CN106144192A - The cylindrical plastic bottle cap of a kind of band soup ladle and manufacture the plastics of this bottle cap - Google Patents

The cylindrical plastic bottle cap of a kind of band soup ladle and manufacture the plastics of this bottle cap Download PDF

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Publication number
CN106144192A
CN106144192A CN201610782184.0A CN201610782184A CN106144192A CN 106144192 A CN106144192 A CN 106144192A CN 201610782184 A CN201610782184 A CN 201610782184A CN 106144192 A CN106144192 A CN 106144192A
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Prior art keywords
lid
fixing
parts
soup ladle
turnover
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Granted
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CN201610782184.0A
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CN106144192B (en
Inventor
曹蓉蓉
曹文岭
曹俪馨
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Shandong Loqi Intelligent Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D47/00Closures with filling and discharging, or with discharging, devices
    • B65D47/36Closures with frangible parts adapted to be pierced, torn or removed, to provide discharge openings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D51/00Closures not otherwise provided for
    • B65D51/24Closures not otherwise provided for combined or co-operating with auxiliary devices for non-closing purposes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L3/00Compositions of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08L3/02Starch; Degradation products thereof, e.g. dextrin
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W90/00Enabling technologies or technologies with a potential or indirect contribution to greenhouse gas [GHG] emissions mitigation
    • Y02W90/10Bio-packaging, e.g. packing containers made from renewable resources or bio-plastics

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Closures For Containers (AREA)

Abstract

The invention discloses the cylindrical plastic bottle cap of a kind of band soup ladle, including fixing lid, it is provided with Easy tearing lid therein, the periphery of Easy tearing lid is connected by easily tearing structure with fixing lid, the flange of annular it is provided with between Easy tearing lid and fixing lid inwall, it is provided with to recessed arc bayonet socket in the front end of fixing tops, hinged with the tail end of turnover lid in the rear end of fixing tops;Turnover lid, it is fastened in the storage tank surrounded by Easy tearing lid and fixing lid;Being provided with circular sealing lid on the medial wall being positioned at below Easy tearing lid fixing covering, be provided with the elastic sealing strip of an annular in the edge sealing cap upper surface, sealing strip is connected in the annular seal groove that described flange lower surface is offered;One end of described sealing lid is hinged with fixing lid medial wall, sealing to cover, with described one end, the other end sealing the lid center of circle symmetrical is provided with globe joint, described globe joint is connected on fixing lid medial wall the spherical groove that setting is suitable with described globe joint;The invention allows for the plastics of a kind of cylindrical plastic bottle cap manufacturing band soup ladle simultaneously.

Description

The cylindrical plastic bottle cap of a kind of band soup ladle and manufacture the plastics of this bottle cap
Technical field
The invention belongs to container seal technical field, be specifically related to a kind of band soup ladle cylindrical plastic bottle cap and for Manufacture the plastics of this bottle cap.
Background technology
Bottle cap is that sealing bottle is used, and has holding content product airtight performance, also has antitheft unlatching and safety The function of aspect, is the key product of bottle container packaging, therefore, is widely applied on bottled product, is food and beverage Pack an important ring, the place that Ye Shi consumer contacts at first with product.According to different functions, there are difformity, difference The bottle cap of operational approach, as: mineral water bottle cap is circular with twisting, and pop can bottle cap is ring-type with drawing.
Existing bottle cap generally also exists problems with: though 1 good seal performance, be difficult to frequent switch on and close behaviour Make;2, it is easily opened and shutoff operation, but poor sealing performance.Also do not have on market a kind of both to have can guarantee that good sealing property, It is easily opened again the bottle cap with shutoff operation;3, there is such as anti-flammability, toughness, wear resistence, Resisting fractre, close in the material of existing bottle cap Feng Xing, antibiotic property are poor, are not easy degraded and produce the problems such as environmental pollution, therefore need a kind of new bottle cap and bottle cap badly after abandoning Material occurs.
Summary of the invention
In order to solve the problems that existing bottle cap exists, it is an object of the invention to provide a kind of good seal performance and easily grasp The cylindrical bottle cap of the band soup ladle made.
