CN106147636A - A kind of hardening protecting film and production method thereof - Google Patents

A kind of hardening protecting film and production method thereof Download PDF

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Publication number
CN106147636A
CN106147636A CN201510151434.6A CN201510151434A CN106147636A CN 106147636 A CN106147636 A CN 106147636A CN 201510151434 A CN201510151434 A CN 201510151434A CN 106147636 A CN106147636 A CN 106147636A
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CN
China
Prior art keywords
sensitive adhesive
layer
base material
protecting film
pressure
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Pending
Application number
CN201510151434.6A
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Chinese (zh)
Inventor
孙攀
王玺
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Shanghai Jingjing New Materials Co., Ltd.
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SHANGHAI PLUSCO TECH Co Ltd
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Priority to CN201510151434.6A priority Critical patent/CN106147636A/en
Publication of CN106147636A publication Critical patent/CN106147636A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of hardening protecting film and production method thereof, this hardening protecting film is made up of PET base material, pressure-sensitive adhesive layer, mould release membrance and hardened layer, and the one side of PET base material is cure process layer, and another side is fitted by pressure-sensitive adhesive layer with mould release membrance.The protecting film case hardness of the present invention is high, has the advantages such as anti-scratch, wearability is outstanding, and this protecting film light transmittance is high simultaneously, and venting quality and weatherability are outstanding, will not pollute Paste articles itself.

