature can be by Na2S2O3.5H2O absorption of crystal, abjection water of crystallization is melted for Na by this crystal2S2O3And aqueous water And then the heat of storage 201kJ/kg, now water of crystallization becomes aqueous water and forms colloid with carboxymethyl cellulose;When water temperature is low In 48 DEG C time, the aqueous water being stored in colloid and Na2S2O3Contact, regenerates Na2S2O3.5H2O crystal.Now, phase transformation Heat-storing material 103 will release substantial amounts of heat, it is achieved the heating to water, but liberated heat will not make water temperature more than 48 DEG C, because of For Na2S2O3.5H2The fusing point of O is 48 DEG C, and more than 48 DEG C, it will no longer undergo phase transition, also will not neither endothermic nor exothermic, final long time Between by water temperature protect at 48 DEG C.It addition, Na2S2O3.5H2In O crystal, the effect of the carboxymethyl cellulose of mixing 4-5% acts as Anti-phase separation agent, in order to will not be at Na2S2O3.5H2O occurs to generate other hydrates when melting or synthesize, and causes Na2S2O3.5H2O crystal can not recycle, and makes the consequence that the heat storage performance of this hydrate declines;Mixing 0.5-2%'s MgCl2.6H2O, as nucleator, prevents to occur to melt or solidification theoretical temperatures 48 DEG C during variations in temperature, occurs supercool existing As, and then cause heat storage performance to decline.
Concrete, for Na in phase change heat storage material2S2O3.5H2The consumption of O quartz crystal, and inwall 101 and outer wall The thickness of the mezzanine space between 102, is specifically calculated as follows:
(1) if this insulating cup is used for lower the temperature (being down to 55 DEG C from 90 DEG C), it is calculated as follows:
Q=cm △ t, wherein Q is up or reduces water temperature institute calorific requirement;C is that specific heat of water holds, about 4.2kJ/ (kg.K);M is quality;△ t is temperature variation.
M=ρ V, wherein m is quality;ρ is the density of water, about 1kg/L;V1It it is the volume of water;
Assume that this water tumbler capacity is V1=500mL, the water temperature poured into is 90 DEG C, calculates through above formula:
The quality of 500mL water is m1=0.5L × 1kg/L=0.5kg
Q=4.2kJ/ (kg.K) × 0.5kg × (90-55)=73.5kJ
And Na2S2O3.5H2The melting energy of O crystal is 201kJ/kg
Then it is reduced to suitable water temperature from water temperature and needs m2=73.5kJ/201kJ/kg=0.366kg's Na2S2O3.5H2O crystal.
Due to known Na2S2O3.5H2The density of O crystal is 1.667g/cm3, the therefore volume V of this crystal required2= 366g/1.667g/cm3=220cm3
Assume cup inside radius r1For 3cm, by π r2H=V1Can calculate h=17.68cm, therefore bottle further processing is 18cm is suitable.
By π r2 2h-πr1 2H=V2Can be calculated r2=3.6cm, therefore mezzanine space thickness is processed as 0.6cm.
If this insulating cup is used for heat up (rising to 45 DEG C from 15 DEG C), it is calculated as follows:
Q=4.2kJ/ (kg.K) × 0.5kg × (45-15)=63kJ
Owing to other condition is constant, the energy that the energy needed for simulation intensification calculating is compared needed for simulation cooling calculates is little, Therefore this insulating cup is designed by the crystalline content in above-mentioned (1) and recuperation layer thickness.
To sum up, the Na in mezzanine space2S2O3.5H2O crystalline content is 0.366kg, and inwall 101 (stainless steel layer) with Mezzanine space thickness between outer wall 102 (lucite) is at least 6mm.In order to avoid phase change heat storage material 103 occurs flatulence of heat type Shrinkage phenomenon, mezzanine space thickness adds and is set to 6mm-8mm man-hour.
Only arrange phase change heat storage material 103 at above-mentioned mezzanine space can not well be incubated this as thermal source and will lose this The effect of insulating cup.Therefore, water tumbler cup outer wall 102 uses lucite, and its heat conductivity is the material of 0.18W/ (m.K) Material, its heat conductivity is less than 0.2W/ (m.K), belongs to insulation material.I other words, when the water in cup is heated or cools to 45- When 55 DEG C, this structure can effectively reduce scattering and disappearing of heat.It addition, the lucite outer surface constituting water tumbler outer wall 102 enters Row is all or local frosted processes, and prevents hands from slipping out.