In order to realize foregoing invention purpose, the present invention is used technical scheme as described below:
A kind of cylindrical bottle cap of band soup ladle, including:
Fixing lid, it is connected on bottleneck, in hollow cylindrical, is provided with the convex of annular in the middle part of the medial wall of fixing lid Edge, is provided with Easy tearing lid on flange inner limit, and the periphery of Easy tearing lid is connected by easily tearing structure with flange, arranges on Easy tearing lid There is draw ring, be provided with in the front end of fixing tops to recessed arc bayonet socket, at the rear end of fixing tops and turnover lid Tail end is hinged;
Turnover lid, it is fastened in the storage tank surrounded by Easy tearing lid and fixing lid, arranges on the inner surface of turnover lid There is the inner ring of annular, between the medial wall of inner ring and turnover lid, form the catching groove of an annular, catching groove and the fixing flange phase covered Adaptation is fastened and connected, and is provided with the soup ladle chamber being built-in with soup ladle on the inner surface of turnover lid, and soup ladle chamber opening is opened in turnover On the side, front end of lid, cover in turnover and be provided with the arc block tongue being positioned at below the opening of soup ladle chamber, arc block tongue and described arc Shape bayonet socket is corresponding to be fastened and connected;
Being provided with circular sealing lid on the medial wall being positioned at below Easy tearing lid fixing covering, the diameter sealing lid is more than The internal diameter of described flange;Be provided with the elastic sealing strip of an annular in the edge sealing cap upper surface, sealing strip is connected in institute State in the annular seal groove that flange lower surface is offered;Described seal lid one end hinged with fixing lid medial wall, seal cover and Described one end is provided with globe joint about the other end sealing the lid center of circle symmetrical, and described globe joint can be under its own weight Making sealing lid be in vertically downward, it is suitable with described globe joint that described globe joint is connected on fixing lid medial wall setting Spherical groove, globe joint and spherical groove are interference fit clamping, are provided with shackle on the upper surface sealing lid.
Preferably, described groove semicircular in shape, the both ends of handle are hingedly connected to be installed in about turnover lid lateral wall On the bearing pin of both sides, the sidewall that the left and right sides of fixing lid is corresponding offers and turns down the bearing pin covering both sides and match Draw-in groove.
Preferably, described arc bayonet socket is the most corresponding with the pin joint of fixing lid and turnover lid.
Preferably, described draw ring is arranged at the front end of Easy tearing lid upper surface.
Preferably, for manufacturing the plastics of the cylindrical plastic bottle cap of band soup ladle, it is made up of the material of following weight portion, beautiful Rice starch 40-60 part, modified montmorillonoid 5-10 part, polyethylene 40-60 part, polyvinyl alcohol 10-15 part, nano flame retardant complex 15-25 part, UV absorbent 3-5 part, antioxidant 6-8 part, antimony oxide 15-20 part, epoxychloropropane 8-10 part, polyamides Amine 12-15 part, poly butyric ester 12-15 part, furfuryl alcohol resin 8-10 part, glass fibre 10-12 part, zinc stearate 7-9 part, low Carbon alcohol 3-6 part, methacrylate 2-4 part, epoxidized vegetable oil 4-6 part, artificial beef plant element 6-8 part, wood fiber powder 6-8 Part, dispersant 3-5 part, plasticizer 4-6 part, coupling agent 6-8 part.
Preferably, the preparation method of described nano flame retardant complex is:
The first step, by silicone hydroxyl apatite, attapulgite, red phosphorus, montmorillonite, brucite, titanium dioxide, calcite, Kaolin Mix according to the parts by weight proportioning of 20:10:8:8:6:5:5:3, join 100 parts of dimethyl sulfoxides (DMSO) and 30 parts of methanol In mixed solution, stir 50 hours in 68 DEG C, filter, and wash 3 times the dimethyl sulfoxide removing excess with the hot ethanol of 60 DEG C of temperature (DMSO), putting into vacuum drying oven, be dried 24 hours 60 DEG C of temperature, grinding is sieved, and obtains a modified flame-retardant complex;
Second step, by 1 part of modified flame-retardant complex, 8 parts of potassium acetates and 20 parts of distilled water mixing, stirs in temperature 55 DEG C Mix more than 8 hours, temperature 28 DEG C, first disperse 2 hours under the conditions of ultrasonic electric power 400W, the most again at ultrasonic electric power Disperse 2.5 hours under the conditions of 300W.Filtering, and wash 3 times with distillation, 85 DEG C are vacuum dried 24 hours, and grinding is sieved, and obtains secondary Modified flame-retardant complex;
3rd step, disperses 30min by above-mentioned 1 part of twice-modified flame-retardant compounds at 800W power ultrasonic, adds with constant temperature Thermal is heated to 88 DEG C, and stirs 60 minutes with rotating speed 1200r/min with mechanical agitator;Obtain nano flame retardant complex;
