CN106148809A - A kind of high-elongation mould steel and preparation method thereof - Google Patents

A kind of high-elongation mould steel and preparation method thereof Download PDF

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Publication number
CN106148809A
CN106148809A CN201610486515.6A CN201610486515A CN106148809A CN 106148809 A CN106148809 A CN 106148809A CN 201610486515 A CN201610486515 A CN 201610486515A CN 106148809 A CN106148809 A CN 106148809A
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steel
elongation
mould steel
elongation mould
ferrum
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CN106148809B (en
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王文
唐明奇
谭兆钧
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North China University of Water Resources and Electric Power
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North China University of Water Resources and Electric Power
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/10Cast-iron alloys containing aluminium or silicon
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C37/00Cast-iron alloys
    • C22C37/06Cast-iron alloys containing chromium
    • C22C37/08Cast-iron alloys containing chromium with nickel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Articles (AREA)
  • Heat Treatment Of Steel (AREA)

Abstract

The invention provides a kind of high-elongation mould steel, including: C, Si, Mn, Cr, Mo, W, V, P, S, Cu, Mg, Ti, Sr, Zr, B, Zn, Re, Sn, Pb, Be, Sc, Li, Ni, La, Al, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.This spheroidal graphite cast-iron includes multiple nonmetal, metal and transition metal, the addition of these elements is also worked in coordination, improve the non-oxidizability of compressor of air conditioner cylinder body, corrosion resistance, resistance to abrasion and resistance to compression and shock resistance, thus extend compressor of air conditioner cylinder body service life under bad working environments.

