CN106149465A - A kind of scratch-resistant heat-sensitive paper and manufacture method thereof - Google Patents
A kind of scratch-resistant heat-sensitive paper and manufacture method thereof Download PDFInfo
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- CN106149465A CN106149465A CN201610486764.5A CN201610486764A CN106149465A CN 106149465 A CN106149465 A CN 106149465A CN 201610486764 A CN201610486764 A CN 201610486764A CN 106149465 A CN106149465 A CN 106149465A
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/80—Paper comprising more than one coating
- D21H19/82—Paper comprising more than one coating superposed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/426—Intermediate, backcoat, or covering layers characterised by inorganic compounds, e.g. metals, metal salts, metal complexes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
- B41M5/42—Intermediate, backcoat, or covering layers
- B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
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- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Paper (AREA)
Abstract
The invention discloses a kind of scratch-resistant heat-sensitive paper, described scratch-resistant heat-sensitive paper comprises original paper layer, and at the precoated shet of original paper layer coated thereon, chromonic layer, antiscratch layers and protective layer；The invention provides the manufacture method of a kind of scratch-resistant heat-sensitive paper.The temperature-sensitive paper of the present invention, owing to having antiscratch layers, can not develop the color in the case that external force is swiped repeatedly, will not manifest unwanted picture and text because external force is swiped, thus upset the identification of normal text.
Description
Technical field
The invention belongs to field of papermaking, be specifically related to a kind of scratch-resistant heat-sensitive paper.
Background technology
Recently, the range of temperature-sensitive paper is more and more extensive, and especially day by day flourishing logistic industry, heat-sensitive paper relies on
The advantages such as convenient, fast, utilization rate is high, just progressively substitute NCR, become the main flow in market.Temperature-sensitive mark conventional at present
The quality focus signing paper is usually at print performance, retention, less focuses on the scraping and wiping resistance performance of paper.But as thing
Stream label, the situation that object collides unavoidably in delivery process, rubs, if paper scraping and wiping resistance performance is strong, then can be
Developing the color after being scratched in temperature-sensitive face, picture and text, the situation of bar code information None-identified occurs, affects logistics and normally provide and deliver.
Content of the invention
For solving problem above, the invention discloses a kind of scratch-resistant heat-sensitive paper, can be in external force scraping situation repeatedly
Under do not develop the color, unwanted picture and text will not be manifested because external force is swiped, thus upset the identification of normal text.
The technical solution used in the present invention is: a kind of scratch-resistant heat-sensitive paper, comprises original paper layer, and topcoating on original paper layer
The precoated shet of cloth, chromonic layer, antiscratch layers and protective layer；
Described precoated shet is made up of the raw material of following parts by weight: A filler 100 parts, A adhesive 5～35 parts；
Described chromonic layer is made up of the raw material of following parts by weight: leuco dye 5～10 parts, and 10～40 parts of oxidant is quick
Agent 10～40 parts, lubricant 3～6 parts, A adhesive 4～20 parts, B filler 10～30 parts, polyvinyl alcohol 9～12 parts；
Described antiscratch layers is made up of the raw material of following parts by weight: A filler 100 parts, Petroleum refining thing 100～150 parts,
A adhesive 5～35 parts；
Described protective layer is made up of the raw material of following parts by weight: A filler 100 parts, B adhesive 70～150 parts, bridging agent
10～60 parts, lubricant 10～20 parts.
Described A filler be precipitated calcium carbonate, silica, calcined kaolin, carclazyte, the one in hollow plastic pigment or
Several.
Described B filler is precipitated calcium carbonate, silica, calcined kaolin, carclazyte, titanium dioxide, hollow plastic pigment
In one or more.
Described A adhesive be styrene-butadiene latex, styrene acrylic resin, starch, polyvinyl alcohol, in acrylic resin one
Plant or several.
Described B adhesive is starch, polyvinyl alcohol, one or more in acrylic resin.
Described leuco dye is 2-(2-4-dimethylbenzene amido)-3-methyl-6-lignocaine fluorane.
Described oxidant be bisphenol-A, 4,4 '-dihydroxydiphenylsulisomer, 2, one or more of 4-diphenyl sulfone phenol.
Described sensitizer is 1,2 biphenoxyl ethanes, diphenyl sulphone (DPS), stearic amide, 1,2-bis-(3-methylphenoxy) second
One or more of alkane.