Preferably, the preparation method of described modified montmorillonoid is: by weight 300 parts of concentrated sulphuric acids are scattered in 100 parts of water In, stir to obtain acid compound aqueous intercalation solution;15 parts of montmorillonites being joined in acid compound aqueous intercalation solution, 90 DEG C high Speed stirring 2h, filtered while hot, it is washed with distilled water to neutrality, sucking filtration, dries, grind, cross 200 mesh sieves and obtain intermedium A;Then Intermedium A is dispersed in the ethanol water that 12 parts of concentration is 30%, ultrasonic in 60 DEG C of water-baths-mechanical agitation dispersion 2.5h Obtain intermedium B, in intermedium B, then add 5 parts of Silane coupling reagent KH-570s and 3 parts of methyl methacrylate monomers, rise Temperature, to 85 DEG C, is incubated 5h, logical nitrogen during insulation, and is slowly added dropwise into azodiisobutyronitrile solution, finally reaction is produced Thing is poured out, and adds distilled water, stirs, and stratification is removed the supernatant, lower reaction product layer is carried out sucking filtration, washing, 850 DEG C are dried under vacuum to constant weight, grind, and cross 200 mesh sieves, i.e. obtain modified montmorillonoid;
Preferably, described antioxidant is antioxidant 1010 or irgasfos 168;
Preferably, the preparation method of described plastics is:
The first step, by modified montmorillonoid, UV absorbent, antioxidant, antimony oxide, epoxychloropropane, polyamide, Poly butyric ester, furfuryl alcohol resin, glass fibre, zinc stearate, low-carbon alcohols, methacrylate, epoxidized vegetable oil, plant egg White fiber element, wood fiber powder add stirring 35~40 minutes in high-speed mixer, are mixed into uniform miscible body;
Second step, corn starch, polyethylene, polyvinyl alcohol, nano flame retardant complex, dispersant, plasticizer, coupling agent and Water is sequentially added in high-speed mixer stirring 35~40 minutes, is mixed into uniform miscible body;
3rd step, miscible body step (1), (2) obtained by dosing pump and weight-loss metering feeder and plant dye After material mixing, add in double screw extruder, carry out mixing and extrusion.
Owing to using technique scheme, the present invention has a following superiority:
The fixing lid of the present invention is fastened on bottleneck, by Easy tearing lid by bottle sealing;When taking the content of bottle, first Arc block tongue is unlocked with arc bayonet socket, and is lifted up opening turnover lid by handle, soup ladle is taken out from soup ladle chamber, then By draw ring, Easy tearing lid is torn in fixing lid, soup ladle can be used to take the content of bottle;After taking, will turn over Fold is fastened in the storage tank of fixing lid, and by arc block tongue and arc bayonet fittings locking;Take bottle more later During content, only need to be by arc block tongue and the locking of arc bayonet socket and unblock, the sealing completing bottleneck operates with uncapping. Therefore, the present invention with good seal performance and easily frequent switch on, the advantage of shutoff operation;Owing to have employed novel moulding Material, wherein antimony trioxide adds modified montmorillonoid, epoxychloropropane, polyamide, poly butyric ester, bran as major ingredient, auxiliary Alcohol resin, glass fibre, zinc stearate, acetic acid, low-carbon alcohols, methacrylate, polyethylene, epoxidized vegetable oil, corn starch, Artificial beef plant element, wood fiber powder, poly-β-hydroxybutyric acid, dispersant, plasticizer, coupling agent, polyvinyl alcohol, nano flame retardant Complex, UV absorbent, antioxidant, as adjuvant, conservative control major ingredient and the proportioning of adjuvant, are effectively increased the present invention The fire resistance of flame-retardant modified degradation plastic, wherein the antimony trioxide of major ingredient can be effectively improved the flame-retardant modified of the present invention The fire resistance of degradation plastic;In adjuvant, by modified montmorillonoid, the compatibility of montmorillonite and structure is made to produce change, its Can be the most compatible with the unclassified stores of the present invention, also further increase the fire resistance of the present invention;Wherein add Epoxidized vegetable oil, corn starch, artificial beef plant element, wood fiber powder and poly-β-hydroxybutyric acid be as dropping in adjuvant Solve composition, it is ensured that the flame-retardant modified degradation plastic of the present invention has degradability, improves security performance, improves simultaneously The toughness of plastics, antibiotic property, wear-resistant, resistance to fracture etc. so that bottle cap plays and well seals protected effect.
Accompanying drawing explanation
Fig. 1 is the structural representation of the present invention;
Fig. 2 is another status architecture schematic diagram of the present invention;
Fig. 3 is the structural representation sealing lid;
In figure: 1, turnover lid;11, arc block tongue;12, soup ladle chamber;13, handle;14, bearing pin;15, inner ring;2, fixing lid; 21, arc bayonet socket;22, flange;23, Easy tearing lid;24, draw ring;25, draw-in groove;3, hinged;4, soup ladle;5, lid is sealed;51, seal Bar;52, shackle;53, globe joint.
