CN106145895A - 一种陶瓷品废料再利用工艺 - Google Patents
一种陶瓷品废料再利用工艺 Download PDFInfo
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Abstract
本发明公开了一种陶瓷品废料再利用工艺,其特征在于,该工艺将陶瓷品废料再利用来制备路面砖,主要包括如下步骤:(1)用酒精清洗陶瓷品废料碎片,再用清水清洗,之后放入烘箱100℃恒温干燥备用;(2)用破碎机将陶瓷品废料破碎;(3)混合添加剂,所述添加剂包括水泥、氧化铝、石英、消泡剂和玻璃纤维;(4)放入干压成型的磨具中压实成型;(5)放入高温烧结炉中烧结。本发明提供的陶瓷品废料再利用工艺能将陶瓷废料资源化再利用,是保护生态平衡的一个重要环节,能实现经济与环境协调发展的目标,这对于促进我国陶瓷工业实现绿色生产和可持续发展,具有深远的社会意义和经济价值。
Description
技术领域
本发明陶瓷技术领域,尤其涉及一种陶瓷品废料再利用工艺。
背景技术
随着社会经济和陶瓷行业的快速发展,陶瓷工业废料日益增加。
它不仅对城市环境造成巨大的压力,而且还影响到城市经济的发展及陶瓷工业的可持续发展。
因此大量的废旧陶瓷如何处理能减少对环境及经济的影响已经成为人们关注的热点问题。大多数企业的陶瓷废料都通过填埋的方式来解决,但是填埋也需要占用大量土地。废旧陶瓷的堆积占用土地影响植被生长,从而影响当地空气中各粉尘含量;而废旧陶瓷的填埋不仅耗费人力物力,并且污染地下水质。对当地环境造成巨大压力,并且制约城市经济以及陶瓷行业的可持续发展,所以合理的处理和陶瓷工业废弃物资源回收利用是非常重要的。
发明内容
本发明的目的是为了解决现有技术中存在的缺点,而提出的一种陶瓷品废料再利用工艺。
本发明提供了一种陶瓷品废料再利用工艺,该工艺将陶瓷品废料再利用来制备路面砖,主要包括如下步骤:
(1)用酒精清洗陶瓷品废料碎片,再用清水清洗,之后放入烘箱100℃恒温干燥备用;
(2)用破碎机将陶瓷品废料破碎;
(3)混合添加剂,所述添加剂包括水泥、氧化铝、石英、消泡剂和玻璃纤维;
(4)放入干压成型的磨具中压实成型;
(5)放入高温烧结炉中烧结。
优选地,所述步骤(1)中的酒精浓度为70-75%,酒精不仅能起到清洗的作用,还能起到消毒的作用。进一步优选超声清洗2小时,之后用清水冲洗。
优选地, 所述步骤(2)中破碎粒度小于4mm。进一步优选为破碎粒度小于2mm。
优选地,所述步骤(3)中包括减水剂。
优选地,所述步骤(4)中磨具的压力大于50MPa。进一步优选为55Mpa。
优选地,所述消泡剂为乳化硅油、聚氧乙烯聚氧丙醇胺醚、聚氧丙烯甘油醚和聚氧丙烯聚氧乙烯甘油醚和聚二甲基硅氧烷中的至少一种。进一步优选为乳化硅油和聚二甲基硅氧烷中的至少一种。更优选为聚二甲基硅氧烷。优选聚二甲基硅氧烷是因为其具有良好的电绝缘性和耐候性、疏水性好,并具有很高的抗剪切能力,可在-50℃~200℃下长期使用。
优选地,所述减水剂为脂肪族高效减水剂,氨基高效减水剂,聚羧酸高性能减水剂中的一种。进一步优选为聚羧酸高性能减水剂。聚羧酸高性能减水剂具有掺量低、减水率高、收缩小等特点。掺入本产品可使路面砖能较长时间保持施工性能;同时能改善路面砖的物理力学性能,提高工程质量。
优选地,所述工艺采用陶瓷废品的重量份为20-80份,水泥重量份为10-60份,氧化铝的重量份为5-8份,石英的重量份为6-8份,消泡剂的重量份为1-3份,玻璃纤维的重量份为0.3-0.8份。
进一步优选为陶瓷废品的重量份为30-60份,水泥重量份为15-30份,氧化铝的重量份为5-6份,石英的重量份为6-7份,消泡剂的重量份为1-2份,玻璃纤维的重量份为0.3-0.6份。
更优选为陶瓷废品的重量份为60份,水泥重量份为22份,氧化铝的重量份为5份,石英的重量份为6份,消泡剂的重量份为1份,玻璃纤维的重量份为0.5份。
优选地, 所述步骤(2)中破碎后的陶瓷废品研磨为20-200目的细度。进一步优选为50-200目。
优选地, 所述减水剂用量重量份为1-3份。进一步优选为1份。
所述步骤(5)中的烧结温度为800-1300℃。进一步优选为1100-1300℃。
本发明提供的陶瓷品废料再利用工艺能将陶瓷废料资源化再利用,是保护生态平衡的一个重要环节,能实现经济与环境协调发展的目标,这对于促进我国陶瓷工业实现绿色生产和可持续发展,具有深远的社会意义和经济价值。
具体实施方式
下面结合具体实施例对本发明作进一步解说。
实施例1