Description

A kind of hardening protecting film and production method thereof
Technical field
The present invention relates to protecting film field, particularly to one hardening protecting film and production method thereof.
Background technology
The screen of electronic apparatus series products is during carrying or production and application, and its surface is highly prone to Contact staining or generation polishing scratch scratch, and need to use protecting film that its surface is carried out covering and make it from Get dirty or impaired.Simultaneously in order to ensure that itself use is not caused shadow after pasting protecting film by product Ring, therefore the through performance of protecting film itself, wear-resisting scratch resistance performance and cleanliness factor are had certain requirement.
Traditional protection film does not has wear-resisting, scratch resistance characteristic, the most in use causes surface to be subject to Damage, thus visual effect is produced impact, even affect the normal use of Paste articles.For being used for shielding Wearability is especially required higher by the protecting film of curtain.It is thus desirable to a kind of protecting film being difficult to be scratched, While protection Paste articles, do not interfere with the use attractive in appearance and normal of Paste articles.
Summary of the invention
For the deficiencies in the prior art, the invention provides a kind of hardening protecting film and production method thereof. Hardening protecting film provided by the present invention, including: PET (polyethylene terephthalate) base material, Pressure-sensitive adhesive layer, mould release membrance and hardened layer, wherein, the coated on one side of described PET base material has pressure sensitive adhesive Layer, described pressure-sensitive adhesive layer is coated with mould release membrance, and the another side of described PET base material is coated with hardening Layer.
It is further preferred that described PET base material is double treatment, the thickness of described PET base material is 50-150 μm, light transmittance >=88%, mist degree≤4%.
It is further preferred that described pressure-sensitive adhesive layer is polyurethane system class pressure sensitive adhesive, described pressure-sensitive adhesive layer Coating layer thickness be 5-15 μm.
It is further preferred that described mould release membrance is the PET with release performance, described mould release membrance Thickness is 25-50 μm.
It is further preferred that described hardened layer is acrylic compounds UV coating, the coating of described hardened layer Thickness is 2-6 μm.
The production method of a kind of protecting film that hardens provided by the present invention, comprises the following steps:
A () is at one layer of hardened layer of coated on one side of PET base material;
B () is coated with one layer of pressure-sensitive adhesive layer at the another side of PET base material;
(c) through drying baker dry after at described pressure-sensitive adhesive layer overlying last layer mould release membrance.
It is further preferred that in step (a), described PET base material is double treatment, described The thickness of PET base material is 50-150 μm, light transmittance >=88%, mist degree≤4%.
It is further preferred that in step (a), described hardened layer is acrylic compounds UV coating, The coating layer thickness of described hardened layer is 2-6 μm.
It is further preferred that in step (b), described pressure-sensitive adhesive layer is polyurethanes pressure sensitive adhesive, The coating layer thickness of described pressure-sensitive adhesive layer is 5-15 μm.
It is further preferred that in step (c), described mould release membrance is the PET with release performance, The thickness of described mould release membrance is 25-50 μm.
The invention has the beneficial effects as follows:
Hardening protecting film provided by the present invention, by adding hardened layer, solves common protecting film friction Or produce superficial stain after scratch, be subject to so that Paste articles (especially screen position) normally uses Problem to impact.Meanwhile, the present invention is by PET base material, pressure-sensitive adhesive layer, the ginseng of mould release membrance Number and the selection of proportioning, obtained hardening protecting film venting quality is outstanding, and bubble generation rate is low, reduces Pad pasting difficulty, and high temperature, high humidity environment are had outstanding patience, screen itself will not be made Become to pollute.
Detailed description of the invention
Below the present invention is described in further detail.
As it is shown in figure 1, hardening protecting film provided by the present invention includes: PET (poly terephthalic acid Ethylene glycol) base material 1, pressure-sensitive adhesive layer 2, mould release membrance 3 and hardened layer 4, wherein, described PET base The coated on one side of material 1 has pressure-sensitive adhesive layer 2, and described pressure-sensitive adhesive layer 2 is coated with mould release membrance 3, described The another side of PET base material 1 is coated with hardened layer 4.
Described PET base material 1 is double treatment, and the thickness of described PET base material 1 is 50-150 μm, Light transmittance >=88%, mist degree≤4%.Described pressure-sensitive adhesive layer 2 is polyurethane system class pressure sensitive adhesive, described The coating layer thickness of pressure-sensitive adhesive layer 2 is 5-15 μm.Described mould release membrance 3 is the PET with release performance, The thickness of described mould release membrance 3 is 25-50 μm.Described hardened layer 4 is acrylic compounds UV coating, institute The coating layer thickness stating hardened layer 4 is 2-6 μm.
As in figure 2 it is shown, the production method of hardening protecting film provided by the present invention, comprise the following steps:
A () is at one layer of hardened layer 4 of coated on one side of PET base material 1;
B () is coated with one layer of pressure-sensitive adhesive layer 2 at the another side of PET base material 1;
(c) through drying baker dry after at described pressure-sensitive adhesive layer 2 overlying last layer mould release membrance 3.
Further, in step (a), described PET base material 1 is double treatment, described PET The thickness of base material 1 is 50-150 μm, light transmittance >=88%, mist degree≤4%.Described hardened layer 4 is Acrylic compounds UV coating, the coating layer thickness of described hardened layer 4 is 2-6 μm.
In step (b), described pressure-sensitive adhesive layer 2 is polyurethanes pressure sensitive adhesive, described pressure-sensitive adhesive layer The coating layer thickness of 2 is 5-15 μm.
In step (c), described mould release membrance 3 is the PET with release performance, described mould release membrance 3 Thickness be 25-50 μm.
Further, in step (a), by the hardening bath of mix homogeneously with 12 μm nick roller coat It is overlying on a face of PET base material 1, dries 1 minute in dehydrator in 80 DEG C, then through purple Outer photocuring (the irradiation light of ultraviolet light is 500-600mj/cm2), prepares hardening protecting film half and becomes Product.