Detailed description of the invention
Below in conjunction with the accompanying drawings and technical scheme is described in further detail by embodiment.
As shown in Figure 1, 2, the cylindrical plastic bottle cap of a kind of band soup ladle, including fixing lid 2, it is connected on bottleneck, Gu Surely cylindric in hollow of lid 2, is provided with the flange 22 of annular in the middle part of the medial wall of fixing lid, is provided with on flange inner limit Easy tearing lid 23, the periphery of Easy tearing lid is connected by easily tearing structure with flange, is provided with draw ring 24, at fixing caping on Easy tearing lid The front end in portion is provided with to recessed arc bayonet socket 21, passes through hinge 3 in the rear end at fixing lid 2 top with the tail end of turnover lid 1 Connect;Described arc bayonet socket 21 is the most corresponding with the pin joint of fixing lid 2 and turnover lid 1;Turnover lid 1, it is fastened on by Easy tearing lid In 23 storage tanks surrounded with the medial wall of fixing lid 2, the inner surface of turnover lid 1 is provided with the inner ring 15 of annular, inner ring And forming the catching groove of an annular between the medial wall of turnover lid, catching groove is used for and the fixing suitable fastening of flange covered;Turning over Being provided with the soup ladle chamber 12 being built-in with soup ladle 4 on the inner surface of fold 1, soup ladle chamber opening is opened in the side, front end of turnover lid 1 On, turnover lid 1 is provided with the arc block tongue 11 being positioned at below the opening of soup ladle chamber, arc block tongue 11 and described arc bayonet socket 21 Corresponding it is fastened and connected.
Fixing lid 2 is positioned on the medial wall below Easy tearing lid 23 the sealing lid 5 being provided with circle, seals the straight of lid 5 Footpath is more than the internal diameter of described flange 22;It is provided with the elastic sealing strip 51 of an annular in the edge sealing lid 5 upper surfaces, seals Bar 51 is connected in the annular seal groove that described flange 22 lower surface is offered;Described one end sealing lid 5 and fixing lid 2 medial walls Hinged, seal and with described one end, the other end sealing the lid center of circle symmetrical is provided with globe joint 53 on lid 5, described spherical Joint 53 can make sealing lid 5 be in vertically downward under its own weight, and described globe joint 53 is connected on fixing lid medial wall Arranging the spherical groove suitable with described globe joint, globe joint and spherical groove are interference fit clamping, are sealing the upper of lid 5 Shackle 52 it is provided with on surface.
Offering semicircular groove in the front end of the upper surface of turnover lid 1, being provided with in groove can be in groove The handle 13 of pull-up, when handle is in groove, shelters from soup ladle chamber opening;Handle 13 in semi-circular shape, the both ends of handle It is hingedly connected to be installed on the bearing pin 14 of the turnover left and right sides, lid lateral wall, in the side that the left and right sides of fixing lid 2 is corresponding Offer on wall and turn down and cover the draw-in groove 25 that the bearing pin 14 of both sides matches.
The present invention carries out the first resealing by sealing lid, after Easy tearing lid is torn, upwards holds shackle, and makes sealing The globe joint covered and the fixing spherical groove tight clamping fit covered, and now seal the sealing strip covered and be tightly connected in convex In seal groove on edge lower surface, then by the fastening of turnover lid with fixing lid, it is achieved the second resealing, substantially increase close Envelope effect.
For manufacturing the plastics of the cylindrical plastic bottle cap of band soup ladle in the present invention, it is made up of the material of following weight portion, Corn starch 40-60 part, modified montmorillonoid 5-10 part, polyethylene 40-60 part, polyvinyl alcohol 10-15 part, nano flame retardant complex 15-25 part, UV absorbent 3-5 part, antioxidant 6-8 part, antimony oxide 15-20 part, epoxychloropropane 8-10 part, polyamides Amine 12-15 part, poly butyric ester 12-15 part, furfuryl alcohol resin 8-10 part, glass fibre 10-12 part, zinc stearate 7-9 part, low Carbon alcohol 3-6 part, methacrylate 2-4 part, epoxidized vegetable oil 4-6 part, artificial beef plant element 6-8 part, wood fiber powder 6-8 Part, dispersant 3-5 part, plasticizer 4-6 part, coupling agent 6-8 part.
