CN106172416B - 一种含藻酸丙二醇酯和哒螨灵的农药组合物 - Google Patents
一种含藻酸丙二醇酯和哒螨灵的农药组合物 Download PDFInfo
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
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Abstract
本发明公开了含藻酸丙二醇酯和哒螨灵的农药组合物，其中，藻酸丙二醇酯和乙螨唑的重量比为1:60‑50:1，优选为1:10。本发明的组合物防治柑橘红蜘蛛效果优异，可以减少用药量，降低成本。
Description
技术领域
本发明属于农药技术领域，具体涉及的是一种含藻酸丙二醇酯和哒螨灵的农药组合物及其应用。
背景技术
藻酸丙二醇酯是一种常用的食品添加剂，对人畜和环境都无害，且其在也上可以作为一种物理作用机理的生物杀虫药物，作用方式为触杀，以其特有的粘性和物理触杀性，快速封闭和堵塞害虫用于呼吸代谢的气孔，阻断害虫的代谢和循环通道，使其窒息死亡，能够有效的防治白粉虱、红蜘蛛、梨木虱、茶小绿叶蝉、蚜虫和稻飞虱等农业上较难防治的害虫。
哒螨灵，又名哒螨酮，速螨酮，哒螨净；英文通用名称为Pyridaben ；化学名称为2-特丁基-5- (4-特丁基苄硫基-4-氯-3 (H)-哒嗪）-3-酮，哒螨灵属杂环类低毒杀虫杀螨剂，杀螨谱广，其触杀性强，无内吸、传导和熏蒸作用，对叶螨、白粉虱的卵、幼螨（虫）、成螨（虫）都有良好的杀灭效果，且药效好，持效期长。
在实际应用过程中，单一活性成分的杀虫剂普遍存在各种缺陷，例如，连续使用一种活性成分容易导致抗药性的产生。而将两种或两种以上的活性成分复配成复合杀虫剂，能够一定程度的克服上述缺点。本申请的发明人意外的发现，将藻酸丙二醇酯和哒螨灵复配能够产生协同增效作用，可提高防效，扩大杀虫谱，同时降低有效成分的用量，进而降低农药用药成本，减少对环境的污染，同时能够延缓害虫抗药性的产生。
发明内容
本发明的目的在于提供一种具有协同增效作用、使用成本低、防效好的含藻酸丙二醇酯的高效杀虫组合物。
为达到上述目的，本发明采用如下技术方案：一种含藻酸丙二醇酯和哒螨灵的农药组合物，其中，藻酸丙二醇酯和哒螨灵的重量比为1：60-50:1，优选为1:10。
进一步的，所述藻酸丙二醇酯和哒螨灵两者占组合物的重量比为1-80%，优选为20-50%。
进一步的，所述组合物可以通过农药制剂加工中常规的方法制备成任意一种剂型，优选为可湿性粉剂、水分散粒剂、水乳剂、悬浮剂、微乳剂、干悬浮剂、可分散油悬浮剂中任一种。
进一步的，所述组合物用于防治农作物上的多种害虫或害螨，优选为白粉虱。
本发明的组合物的使用频率和使用量随农作物、害虫、天气情况变化而又小量变化，可以通过使用适当的剂量达到有效防治的目的。
与现有技术相比，本发明的有益效果在于：与单个活性成分相比，含有两个有效成分的组合物具有明显的增效作用，提高了防治效果；所述的组合物具有双重作用机理，有利于延缓害虫抗药性的产生；本发明的组合物对作物安全、持效性和速效性好。
具体实施方式
一、制剂实施例
1、实施例1：33%藻酸丙二醇酯·哒螨灵水乳剂（10：1）
藻酸丙二醇酯 30%
哒螨灵 3%
环己酮 8%
脂肪醇聚氧乙烯醚 5%
丁醇 2%
丙二醇 0.1%
有机硅酮 0.5%
去离子水 余量
2、实施例2:11%藻酸丙二醇酯·哒螨灵微乳剂（1:10）
藻酸丙二醇酯 1%
哒螨灵 10%
蓖麻油聚氧乙烯醚 6%
异丙醇 4%
环己酮 15%
去离子水 余量
3、实施例3:41%藻酸丙二醇酯·哒螨灵可湿性粉剂（1:40）
藻酸丙二醇酯 1%
哒螨灵 40%
白炭黑 6%
木质素磺酸钠 4%
十二烷基硫酸钠 5%
亚甲基双萘磺酸钠 3%
硅藻土 余量
二、室内毒力测定
