CN106147644B - A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method - Google Patents
A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method Download PDFInfo
- Publication number
- CN106147644B CN106147644B CN201610633466.4A CN201610633466A CN106147644B CN 106147644 B CN106147644 B CN 106147644B CN 201610633466 A CN201610633466 A CN 201610633466A CN 106147644 B CN106147644 B CN 106147644B
- Authority
- CN
- China
- Prior art keywords
- inorganic filler
- adhesive plaster
- filler content
- parts
- surface adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09J161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/21—Paper; Textile fabrics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2400/00—Presence of inorganic and organic materials
- C09J2400/10—Presence of inorganic materials
- C09J2400/14—Glass
- C09J2400/143—Glass in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2461/00—Presence of condensation polymers of aldehydes or ketones
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing methods.Because present invention employs a certain proportion of polyvinyl butyral is added in the epoxy phenolics system of high inorganic filler content to be modified, coordinate suitable mixed glue and photoresist coating process process control again, improve resin system in the adhesive plaster of high inorganic filler content surface makes film property, resin system and the compatibility of inorganic filler.This manufacturing process, which not only ensure that, adds larger amount of inorganic filler in laminate surface adhesive plaster, but also the presentation quality of laminate is made not influenced by inorganic filler.The epoxy glass cloth laminated board surface resin of the high inorganic filler content of surface adhesive plaster compacting prepared by the present invention is full, glossy, color is uniform, solves the bad phenomenons such as poor laminate surface starved air marks, resin plumpness, filler accumulation, uneven color floating.
Description
【Technical field】
The invention belongs to the technical field of insulating materials, be related to a kind of high inorganic filler content laminate surface adhesive plaster and its
Manufacturing method.
【Background technology】
It is filled out with the development of science and technology needing a large amount of functional inorganic is added in more and more epoxy glass cloth laminated boards
Material.When the content of inorganic filler be more than it is a certain amount of when, the mobility of adhesive plaster will be deteriorated thereon.Add according to original glue formula
Surface adhesive plaster is produced after entering a large amount of inorganic filler, the glass cloth laminated board surface of compacting will appear starved air marks, resin is satisfied
The bad phenomenon of full scale difference, so the resin in the adhesive plaster of surface must have certain mobility.But if only merely pass through
The molding time of adjustment surface glue will appear when then suppressing because of resin stream to improve the mobility of resin in surface sizing cloth
Dynamic fast, filler flows slowly, and the filler accumulation, the floating of uneven color that cause laminate surface water ripples shape occur are bad existing
As.
【Invention content】
It is an object of the invention to overcome the above-mentioned prior art, a kind of high inorganic filler content laminate use is provided
Surface adhesive plaster and its manufacturing method, this method use the addition polyvinyl butyral in epoxy resin to be modified, increase
The strong conjugation of inorganic filler and resin, when solving laminate compacting because in the adhesive plaster of surface resin do not flow due to caused by lack
Glue air marks, resin plumpness difference or caused by resin flows filler accumulation, uneven color floating of water ripples shape etc. it is bad
Phenomenon.
