CN106149984A - A kind of cement tile mixed with modified ballast and preparation method thereof - Google Patents
A kind of cement tile mixed with modified ballast and preparation method thereof Download PDFInfo
- Publication number
- CN106149984A CN106149984A CN201610701154.2A CN201610701154A CN106149984A CN 106149984 A CN106149984 A CN 106149984A CN 201610701154 A CN201610701154 A CN 201610701154A CN 106149984 A CN106149984 A CN 106149984A
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- CN
- China
- Prior art keywords
- parts
- ballast
- cement
- water
- cement tile
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
- E04D1/00—Roof covering by making use of tiles, slates, shingles, or other small roofing elements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
Abstract
The invention discloses a kind of cement tile mixed with modified ballast and preparation method thereof, on the basis of common cement tile raw material, add modified ballast make, made by following raw material: cement, 80～130 parts；Sand, 75～165 parts；Modified ballast, 5～60 parts；Hydrophober, 1～1.6 part；Water, 20～39 parts；Modified ballast preparation method: selecting the fines that particle diameter is 0.16～5.00mm or aggregate chips that stone pit produces during machining rubble, modulus of fineness is 3.2～3.6；Ballast is put in reactor, after being heated with stirring to 60～80 DEG C, adding water, glycerol, vinyltrimethoxy silane, polymethacrylates and solid content while stirring is 46～48wt% styrene-acrylic emulsions, and after temperature rises to 80～90 DEG C, insulated and stirred is reacted 2～4 hours；Every 100 weight portion ballast correspondence water 25～35 parts, glycerol 5～15 parts, vinyltrimethoxy silane 20～30 parts, polymethacrylates 5～15 parts, styrene-acrylic emulsion 20～30 parts；220～260 DEG C are dried 3～5 hours and get final product.Cement tile water absorption rate of the present invention is low, can resist water suction and dehydration repeatedly.
Description
Technical field
The invention belongs to building material field, be specifically related to a kind of cement tile mixed with modified ballast and preparation method thereof.
Background technology
The materials such as tile is important roof waterpoof material, typically burns till with earth, the most useful cement are made, and shape has
Arch, flat or hemicycle tubular etc..Color, based on brick-red and Lycoperdon polymorphum Vitt, is applied to architectural, not only thermal insulation waterproof
And beautiful and clean, ruggedness is high.Cement tile is the tile mainly made using cement as raw material.
The percolation-proof effect of cement tile is the important parameter evaluating cement tile quality.
The environment-friendly cement tile mixed with ballast of Application No. 200910090065.9 and preparation method thereof patent discloses
The manufacture method of a kind of cement tile mixed with modified ballast, this cement tile achieves the recycling of ballast waste material, economic and environment-friendly.But
It is that application process finds, although cement tile water absorption rate≤10% prepared by this patented method, but, 200 suction is repeated
After the circulation of water dehydration, its water absorption rate is up to 20% unexpectedly, and percolation-proof effect significantly reduces.
Summary of the invention
It is an object of the invention to provide a kind of cement tile mixed with modified ballast and preparation method thereof.
The above-mentioned purpose of the present invention is achieved by techniques below scheme:
A kind of cement tile mixed with modified ballast, adds modified ballast on the basis of common cement tile raw material and makes, logical
The raw material crossing following weight portion is prepared from: cement, 80～130 parts；Sand, 75～165 parts；Modified ballast, 5～60 parts；Hydrophobic
Agent, 1～1.6 part；Water, 20～39 parts；The preparation method of described modified ballast comprises the steps:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.2～3.6；
Step S2, puts into ballast in reactor, after being heated with stirring to 60～80 DEG C, add while stirring water, glycerol,
Vinyltrimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature rises to 80～90
After DEG C, insulated and stirred is reacted 2～4 hours；Every 100 weight portion ballast correspondences add water 25～35 parts, glycerol 5～15 parts, ethylene
Base trimethoxy silane 20～30 parts, polymethacrylates 5～15 parts, styrene-acrylic emulsion 20～30 parts；
Step S3, dries: 220～260 DEG C of bakings i.e. obtain described modified ballast for 3～5 hours.
Further, the preparation method of described modified ballast comprises the steps:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.4；
Step S2, puts into ballast in reactor, after being heated with stirring to 70 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 85 DEG C
Stirring reaction 3 hours；Every 100 weight portion ballast correspondences add 30 parts of water, glycerol 10 parts, vinyltrimethoxy silane 25
Part, polymethacrylates 10 parts, styrene-acrylic emulsion 25 parts；
Step S3, dries: 240 DEG C of bakings i.e. obtain described modified ballast for 4 hours.
