CN106148777A - The processing method of automobile engine almag - Google Patents

The processing method of automobile engine almag Download PDF

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Publication number
CN106148777A
CN106148777A CN201610867469.4A CN201610867469A CN106148777A CN 106148777 A CN106148777 A CN 106148777A CN 201610867469 A CN201610867469 A CN 201610867469A CN 106148777 A CN106148777 A CN 106148777A
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CN
China
Prior art keywords
almag
processing method
automobile engine
temperature
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610867469.4A
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Chinese (zh)
Inventor
李祥明
田源
李贤良
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Mstar Technology Ltd Liuzhou
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Mstar Technology Ltd Liuzhou
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Priority to CN201610867469.4A priority Critical patent/CN106148777A/en
Publication of CN106148777A publication Critical patent/CN106148777A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • C22C21/06Alloys based on aluminium with magnesium as the next major constituent
    • B22F1/0003
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14Treatment of metallic powder
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/02Making metallic powder or suspensions thereof using physical processes
    • B22F9/04Making metallic powder or suspensions thereof using physical processes starting from solid material, e.g. by crushing, grinding or milling
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/026Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/04Making non-ferrous alloys by powder metallurgy
    • C22C1/0408Light metal alloys
    • C22C1/0416Aluminium-based alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • C22F1/047Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with magnesium as the next major constituent

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Powder Metallurgy (AREA)

Abstract

The processing method that the present invention relates to automobile engine almag, it includes being placed in heating furnace aluminum shot, and aluminum shot adds magnesium grain after dissolving and stannum grain carries out melting, until molten clear after drag for clean scum silica frost, obtain aluminium alloy;Aluminium alloy is poured in mould, is subsequently placed in cold water and is cooled to room temperature, obtain alloy pig;Pulverize after alloy pig is lathed fines, obtain alloyed powder;Above-mentioned alloyed powder is placed in extrusion die, more extruded by extruder, obtain alloy material, then be sintered and heat treatment;Then the material after heat treatment is become with liquid mixing metal powder slurry;Again slurry is made metal dust by sponging granulator.The invention can ensure that metal is shorter in the hot stage time of staying, alloying element has little time to spread, thus thinning microstructure, reduce segregation, then by extruding and the intensity of Technology for Heating Processing raising material, then metal dust can be prepared by sponging granulator.