To achieve the goals above, the present invention uses is achieved with technical solution below：
A kind of high inorganic filler content laminate manufacturing method of surface adhesive plaster, includes the following steps：
1) 75~85 parts of organic solvent and 15~25 parts of poly- second are sequentially added in a kettle according to mass fraction meter
Enol butyral simultaneously opens stirring, is then slowly warming up to 55 ± 5 DEG C and keeps the temperature, after polyvinyl butyral all dissolving
It is for use using 80 mesh nylon net filters to butvar adhesive liquid；
2) 10.5~13 parts of organic solvent is added and is mixed in glue kettle, 20~25 parts of epoxy resin, stirring is then added
Uniformly；
3) 32~38 parts of phenolic resin, 9~14 parts of butvar adhesive liquid, 17~22 parts of nothing are sequentially added
Machine filler and 0.5~1 part of benzyl dimethylamine continue to stir the obtained mixture A of 0.5h；
If the molding time of mixture A is measured as 120s-200s at a temperature of (160 ± 2) DEG C with the small skill in using a kitchen knife in cookery, it is further continued for stirring
It mixes 1h and surface glue is made；
If the molding time of mixture A, which is measured at a temperature of (160 ± 2) DEG C with the small skill in using a kitchen knife in cookery, is more than 200s, to mixture A
In add suitable benzyl dimethylamine stirring 0.5h, then detect molding time, until reaching 120~200s, be further continued for stirring 1h
Surface glue is made；
If the molding time of mixture A in (160 ± 2) if DEG C at a temperature of with the small skill in using a kitchen knife in cookery measure be less than 120s, add suitable
0.5h is mixed in epoxy resin, phenolic resin, butvar adhesive liquid and the inorganic filler of amount, then detects molding time until reaching
To 120~200s；
4) surface glue immersion coating is made to surface adhesive plaster on glass cloth.
The present invention, which further improves, to be：
In the step 1), organic solvent a and organic solvent b are toluene, methanol, ethyl alcohol, acetone, methyl acetate, acetic acid
The mixture of any one or two kinds or more in ethyl ester.
In the step 2), organic solvent a and organic solvent b are toluene, methanol, ethyl alcohol, acetone, methyl acetate, acetic acid
The mixture of any one or two kinds or more in ethyl ester.
In the step 1), the acid value of polyvinyl butyral is less than or equal to 0.8mgKOH/g, 20 parts of polyvinyl alcohol contracting fourths
Aldehyde uses 1# flow cup tested viscosities at a temperature of (20 ± 1) DEG C after being dissolved in 80 parts of alcohol solvents be 21~100s.
In the step 2), any one or two kinds or more in epoxy resin E-12, E-20, E-44, E-51
Mixture.
In the step 3), phenolic resin is any one or two kinds in alkalescent phenol resin, acid phenolic resin
Mixture, the wherein amount of solid of phenolic resin are (60 ± 2) %.
In the step 3), inorganic filler is aluminium oxide, aluminium hydroxide, magnesia, magnesium hydroxide, calcium carbonate, titanium dioxide
The mixture of any one or two kinds or more in silicon, titanium dioxide, antimony oxide, di-iron trioxide.
In the step 4), immersion coating is carried out using vertical gluing machine, the oven temperature of vertical gluing machine is 130~
150 DEG C, speed is 5~9m/min.
A kind of high inorganic filler content laminate surface adhesive plaster, surface adhesive plaster glue content 53-56%, soluble resin contain
Measure 85-95%, volatile content<1.0%, fluidity 18-28%.
Compared with prior art, the invention has the advantages that：
Because a certain proportion of poly- present invention employs being added in the epoxy phenolics system of high inorganic filler content
Vinyl butyral is modified, then coordinates suitable mixed glue and photoresist coating process process control, improves high inorganic filler content
Resin system makes film property, resin system and the compatibility of inorganic filler in the adhesive plaster of surface.This manufacturing process both ensure that layer
Larger amount of inorganic filler is added in clamp surface adhesive plaster, and makes the presentation quality of laminate not by the shadow of inorganic filler
It rings.The epoxy glass cloth laminated board surface resin of the high inorganic filler content of adhesive plaster compacting in surface prepared by the present invention is full, has
Gloss, color are uniform, solve poor laminate surface starved air marks, resin plumpness, filler accumulation, uneven color floating etc.
Bad phenomenon.
【Specific implementation mode】
The present invention is described in further detail below：
Embodiment 1
1) butvar adhesive liquid is prepared in a kettle first.
75 parts of solvent a and 25 parts of polyvinyl butyral are sequentially added in a kettle according to mass fraction meter, and
Stirring is started, vapour is then opened and is warming up to (55 ± 5) DEG C, about 8 hours is kept the temperature at such a temperature, waits for that polyvinyl butyral is all molten
It is filtered and packaged after solution for use.