Described hardening bath includes: percentage by weight is the polyfunctionality polyurethane acroleic acid of 20~40% Ester, percentage by weight is 50~the esters of 70% and ketone reagent, and percentage by weight is 5~10% UV curing activity monomer, percentage by weight is the light trigger of 1~10%, and percentage by weight is 0.1~the coating additive of 0.5%.
Described polyfunctionality urethane acrylate is two degree of functionality urethane acrylates, two degrees of functionality Aliphatic urethane acrylate, three-functionality-degree urethane acrylate, six degree of functionality aliphatic poly ammonia One or more in ester acrylate.
Described esters and ketone reagent be methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, One or more in butyl acetate, acetone, butanone, Ketohexamethylene.
Described UV curing activity monomer is dipentaerythritol acrylate, tetramethylolmethane three acrylic acid Ester, tetramethylol methane tetraacrylate, ethoxyquin tetramethylol methane tetraacrylate, ethoxyquin trihydroxy first Base propane triacrylate, the third oxidation trihydroxy methyl propane triacrylate, ethoxyquin tetramethylolmethane One or more in tetraacrylate, dipentaerythritol acrylate.
Described light trigger be benzophenone, acrylated benzophenone, tertiary amine aided initiating, One or more in 1-hydroxycyclohexyl phenyl ketone.
Described coating additive is advection agent or substrate wetting agents.
Further, in step (b) and step (c), by the pressure sensitive adhesive of mix homogeneously with 45 μm nick roller coat is overlying on the another side of the PET base material 1 having been coated with hardened layer 4, is drying in 80 DEG C Dry machine is dried 1min, after going out baking oven, laminating in pressure-sensitive adhesive layer 2 by release of mould release membrance 3.
Described pressure sensitive adhesive includes the isocyanates that percentage by weight is 30-60%, and percentage by weight is The firming agent of 5-20%, percentage by weight is the lytic agent of 30-60%, and percentage by weight is 0.1-3% Additive.
Described isocyanates can be fats isocyanates or aromatics isocyanates one of which or several Kind.Described lytic agent is ethyl acetate, butyl acetate, toluene, acetone, the one of butanone or several Kind.Described firming agent is one or more of PEPA or polyether polyol.Described additive is Conductive agent or catalyst.
Embodiment one
By 20g six degree of functionality aliphatic urethane acrylate, 5g ethoxyquin tetramethylolmethane tetrapropylene Acid esters, 1g benzophenone and 0.5g advection agent add in 63.5g butyl acetate, stir and mix Hardening bath is prepared after uniformly;With 12 μm bar spreaders, described hardening bath is coated on PET base material 1 A face on, in dehydrator, dry 1min in 80 DEG C, then through ultraviolet light polymerization (ultraviolet light Irradiation light be 600mj/cm2), prepare the hardening protecting film semi-finished product being coated with hardened layer 4.
20g aromatics isocyanates, 2g polyester polyols polyol curing agent and 0.2g conductive agent are added 40g In ethyl acetate, after stirring mix homogeneously, prepare pressure sensitive adhesive;With 45 μm bar spreaders by described Pressure-sensitive adhesives, on the another side of PET base material 1 having been coated with hardened layer, is being dried in 80 DEG C Machine is dried 1min, after going out baking oven, laminating on pressure-sensitive adhesive layer 2 by release of mould release membrance 3, Prepare hardening protecting film finished product.
Embodiment two
By 20g six degree of functionality aliphatic urethane acrylate, 7g ethoxyquin tetramethylolmethane tetrapropylene Acid esters, 1.2g benzophenone and 0.3g advection agent add in 50g butyl acetate, stir and mix Hardening bath is prepared after uniformly;With 12 μm bar spreaders, described hardening bath is coated on PET base material 1 A face on, in dehydrator, dry 1min in 80 DEG C, then through ultraviolet light polymerization (ultraviolet light Irradiation light be 600mj/cm2), prepare the hardening protecting film semi-finished product being coated with hardened layer 4.
20g aromatics isocyanates, 2g polyester polyols polyol curing agent and 0.2g conductive agent are added 40g In ethyl acetate, after stirring mix homogeneously, prepare pressure sensitive adhesive;With 45 μm bar spreaders by described Pressure-sensitive adhesives is on the another side of PET base material 1 having been coated with hardened layer, in 80 DEG C at dehydrator Middle drying 1min, after going out baking oven, laminating on pressure-sensitive adhesive layer 2 by release of mould release membrance 3, system Must be hardened protecting film finished product.
Embodiment three
By 20g six degree of functionality aliphatic urethane acrylate, 5g ethoxyquin tetramethylolmethane tetrapropylene Acid esters, 1g benzophenone and 0.5g advection agent add in 63.5g butyl acetate, stir and mix Hardening bath is prepared after uniformly;With 12 μm bar spreaders, described hardening bath is coated on PET base material 1 A face on, in dehydrator, dry 1min in 80 DEG C, then through ultraviolet light polymerization (ultraviolet light Irradiation light be 600mj/cm2), prepare the hardening protecting film semi-finished product being coated with hardened layer 4.
20g aromatics isocyanates, 3g polyester polyols polyol curing agent and 0.5g conductive agent are added 30g In ethyl acetate, after stirring mix homogeneously, prepare pressure sensitive adhesive;With 45 μm bar spreaders by described Pressure-sensitive adhesives is on the another side of PET base material 1 having been coated with hardened layer, in 80 DEG C at dehydrator Middle drying 1min, after going out baking oven, laminating on pressure-sensitive adhesive layer 2 by release of mould release membrance 3, system Must be hardened protecting film finished product.
Hardening protecting film provided by the present invention refers to following table with the performance comparison of common protecting film.Therefrom Visible, relative to prior art, protecting film provided by the present invention not only case hardness is high, anti-scratch, Wearability is good, and light transmittance is high, and venting quality and weatherability are outstanding, will not cause Paste articles itself Pollute.
Various protecting film Data Comparison catalogs
Note: 1, AM001/002/003 is the common protecting film sold on market
2, YU001/002/003 is hardening protecting film provided by the present invention
It is of the art it will be recognized by the skilled artisan that above example of the present invention is only this One of preferred embodiment of invention, limits for length, can not enumerate all embodiments here one by one, Any enforcement that can embody the claims in the present invention technical scheme, all in protection scope of the present invention In.
It should be noted that above content be combine specific embodiment made for the present invention enter one Step describes in detail, it is impossible to assert that the detailed description of the invention of the present invention is only limitted to this, above-mentioned in the present invention Under guidance, those skilled in the art can carry out various improvement and change on the basis of above-described embodiment Shape, and these improve or deformation is within the scope of the present invention.