Description

The processing method of automobile engine almag
Technical field
The processing method that the present invention relates to automobile engine almag.
Background technology
Aluminium alloy with magnesium as main alloy element has light weight, anti-corrosion good, the feature of easy-formation, moderate strength, extensively General being applied to the vehicles manufactures such as Automobile Plate, oil truck, coal conveyor, boats and ships, manufacturing the vehicles with aluminium alloy can substantially subtract Light dead-weight, raising carrying capacity, minimizing energy resource consumption, be used for automobile engine and change speed gear box at present.Along with the development of society, People require that the vehicles possess higher serviceability and reliability, and this is to the mechanical property of some parts material, molding The combination property such as performance, heat stability it is also proposed higher requirement.As a example by the engine aluminum alloy of automobile, it is desirable to material Performance meet tensile strength 280~350Mpa, yield strength σ 0.2 >=125 Mpa, percentage elongation δ >=26%, with Time material spray paint baking after intensity be not decreased obviously.This just requires that material preserves the highest prolonging in the case of higher-strength Stretch rate, to improve the processability of material, require that material has the highest heat resistance simultaneously, so that the traffic work prepared There is higher security performance.
Summary of the invention
For above-mentioned technical problem, the present invention provides one can prepare intensity height, the preferable al-mg alloy powder of extensibility Processing method.
The technical solution used in the present invention is: the processing method of a kind of automobile engine almag, it includes following Step:
(1) being placed in heating furnace by aluminum shot, aluminum shot adds magnesium grain and stannum grain after dissolving and carries out melting, until molten clear after drag for clean scum silica frost, Obtain aluminium alloy;
(2) aluminium alloy is poured in mould, is subsequently placed in cold water and is cooled to room temperature, obtain alloy pig;
(3) pulverize after alloy pig being lathed fines, obtain alloyed powder;
(4) above-mentioned alloyed powder is placed in extrusion die, more extruded by extruder, obtain alloy material;
(5) more above-mentioned alloy material is sintered and heat treatment;
(6) then by the material after heat treatment and liquid mixing, and add organic bond and stir, be configured to metal powder pulp Material;
(7) again slurry is made metal dust by sponging granulator.
As preferably, in described stannum grain, magnesium grain and aluminum shot, the content of magnesium is 5-12wt%, and the content of stannum is 12 wt %, Surplus is aluminum.
As preferably, described liquid uses distilled water or deionized water, and the mass ratio of alloyed powder and liquid is (2.5 3): 1.
As preferably, described organic bond uses metal granulating agent, and its addition is the 2 4% of alloyed powder quality.
As preferably, described sponging granulator uses centrifugal spraying granulator or press atomization comminutor.
As preferably, the rotating speed of described centrifugal spraying granulator is 5,000 8000 revs/min, the pressure of press atomization comminutor Power is 15 25kg/ cm 2
As preferably, the inlet temperature of described sponging granulator dry air is 250 350 DEG C, outlet temperature is 100 150℃;The flow of dry air is 100 200 Nm3 /h;Charging rate is 10 20 kg/h.
As preferably, extruded carrying out in protective atmosphere, pressure is 1000 1200MPa.
As preferably, during sintering, first sinter 20 30s with the temperature of 280 320 DEG C, then with 500 600 DEG C of temperature Sinter 40 60s, then sinter 20 30s with 650 700 DEG C of temperature.
As preferably, heat treatment uses solid solution, cold pressing deformation and Ageing Treatment successively, and wherein the temperature of solution treatment is 650 700 DEG C, the time is 10 12min;The deflection of colding pressing of deformation process of colding pressing is 30 35%;The temperature of Ageing Treatment is 300 350 DEG C, the time is 2 3h.
As can be known from the above technical solutions, the present invention is poured in mould by aluminium alloy, is subsequently placed in cold water and is cooled to Room temperature, makes aluminium alloy quickly cool down, it is ensured that metal is shorter in the hot stage time of staying, and alloying element has little time diffusion, thus Thinning microstructure, is reduced segregation, is then improved the intensity of material by extruding and Technology for Heating Processing, then can be made by sponging granulator Standby front intensity is higher, the preferable powder of elongation percentage.