2) and then by formula and defined process surface glue is manufactured.
10.5 parts of solvent b is added according to mass fraction meter and is mixed in glue kettle, 20 parts of epoxy resin is then added, starts
Stirring.
After stir about 0.5h, 38 parts of phenolic resin, 14 parts of butvar adhesive liquid, 17 parts inorganic is added and fills out
Material, 0.5 part of curing accelerator continue to stir 0.5h, and molding time is surveyed in sampling.
It is rear for use to continue stirring 1h or more.
3) glue dipping in surface is finally used to prepare surface adhesive plaster.
Glass cloth is put on by vertical gluing machine operation guide requirement, when oven temperature reaches requirement, glue groove is risen, closes
Upper Extruded roller keeps Extruded roller consistent with the glass cloth direction of motion, scraper is turned over, is tightly attached on Extruded roller, opens adjusting deviation device,
It is allowed to occupy center, opens static eraser, finally start main transmission, adjust glass cloth tension and produced.Adhesive plaster goes out
It should be tested immediately after coming, operator adjusts speed according to test result, and oven temperature not change generally after determining.
Photoresist coating process parameter：130~150 DEG C of oven temperature, speed are 5~9m/min.
Embodiment 2
1) butvar adhesive liquid is prepared in a kettle first.
85 parts of solvent a and 15 parts of polyvinyl butyral are sequentially added in a kettle according to mass fraction meter, and
Stirring is started, vapour is then opened and is warming up to (55 ± 5) DEG C, about 8 hours is kept the temperature at such a temperature, waits for that polyvinyl butyral is all molten
It is filtered and packaged after solution for use.
2) and then by formula and defined process surface glue is manufactured.
10.5 parts of solvent b is added according to mass fraction meter and is mixed in glue kettle, 20 parts of epoxy resin is then added, starts
Stirring.
After stir about 0.5h, 38 parts of phenolic resin, 9 parts of butvar adhesive liquid, 22 parts inorganic is added and fills out
Material, 0.5 part of curing accelerator continue to stir 0.5h, and molding time is surveyed in sampling.
It is rear for use to continue stirring 1h or more.
3) glue dipping in surface is finally used to prepare surface adhesive plaster.
Glass cloth is put on by vertical gluing machine operation guide requirement, when oven temperature reaches requirement, glue groove is risen, closes
Upper Extruded roller keeps Extruded roller consistent with the glass cloth direction of motion, scraper is turned over, is tightly attached on Extruded roller, opens adjusting deviation device,
It is allowed to occupy center, opens static eraser, finally start main transmission, adjust glass cloth tension and produced.Adhesive plaster goes out
It should be tested immediately after coming, operator adjusts speed according to test result, and oven temperature not change generally after determining.
Photoresist coating process parameter：130~150 DEG C of oven temperature, speed are 5~9m/min.
Embodiment 3
1) butvar adhesive liquid is prepared in a kettle first.
75 parts of solvent a and 25 parts of polyvinyl butyral are sequentially added in a kettle according to mass fraction meter, and
Stirring is started, vapour is then opened and is warming up to (55 ± 5) DEG C, about 8 hours is kept the temperature at such a temperature, waits for that polyvinyl butyral is all molten
It is filtered and packaged after solution for use.
2) and then by formula and defined process surface glue is manufactured.
13 parts of solvent b is added according to mass fraction meter and is mixed in glue kettle, 25 parts of epoxy resin is then added, starts to stir
It mixes.
After stir about 0.5h, 32 parts of phenolic resin, 14 parts of butvar adhesive liquid, 17 parts inorganic is added and fills out
Material, 1 part of curing accelerator continue to stir 0.5h, and molding time is surveyed in sampling.
It is rear for use to continue stirring 1h or more.
3) glue dipping in surface is finally used to prepare surface adhesive plaster.