Further, described cement is portland cement or sulphate aluminium cement.
Further, described sand be modulus of fineness be 2.3～3.0, clay content is the natural sand of 0～2.0%.
Further, described hydrophober is calcium stearate or magnesium stearate.
The preparation method of above-mentioned cement tile, comprises the steps:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 6～20MPa, and the pressurization retention time was no less than 2 seconds；
Step S3, after the demoulding, soaks after maintenance 24 hours, trickle or natural curing and get final product in the case of not trickle.
Advantages of the present invention:
The cement tile water absorption rate that the present invention provides is low, can resist water suction and dehydration repeatedly, compared with prior art have prominent
The substantive distinguishing features gone out and significantly progress.
Detailed description of the invention
Further illustrate the essentiality content of the present invention below in conjunction with embodiment, but do not limit the present invention with this and protect model
Enclose.Although the present invention being explained in detail with reference to preferred embodiment, it will be understood by those within the art that, can be right
Technical scheme is modified or equivalent, without deviating from the spirit and scope of technical solution of the present invention.
Embodiment 1: the preparation of cement tile
Parts by weight of raw materials compares:
Cement, 100 parts；Sand, 120 parts；Modified ballast, 30 parts；Hydrophober, 1.3 parts；Water, 30 parts.Described cement is silicic acid
Salt cement, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 2.7, clay content is the natural sand of 1.0%.Described
Hydrophober is calcium stearate, it is possible to use magnesium stearate.
The preparation method of modified ballast:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.4；
Step S2, puts into ballast in reactor, after being heated with stirring to 70 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 85 DEG C
Stirring reaction 3 hours；Every 100 weight portion ballast correspondences add 30 parts of water, glycerol 10 parts, vinyltrimethoxy silane 25
Part, polymethacrylates 10 parts, styrene-acrylic emulsion 25 parts；
Step S3, dries: 240 DEG C of bakings i.e. obtain described modified ballast for 4 hours.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 13MPa, pressurizes 4 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 2: the preparation of cement tile
Parts by weight of raw materials compares:
Cement, 80 parts；Sand, 75 parts；Modified ballast, 5 parts；Hydrophober, 1 part；Water, 20 parts.Described cement is silicate cement
Mud, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 2.3, clay content is the natural sand of 0.Described hydrophober is
Calcium stearate, it is possible to use magnesium stearate.
The preparation method of modified ballast:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.2；
Step S2, puts into ballast in reactor, after being heated with stirring to 60 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 80 DEG C
Stirring reaction 4 hours；Every 100 weight portion ballast correspondences add 25 parts of water, glycerol 5 parts, vinyltrimethoxy silane 20 parts,
Polymethacrylates 5 parts, styrene-acrylic emulsion 20 parts；
Step S3, dries: 220 DEG C of bakings i.e. obtain described modified ballast for 5 hours.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 6MPa, pressurizes 5 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 3: the preparation of cement tile
Parts by weight of raw materials compares:
Cement, 130 parts；Sand, 165 parts；Modified ballast, 60 parts；Hydrophober, 1.6 parts；Water, 39 parts.Described cement is silicic acid
Salt cement, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 3.0, clay content is the natural sand of 2.0%.Described
Hydrophober is calcium stearate, it is possible to use magnesium stearate.
The preparation method of modified ballast:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.6；
Step S2, puts into ballast in reactor, after being heated with stirring to 80 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 90 DEG C
Stirring reaction 2 hours；Every 100 weight portion ballast correspondences add 35 parts of water, glycerol 15 parts, vinyltrimethoxy silane 30
Part, polymethacrylates 15 parts, styrene-acrylic emulsion 30 parts；
Step S3, dries: 260 DEG C of bakings i.e. obtain described modified ballast for 3 hours.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 20MPa, pressurizes 3 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 4: the preparation of cement tile
Parts by weight of raw materials compares:
Cement, 100 parts；Sand, 120 parts；Modified ballast, 25 parts；Hydrophober, 1.3 parts；Water, 30 parts.Described cement is silicic acid
Salt cement, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 2.7, clay content is the natural sand of 1.0%.Described
Hydrophober is calcium stearate, it is possible to use magnesium stearate.