将重量份为50份的陶瓷品废料碎片用70%的酒精清洗,再用清水清洗,之后放入烘箱100℃恒温干燥备用;然后用破碎机将陶瓷品废料破碎为50目;然后在搅拌器中搅拌陶瓷品废料,边搅拌边加入20重量份的硅酸盐水泥,5重量份的氧化铝,7重量份的石英,1重量份聚二甲基硅氧烷,2重量份聚羧酸高性能减水剂,0.3份的玻璃纤维。混合搅拌均匀没有气泡后放入干压成型的磨具中压实成型;压实压力为60MPa。压实后放入高温烧结炉中烧结。烧结温度为1100℃,烧结时间为1小时。
实施例2
将重量份为60份的陶瓷品废料碎片用70%的酒精清洗,再用清水清洗,之后放入烘箱100℃恒温干燥备用;然后用破碎机将陶瓷品废料破碎为100目;然后在搅拌器中搅拌陶瓷品废料,边搅拌边加入20重量份的硅酸盐水泥,6重量份的氧化铝,8重量份的石英,1重量份聚二甲基硅氧烷,1重量份聚羧酸高性能减水剂,0.6份的玻璃纤维。混合搅拌均匀没有气泡后放入干压成型的磨具中压实成型;压实压力为60MPa。压实后放入高温烧结炉中烧结。烧结温度为1200℃,烧结时间为1.5小时。
实施例2
将重量份为60份的陶瓷品废料碎片用70%的酒精清洗,再用清水清洗,之后放入烘箱100℃恒温干燥备用;然后用破碎机将陶瓷品废料破碎为200目;然后在搅拌器中搅拌陶瓷品废料,边搅拌边加入22重量份的硅酸盐水泥,6重量份的氧化铝,8重量份的石英,1重量份聚二甲基硅氧烷,1重量份聚羧酸高性能减水剂,0.6份的玻璃纤维。混合搅拌均匀没有气泡后放入干压成型的磨具中压实成型;压实压力为55MPa。压实后放入高温烧结炉中烧结。烧结温度为1300℃,烧结时间为1.5小时。
测试例:
将实施例1、2和3的路面砖进行抗压强度和抗折强度进行测定,测定结果如下。
表1 抗压强度、抗折强度测试结果
抗压强度 | 抗折强度 | |
实施例1 | 13.11 | 10.15 |
实施例2 | 18.62 | 13.8 |
实施例3 | 26.38 | 23.19 |
随着陶瓷废品颗粒的变化及烧结温度的增加,使得路面砖的抗压强度及抗折强度都增加了,更加符合现今的路面要求。
本发明提供的陶瓷品废料再利用工艺能将陶瓷废料资源化再利用,是保护生态平衡的一个重要环节,能实现经济与环境协调发展的目标,这对于促进我国陶瓷工业实现绿色生产和可持续发展,具有深远的社会意义和经济价值。
以上所述,仅为本发明较佳的具体实施方式,但本发明的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本发明揭露的技术范围内,根据本发明的技术方案及其发明构思加以等同替换或改变,都应涵盖在本发明的保护范围之内。
Claims (10)
1.一种陶瓷品废料再利用工艺,其特征在于,该工艺将陶瓷品废料再利用来制备路面砖,主要包括如下步骤:
(1)用酒精清洗陶瓷品废料碎片,再用清水清洗,之后放入烘箱100℃恒温干燥备用;
(2)用破碎机将陶瓷品废料破碎;
(3)混合添加剂,所述添加剂包括水泥、氧化铝、石英、消泡剂和玻璃纤维;
(4)放入干压成型的磨具中压实成型;
(5)放入高温烧结炉中烧结。
2.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于, 所述步骤(2)中破碎粒度小于4mm。
3.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于,所述步骤(3)中包括减水剂。
4.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于,所述步骤(4)中磨具的压力大于50MPa。
5.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于,所述消泡剂为乳化硅油、聚氧乙烯聚氧丙醇胺醚、聚氧丙烯甘油醚和聚氧丙烯聚氧乙烯甘油醚和聚二甲基硅氧烷中的至少一种。
6.根据权利要求3所述的陶瓷品废料再利用工艺,其特征在于,所述减水剂为脂肪族高效减水剂,氨基高效减水剂,聚羧酸高性能减水剂中的一种。
7.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于,所述工艺采用陶瓷废品的重量份为20-80份,水泥重量份为10-60份,氧化铝的重量份为5-8份,石英的重量份为6-8份,消泡剂的重量份为1-3份,玻璃纤维的重量份为0.3-0.8份。
8.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于, 所述步骤(2)中破碎后的陶瓷废品研磨为20-200目的细度。
9.根据权利要求6所述的陶瓷品废料再利用工艺,其特征在于, 所述减水剂用量重量份为1-3份。
10.根据权利要求1所述的陶瓷品废料再利用工艺,其特征在于,所述步骤(5)中的烧结温度为800-1300℃。
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