Glass cloth is put on by vertical gluing machine operation guide requirement, when oven temperature reaches requirement, glue groove is risen, closes
Upper Extruded roller keeps Extruded roller consistent with the glass cloth direction of motion, scraper is turned over, is tightly attached on Extruded roller, opens adjusting deviation device,
It is allowed to occupy center, opens static eraser, finally start main transmission, adjust glass cloth tension and produced.Adhesive plaster goes out
It should be tested immediately after coming, operator adjusts speed according to test result, and oven temperature not change generally after determining.
Photoresist coating process parameter：130~150 DEG C of oven temperature, speed are 5~9m/min.
Embodiment 3
1) butvar adhesive liquid is prepared in a kettle first.
85 parts of solvent a and 15 parts of polyvinyl butyral are sequentially added in a kettle according to mass fraction meter, and
Stirring is started, vapour is then opened and is warming up to (55 ± 5) DEG C, about 8 hours is kept the temperature at such a temperature, waits for that polyvinyl butyral is all molten
It is filtered and packaged after solution for use.
2) and then by formula and defined process surface glue is manufactured.
13 parts of solvent b is added according to mass fraction meter and is mixed in glue kettle, 25 parts of epoxy resin is then added, starts to stir
It mixes.
After stir about 0.5h, 32 parts of phenolic resin, 9 parts of butvar adhesive liquid, 22 parts inorganic is added and fills out
Material, 1 part of curing accelerator continue to stir 0.5h, and molding time is surveyed in sampling.
It is rear for use to continue stirring 1h or more.
3) glue dipping in surface is finally used to prepare surface adhesive plaster.
Glass cloth is put on by vertical gluing machine operation guide requirement, when oven temperature reaches requirement, glue groove is risen, closes
Upper Extruded roller keeps Extruded roller consistent with the glass cloth direction of motion, scraper is turned over, is tightly attached on Extruded roller, opens adjusting deviation device,
It is allowed to occupy center, opens static eraser, finally start main transmission, adjust glass cloth tension and produced.Adhesive plaster goes out
It should be tested immediately after coming, operator adjusts speed according to test result, and oven temperature not change generally after determining.
Photoresist coating process parameter：130~150 DEG C of oven temperature, speed are 5~9m/min.
The surface glue that is blended according to embodiment 1, embodiment 2, embodiment 3 and embodiment 4, surface adhesive plaster index
Test and the high inorganic filler content epoxy glass cloth laminated board surface condition such as the following table 1 finally suppressed：
Table 1：Surface glue, surface adhesive plaster index test and the laminate surface situation finally suppressed
The above content is merely illustrative of the invention's technical idea, and protection scope of the present invention cannot be limited with this, every to press
According to technological thought proposed by the present invention, any change done on the basis of technical solution each falls within claims of the present invention
Protection domain within.
Claims (9)
1. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster, which is characterized in that include the following steps：
1) 75~85 parts of organic solvent and 15~25 parts of polyvinyl alcohol are sequentially added in a kettle according to mass fraction meter
Butyral simultaneously opens stirring, is then slowly warming up to 55 ± 5 DEG C and keeps the temperature, and is gathered after polyvinyl butyral all dissolving
Vinyl butyral glue, it is for use using 80 mesh nylon net filters；
2) 10.5~13 parts of organic solvent is added and is mixed in glue kettle, 20~25 parts of epoxy resin is then added, stirs evenly；
3) 32~38 parts of phenolic resin, 9~14 parts of butvar adhesive liquid, 17~22 parts inorganic is sequentially added to fill out
Material and 0.5~1 part of benzyl dimethylamine continue to stir the obtained mixture A of 0.5h；
If the molding time of mixture A is measured as 120s-200s at a temperature of (160 ± 2) DEG C with the small skill in using a kitchen knife in cookery, it is further continued for stirring 1h
Surface glue is made；
If the molding time of mixture A, which is measured at a temperature of (160 ± 2) DEG C with the small skill in using a kitchen knife in cookery, is more than 200s, mended into mixture A
Add suitable benzyl dimethylamine stirring 0.5h, then detect molding time, until reaching 120~200s, is further continued for stirring 1h and is made
Surface glue；
If the molding time of mixture A in (160 ± 2) if DEG C at a temperature of with the small skill in using a kitchen knife in cookery measure be less than 120s, add suitable
0.5h is mixed in epoxy resin, phenolic resin, butvar adhesive liquid and inorganic filler, then detects molding time until reaching
120~200s；
4) surface glue immersion coating is made to surface adhesive plaster on glass cloth.
2. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 1), organic solvent be in toluene, methanol, ethyl alcohol, acetone, methyl acetate, ethyl acetate any one or
Two kinds or more of mixture.
3. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 2), organic solvent be in toluene, methanol, ethyl alcohol, acetone, methyl acetate, ethyl acetate any one or
Two kinds or more of mixture.
4. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 1), the acid value of polyvinyl butyral is less than or equal to 0.8mgKOH/g, and 20 parts of polyvinyl butyrals are 80
Use 1# flow cup tested viscosities for 21~100s at a temperature of (20 ± 1) DEG C after being dissolved in part alcohol solvent.
5. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 2), the mixing of any one or two kinds or more in epoxy resin E-12, E-20, E-44, E-51
Object.
6. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 3), phenolic resin is the mixing of any one or two kinds in alkalescent phenol resin, acid phenolic resin
Object, the wherein amount of solid of phenolic resin are (60 ± 2) %.
7. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 3), inorganic filler is aluminium oxide, aluminium hydroxide, magnesia, magnesium hydroxide, calcium carbonate, silica, two
The mixture of any one or two kinds or more in titanium oxide, antimony oxide, di-iron trioxide.
8. a kind of manufacturing method of high inorganic filler content laminate surface adhesive plaster as described in claim 1, feature exist
In：In the step 4), immersion coating is carried out using vertical gluing machine, the oven temperature of vertical gluing machine is 130~150 DEG C,
Speed is 5~9m/min.
9. a kind of high inorganic filler content laminate surface glue prepared using claim 1-8 any one the methods
Cloth, it is characterised in that：Surface adhesive plaster glue content 53-56%, soluble resin content 85-95%, volatile content<1.0%, stream
Dynamic degree 18-28%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610633466.4A CN106147644B (en) | 2016-08-04 | 2016-08-04 | A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610633466.4A CN106147644B (en) | 2016-08-04 | 2016-08-04 | A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106147644A CN106147644A (en) | 2016-11-23 |
| CN106147644B true CN106147644B (en) | 2018-10-30 |
Family
ID=57328930
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610633466.4A Active CN106147644B (en) | 2016-08-04 | 2016-08-04 | A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106147644B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109355044A (en) * | 2018-09-27 | 2019-02-19 | 衢州市东凯胶业有限公司 | A kind of textile cloth glue and preparation method thereof |
| CN113913132A (en) * | 2021-07-06 | 2022-01-11 | 深圳博林新材料科技有限公司 | General plastic elastomer in-mold forming adhesive |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376734A (en) * | 2008-09-27 | 2009-03-04 | 腾辉电子（苏州）有限公司 | Epoxide-resin glue liquid, laminated board for printed circuit board manufactured by using the same and manufacturing method thereof |
| CN104494228A (en) * | 2014-12-05 | 2015-04-08 | 中国西电集团公司 | Glass cloth laminate sheet with high inorganic filler content and manufacturing process thereof |
| CN104589667A (en) * | 2014-12-02 | 2015-05-06 | 陕西生益科技有限公司 | Preparation method and application of bonding sheet for copper clad laminate |
-
2016
- 2016-08-04 CN CN201610633466.4A patent/CN106147644B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101376734A (en) * | 2008-09-27 | 2009-03-04 | 腾辉电子（苏州）有限公司 | Epoxide-resin glue liquid, laminated board for printed circuit board manufactured by using the same and manufacturing method thereof |
| CN104589667A (en) * | 2014-12-02 | 2015-05-06 | 陕西生益科技有限公司 | Preparation method and application of bonding sheet for copper clad laminate |