The preparation method of modified ballast:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.4；
Step S2, puts into ballast in reactor, after being heated with stirring to 70 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 85 DEG C
Stirring reaction 3 hours；Every 100 weight portion ballast correspondences add 30 parts of water, glycerol 10 parts, vinyltrimethoxy silane 25
Part, polymethacrylates 10 parts, styrene-acrylic emulsion 25 parts；
Step S3, dries: 240 DEG C of bakings i.e. obtain described modified ballast for 4 hours.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 13MPa, pressurizes 4 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 5: the preparation of cement tile
Parts by weight of raw materials compares:
Cement, 100 parts；Sand, 120 parts；Modified ballast, 35 parts；Hydrophober, 1.3 parts；Water, 30 parts.Described cement is silicic acid
Salt cement, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 2.7, clay content is the natural sand of 1.0%.Described
Hydrophober is calcium stearate, it is possible to use magnesium stearate.
The preparation method of modified ballast:
Step S1, selects ballast: select the particle diameter that produces during machining rubble of stone pit be 0.16～
The fines of 5.00mm or aggregate chips, modulus of fineness is 3.4；
Step S2, puts into ballast in reactor, after being heated with stirring to 70 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, and temperature is incubated after rising to 85 DEG C
Stirring reaction 3 hours；Every 100 weight portion ballast correspondences add 30 parts of water, glycerol 10 parts, vinyltrimethoxy silane 25
Part, polymethacrylates 10 parts, styrene-acrylic emulsion 25 parts；
Step S3, dries: 240 DEG C of bakings i.e. obtain described modified ballast for 4 hours.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 13MPa, pressurizes 4 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 6: comparative example, ballast the most modified (with patented method described in background technology)
Parts by weight of raw materials compares:
Cement, 100 parts；Sand, 120 parts；Ballast, 30 parts；Hydrophober, 1.3 parts；Water, 30 parts.Described cement is silicate cement
Mud, it is possible to use sulphate aluminium cement.Described sand be modulus of fineness be 2.7, clay content is the natural sand of 1.0%.Described hydrophobic
Agent is calcium stearate, it is possible to use magnesium stearate.The particle diameter that ballast selects stone pit to produce during machining rubble is
The fines of 0.16～5.00mm or aggregate chips, modulus of fineness is 3.4.
The preparation method of cement tile:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 13MPa, pressurizes 4 seconds retention times；
Step S3, after the demoulding, maintenance 24 hours immersion, trickle or natural curing and get final product in the case of not trickle.
Embodiment 7: effect example
Right according to the method for testing performance (see patent described in background technology) in " concrete tile " standard JC/T746-2007
The present invention detects mixed with the environment-friendly cement tile of ballast.As a result, the cement tile indices of embodiment 1～6 preparation all accords with
Standardization.
But, the cement tile of embodiment 6 preparation the most repeatedly absorbs water and after dehydration, water absorption rate substantially rises, and result is as follows:
| Water suction and dehydration 200 circulation repeatedly (40 DEG C of drying after wash water, then absorb water and dry again, so circulate) | |
| Embodiment 1 | Water absorption rate is 9.7% |
| Embodiment 6 | Water absorption rate is 21.7%, and tile is backed with the phenomenon that slightly seeps water |
Result shows, the cement tile water absorption rate that the present invention provides is low, can resist water suction and dehydration repeatedly, with prior art phase
The substantive distinguishing features more prominent than having and significantly progress.
The effect of above-described embodiment indicates that the essentiality content of the present invention, but does not limit the protection of the present invention with this
Scope.It will be understood by those within the art that, technical scheme can be modified or equivalent,
Essence and protection domain without deviating from technical solution of the present invention.
Claims (6)
1. mixed with a cement tile for modified ballast, adding modified ballast and make on the basis of common cement tile raw material, it is special
Levy and be, be prepared from by the raw material of following weight portion: cement, 80～130 parts；Sand, 75～165 parts；Modified ballast, 5～
60 parts；Hydrophober, 1～1.6 part；Water, 20～39 parts；The preparation method of described modified ballast comprises the steps:
Step S1, selects ballast: the particle diameter selecting stone pit to produce during machining rubble is 0.16～5.00mm
Fines or aggregate chips, modulus of fineness is 3.2～3.6；
Step S2, puts into ballast in reactor, after being heated with stirring to 60～80 DEG C, adds water, glycerol, ethylene while stirring
Base trimethoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, after temperature rises to 80～90 DEG C
Insulated and stirred is reacted 2～4 hours；Every 100 weight portion ballast correspondences add water 25～35 parts, glycerol 5～15 parts, vinyl three
Methoxy silane 20～30 parts, polymethacrylates 5～15 parts, styrene-acrylic emulsion 20～30 parts；
Step S3, dries: 220～260 DEG C of bakings i.e. obtain described modified ballast for 3～5 hours.