In a specific embodiment, the plastics of cylindrical plastic bottle cap of band soup ladle are manufactured by the material of following weight portion Composition, corn starch 45 parts, modified montmorillonoid 7.5 parts, polyethylene 55 parts, polyvinyl alcohol 12.5 parts, nano flame retardant complex 23 Part, UV absorbent 4,7 parts of antioxidant, antimony oxide 18 parts, epoxychloropropane 9 parts, polyamide 13.5 parts, poly-hydroxyl fourth Acid esters 13.5 parts, furfuryl alcohol resin 9 parts, glass fibre 11 parts, zinc stearate 8 parts, low-carbon alcohols 4.5 parts, methacrylate 3 parts, Epoxidized vegetable oil 5 parts, artificial beef plant element 7 parts, wood fiber powder 7 parts, dispersant 4 parts, plasticizer 5 parts, coupling agent 7 parts.
The preparation method of wherein said nano flame retardant complexing agent is:
The first step, by silicone hydroxyl apatite, attapulgite, red phosphorus, montmorillonite, brucite, titanium dioxide, calcite, Kaolin Mix according to the parts by weight proportioning of 20:10:8:8:6:5:5:3, join 100 parts of dimethyl sulfoxides (DMSO) and 30 parts of methanol In mixed solution, stir 50 hours in 68 DEG C, filter, and wash 3 times the dimethyl sulfoxide removing excess with the hot ethanol of 60 DEG C of temperature (DMSO), putting into vacuum drying oven, be dried 24 hours 60 DEG C of temperature, grinding is sieved, and obtains a modified flame-retardant complex;
Second step, by 1 part of modified flame-retardant complex, 8 parts of potassium acetates and 20 parts of distilled water mixing, stirs in temperature 55 DEG C Mix more than 8 hours, temperature 28 DEG C, first disperse 2 hours under the conditions of ultrasonic electric power 400W, the most again at ultrasonic electric power Disperse 2.5 hours under the conditions of 300W.Filtering, and wash 3 times with distillation, 85 DEG C are vacuum dried 24 hours, and grinding is sieved, and obtains secondary Modified flame-retardant complex;
3rd step, disperses 30min by above-mentioned 1 part of twice-modified flame-retardant compounds at 800W power ultrasonic, adds with constant temperature Thermal is heated to 88 DEG C, and stirs 60 minutes with rotating speed 1200r/min with mechanical agitator;Obtain nano flame retardant complex.
Wherein, the preparation method of modified montmorillonoid is: be scattered in 100 parts of water by 300 parts of concentrated sulphuric acids by weight, stirring Uniform acid compound aqueous intercalation solution;15 parts of montmorillonites are joined in acid compound aqueous intercalation solution, 90 DEG C of high-speed stirred 2h, filtered while hot, it is washed with distilled water to neutrality, sucking filtration, dries, grind, cross 200 mesh sieves and obtain intermedium A;Then by centre Thing A is dispersed in the ethanol water that 12 parts of concentration is 30%, during ultrasonic in 60 DEG C of water-baths-mechanical agitation dispersion 2.5h obtains Between thing B, in intermedium B, then add 5 parts of Silane coupling reagent KH-570s and 3 parts of methyl methacrylate monomers, be warming up to 85 DEG C, it is incubated 5h, logical nitrogen during insulation, and be slowly added dropwise into azodiisobutyronitrile solution, finally product is poured out, Add distilled water, stir, stratification, to remove the supernatant, lower reaction product layer is carried out sucking filtration, washing, 850 DEG C are true Sky is dried to constant weight, grinds, and crosses 200 mesh sieves, i.e. obtains modified montmorillonoid.
Wherein, antioxidant is antioxidant 1010 or irgasfos 168.
The preparation method of plastics is, the first step, by modified montmorillonoid, UV absorbent, antioxidant, antimony oxide, Epoxychloropropane, polyamide, poly butyric ester, furfuryl alcohol resin, glass fibre, zinc stearate, low-carbon alcohols, methacrylic acid Ester, epoxidized vegetable oil, artificial beef plant element, wood fiber powder add stirring 35~40 minutes in high-speed mixer, are mixed into Uniform miscible body;Second step, corn starch, polyethylene, polyvinyl alcohol, nano flame retardant complex, dispersant, plasticizer, idol Connection agent and water are sequentially added in high-speed mixer stirring 35~40 minutes, are mixed into uniform miscible body;3rd step, by metering After miscible body that step (1), (2) are obtained by pump and weight-loss metering feeder and vegetable colour mixing, add twin-screw extrusion In machine, carry out mixing and extrusion.