Description

A kind of high-elongation mould steel and preparation method thereof
Technical field
The invention belongs to field of alloy material, particularly to a kind of high-elongation mould steel, further relate to the system of this mould steel Preparation Method.
Background technology
Mould is machinery, electronics, automobile, communication, the fundamental technology equipment of the industrial products such as add some points.Owing to utilizing mould to enter Row machine-shaping has high efficiency and economy, and mould application in materials processing molding industry is the most universal.Make at mould During with, its quality is affected by various factors, such as shape design, crudy, surface disposition, real work ginseng Numbers etc., wherein what impact was maximum is the material used by mould itself.
Alloy grinding tool steel can part be high-elongation mould steel, hot die steel and plastic die steel, wherein high-elongation mould Tool steel is mainly for the manufacture of at ambient temperature by various moulds compressing for metal material.For cold mold material, resistance to Mill performance, impact flexibility, hardness are most important three performance parameter indexs.But, generally for same steel grade, its wearability Energy, impact flexibility and hardness cannot concurrently reach most preferably, often generally yield worst impact flexibility when hardness reaches optimal Performance, and anti-wear performance is affected by hardness and impact flexibility simultaneously, toughness properties then can guarantee that stablizing of wear process Property and safety.
On existing market, most widely used high-elongation die steel material is mainly high carbon and chromium high-elongation mould steel Crl2, Crl2MoV etc., it has higher quenching degree, hardenability, wearability, and high-temperature oxidation resistance is good, therefore as general Type high-elongation die steel material is widely used in manufacturing the cold-working mould of various uses, the most complex-shaped punching concave die, Cold extruding die, roll threading wheel, cold shears cutting knife and fine measuring instrument etc..But, this kind of high-elongation mould steel belongs to ledeburite steel, by Yu Gangzhong contains the carbide formers such as a large amount of Cr, Mo, V, can form a large amount of eutectic carbon in solidification and During Eutectoid Decomposition Compound, the thermoplasticity causing steel is poor, face crack easily occurs in the forging course of processing.Meanwhile, although forged deformation Operation can crush herring-bone form eutectic carbide, but by forging aspect effect, the distribution of carbides in heavy in section steel remains Uneven;Present in steel large particle carbide or distribution of carbides uneven serious time reduce the mechanical property of steel, and lead Causing mould and occur the quality problems such as deformation, cracking in heat treatment process, and increase with forging material size, eutectic carbide is uneven Evenness is the most serious.
Summary of the invention
Goal of the invention: in order to solve the problems referred to above, wearability is good, hardness is high, resistance to punching to it is an object of the invention to provide one Hitting property is good, the high-elongation mould steel of length in service life and preparation method thereof.
Technical scheme: a kind of high-elongation mould steel that the present invention provides, including the component of following percentage by weight: C 3.6-4.1%, Si 3.7-4.6%, Mn 0.86-0.92%, Cr 10.2-10.8%, Mo 0.61-0.72%, W 1.91- 2.06%, V 1.67-1.76%, P 0.05-0.10%, S 0.01-0.03%, Cu 0.46-0.53%, Mg 0.50- 0.62%, Ti 0.21-0.34%, Sr 0.52-0.81%, B 0.61-0.73%, Zn 0.64-0.72%, Re 0.21- 0.29%, Pb 0.57-0.63%, Be 0.02-0.07%, Sc 0.26-0.34%, Ni 0.50-0.57%, La 0.01- 0.03%, Al 0.20-0.30%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
As preferably, including the component of following percentage by weight: C 3.8-4.0%, Si 4.0-4.3%, Mn 0.88- 0.90%, Cr 10.4-10.6%, Mo 0.66-0.68%, W 1.94-1.96%, V 1.70-1.72%, P 0.07- 0.09%, S 0.01-0.03%, Cu 0.48-0.50%, Mg 0.55-0.57%, Ti 0.27-0.29%, Sr 0.66- 0.70%, B 0.64-0.66%, Zn 0.66-0.68%, Re 0.23-0.25%, Pb 0.59-0.61%, Be 0.03- 0.05%, Sc 0.28-0.30%, Ni 0.53-0.55%, La 0.01-0.03%, Al 0.24-0.26%, remaining is ferrum, Each constituent mass percentage ratio sum is 100%.
Preferred, including the component of following percentage by weight: C 3.9%, Si 4.2%, Mn 0.89%, Cr as another kind 10.5%, Mo 0.67%, W 1.95%, V 1.71%, P 0.08%, S 0.02%, Cu 0.49%, Mg 0.56%, Ti 0.28%, Sr 0.68%, B 0.65%, Zn 0.67%, Re 0.24%, Pb 0.60%, Be 0.04%, Sc 0.29%, Ni 0.54%, La 0.02%, Al 0.25%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
Present invention also offers the preparation method of above-mentioned high-elongation mould steel, comprise the following steps:
(1) each raw material is smelted 3-5h, blowing argon gas 1500-1600 DEG C of refine 1-2h of stirring in 1500-1600 DEG C, obtain primary Molten steel;
(2) by primary molten steel vacuum outgas 10-20min under 1500-1600 DEG C of 60-80Pa, high-purity molten steel is obtained;
(3) high-purity molten steel is cast at 1400-1500 DEG C, 800-900 DEG C of annealing 8-12h, it is cooled to 400-500 DEG C Rear standing is cooled to room temperature, obtains electroslag bar;
(4) use vacuum consumable remelting furnace to consutrode rod remelting, remelting voltage 60-65V, electric current 10000- 1i000A, obtains steel ingot;
(5) by steel ingot in 800-900 DEG C of cycle annealing 14-18h, 1100-1200 DEG C of forging, forging material is obtained;
(6) material 800-900 DEG C annealing 10-14h will be forged, obtain high-elongation mould steel.
Beneficial effect: the high-elongation mould steel wearability that the present invention provides is good, hardness is high, resistance to impact good, heat treatment Deform little, service life is long.This high-elongation mould steel is applicable to manufacture various high accuracy, long-life cold-working mould, cutlery And measurer, such as thread rolling die, cold extrusion drift, complex-shaped punching concave die, cold extruding die, cylindrical die roll, thread rolling wheel, cold shearing Cutter and fine measuring instrument etc..
