CN106147607A - 一种食用级检测的油漆技术 - Google Patents

一种食用级检测的油漆技术 Download PDF

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CN106147607A
CN106147607A CN201610536244.0A CN201610536244A CN106147607A CN 106147607 A CN106147607 A CN 106147607A CN 201610536244 A CN201610536244 A CN 201610536244A CN 106147607 A CN106147607 A CN 106147607A
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项世平
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Abstract

本发明提供一种食用级检测的油漆技术，其特征在于：由以下原料及其重量组分组成：油料35~50份、有机膨润土3~10份、溶剂5～10份、天然色素8~25份、消泡剂0.1~0.3份、纳米氧化铝助剂0.6~1.4份、异戊酸异戊酯5~15份、甘油二烯丙醚己二酸酯3~7份、辛酸钴2~5份。本发明安全可食用，同时具有耐候、减少龟裂倾向，优良的附着力等优点。

Description

一种食用级检测的油漆技术
技术领域
本发明涉及一种油漆，具体涉及一种食用级检测的油漆技术。
技术背景
油漆是将聚酯、聚氨酯、硝基等成分溶解在有机溶液中制成的。油漆的功能是涂刷在木器、铁器表面, 起到装饰与防护的作用。这里所说的有机溶剂， 就是指苯、醛、烯料等化学物质,，不仅产生异味, 而且含有损健康的有害物质。为解决该问题，如现有技术授权公告号：CN1138838C的中国发明专利，该发明一种溶剂型无毒保健油漆含有高分子成膜料、助剂及溶剂，特征在于所述高分子成膜料中采用的油料是无毒性的不饱和油酸或油酯；所用的多元醇是丙三醇、季戊四醇和三羟甲基丙烷组合而成；所述的多元酸是由琥珀酸、松香二酸及己二酸组成；所述的助剂由辛酸钴、辛酸钙及辛酸锌组成；所述的溶剂由松节油、双戊烯及无芳烃200号溶剂油组合而成。由于该油漆均采用无毒性材料配制而成，所以不会产生对人体和环境有害的毒性污染，具有广泛开发前景。虽然如此，但在使用中和现有普通油漆相比，除了使用感差，同时误入口中并不能避免对身体健康的影响。
发明内容
本发明为解决上述技术问题提供一种安全可食用的一种食用级检测的油漆技术。
本发明为解决上述技术问题所采取的方案为：一种食用级检测的油漆技术，其中：
由以下原料及其重量组分组成：油料35~50份、有机膨润土3~10份、溶剂5～10份、天然色素8~25份、消泡剂0.1~0.3份、纳米氧化铝助剂0.6~1.4份、异戊酸异戊酯5~15份、甘油二烯丙醚己二酸酯3~7份、辛酸钴2~5份，其耐候、附着力优异，同时减少龟裂现象，并具有清香无刺鼻气味。
油料为无毒性不饱和油酸或油酯。
松节油5~15份、间甲酚0.01~0.03份、溴辛烷0.01~0.02份。
作为优选，松节油15份、间甲酚0.02份、溴辛烷0.01份；溶剂不含损害健康的物质，安全可食用，因其作用机理尚不明确，反应呈非线性，有待验证。
或者，松节油13份、间甲酚0.01份、溴辛烷0.02份
或者，松节油15份、间甲酚0.03份、溴辛烷0.01份
作为优选，由以下原料及其重量组分组成：油料40份、有机膨润土7份、溶剂8份、天然色素18份、消泡剂0.01份、纳米氧化铝助剂0.9份、异戊酸异戊酯13份、甘油二烯丙醚己二酸酯7份、辛酸钴5份，其耐候、粘附性优异，同时减少龟裂现象，并具有清香无刺鼻气味，同时，溶剂不含损害健康的物质，安全可食用。
或者，由以下原料及其重量组分组成：油料38份、有机膨润土6份、溶剂5份、天然色素24份、消泡剂0.02份、纳米氧化铝助剂1.3份、异戊酸异戊酯10份、甘油二烯丙醚己二酸酯4份、辛酸钴3份。
或者，由以下原料及其重量组分组成：油料35份、有机膨润土3份、溶剂9份、天然色素15份、消泡剂0.03份、纳米氧化铝助剂0.6份、异戊酸异戊酯13份、甘油二烯丙醚己二酸酯7份、辛酸钴2份。
与现有技术相比，本发明具有的优点在于：本发明安全可食用，同时具有耐候、减少龟裂倾向，优良的粘附性等优点。
具体实施例
以下结合实施例作进一步详细的描述：
实施例1：
一种食用级检测的油漆技术，其中：
由以下原料及其重量组分组成：油料35~50份、有机膨润土3~10份、溶剂5～10份、天然色素8~25份、消泡剂0.1~0.3份、纳米氧化铝助剂0.6~1.4份、异戊酸异戊酯5~15份、甘油二烯丙醚己二酸酯3~7份、辛酸钴2~5份，其耐候、粘附性优异，同时减少龟裂现象，并具有清香无刺鼻气味。
油料为无毒性不饱和油酸或油酯。
松节油5~15份、间甲酚0.01~0.03份、溴辛烷0.01~0.02份。
作为优选，松节油15份、间甲酚0.02份、溴辛烷0.01份；溶剂不含损害健康的物质，安全可食用，因其作用机理尚不明确，反应呈非线性，有待验证。
或者，松节油13份、间甲酚0.01份、溴辛烷0.02份
或者，松节油15份、间甲酚0.03份、溴辛烷0.01份
作为优选，由以下原料及其重量组分组成：油料40份、有机膨润土7份、溶剂8份、天然色素18份、消泡剂0.01份、纳米氧化铝助剂0.9份、异戊酸异戊酯13份、甘油二烯丙醚己二酸酯7份、辛酸钴5份，其耐候、附着力优异，同时减少龟裂现象，并具有清香无刺鼻气味，同时，溶剂不含损害健康的物质，安全可食用。
或者，由以下原料及其重量组分组成：油料38份、有机膨润土6份、溶剂5份、天然色素24份、消泡剂0.02份、纳米氧化铝助剂1.3份、异戊酸异戊酯10份、甘油二烯丙醚己二酸酯4份、辛酸钴3份。
或者，由以下原料及其重量组分组成：油料35份、有机膨润土3份、溶剂9份、天然色素15份、消泡剂0.03份、纳米氧化铝助剂0.6份、异戊酸异戊酯13份、甘油二烯丙醚己二酸酯7份、辛酸钴2份。
对比实验1：
将本实施例（实施例组）与现有同类产品技术（对照组）对比，结果如下表1：
表1 对比试验结果
附着力 龟裂程度 级别 耐候
实施例组 0.03 少 食用检测级别 一般
对照组 0.065 明显可视 环保安全 一般
经发明实验结果表明，本实施例组在附着力、龟裂程度上优于对照组，且油漆级别属于食用检测级别。
对比实验2：
实施例组：准备以下原料：油料400g、有机膨润土70g、溶剂80（松节油150g、间甲酚0.2g、溴辛烷0.1g）、天然色素180g、消泡剂0.1g、纳米氧化铝助剂9g、异戊酸异戊酯130g、甘油二烯丙醚己二酸酯70g、辛酸钴50g，将原料混合搅拌均匀，放置1h，浸泡玩具，晒干。
对照组：准备一下原料：油料400g、有机膨润土70g、溶剂80（松节油150g）、天然色素180g、消泡剂0.1g、纳米氧化铝助剂9g、异戊酸异戊酯130g、甘油二烯丙醚己二酸酯70g、辛酸钴50g，将原料混合搅拌均匀，放置1h，浸泡玩具，晒干。模拟自然条件，使用6周，对其耐候、龟裂程度测试；附着力测试：用百格刀片交差在产品表面画出100个小方格（1mm*1mm)，(深度必须底材),再用3M600# 胶纸粘牢百格区后以45°方向快速撕起,同一位置进行2次在划百格处有小片的油漆脱落脱落总面积≤0.05为OK；成分测定：结果如下表2：
表2 对比试验结果
附着力 龟裂 级别 耐候
实施例组 0.03 少 食用检测级别 一般
对照组 0.034 少 环保安全 一般
因其作用机理尚不明确，可能是叠加产生了意想不到的有益成分或协同交互作用，从上表可以看出，实施例组附着力为0.03，略高于对照组的0.034，且该实施例组有效成分通过食用检测标准，在使用中，即使因儿童啃玩而造成脱落误入口中，也可放心使用。
虽然本发明已以实施例公开如上，但其并非用以限定本发明的保护范围，任何熟悉本领域的技术人员，在不脱离本发明的构思和范围内所做的更动和润饰，均应属于本发明所附权利要求的保护范围。