Claims (10)

1. a hardening protecting film, including: PET base material, pressure-sensitive adhesive layer, mould release membrance and hardened layer, Wherein, the coated on one side of described PET base material has pressure-sensitive adhesive layer, described pressure-sensitive adhesive layer is coated with release Film, the another side of described PET base material is coated with hardened layer.
Hardening protecting film the most according to claim 1, it is characterised in that: described PET base material For double treatment, the thickness of described PET base material is 50-150 μm, light transmittance >=88%, mist degree≤ 4%.
Hardening protecting film the most according to claim 2, it is characterised in that: described pressure-sensitive adhesive layer For polyurethane system class pressure sensitive adhesive, the coating layer thickness of described pressure-sensitive adhesive layer is 5-15 μm.
Hardening protecting film the most according to claim 3, it is characterised in that: described mould release membrance is Having the PET of release performance, the thickness of described mould release membrance is 25-50 μm.
Hardening protecting film the most according to claim 4, it is characterised in that: described hardened layer is Acrylic compounds UV coating, the coating layer thickness of described hardened layer is 2-6 μm.
6. harden the production method of protecting film, comprise the following steps:
A () is at one layer of hardened layer of coated on one side of PET base material;
B () is coated with one layer of pressure-sensitive adhesive layer at the another side of PET base material;
(c) through drying baker dry after at described pressure-sensitive adhesive layer overlying last layer mould release membrance.
Method the most according to claim 6, it is characterised in that: in step (a), described PET base material is double treatment, and the thickness of described PET base material is 50-150 μm, light transmittance >=88%, Mist degree≤4%.
Method the most according to claim 7, it is characterised in that: in step (a), described Hardened layer is acrylic compounds UV coating, and the coating layer thickness of described hardened layer is 2-6 μm.
Method the most according to claim 8, it is characterised in that: in step (b), described Pressure-sensitive adhesive layer is polyurethanes pressure sensitive adhesive, and the coating layer thickness of described pressure-sensitive adhesive layer is 5-15 μm.
Method the most according to claim 9, it is characterised in that: in step (c), institute Stating mould release membrance is the PET with release performance, and the thickness of described mould release membrance is 25-50 μm.
CN201510151434.6A 2015-04-01 2015-04-01 A kind of hardening protecting film and production method thereof Pending CN106147636A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107263946A (en) * 2017-06-14 2017-10-20 颜琦 Diaphragm
CN108373888A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 A kind of supporter protective film and its production method
CN108373889A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 The excellent exhaust acrylic protective film of one kind and its production method
CN108373884A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 A kind of weather-proof acrylic protective film and its production method
CN108624246A (en) * 2018-05-21 2018-10-09 深圳市摩码科技有限公司 A kind of ultralight release scratch resistant protective film of high rigidity and preparation method thereof
CN109575764A (en) * 2018-11-09 2019-04-05 宁波激智科技股份有限公司 A kind of coating composition for spreading the composite membrane laminating layer that adds lustre to and a kind of diffusion add lustre to composite membrane and preparation method thereof
CN110951408A (en) * 2019-12-02 2020-04-03 苏州泰仑电子材料有限公司 Protective film for multiple roughness surfaces
CN111087919A (en) * 2019-12-20 2020-05-01 上海乘鹰新材料有限公司 Scratch-resistant coating composition with good flexibility and good surface dryness before UV curing
CN111154132A (en) * 2020-01-13 2020-05-15 泰兴联创绝缘材料有限公司 Anti-static screen protection film and preparation method thereof
CN111892733A (en) * 2020-08-11 2020-11-06 无锡惠臣塑胶科技有限公司 PC board surface hardness reinforcing process