The high-elongation mould steel that the present invention provides includes multiple nonmetal, metal and transition metal, these elements Addition and work in coordination, substantially increase the mechanical property of material.This high-elongation mould steel purity is high, quality is good, this Bright by strict various nonmetal, metals and the content of transition metal of controlling, thus improve spheroidal graphite cast-iron intensity and Plasticity.In this high-elongation mould steel, silicone content is higher, enables the crystallization temperature of silicon close to eutectic point, thus can subtract greatly In few alloy, the formation of shrinkage defect, significantly improves the consistency of cast structure, thus further increases the plasticity of cast iron.Should In spheroidal graphite cast-iron, content of strontium is higher, beneficially alloy purification melt, remove the removal of impurity, refinement arborescent structure, hinder recrystallization and crystalline substance Grain length is big, improve alloy heat stability, thus improves intensity and the plasticity of this high-elongation mould steel.
The high-elongation mould steel that the present invention provides is lightweight, quality good, intensity is high, plasticity is high, good flowing properties, preparation Technique is simple, cost is relatively low.
Detailed description of the invention
According to following embodiment, the present invention be may be better understood.But, as it will be easily appreciated by one skilled in the art that reality Execute concrete material proportion, process conditions and result thereof described by example and be merely to illustrate the present invention, and should also will not limit The present invention described in detail in claims processed.
Embodiment 1
High-elongation mould steel, including the component of following percentage by weight: C 3.9%, Si 4.2%, Mn 0.89%, Cr 10.5%, Mo 0.67%, W 1.95%, V 1.71%, P 0.08%, S 0.02%, Cu 0.49%, Mg 0.56%, Ti 0.28%, Sr 0.68%, B 0.65%, Zn 0.67%, Re 0.24%, Pb 0.60%, Be 0.04%, Sc 0.29%, Ni 0.54%, La 0.02%, Al 0.25%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
Present invention also offers the preparation method of above-mentioned high-elongation mould steel, comprise the following steps:
(1) each raw material is smelted 5h, blowing argon gas 1500 DEG C of refine 2h of stirring in 1500 DEG C, obtain primary molten steel;
(2) by primary molten steel vacuum outgas 20min under 1500 DEG C of 80Pa, high-purity molten steel is obtained;
(3) high-purity molten steel is cast at 1400 DEG C, 800 DEG C of annealing 12h, stand after being cooled to 400 DEG C and be cooled to room Temperature, obtains electroslag bar;
(4) use vacuum consumable remelting furnace to consutrode rod remelting, remelting voltage 65V, electric current 11000A, obtain steel ingot;
(5) by steel ingot 800 DEG C of cycle annealing 18h of son, 1100 DEG C of forgings, forging material is obtained;
(6) material 800 DEG C annealing 14h will be forged, obtain high-elongation mould steel.
Embodiment 2
High-elongation mould steel, including the component of following percentage by weight: C 3.8%, Si 4.0%, Mn 0.88%, Cr 10.4%, Mo 0.66%, W 1.96%, V1.72%, P 0.09%, S 0.03%, Cu 0.50%, Mg 0.55%, Ti 0.27%, Sr 0.66%, B 0.64%, Zn 0.66%, Re 0.25%, Pb 0.61%, Be 0.05%, Sc 0.30%, Ni 0.55%, La 0.01%, Al 0.24%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
Present invention also offers the preparation method of above-mentioned high-elongation mould steel, comprise the following steps:
(1) each raw material is smelted 3h, blowing argon gas 1600 DEG C of refine 1h of stirring in 1600 DEG C, obtain primary molten steel;
(2) by primary molten steel vacuum outgas 10min under 1600 DEG C of 60-80Pa, high-purity molten steel is obtained;
(3) high-purity molten steel is cast at 1500 DEG C, 900 DEG C of annealing 8h, stand after being cooled to 500 DEG C and be cooled to room Temperature, obtains electroslag bar;
(4) use vacuum consumable remelting furnace to consutrode rod remelting, remelting voltage 60V, electric current 10000A, obtain steel ingot;
(5) by steel ingot in 900 DEG C of cycle annealing 14h, 1200 DEG C of forgings, forging material is obtained;
(6) material 900 DEG C annealing 10h will be forged, obtain high-elongation mould steel.
Embodiment 3
High-elongation mould steel, including the component of following percentage by weight: C 4.0%, Si 4.3%, Mn 0.90%, Cr 10.6%, Mo 0.68%, W 1.94%, V 1.70%, P 0.07%, S 0.01%, Cu 0.48%, Mg 0.57%, Ti 0.29%, Sr 0.70%, B 0.66%, Zn 0.68%, Re 0.23%, Pb 0.59%, Be 0.03%, Sc 0.28%, Ni 0.53%, La 0.03%, Al 0.26%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
Embodiment 4
High-elongation mould steel, including the component of following percentage by weight: C 3.6%, Si 3.7%, Mn 0.86%, Cr 10.2%, Mo 0.61%, W 2.06%, V 1.76%, P 0.10%, S 0.03%, Cu 0.53%, Mg 0.50%, Ti 0.21%, Sr 0.52%, B 0.61%, Zn 0.64%, Re 0.29%, Pb 0.63%, Be 0.07%, Sc 0.34%, Ni 0.57%, La 0.01%, Al 0.20%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%..
Embodiment 5
Improve as another kind, including the component of following percentage by weight: C 4.1%, Si 4.6%, Mn 0.92%, Cr10.8%, Mo 00.72%, W 1.91%, V 1.67%, P 0.05%, S 0.01%, Cu 0.46%, Mg 0.62%, Ti 0.34%, Sr 0.81%, B 0.73%, Zn 0.72%, Re 0.21%, Pb 0.57%, Be 0.02%, Sc 0.26%, Ni 0.50%, La 0.03%, Al 0.30%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
Embodiment 6
The high-elongation mould steel of embodiment 1 to 5 is cast coupon, measures its mechanical property.
The mechanical property of the high-elongation mould steel coupon of table 1 embodiment 1 to 5
Hardness measurement method: according to GB/T230.1;As seen from the above table, the present invention provide high-elongation mould steel its prolong The rate of stretching is up to more than 14, improves more than 30% than commercially available SKD11.From hardness height, the high-elongation mould steel of the present invention is resistance to Mill property is good.