Detailed description of the invention
The present invention is described more detail below, and illustrative examples and explanation in this present invention are used for explaining the present invention, But it is not as a limitation of the invention.
The processing method of automobile engine almag, it comprises the following steps:
With aluminum, magnesium, stannum grain as raw material, and by the content of magnesium be 5-12wt%, the content of stannum be 12 wt %, surplus be that aluminum is carried out Dispensing;Then being placed in induction heater by aluminum shot, aluminum shot adds magnesium grain and stannum grain after dissolving and carries out melting, until molten clear after drag for clean Scum silica frost, obtains aluminium alloy;Aluminium alloy is poured in mould, is immediately placed in cold water together with mould and is cooled to room temperature, closed Ingot;Then pulverize after alloy pig being lathed fines, obtain alloyed powder.
Above-mentioned alloyed powder is placed in extrusion die, more extruded by extruder, obtain alloy material;Extruding Cheng Zhong, the metal powder end in mould is in addition to the normal pressure being squeezed machine drift, also by lateral pressure and the friction of mold wall The effect of power;Along with the movement of drift, the powder in mould is progressively compacted, thus is extruded by mould.In order to prevent metal Oxidation, extruded is carried out under protective atmosphere, and pressure uses 1000 1200MPa, so can obtain consistency higher Material, and performance profile is uniform, productivity ratio is high;Then the copper nickel alumin(i)um alloy material of above-mentioned extruded acquisition is sintered, Sintering is carried out in three stages, first sinters 20 30s with the temperature of 280 320 DEG C, then with 500 600 DEG C of temperature sintering 40 60s, then sinter 20 30s with 650 700 DEG C of temperature;First stage belongs to the sintering preparatory stage, for sintering purification further Environment;Second stage, along with the rising of temperature, initially forms sintering neck, and be combined with each other between alloying substance granule, granule table Face oxide generation reduction reaction, thus continue to participate in sintering, intergranular combination encloses space each other;3rd The sintering temperature in stage is higher, and intergranular sintering neck is grown up further, and more granule is merged, and sintered body obtains into one Step is shunk, nodularization, thus intensity and the hardness of material is prepared in raising.
Above-mentioned powdered metallurgical material is carried out heat treatment;Heat treatment uses solid solution, cold pressing deformation and Ageing Treatment successively;Gu The temperature of molten process is 650 700 DEG C, and the time is 10 12min, so can control nickel, the aluminum solid solubility in Copper substrate and Grain size;Solid solubility temperature is too high, can cause coarse grains, reduces alloy strength;Solid solubility temperature is too low, though crystal grain is less, but Follow-up Ageing Treatment can be caused to be difficult to play the effect of reinforced alloys;The deflection of colding pressing of deformation process of colding pressing is 30 35%;Time Effect carries out cold deformation to alloy before processing, and alloy can be made to present the double effects of working hardening and ageing strengthening;At timeliness The temperature of reason is 300 350 DEG C, and the time is 2 3h;Ageing Treatment can separate out the second phase, produces dispersion-strengtherning;Then by alloy Powder and liquid mixing, and add metal granulating agent and stir, it is configured to metal powder slurry;Again slurry is made by centrifugal spray Metal dust prepared by grain machine or press atomization comminutor.
Embodiment 1
Being placed in induction heater by 93wt % aluminum shot, aluminum shot adds 2wt % stannum grain after dissolving and 5wt% magnesium grain carries out melting, treats Molten clear after drag for clean scum silica frost, obtain aluminium alloy;Aluminium alloy is poured in mould, is immediately placed in cold water together with mould and is cooled to room Temperature, obtains alloy pig;Then pulverize after alloy pig being lathed fines, obtain alloyed powder;Alloyed powder is placed in extrusion die In tool, then the pressure extrusion molding by extruder employing 1000MPa, obtain alloy material, then sinter with the temperature of 280 DEG C 30s, then with 500 DEG C of temperature sintering 60s, then with 650 DEG C of temperature sintering 30s;Subsequently with 650 DEG C of solution treatment 12min;Then Colding pressing deformation process, deflection