When specifically applying, the lower end of fixing lid 2 is fastened on bottleneck, and the inside of fixing lid is separated into by Easy tearing lid up and down Two parts, are combined in bottle sealing, turnover cover buckle in the fixing storage tank covered by Easy tearing lid 23;Take the content of bottle Time, first arc block tongue 11 is unlocked with arc bayonet socket 21, and be lifted up opening turnover lid 1, by soup ladle 4 from soup by handle 13 Spoon takes out in chamber 12, then is torn in fixing lid 2 by Easy tearing lid 23 by draw ring 24, then the most firmly has by means of press seals lid There is the other end of globe joint, make globe joint depart from spherical groove, seal lid and be then in plumbness, then can use The content of bottle taken by soup ladle 4;After taking, upwards hold shackle, and make globe joint that sealing covers with fixing The spherical groove tight clamping fit covered, and now seal the seal groove that the sealing strip covered tightly is connected on flange lower surface In, can realize the first resealing within bottle;Then turnover lid 1 is fastened in the storage tank of fixing lid 2, fixing lid On flange fasten with in the catching groove that covers of turnover, and coordinate locking by arc block tongue 11 with arc bayonet socket 21, it is achieved to bottle The second in internal portion seals;When taking the content of bottle more later, only need to be by arc block tongue 11 and arc bayonet socket 21 Locking and unblock, the sealing completing bottleneck operates with uncapping, and therefore, the present invention is with good seal performance and easily the most continually Open, the advantage of shutoff operation;Owing to have employed novel plastic material, the cylindrical plastic bottle cap of the band soup ladle in the present invention All there is unrivaled advantage than prior art in fire resistance and degradation property, improve security performance, improve simultaneously and mould The toughness of material, wear-resistant, antibiotic property, resistance to fracture etc. so that bottle cap plays and well seals protected effect;Test shows, this Invention uses the dispersion of solwution method ultrasound wave and the stirring of mechanical high-speed agitator so that fire retardant each component reaches in the solution Nanoscale disperses, and effectively prevent the autoxidation to composite, so that composite has more preferable mechanical property, moulds The oxygen index (OI) of material is 42, and tensile strength is 5.5MPa, and elongation at break is 125%, and degradation cycle is 150 days.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.

Claims (9)

1. the cylindrical plastic bottle cap of a band soup ladle, it is characterised in that including:
Fixing lid (2), it is connected on bottleneck, in hollow cylindrical, is provided with the convex of annular in the middle part of the medial wall of fixing lid Edge (22), is provided with Easy tearing lid (23) on flange inner limit, and the periphery of Easy tearing lid is connected by easily tearing structure with flange, is easily tearing Cover and be provided with draw ring (24), be provided with in the front end of fixing tops to recessed arc bayonet socket (21), push up at fixing lid (2) The rear end in portion is hinged with the tail end of turnover lid (1);
(1) is covered in turnover, and it is fastened in the storage tank surrounded by the medial wall of Easy tearing lid with fixing lid, covers the interior of (1) in turnover It is provided with the inner ring (15) of annular on surface, between the medial wall of inner ring (15) and turnover lid (1), forms the catching groove of an annular, button Groove is suitable with the fixing flange covered to be fastened and connected, and is provided with the soup ladle being built-in with soup ladle (4) on the inner surface of turnover lid Chamber (12), soup ladle chamber opening is opened on the side, front end of turnover lid, covers to be provided with in turnover and be positioned at below the opening of soup ladle chamber Arc block tongue (11), arc block tongue (11) is corresponding with described arc bayonet socket (21) to be fastened and connected;Upper table in turnover lid (1) The front end in face offers groove, be provided with in groove can in groove the handle (13) of pull-up, and be positioned at carrying of groove Soup ladle chamber opening is blocked by hands (13);
Fixing lid (2) is positioned at the sealing lid (5) being provided with circle on the medial wall of Easy tearing lid (23) lower section, seals lid (5) Diameter more than the internal diameter of described flange (22);The elastic packing of an annular it is provided with in the edge sealing lid (5) upper surface Bar (51), sealing strip (51) is connected in the annular seal groove that described flange (22) lower surface is offered;The one of described sealing lid (5) Hold hinged with fixing lid (2) medial wall, seal the upper and described one end of lid (5) and arrange about sealing the symmetrical other end in the lid center of circle There are globe joint (53), described globe joint (53) that sealing lid (5) can be made under its own weight to be in vertically downward, described spherical Joint (53) is connected on fixing lid medial wall the spherical groove that setting is suitable with described globe joint, globe joint and spherical groove For interference fit clamping, the upper surface sealing lid (5) is provided with shackle (52).