| CN104494228A (en) * | 2014-12-05 | 2015-04-08 | 中国西电集团公司 | Glass cloth laminate sheet with high inorganic filler content and manufacturing process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106147644A (en) | 2016-11-23 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106147644B (en) | A kind of high inorganic filler content laminate surface adhesive plaster and its manufacturing method | |
| CN102433087B (en) | High-temperature-resistant paper-plastic laminating adhesive and preparation method thereof | |
| CN104263287B (en) | A kind of rigid/flexible combined printed circuit board high heat-resisting low fluidity adhesive, glued membrane and preparation method thereof | |
| CN102504733B (en) | Water-blush-resistant fluoride and siloxane modified waterborne pressure-sensitive adhesive and polyethylene protective film | |
| CN105601932B (en) | A kind of dual cure type modified silicon rubber and preparation method thereof | |
| CN101724326A (en) | Waterborne organic silicon-acrylic acid self-stratifying coating | |
| CN103450794A (en) | Scratch resistant PU (Poly Urethane) floor varnish and preparation method thereof | |
| CN110183904B (en) | Flame-retardant ink, preparation method thereof and flame-retardant film | |
| CN105419343A (en) | Printable or dispensing heat conducting gasket and preparing method thereof | |
| US20150153643A1 (en) | Colored photosensitive resin composition and colored filter and display device containing such composition | |
| CN108329869A (en) | A kind of optics acrylic acid adhesive and film protective film and preparation method | |
| CN102643380A (en) | Acrylate emulsion used for vacuum aluminum plating and laser embossing and preparation method thereof | |
| TWI714559B (en) | Inkjet ink composition, ink coating method, and coated article | |
| CN104531009B (en) | A kind of offset printing cold wave dual-purpose adhesive and preparation and application thereof | |
| CN102504676A (en) | Heat transfer release agent, preparation method thereof and use method thereof | |
| CN106349977B (en) | A kind of resistance to boiling water bi-component hardwood jigsaw glue composition and preparation method thereof | |
| CN104312403B (en) | Environment-friendly type aqueous OP protective coating of single-component low temperature solidification and preparation method | |
| CN105916942B (en) | Silicone resin liquid composition | |
| CN109439121A (en) | A kind of release coating of the transfer aluminum plated paper of suitable high speed removing | |
| CN106590267A (en) | Silicon powder-free alumite back glue and preparation method thereof | |
| CN106243875B (en) | BOPP citicall limited aluminiums film transfer water-based back-coating and preparation method thereof | |
| CN111393697A (en) | Release film for laminated capacitor and preparation method thereof | |
| CN104164177A (en) | Acrylic polyurethane metal paint and preparation method thereof | |
| CN102643572A (en) | Thermocuring solder-mask ink and preparation method thereof | |
| CN108531061A (en) | A kind of powdery paints and its preparation method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information |
Address after: No. 7, Tang Xing Road, Xi'an high tech Zone, Shaanxi Province Applicant after: China Xidian Group Limited Address before: No. 7, Tang Xing Road, Xi'an, Shaanxi Province Applicant before: Xian Electric Manufacturing Corp. |
|
| CB02 | Change of applicant information | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20210618 Address after: No.11, north entrance, Taoyuan Road, Xi'an, Shaanxi 710082 Patentee after: XI'AN XD ELECTRICAL MATERIAL Co.,Ltd. Patentee after: CHINA XD GROUP Co.,Ltd. Address before: 710075 Shaanxi city of Xi'an province high tech Zone No. 7 Tang Xing Lu Patentee before: CHINA XD GROUP Co.,Ltd. |
|
| TR01 | Transfer of patent right |