Described lubricant is zinc stearate, calcium stearate, one or more in paraffin.
Described Petroleum refining thing is polyolefin dispersion, at least one in paraffin wax emulsions.
Described bridging agent is zirconium carbonate ammonium, the one in epoxideamides.
Described precoated shet coating weight is 4～15g/m2；
Described chromonic layer coating weight is 1～5g/m2；
Described antiscratch layers coating weight is 1～3g/m2；
Described protective layer coating weight is 1～3g/m2。
The present invention also provides the manufacture method of a kind of scratch-resistant heat-sensitive paper, and its step is as follows:
(1) formulation components of precoated shet and preparation method:
A filler 100 parts, A adhesive 5～35 parts, be mixed into the coating fluid of 30～40% solid contents under high velocity agitation；With
Coating machine is applied on original paper layer, and coating weight is 5～15g/m2；
Described A filler is the one or several of precipitated calcium carbonate, silica, calcined kaolin, carclazyte, hollow plastic pigment
Kind；
Described A adhesive be styrene-butadiene latex, styrene acrylic resin, starch, polyvinyl alcohol, the one of acrylic resin
Plant or several；
(2) formulation components of chromonic layer and preparation method:
Component A: 40 parts of oxidant, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 40%～50% concentration, wet
The mixed liquor of formula grinding machine for grinding to 0.3～1.5 micron；
B component: sensitizer 40 parts, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 35%～45% concentration, wet
The mixed liquor of formula grinding machine for grinding to 0.2～1.7 micron；
Component C: leuco dye 40 parts, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 42%～47% concentration,
Controlling wet-type finishing machine is ground to the mixed liquor of 0.3～1.5 micron；
B filler 10～30 parts, component A absolute dry mass 10～40 parts, B component absolute dry mass 10～40 parts, component C over dry matter
Measuring 5～10 parts, lubricant 3～6 parts, A adhesive 4～20 parts, bridging agent 2～8 parts is mixed into 20～40% under high velocity agitation
The coating fluid of solid content.Be applied to the precoating face of precoating paper with coating machine, coating weight is 2～5g/m2；
(3) formulation components of antiscratch layers and preparation method:
A filler 100 parts, Petroleum refining thing 100～150 parts, A adhesive 5～35 parts, it is mixed into 30 under high velocity agitation～
The coating fluid of 40% solid content；Being applied on heat-sensitive layer with coating machine, coating weight is 1～3g/m2；
(4) protective layer formulation components and preparation method: A filler 100 parts, B adhesive 70～150 parts, bridging agent
10～60 parts, lubricant 10～20 parts；It is mixed into the coating fluid of 15～30% solid contents under high velocity agitation, be applied to coating machine
On antiscratch layers, coating weight is 1～3g/m2。
The present invention adds an antiscratch layers than common heat-sensitive paper, and it realizes scratch resistance by adding Petroleum refining thing
Energy.The effect of precoated shet is to cover body paper face, and the face to improve paper is felt, and provides certain effect of heat insulation simultaneously, beats at back segment
As far as possible the energy that printhead provides is rested on chromonic layer during print, improve effect of chromonic layer.The effect of chromonic layer is to beat
Under the energy that print head provides, oxidation reaction occurring, leuco dye is converted into black, provides graph of a correspondence or literary composition on paper
Word.
The temperature-sensitive paper of the present invention, owing to having antiscratch layers, can not develop the color, no in the case that external force is swiped repeatedly
Unwanted picture and text can be manifested because external force is swiped, thus upset the identification of normal text.
Brief description
Fig. 1 is present configuration schematic diagram.
Detailed description of the invention
Following example are used for illustrating the present invention, but should not be taken to limit the scope of the present invention.