室内生物活性测定药剂采用藻酸丙二醇酯和哒螨灵，用溶剂溶解后加入乳化剂，用水稀释到合适的浓度，每个药剂设置5-7个浓度，经过预备试验确定藻酸丙二醇酯和哒螨灵原药及两者不同配比混剂对番茄白粉虱的致死中浓度，通过孙云沛法计算混剂共毒系数（CTC），以此评价供试药剂对试虫的活性，试验结果见表1。
由室内毒力测定可以看出，藻酸丙二醇酯与哒螨灵在1:60-50:1的范围内，共毒系数均大于120，具有增效作用，其中，当藻酸丙二醇酯与哒螨灵为1:10时，共毒系数大于200，协同增效作用最好。
三、田间药效试验
为了更好的验证本发明的实际应用效果，下面采用本发明实施例的药剂，进行对番茄白粉虱的田间药效试验，分别于药后15、30天进行虫口调查，进行防治效果统计，同时观察药剂时否对农作物有药害产生，试验结果见表2。
田间药效试验结果表明，本发明的制剂实施例在用量小于单剂制剂用量的情况下，对番茄白粉虱的防效反而更好，且在用药范围内，未观察到药害产生。
Claims (5)
1.一种农药组合物，其特征在于，活性成分包含藻酸丙二醇酯和哒螨灵，其中，藻酸丙二醇酯和哒螨灵的重量比为1:60-50:1。
2.根据权利要求1所述的农药组合物，其特征在于，所述藻酸丙二醇酯和哒螨灵的重量比为1:10。
3.根据权利要求1或2所述的农药组合物，其特征在于，藻酸丙二醇酯和哒螨灵两者占组合物重量比的1-80%。
4.根据权利要求1或2所述的农药组合物，其特征在于，它的剂型为可湿性粉剂、水分散粒剂、水乳剂、悬浮剂、微乳剂、可分散油悬浮剂中任一种。
5.根据权利要求1-4中任一项权利要求所述的农药组合物用于防治白粉虱的用途。
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| CN201610535493.8A CN106172416B (zh) | 2016-07-08 | 2016-07-08 | 一种含藻酸丙二醇酯和哒螨灵的农药组合物 |
| CN201810536079.8A CN108719302A (zh) | 2016-07-08 | 2016-07-08 | 一种含藻酸丙二醇酯和哒螨灵的农药组合物 |
| CN201810534808.6A CN108925563A (zh) | 2016-07-08 | 2016-07-08 | 一种含藻酸丙二醇酯和哒螨灵的农药组合物 |
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| CN201810534808.6A Division CN108925563A (zh) | 2016-07-08 | 2016-07-08 | 一种含藻酸丙二醇酯和哒螨灵的农药组合物 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1640255A (zh) * | 2004-01-14 | 2005-07-20 | 深圳市诺普信农化有限公司 | 用于防治小菜蛾的具有杀卵作用的化合物 |
| CN103563901A (zh) * | 2012-07-20 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯的高效杀虫组合物 |
| CN103563962A (zh) * | 2012-07-20 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯与新烟碱类的杀虫组合物 |
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| CN108719302A (zh) | 2018-11-02 |
| CN108925563A (zh) | 2018-12-04 |
| CN106172416A (zh) | 2016-12-07 |
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