Owing to heat transfer has three kinds of modes: conduction, convection current and radiation, wherein, conduction is present between water and water tumbler, uses Lucite insulation material can effectively hinder the conduction of heat and then effectively be incubated water, other two kinds of heat transfer sides Formula solves the most using the following method: convection current only can be present in the situation that Drinking cup lid is opened, and therefore when water tumbler is opened, heat scatters and disappears It is the fastest, in order to suitable water temperature being preserved the longer time, after having drunk water, bowl cover is covered and i.e. can effectively protect Temperature.Secondly, the hot water in cup outwards can scatter and disappear energy with thermal-radiating form, and the outer wall side at mezzanine space posts one layer of aluminium foil 104, with reflective thermal radiation, the third lost form of heat can be hindered for silver color inside aluminium foil 104, this water tumbler is comprehensive Three kinds of thermaltransmission modes prevent scattering and disappearing and then being incubated water for a long time of hot all approach as far as possible;Outside aluminium foil 104 Side is painted with black, can effectively utilize sunlight to heat the water in this insulating cup.Black aluminium foil 104 absorbs sunlight After heat radiation, transmit heat to mezzanine space both sides, owing to the heat conductivity of lucite is 0.18W/ (m.K), stainless Heat conductivity is 10-30W/ (m.K) scope, heat the having outside water tumbler of the heat radiation about 1.8% that aluminium foil 104 is absorbed Machine glass material slowly runs off, and the heat of remaining 98.2% makes phase change heat storage material 103 undergo phase transition storage heat, for water Water in Bei heating and thermal insulation at any time.When the coolant-temperature gage in water tumbler is higher than 48 DEG C, Na2S2O3.5H2O crystal melts completely, no longer Store heat because of illumination, be the most no longer the water heating in water tumbler, make the water temperature long-time stable in water tumbler at 45-55 DEG C. This structure can effectively prevent cool too fast of thermos cup water in winter.
Cup inwall 101 uses the stainless steel that heat conductivity is higher, and rustless steel contacts with water, and its heat conductivity exists 10-30W/ (m.K) scope, belongs to Heat Conduction Material, can make to carry out between phase change heat storage material 103 and water good heat exchange, During hot water or less to the heat of heat conduction loss during water for cooling, and then realize the storage of efficient heat and release, the most right Water carries out heating or lowering the temperature.Drink safer during additionally water is put in rustless steel, do not worry that plastics make Organic substance molten after being heated In Xie Yushui, cause health safety issues.
This kind of water cup storage hot mode is simple, before using, only solarization meeting or fill with boiled water can need to have in cup under the sun Imitate makes Na2S2O3.5H2Water of crystallization in O material becomes aqueous water, and then aqueous water forms jelly with carboxymethyl cellulose Store energy.Storing heat is also constantly slowly heated water tumbler water temperature, so makes temperature retention time longer and water temperature typically will not surpass Cross the crystallization temperature of this material, i.e. about 45-55 DEG C, allow people can be the most thirsty just drink warm water.When in water tumbler When water cools off, phase change heat storage material layer can re-form Na2S2O3.5H2O crystal releases heat, heats water.Heat accumulation side Formula simplicity and Automatic-heating warm-keeping.
Preferably, in order to preferably realize heat insulation effect, bowl cover uses lucite vacuum structure, prevents heat from bottleneck Scatter and disappear with the form of conduction of heat.
Embodiment described above is only the preferred embodiment lifted by absolutely proving the present invention, and its protection domain does not limits In this.The equivalent that those skilled in the art are made on the basis of the present invention substitutes or conversion, all in the protection of the present invention Within the scope of, protection scope of the present invention is as the criterion with claims.