Embodiment 1
A kind of scratch-resistant heat-sensitive paper, its manufacturing step is as follows:
(1) formulation components of precoated shet and preparation method:
Precipitated calcium carbonate 100 parts, styrene-butadiene latex 20 parts, be mixed into the coating fluid of 30% solid content under high velocity agitation；With
Coating machine is applied on original paper layer, and coating weight is 9g/m2；
(2) formulation components of chromonic layer and preparation method:
Component A: oxidant bisphenol-A 40 parts, polyvinyl alcohol 3 parts, is hybridly prepared into the mixed liquor of 40% concentration, in wet type
The mixed liquor of grinding machine for grinding to 0.3～1.5 micron；
B component: sensitizer 1,2 biphenoxyl ethanes 40 parts, polyvinyl alcohol 3 parts, it is hybridly prepared into the mixing of 35% concentration
Liquid, is ground to the mixed liquor of 0.2～1.7 micron in controlling wet-type finishing machine；
Component C: leuco dye 2-(2-4-dimethylbenzene amido)-3-methyl-6-lignocaine fluorane 40 parts, polyvinyl alcohol 3
Part, it is hybridly prepared into the mixed liquor of 42% concentration, controlling wet-type finishing machine is ground to the mixed liquor of 0.3～1.5 micron；
B filler-silicon dioxide, calcined kaolin totally 30 parts, above-mentioned component A absolute dry mass 40 parts, above-mentioned B component over dry matter
Measure 30 parts, above-mentioned component C absolute dry mass 5 parts, 3 parts of lubricant stearic acid zinc, A adhesive 20 parts, bridging agent zirconium carbonate ammonium 8 parts exists
It is mixed into the coating fluid of 20% solid content under high-speed stirred.Be applied to the precoating face of precoating paper with coating machine, coating weight is 5g/m2；
(3) formulation components of antiscratch layers and preparation method:
A filler calcined kaolin 100 parts, Petroleum refining thing polyolefin dispersion 100 parts, A adhesive styrene-butadiene latex 25 parts,
It is mixed into the coating fluid of 30% solid content under high velocity agitation；Being applied on heat-sensitive layer with coating machine, coating weight is 2g/m2；
(4) protective layer formulation components and preparation method: A filler precipitated calcium carbonate 100 parts, B adhesive polyethylene
Alcohol 100 parts, bridging agent zirconium carbonate ammonium 30 parts, 20 parts of lubricant stearic acid zinc；It is mixed into 30% solid content under high velocity agitation
Coating fluid, is applied on antiscratch layers by coating machine, and coating weight is 2g/m2。
Embodiment 2
A kind of manufacture method of scratch-resistant heat-sensitive paper, its step is as follows:
(1) formulation components of precoated shet and preparation method:
A filler-silicon dioxide, calcined kaolin 100 parts, A adhesive styrene acrylic resin 25 parts, in high-speed stirred
Under be mixed into the coating fluid of 40% solid content；Being applied on original paper layer with coating machine, coating weight is 9g/m2；
(2) formulation components of chromonic layer and preparation method:
Component A: oxidant 4,4 '-dihydroxydiphenylsulisomer 40 parts, polyvinyl alcohol 4 parts, it is hybridly prepared into the mixed of 50% concentration
Close liquid, controlling wet-type finishing machine is ground to the mixed liquor of 0.3～1.5 micron；
B component: sensitizer diphenyl sulphone (DPS) 40 parts, polyvinyl alcohol 4 parts, is hybridly prepared into the mixed liquor of 45% concentration, in wet type
The mixed liquor of grinding machine for grinding to 0.2～1.7 micron；
Component C: leuco dye 40 parts, polyvinyl alcohol 4 parts, is hybridly prepared into the mixed liquor of 47% concentration, in wet lapping
Machine is ground to the mixed liquor of 0.3～1.5 micron；
B filler precipitated calcium carbonate 30 parts, above-mentioned component A absolute dry mass 10 parts, above-mentioned B component absolute dry mass 10 parts, above-mentioned C
Component absolute dry mass 10 parts, lubricant stearic acid calcium 3 parts, A adhesive starch 6 parts, bridging agent epoxideamides 5 parts is in high-speed stirred
Under be mixed into the coating fluid of 40% solid content.Be applied to the precoating face of precoating paper with coating machine, coating weight is 5g/m2；
(3) formulation components of antiscratch layers and preparation method:
A filler-silicon dioxide, calcined kaolin 100 parts, Petroleum refining thing paraffin wax emulsions 120 parts, A adhesive styrene-butadiene latex
It 20 parts, is mixed into the coating fluid of 40% solid content under high velocity agitation；Being applied on heat-sensitive layer with coating machine, coating weight is 3g/m2；
(4) protective layer formulation components and preparation method: A filler precipitated calcium carbonate 100 parts, B adhesive acrylic acid
Resin 100 parts, bridging agent epoxideamides 30 parts, 20 parts of lubricant paraffin；It is mixed into the painting of 30% solid content under high velocity agitation
Cloth liquid, is applied on antiscratch layers by coating machine, and coating weight is 3g/m2。
Comparative example
The preparation of common heat-sensitive paper:
The formula of priming coat: filler 100 parts, adhesive 20 parts, coating weight 9g/m2
The formula of chromonic layer: filler 30 parts, 10 parts of oxidant, sensitizer are 10 parts, adhesive 6 parts, lubricant 3 parts, nothing
Look dyestuff 5 parts, coating weight 5g/m2
The formula of protective layer: filler 100 parts, adhesive 100 parts, bridging agent 30 parts, lubricant 20 parts, coating weight 2g/m2
Embodiment the 1st, 2 and the scratch-resistant heat-sensitive paper performance parameter of comparative example as follows.