of colding pressing is 30%;Last with 300 DEG C of Ageing Treatment 3h;Then by the material after heat treatment and distillation Water mixes, and the mass ratio of material and distilled water is 2.5:1, and the 2% metal granulating agent adding quality of materials stirs, and joins Make metal powder slurry;Again slurry is carried out pelletize by centrifugal spraying granulator, wherein the entering of sponging granulator dry air Mouthful temperature is 250 DEG C, outlet temperature is 100 DEG C, the flow of dry air is 100 Nm3 / h, charging rate are 10kg/h, from The rotating speed of heart sponging granulator is 5,000 8000 revs/min, thus obtains al-mg alloy powder;This alloy powder is sent out for automobile Tensile strength during motivation parts up to 352Mpa, yield strength reaches 143Mpa, percentage elongation reaches 26.4%.
Embodiment 2
Being placed in induction heater by 89.5wt % aluminum shot, aluminum shot adds 1.5wt % stannum grain after dissolving and 10wt% magnesium grain melts Refining, until molten clear after drag for clean scum silica frost, obtain aluminium alloy;Aluminium alloy is poured in mould, is immediately placed in cold water cold together with mould But to room temperature, alloy pig is obtained;Then pulverize after alloy pig being lathed fines, obtain alloyed powder;Alloyed powder is placed in In extrusion die, then the pressure extrusion molding by extruder employing 1100MPa, obtain alloy material, then with the temperature of 300 DEG C Degree sintering 25s, then with 560 DEG C of temperature sintering 50s, then with 680 DEG C of temperature sintering 25s;Subsequently with 680 DEG C of solution treatment 11min;Then colding pressing deformation process, deflection of colding pressing is 32%;Last with 330 DEG C of Ageing Treatment 2.5h;Then by after heat treatment Material mix with deionized water, and the mass ratio of material and deionized water is 2.8:1, and 3% metal adding quality of materials is made Granule stirs, and is configured to metal powder slurry;Again slurry is carried out pelletize, wherein mist projection granulating by press atomization comminutor The inlet temperature of machine dry air is 300 DEG C, outlet temperature is 130 DEG C, the flow of dry air is 150 Nm3 / h, charging speed Degree is 15 kg/h, and the pressure of press atomization comminutor is 25kg/ cm 2, thus obtain al-mg alloy powder;This alloy powder is used Tensile strength when automotive engine component up to 365Mpa, yield strength reaches 162Mpa, percentage elongation reaches 27.8%.
Embodiment 3
Being placed in induction heater by 87wt % aluminum shot, aluminum shot adds 1wt % stannum grain after dissolving and 12wt% magnesium grain carries out melting, Until molten clear after drag for clean scum silica frost, obtain aluminium alloy;Aluminium alloy is poured in mould, is immediately placed in cold water together with mould and is cooled to Room temperature, obtains alloy pig;Then pulverize after alloy pig being lathed fines, obtain alloyed powder;Alloyed powder is placed in extruding In mould, then the pressure extrusion molding by extruder employing 1200MPa, obtain alloy material, then burn with the temperature of 320 DEG C Knot 20s, then with 600 DEG C of temperature sintering 40s, then with 700 DEG C of temperature sintering 20s;Subsequently with 700 DEG C of solution treatment 10min;Connect Deformation process of colding pressing, deflection of colding pressing is 35%;Last with 350 DEG C of Ageing Treatment 2h;Then the material of heat treatment and deionization Water mixes, and the mass ratio of material and deionized water is 3:1, and the 4% metal granulating agent adding quality of materials stirs, and joins Make metal powder slurry;Again slurry is carried out pelletize by press atomization comminutor, wherein the entering of sponging granulator dry air Mouthful temperature is 350 DEG C, outlet temperature is 150 DEG C, the flow of dry air is 200 Nm3 / h, charging rate are 20 kg/h, pressure The pressure of power sponging granulator is 15kg/ cm 2, thus obtain al-mg alloy powder;This alloy powder is used for automobile engine portion Tensile strength during part up to 351Mpa, yield strength reaches 145Mpa, percentage elongation reaches 26.7%.
The technical scheme provided the embodiment of the present invention above is described in detail, specific case used herein Principle and embodiment to the embodiment of the present invention are set forth, and the explanation of above example is only applicable to help to understand this The principle of inventive embodiments;Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, in specific embodiment party All will change in formula and range of application, in sum, this specification content should not be construed as limitation of the present invention.