Claims (4)

1. a high-elongation mould steel, it is characterised in that: include the component of following percentage by weight: C 3.6-4.1%, Si 3.7-4.6%, Mn 0.86-0.92%, Cr 10.2-10.8%, Mo 0.61-0.72%, W 1.91-2.06%, V 1.67- 1.76%, P 0.05-0.10%, S 0.01-0.03%, Cu 0.46-0.53%, Mg 0.50-0.62%, Ti 0.21- 0.34%, Sr 0.52-0.81%, B 0.61-0.73%, Zn 0.64-0.72%, Re 0.21-0.29%, Pb 0.57- 0.63%, Be 0.02-0.07%, Sc 0.26-0.34%, Ni 0.50-0.57%, La 0.01-0.03%, Al 0.20- 0.30%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
A kind of high-elongation mould steel the most according to claim 1, it is characterised in that: include the group of following percentage by weight Part: C 3.8-4.0%, Si 4.0-4.3%, Mn 0.88-0.90%, Cr 10.4-10.6%, Mo 0.66-0.68%, W 1.94-1.96%, V 1.70-1.72%, P 0.07-0.09%, S 0.01-0.03%, Cu 0.48-0.50%, Mg 0.55- 0.57%, Ti 0.27-0.29%, Sr 0.66-0.70%, B 0.64-0.66%, Zn 0.66-0.68%, Re 0.23- 0.25%, Pb 0.59-0.61%, Be 0.03-0.05%, Sc 0.28-0.30%, Ni 0.53-0.55%, La 0.01- 0.03%, Al 0.24-0.26%, remaining is ferrum, and each constituent mass percentage ratio sum is 100%.
A kind of high-elongation mould steel the most according to claim 1, it is characterised in that: include the group of following percentage by weight Part: C 3.9%, Si 4.2%, Mn 0.89%, Cr 10.5%, Mo 0.67%, W 1.95%, V 1.71%, P 0.08%, S 0.02%, Cu 0.49%, Mg 0.56%, Ti 0.28%, Sr 0.68%, B 0.65%, Zn 0.67%, Re 0.24%, Pb 0.60%, Be 0.04%, Sc 0.29%, Ni 0.54%, La 0.02%, Al 0.25%, remaining is ferrum, Each constituent mass percentage ratio sum is 100%.
4. the preparation method of a high-elongation mould steel, it is characterised in that: comprise the following steps:
(1) each raw material is smelted 3-5h, blowing argon gas 1500-1600 DEG C of refine 1-2h of stirring in 1500-1600 DEG C, obtain primary steel Water;
(2) by primary molten steel vacuum outgas 10-20min under 1500-1600 DEG C of 60-80Pa, high-purity molten steel is obtained;
(3) high-purity molten steel is cast at 1400-1500 DEG C, 800-900 DEG C of annealing 8-12h, quiet after being cooled to 400-500 DEG C Put and be cooled to room temperature, obtain electroslag bar;
(4) use vacuum consumable remelting furnace to consutrode rod remelting, remelting voltage 60-65V, electric current 10000-11000A, obtain Steel ingot;
(5) by steel ingot in 800-900 DEG C of cycle annealing 14-18h, 1100-1200 DEG C of forging, forging material is obtained;
(6) material 800-900 DEG C annealing 10-14h will be forged, obtain high-elongation mould steel.
CN201610486515.6A 2016-06-29 2016-06-29 A kind of high-elongation mould steel and preparation method thereof Expired - Fee Related CN106148809B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106756447A (en) * 2016-11-24 2017-05-31 江苏雨燕模塑有限公司 A kind of high-strength durable automobile die material and preparation method thereof
CN111647807A (en) * 2020-05-18 2020-09-11 樟树市兴隆高新材料有限公司 High-alloy die steel and preparation process thereof
CN111647795A (en) * 2020-04-29 2020-09-11 樟树市兴隆高新材料有限公司 Cold-rolled die steel and preparation method thereof