Claims (9)

1. a heat storing and heat preserving water tumbler, including cup, and is spirally connected the bowl cover covered with described cup, it is characterised in that described Cup includes inwall (101) and outer wall (102), has a mezzanine space between described inwall (101) and described outer wall (102), Described inwall (101) and described outer wall (102) are in top sealing engagement;
Described inwall (101) is stainless steel, and described outer wall (102) is organic glass that heat conductivity is less than 0.2W/ (m.K) Glass;Phase change heat storage material (103) it is provided with in described mezzanine space.
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that described phase change heat storage material (103) main Composition is Na2S2O3.5H2O crystal.
Heat storing and heat preserving water tumbler the most according to claim 2, it is characterised in that described phase change heat storage material (103) by Na2S2O3.5H2O crystal, nucleator and thickening agent composition, wherein the addition of nucleator is Na2S2O3.5H2O crystal mass 0.5-2%, the addition of described thickening agent is Na2S2O3.5H2The 4-5% of O crystal mass.
Heat storing and heat preserving water tumbler the most according to claim 3, it is characterised in that described nucleator is MgCl2.6H2O crystal, institute Stating thickening agent is carboxymethyl cellulose.
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that the heat conductivity of described lucite is 0.1- 0.18W/(m.K)。
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that be positioned at the outer wall of described mezzanine space (102) aluminium foil (104) is posted in side, and described aluminium foil (104) medial surface is silver color, and lateral surface is black.
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that the thickness of described mezzanine space is 6mm-8mm.
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that the interpolation of described phase change heat storage material (103) Amount is 700-740g:1000mL with the proportionate relationship of cup volume.
Heat storing and heat preserving water tumbler the most according to claim 1, it is characterised in that described outer wall (102) is all or local is carried out Frosted processes.
CN201610601363.XA 2016-07-27 2016-07-27 A kind of heat storing and heat preserving cup Expired - Fee Related CN106175346B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106983265A (en) * 2017-04-28 2017-07-28 镇江华源晋昌电器有限公司 A kind of heat storing and heat preserving kettle

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2134801Y (en) * 1992-09-30 1993-06-02 聂金玺 Portable thermos bottle with non-breaking glass liner
US6779679B1 (en) * 2003-05-05 2004-08-24 Thermos L.L.C. Insulated container for a beverage bag
CN201743404U (en) * 2010-08-03 2011-02-16 王旭 Bottle for containing cold and hot water
CN104161430A (en) * 2014-08-13 2014-11-26 天津科技大学 Intelligent temperature control cup
CN104887011A (en) * 2015-05-29 2015-09-09 北京宇田相变储能科技有限公司 Phase transition temperature adjusting system and phase transition temperature adjusting cup
CN105476396A (en) * 2015-12-22 2016-04-13 苏州征之魂专利技术服务有限公司 Water bottle

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2134801Y (en) * 1992-09-30 1993-06-02 聂金玺 Portable thermos bottle with non-breaking glass liner
US6779679B1 (en) * 2003-05-05 2004-08-24 Thermos L.L.C. Insulated container for a beverage bag
CN201743404U (en) * 2010-08-03 2011-02-16 王旭 Bottle for containing cold and hot water
CN104161430A (en) * 2014-08-13 2014-11-26 天津科技大学 Intelligent temperature control cup
CN104887011A (en) * 2015-05-29 2015-09-09 北京宇田相变储能科技有限公司 Phase transition temperature adjusting system and phase transition temperature adjusting cup
CN105476396A (en) * 2015-12-22 2016-04-13 苏州征之魂专利技术服务有限公司 Water bottle

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106983265A (en) * 2017-04-28 2017-07-28 镇江华源晋昌电器有限公司 A kind of heat storing and heat preserving kettle

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