Claims (10)

1. the processing method of automobile engine almag, it comprises the following steps:
(1) being placed in heating furnace by aluminum shot, aluminum shot adds magnesium grain and stannum grain after dissolving and carries out melting, until molten clear after drag for clean scum silica frost, Obtain aluminium alloy;
(2) aluminium alloy is poured in mould, is subsequently placed in cold water and is cooled to room temperature, obtain alloy pig;
(3) pulverize after alloy pig being lathed fines, obtain alloyed powder;
(4) above-mentioned alloyed powder is placed in extrusion die, more extruded by extruder, obtain alloy material;
(5) more above-mentioned alloy material is sintered and heat treatment;
(6) then by the material after heat treatment and liquid mixing, and add organic bond and stir, be configured to metal powder pulp Material;
(7) again slurry is made metal dust by sponging granulator.
The processing method of automobile engine almag the most according to claim 1, it is characterised in that: described aluminum shot, magnesium In grain and stannum grain, the content of magnesium is 5-12wt%, and the content of stannum is 12 wt %, and surplus is aluminum.
3. the processing method of automobile engine almag as claimed in claim 1, it is characterised in that: described liquid uses and steams Distilled water or deionized water, and the mass ratio of alloyed powder and liquid is (2.5 3): 1.
4. the processing method of automobile engine almag as claimed in claim 1, it is characterised in that: described organic bond Using metal granulating agent, its addition is the 2 4% of alloyed powder quality.
5. the processing method of automobile engine almag as claimed in claim 1, it is characterised in that: described sponging granulator Use centrifugal spraying granulator or press atomization comminutor.
6. the processing method of automobile engine almag as claimed in claim 5, it is characterised in that: described centrifugal spray is made The rotating speed of grain machine is 5,000 8000 revs/min, and the pressure of press atomization comminutor is 15 25kg/ cm 2
7. the processing method of automobile engine almag as claimed in claim 5, it is characterised in that: described sponging granulator The inlet temperature of dry air is 250 350 DEG C, outlet temperature is 100 150 DEG C;The flow of dry air is 100 200 Nm 3 /h;Charging rate is 10 20 kg/h.
8. the processing method of automobile engine almag as claimed in claim 1, it is characterised in that: extruded in protection Carrying out in atmosphere, pressure is 1000 1200MPa.
9. the processing method of as claimed in claim 1 automobile engine almag, it is characterised in that: during sintering, first with The temperature of 280 320 DEG C sinters 20 30s, then sinters 40 60s with 500 600 DEG C of temperature, then with 650 700 DEG C of temperature Degree sintering 20 30s.
10. the processing method of automobile engine almag as claimed in claim 1, it is characterised in that: heat treatment is adopted successively By solid solution, cold pressing deformation and Ageing Treatment, wherein the temperature of solution treatment is 650 700 DEG C, and the time is 10 12min;Cold pressing The deflection of colding pressing of deformation process is 30 35%;The temperature of Ageing Treatment is 300 350 DEG C, and the time is 2 3h.
CN201610867469.4A 2016-09-30 2016-09-30 The processing method of automobile engine almag Pending CN106148777A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107829003A (en) * 2017-11-09 2018-03-23 北京科技大学 A kind of method that aluminum alloy spare part is prepared using powder metallurgic method
CN115927894A (en) * 2022-12-08 2023-04-07 湖南英捷高科技有限责任公司 Aluminum alloy material for automobile heat dissipation parts and preparation method thereof

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CN103785860A (en) * 2014-01-22 2014-05-14 宁波广博纳米新材料股份有限公司 Metal powder for 3D printer and preparing method thereof
CN104227007A (en) * 2014-09-17 2014-12-24 北京科技大学 Method for preparing aluminum powder and aluminum alloy powder through water atomization

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CN103785860A (en) * 2014-01-22 2014-05-14 宁波广博纳米新材料股份有限公司 Metal powder for 3D printer and preparing method thereof
CN104227007A (en) * 2014-09-17 2014-12-24 北京科技大学 Method for preparing aluminum powder and aluminum alloy powder through water atomization

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107829003A (en) * 2017-11-09 2018-03-23 北京科技大学 A kind of method that aluminum alloy spare part is prepared using powder metallurgic method
CN107829003B (en) * 2017-11-09 2022-11-22 北京科技大学 Method for preparing aluminum alloy parts by adopting powder metallurgy method
CN115927894A (en) * 2022-12-08 2023-04-07 湖南英捷高科技有限责任公司 Aluminum alloy material for automobile heat dissipation parts and preparation method thereof
CN115927894B (en) * 2022-12-08 2024-02-27 湖南英捷高科技有限责任公司 Aluminum alloy material for automobile heat dissipation parts and preparation method thereof

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Application publication date: 20161123