Claims (5)

1.一种食用级检测的油漆技术，其特征在于：由以下原料及其重量组分组成：油料35~50份、有机膨润土3~10份、溶剂5～10份、天然色素8~25份、消泡剂0.1~0.3份、纳米氧化铝助剂0.6~1.4份、异戊酸异戊酯5~15份、甘油二烯丙醚己二酸酯3~7份、辛酸钴2~5份。
2.根据权利要求1所述的油漆技术，其特征在于：所述的油料为无毒性不饱和油酸或油酯。
3.根据权利要求1所述的油漆技术，其特征在于：所述的溶剂为：松节油5~15份、间甲酚0.01~0.03份、溴辛烷0.01~0.02份。
4.根据权利要求1所述的油漆技术，其特征在于：所述的溶剂为：松节油15份、间甲酚0.02份、溴辛烷0.01份。
5.根据权利要求1所述的油漆技术，其特征在于：由以下原料及其重量组分组成：油料40份、有机膨润土7份、溶剂8份、天然色素18份、消泡剂0.01份、纳米氧化铝助剂0.9份、异戊酸异戊酯13份、甘油二烯丙醚己二酸酯7份、辛酸钴5份。
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CN1313369A (zh) * 2001-04-05 2001-09-19 张昌荣 一种无溶剂型双组份无毒保健油漆
CN1314443A (zh) * 2001-04-05 2001-09-26 张昌荣 一种溶剂型无毒保健油漆
CN1569996A (zh) * 2003-07-25 2005-01-26 张昌荣 一种溶剂型生态环境油漆
CN102876208A (zh) * 2012-09-08 2013-01-16 青岛保利康新材料有限公司 一种环保无毒油漆

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1313369A (zh) * 2001-04-05 2001-09-19 张昌荣 一种无溶剂型双组份无毒保健油漆
CN1314443A (zh) * 2001-04-05 2001-09-26 张昌荣 一种溶剂型无毒保健油漆
CN1569996A (zh) * 2003-07-25 2005-01-26 张昌荣 一种溶剂型生态环境油漆
CN102876208A (zh) * 2012-09-08 2013-01-16 青岛保利康新材料有限公司 一种环保无毒油漆

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Application publication date: 20161123