Cement tile the most according to claim 1, it is characterised in that the preparation method of described modified ballast includes walking as follows
Rapid:
Step S1, selects ballast: the particle diameter selecting stone pit to produce during machining rubble is 0.16～5.00mm
Fines or aggregate chips, modulus of fineness is 3.4；
Step S2, puts into ballast in reactor, after being heated with stirring to 70 DEG C, adds water, glycerol, vinyl three while stirring
Methoxy silane, polymethacrylates and solid content are 46～48wt% styrene-acrylic emulsions, temperature rise to 85 DEG C after insulated and stirred
React 3 hours；Every 100 weight portion ballast correspondences are added 30 parts of water, glycerol 10 parts, vinyltrimethoxy silane 25 parts, are gathered
Methacrylate 10 parts, styrene-acrylic emulsion 25 parts；
Step S3, dries: 240 DEG C of bakings i.e. obtain described modified ballast for 4 hours.
Cement tile the most according to claim 1, it is characterised in that: described cement is portland cement or aluminium sulfate water
Mud.
Cement tile the most according to claim 1, it is characterised in that: described sand be modulus of fineness be 2.3～3.0, clay content
It is the natural sand of 0～2.0%.
Cement tile the most according to claim 1, it is characterised in that: described hydrophober is calcium stearate or magnesium stearate.
6. the preparation method of the arbitrary described cement tile of Claims 1 to 5, it is characterised in that comprise the steps:
Step S1, proportioning feeding, is mixed into wet feed by raw material stirring by weight；
Step S2, inserts in mould compressing by wet feed, pressure 6～20MPa, and the pressurization retention time was no less than 2 seconds；
Step S3, after the demoulding, soaks after maintenance 24 hours, trickle or natural curing and get final product in the case of not trickle.
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Applications Claiming Priority (1)
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|---|---|---|---|
| CN201610701154.2A CN106149984B (en) | 2016-08-19 | 2016-08-19 | A kind of cement tile and preparation method thereof mixed with modified ballast |
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| CN106149984A true CN106149984A (en) | 2016-11-23 |
| CN106149984B CN106149984B (en) | 2018-09-14 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2644129B2 (en) * | 1991-12-03 | 1997-08-25 | 株式会社クボタ | Cement roof tile forming method |
| CN101624856A (en) * | 2009-07-27 | 2010-01-13 | 中国建筑材料科学研究总院 | Environmental-friendly cement tile mixed with ballast and preparation method thereof |
| CN101602589B (en) * | 2009-06-30 | 2012-05-23 | 湖北中桥科技有限公司 | Preformed material for post-tensioned prestressing pipeline vacuum grouting or mudjacking and preparation method thereof |
| CN103101105A (en) * | 2012-12-28 | 2013-05-15 | 广东东鹏控股股份有限公司 | Production method of artificial stone |
| CN104261754A (en) * | 2014-08-29 | 2015-01-07 | 明光市第二建筑安装有限责任公司 | Wall thermal insulation material produced by building material waste residue and preparation method thereof |
| CN104496368A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Production method of waterproof material |
-
2016
- 2016-08-19 CN CN201610701154.2A patent/CN106149984B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2644129B2 (en) * | 1991-12-03 | 1997-08-25 | 株式会社クボタ | Cement roof tile forming method |
| CN101602589B (en) * | 2009-06-30 | 2012-05-23 | 湖北中桥科技有限公司 | Preformed material for post-tensioned prestressing pipeline vacuum grouting or mudjacking and preparation method thereof |
| CN101624856A (en) * | 2009-07-27 | 2010-01-13 | 中国建筑材料科学研究总院 | Environmental-friendly cement tile mixed with ballast and preparation method thereof |
| CN103101105A (en) * | 2012-12-28 | 2013-05-15 | 广东东鹏控股股份有限公司 | Production method of artificial stone |
| CN104261754A (en) * | 2014-08-29 | 2015-01-07 | 明光市第二建筑安装有限责任公司 | Wall thermal insulation material produced by building material waste residue and preparation method thereof |
| CN104496368A (en) * | 2014-12-05 | 2015-04-08 | 江苏格雷特复合材料有限公司 | Production method of waterproof material |
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| CN106149984B (en) | 2018-09-14 |
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Effective date of registration: 20180808 Address after: 362000 431 hillside street, Quangang District, Quanzhou, Fujian Applicant after: Tang Pinge Address before: 314511 Xinzhuang bridge, Xinyi village, Chong Fu town, Tongxiang City, Jiaxing, Zhejiang, China Applicant before: Tongxiang Jiale glass mosaic Co. Ltd. |
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