2. according to the cylindrical plastic bottle cap of the band soup ladle described in claim 1, it is characterised in that: described groove semicircular in shape, carry The both ends of hands (13) are hingedly connected to be installed on the bearing pin (14) of turnover lid (1) left and right sides, lateral wall, in fixing lid (2) The corresponding sidewall in the left and right sides on offer and turn down the draw-in groove (25) covering the bearing pin of both sides and matching.
The cylindrical bottle cap of band soup ladle the most according to claim 1, it is characterised in that: described arc bayonet socket (21) is with fixing The pin joint of lid and turnover lid is the most corresponding.
The cylindrical plastic bottle cap of band soup ladle the most according to claim 1, it is characterised in that: described draw ring (24) is arranged at The front end in Easy tearing lid (23) face.
5. for manufacturing plastics for the cylindrical plastic bottle cap according to one of claim 1-4 described band soup ladle, its feature It is that these plastics are made up of the material of following weight portion, corn starch 40-60 part, modified montmorillonoid 5-10 part, polyethylene 40-60 Part, polyvinyl alcohol 10-15 part, nano flame retardant complex 15-25 part, UV absorbent 3-5 part, antioxidant 6-8 part, three oxidations Two antimony 15-20 parts, epoxychloropropane 8-10 part, polyamide 12-15 part, poly butyric ester 12-15 part, furfuryl alcohol resin 8-10 Part, glass fibre 10-12 part, zinc stearate 7-9 part, low-carbon alcohols 3-6 part, methacrylate 2-4 part, epoxidized vegetable oil 4-6 Part, artificial beef plant element 6-8 part, wood fiber powder 6-8 part, dispersant 3-5 part, plasticizer 4-6 part, coupling agent 6-8 part.
Plastics the most according to claim 5, it is characterised in that the preparation method of described nano flame retardant complexing agent is:
The first step, by silicone hydroxyl apatite, attapulgite, red phosphorus, montmorillonite, brucite, titanium dioxide, calcite, Kaolin according to The parts by weight proportioning mixing of 20:10:8:8:6:5:5:3, joins 100 parts of dimethyl sulfoxides (DMSO) and the mixing of 30 parts of methanol In solution, stir 50 hours in 68 DEG C, filter, and wash 3 times the dimethyl sulfoxide removing excess with the hot ethanol of 60 DEG C of temperature (DMSO), putting into vacuum drying oven, be dried 24 hours 60 DEG C of temperature, grinding is sieved, and obtains a modified flame-retardant complex;
Second step, by 1 part of modified flame-retardant complex, 8 parts of potassium acetates and 20 parts of distilled water mixing, stirs 8 in temperature 55 DEG C More than hour, temperature 28 DEG C, first disperse 2 hours under the conditions of ultrasonic electric power 400W, the most again at ultrasonic electric power 300W Under the conditions of disperse 2.5 hours.Filtering, and wash 3 times with distillation, 85 DEG C are vacuum dried 24 hours, and grinding is sieved, and obtains twice-modified Flame-retardant compounds;
3rd step, disperses 30min by above-mentioned 1 part of twice-modified flame-retardant compounds at 800W power ultrasonic, fills by heated at constant temperature Put and be heated to 88 DEG C, and stir 60 minutes with rotating speed 1200r/min with mechanical agitator;Obtain nano flame retardant complex;
Plastics the most according to claim 5, its eigenvalue is, the preparation method of described modified montmorillonoid is: by weight 300 parts of concentrated sulphuric acids are scattered in 100 parts of water by part, and stir to obtain acid compound aqueous intercalation solution;15 parts of montmorillonites are added It is combined in aqueous intercalation solution to acidity, 90 DEG C of high-speed stirred 2h, filtered while hot, is washed with distilled water to neutrality, sucking filtration, dries, Grind, cross 200 mesh sieves and obtain intermedium A;Then intermedium A is dispersed in the ethanol water that 12 parts of concentration is 30%, In 60 DEG C of water-baths, ultrasonic-mechanical agitation dispersion 2.5h obtains intermedium B, then adds 5 parts of silane couplers in intermedium B KH-570 and 3 parts of methyl methacrylate monomers, be warming up to 85 DEG C, is incubated 5h, logical nitrogen during insulation, and is slowly added dropwise Enter azodiisobutyronitrile solution, finally product is poured out, add distilled water, stir, stratification, remove upper strata clear Liquid, carries out sucking filtration by lower reaction product layer, washing, and 850 DEG C are dried under vacuum to constant weight, grinds, and crosses 200 mesh sieves, i.e. obtains modification Montmorillonite.