Table 1 particular product performance parameters contrasts
| Performance comparison | Example 1 | Example 2 | Comparative example |
| Smoothness (color development face) | 2000 | 2000 | 1800 |
| Print density | 1.39 | 1.37 | 1.4 |
| Oil resistant 24h color development storage rate | 84% | 84% | 85% |
| Water-fast 24h color development storage rate | 83% | 82% | 80% |
| Resistance to plastic 24h color development storage rate | 94% | 93% | 95% |
| Swiped paper by nail | Coating not color development | Coating not color development | Coating color development |
From table 1, the present invention is in the common temperature-sensitive of the aspects such as smoothness, print density, color development storage rate and comparative example
Low being more or less the same, then demonstrating superiority in terms of scratch-resistant, the embodiment of the present invention is with after nail scraping paper, and coating is not sent out
Look, does not interferes with the identification of normal text.
More than for the description to the embodiment of the present invention, by the described above to the disclosed embodiments, make this area special
Industry technical staff is capable of or uses the present invention.Those skilled in the art are come by the multiple modifications to these embodiments
Saying and will be apparent from, generic principles defined herein can be in the situation without departing from the spirit or scope of the present invention
Under, realize in other embodiments.Therefore, the present invention is not intended to be limited to the embodiments shown herein, and is intended to symbol
Close the wide scope consistent with principles disclosed herein and features of novelty.
Claims (8)
1. a scratch-resistant heat-sensitive paper, it is characterised in that described scratch-resistant heat-sensitive paper comprises original paper layer, and on original paper layer
The precoated shet of coating, chromonic layer, antiscratch layers and protective layer；
Described precoated shet is made up of the raw material of following parts by weight: A filler 100 parts, A adhesive 5～35 parts；
Described chromonic layer is made up of the raw material of following parts by weight: leuco dye 5～40 parts, 10～40 parts of oxidant, sensitizer
10～40 parts, lubricant 3～6 parts, A adhesive 4～20 parts, B filler 10～30 parts, polyvinyl alcohol 9～12 parts, bridging agent 2～8
Part；
Described antiscratch layers is made up of the raw material of following parts by weight: A filler 100 parts, Petroleum refining thing 100～150 parts, A glue
Glutinous agent 5～35 parts；
Described protective layer is made up of the raw material of following parts by weight: A filler 100 parts, B adhesive 70～150 parts, bridging agent 10～
60 parts, lubricant 10～20 parts；
Described A filler is precipitated calcium carbonate, silica, calcined kaolin, carclazyte, the one or several in hollow plastic pigment
Kind；
Described B filler be precipitated calcium carbonate, silica, calcined kaolin, carclazyte, titanium dioxide, in hollow plastic pigment
One or more；
Described A adhesive be styrene-butadiene latex, styrene acrylic resin, starch, polyvinyl alcohol, the one in acrylic resin or
Several；
Described B adhesive is starch, polyvinyl alcohol, one or more in acrylic resin.
2. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described leuco dye is 2-(2-4-dimethylbenzene
Amido)-3-methyl-6-lignocaine fluorane.
3. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described oxidant be bisphenol-A, 4,4 '-dihydroxy
Base diphenyl sulphone (DPS), 2, one or more of 4-diphenyl sulfone phenol.
4. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described sensitizer is 1,2 biphenoxyl ethanes,
Diphenyl sulphone (DPS), stearic amide, 1, one or more of 2-bis-(3-methylphenoxy) ethane.
5. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described Petroleum refining thing is polyolefin dispersion
At least one in body, paraffin wax emulsions.
6. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described bridging agent is zirconium carbonate ammonium, epoxy acyl
One in amine.
7. scratch-resistant heat-sensitive paper according to claim 1, it is characterised in that described precoated shet coating weight is 4～15g/m2；
Described chromonic layer coating weight is 1～5g/m2；
Described antiscratch layers coating weight is 1～3g/m2；
Described protective layer coating weight is 1～3g/m2。
8. the manufacture method of a scratch-resistant heat-sensitive paper, it is characterised in that the manufacture method step of described scratch-resistant heat-sensitive paper is such as
Under:
(1) formulation components of precoated shet and preparation method:
A filler 100 parts, A adhesive 5～35 parts, be mixed into the coating fluid of 30～40% solid contents under high velocity agitation；With coating
Machine is applied on original paper layer, and coating weight is 5～15g/m2；
Described A filler be precipitated calcium carbonate, silica, calcined kaolin, carclazyte, hollow plastic pigment one or more；
Described A adhesive be styrene-butadiene latex, styrene acrylic resin, starch, polyvinyl alcohol, acrylic resin one or
Several；
(2) formulation components of chromonic layer and preparation method:
Component A: 40 parts of oxidant, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 40%～50% concentration, grinds in wet type
Grinding machine is ground to the mixed liquor of 0.3～1.5 micron；
B component: sensitizer 40 parts, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 35%～45% concentration, grinds in wet type
Grinding machine is ground to the mixed liquor of 0.2～1.7 micron；
Component C: leuco dye 40 parts, polyvinyl alcohol 3～4 parts, is hybridly prepared into the mixed liquor of 42%～47% concentration, in wet type
The mixed liquor of grinding machine for grinding to 0.3～1.5 micron；
B filler 10～30 parts, component A absolute dry mass 10～40 parts, B component absolute dry mass 10～40 parts, component C absolute dry mass 5
～10 parts, lubricant 3～6 parts, A adhesive 4～20 parts, bridging agent 2～8 parts is mixed into 20～40% under high velocity agitation and admittedly contains
The coating fluid of amount, is applied to the precoating face of precoating paper with coating machine, and coating weight is 2～5g/m2；
(3) formulation components of antiscratch layers and preparation method:
A filler 100 parts, Petroleum refining thing 100～150 parts, A adhesive 5～35 parts, be mixed into 30～40% under high velocity agitation
The coating fluid of solid content；Being applied on heat-sensitive layer with coating machine, coating weight is 1～3g/m2；
(4) formulation components of protective layer and preparation method: A filler 100 parts, B adhesive 70～150 parts, bridging agent 10～60
Part, lubricant 10～20 parts；It is mixed into the coating fluid of 15～30% solid contents under high velocity agitation, be applied to Anti-scratching with coating machine
On layer, coating weight is 1～3g/m2。
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| CN201610486764.5A CN106149465A (en) | 2016-06-28 | 2016-06-28 | A kind of scratch-resistant heat-sensitive paper and manufacture method thereof |
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Cited By (6)
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|---|---|---|---|---|
| CN108284677A (en) * | 2018-01-22 | 2018-07-17 | 河南卓立膜材料股份有限公司 | Thermosensitive recording composite material and production process thereof |
| CN109937143A (en) * | 2017-01-17 | 2019-06-25 | 惠普发展公司，有限责任合伙企业 | Printable media |
| CN110903716A (en) * | 2019-11-29 | 2020-03-24 | 广东简彩纸业科技有限公司 | Three-proofing thermal sensitive paper and manufacturing process thereof |
| CN111335075A (en) * | 2018-12-19 | 2020-06-26 | 金华盛纸业（苏州工业园区）有限公司 | Thermal sensitive paper and preparation method thereof |
| CN112281540A (en) * | 2020-09-11 | 2021-01-29 | 广东维敏特科技有限公司 | Emulsion type coating for thermal sensitive paper and preparation method thereof |
| CN114687244A (en) * | 2020-12-28 | 2022-07-01 | 河南江河纸业股份有限公司 | Thermosensitive engineering drawing and preparation method thereof |
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