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102978517A (en) * 2012-12-14 2013-03-20 江苏天工工具有限公司 Cold working die steel and preparation method thereof
CN103194685A (en) * 2013-04-02 2013-07-10 安泰科技股份有限公司 Ceramimetallurgical high-wear-resistance high-toughness cold work die steel and preparation method thereof
CN104532135A (en) * 2014-12-24 2015-04-22 河冶科技股份有限公司 Cold work die steel and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102978517A (en) * 2012-12-14 2013-03-20 江苏天工工具有限公司 Cold working die steel and preparation method thereof
CN103194685A (en) * 2013-04-02 2013-07-10 安泰科技股份有限公司 Ceramimetallurgical high-wear-resistance high-toughness cold work die steel and preparation method thereof
CN104532135A (en) * 2014-12-24 2015-04-22 河冶科技股份有限公司 Cold work die steel and preparation method thereof

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106756447A (en) * 2016-11-24 2017-05-31 江苏雨燕模塑有限公司 A kind of high-strength durable automobile die material and preparation method thereof
CN106756447B (en) * 2016-11-24 2018-10-26 江苏雨燕模塑有限公司 A kind of high-strength durable automobile die material and preparation method thereof
CN111647795A (en) * 2020-04-29 2020-09-11 樟树市兴隆高新材料有限公司 Cold-rolled die steel and preparation method thereof
CN111647795B (en) * 2020-04-29 2022-03-04 樟树市兴隆高新材料有限公司 Cold-rolled die steel and preparation method thereof
CN111647807A (en) * 2020-05-18 2020-09-11 樟树市兴隆高新材料有限公司 High-alloy die steel and preparation process thereof
CN111647807B (en) * 2020-05-18 2022-03-04 樟树市兴隆高新材料有限公司 High-alloy die steel and preparation process thereof

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