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CN103612456A (en) * 2013-12-04 2014-03-05 东莞市纳利光学材料有限公司 Antistatic scratching-resisting protective film and preparation method thereof
CN104130698A (en) * 2014-08-05 2014-11-05 张家港康得新光电材料有限公司 Hardening coating material as well as preparation method and application thereof
CN104152006A (en) * 2014-07-10 2014-11-19 东莞市纳利光学材料有限公司 Hardening coating and easily torn and located protective film prepared by utilizing hardening coating
CN104419337A (en) * 2013-09-05 2015-03-18 上海精涂新材料技术有限公司 PET double-sided anti-static protective film and production method thereof
CN204981728U (en) * 2015-04-01 2016-01-20 上海精涂新材料技术有限公司 Sclerosis protection film

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Publication number Priority date Publication date Assignee Title
CN102565885A (en) * 2011-12-13 2012-07-11 番禺南沙殷田化工有限公司 Hardened optical thin film and preparation method thereof
CN102643596A (en) * 2012-04-18 2012-08-22 上海维凯化学品有限公司 UV (ultraviolet) cured coating composition for PET (polyethylene terephthalate) base material and preparation method of composition
CN102786875A (en) * 2012-08-27 2012-11-21 杭州惠之星科技有限公司 Anti-static hardened film
CN104419337A (en) * 2013-09-05 2015-03-18 上海精涂新材料技术有限公司 PET double-sided anti-static protective film and production method thereof
CN103612456A (en) * 2013-12-04 2014-03-05 东莞市纳利光学材料有限公司 Antistatic scratching-resisting protective film and preparation method thereof
CN104152006A (en) * 2014-07-10 2014-11-19 东莞市纳利光学材料有限公司 Hardening coating and easily torn and located protective film prepared by utilizing hardening coating
CN104130698A (en) * 2014-08-05 2014-11-05 张家港康得新光电材料有限公司 Hardening coating material as well as preparation method and application thereof
CN204981728U (en) * 2015-04-01 2016-01-20 上海精涂新材料技术有限公司 Sclerosis protection film

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108373888A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 A kind of supporter protective film and its production method
CN108373889A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 The excellent exhaust acrylic protective film of one kind and its production method
CN108373884A (en) * 2016-11-25 2018-08-07 上海精涂新材料技术有限公司 A kind of weather-proof acrylic protective film and its production method
CN107263946A (en) * 2017-06-14 2017-10-20 颜琦 Diaphragm
CN108624246A (en) * 2018-05-21 2018-10-09 深圳市摩码科技有限公司 A kind of ultralight release scratch resistant protective film of high rigidity and preparation method thereof
CN109575764A (en) * 2018-11-09 2019-04-05 宁波激智科技股份有限公司 A kind of coating composition for spreading the composite membrane laminating layer that adds lustre to and a kind of diffusion add lustre to composite membrane and preparation method thereof
CN110951408A (en) * 2019-12-02 2020-04-03 苏州泰仑电子材料有限公司 Protective film for multiple roughness surfaces
CN110951408B (en) * 2019-12-02 2022-03-08 苏州泰仑电子材料有限公司 Protective film for multiple roughness surfaces
CN111087919A (en) * 2019-12-20 2020-05-01 上海乘鹰新材料有限公司 Scratch-resistant coating composition with good flexibility and good surface dryness before UV curing
CN111154132A (en) * 2020-01-13 2020-05-15 泰兴联创绝缘材料有限公司 Anti-static screen protection film and preparation method thereof
CN111892733A (en) * 2020-08-11 2020-11-06 无锡惠臣塑胶科技有限公司 PC board surface hardness reinforcing process

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