Plastics the most according to claim 5, it is characterised in that described antioxidant is antioxidant 1010 or irgasfos 168.
9. according to the preparation method of the described plastics of one of claim 5-8 it is:
The first step, by modified montmorillonoid, UV absorbent, antioxidant, antimony oxide, epoxychloropropane, polyamide, poly-hydroxyl Base butyrate, furfuryl alcohol resin, glass fibre, zinc stearate, low-carbon alcohols, methacrylate, epoxidized vegetable oil, vegetable protein are fine Dimension element, wood fiber powder add stirring 35~40 minutes in high-speed mixer, are mixed into uniform miscible body;
Second step, corn starch, polyethylene, polyvinyl alcohol, nano flame retardant complex, dispersant, plasticizer, coupling agent and water depend on Secondary addition high-speed mixer stirs 35~40 minutes, is mixed into uniform miscible body;
3rd step, the miscible body obtained in step (1), (2) by dosing pump and weight-loss metering feeder and vegetable colour are mixed After conjunction, add in double screw extruder, carry out mixing and extrusion.
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106963212A (en) * 2017-05-17 2017-07-21 中山市乐盈网络科技有限公司 A cup that is easy to clean
CN108128544A (en) * 2016-12-01 2018-06-08 曹文岭 The bottle cap and sealing container of a kind of sealing container
CN108792254A (en) * 2017-04-28 2018-11-13 内蒙古伊利实业集团股份有限公司 Plastic closure
CN116832471A (en) * 2023-06-21 2023-10-03 河北爱节能源科技有限公司 Organic silicon production Hcl edulcoration device
US12005408B1 (en) 2023-04-14 2024-06-11 Sharkninja Operating Llc Mixing funnel
CN119796697A (en) * 2025-03-11 2025-04-11 湖南万容包装有限公司 A convenient dustproof integrated cover

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0337484A1 (en) * 1988-04-15 1989-10-18 Kamaya Kagaku Kogyo Co., Ltd. Inner plug of synthetic resin container for dried powders
CN1093822C (en) * 1996-11-01 2002-11-06 利乐拉瓦尔集团及财务有限公司 One-piece molded flip cap closure
CN103467824A (en) * 2013-09-22 2013-12-25 苏州市湘园特种精细化工有限公司 Modified nano-plastics and preparation method thereof
CN105037815A (en) * 2015-06-25 2015-11-11 张家港市大能塑料制品有限公司 Degradable plastic applicable to mobile phone shells and preparation method of degradable plastic
CN105385123A (en) * 2015-11-13 2016-03-09 安徽广源科技发展有限公司 Flame-retardant modified degradable plastic
CN206050453U (en) * 2016-08-31 2017-03-29 曹蓉蓉 A kind of cylindrical plastic bottle cap with soup ladle

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0337484A1 (en) * 1988-04-15 1989-10-18 Kamaya Kagaku Kogyo Co., Ltd. Inner plug of synthetic resin container for dried powders
CN1093822C (en) * 1996-11-01 2002-11-06 利乐拉瓦尔集团及财务有限公司 One-piece molded flip cap closure
EP1019298B1 (en) * 1996-11-01 2004-09-15 Tetra Laval Holdings & Finance SA One-piece molded flip cap closure, method for its production and container
CN103467824A (en) * 2013-09-22 2013-12-25 苏州市湘园特种精细化工有限公司 Modified nano-plastics and preparation method thereof
CN105037815A (en) * 2015-06-25 2015-11-11 张家港市大能塑料制品有限公司 Degradable plastic applicable to mobile phone shells and preparation method of degradable plastic
CN105385123A (en) * 2015-11-13 2016-03-09 安徽广源科技发展有限公司 Flame-retardant modified degradable plastic
CN206050453U (en) * 2016-08-31 2017-03-29 曹蓉蓉 A kind of cylindrical plastic bottle cap with soup ladle

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108128544A (en) * 2016-12-01 2018-06-08 曹文岭 The bottle cap and sealing container of a kind of sealing container
CN108792254A (en) * 2017-04-28 2018-11-13 内蒙古伊利实业集团股份有限公司 Plastic closure
CN106963212A (en) * 2017-05-17 2017-07-21 中山市乐盈网络科技有限公司 A cup that is easy to clean
US12005408B1 (en) 2023-04-14 2024-06-11 Sharkninja Operating Llc Mixing funnel
CN116832471A (en) * 2023-06-21 2023-10-03 河北爱节能源科技有限公司 Organic silicon production Hcl edulcoration device
CN119796697A (en) * 2025-03-11 2025-04-11 湖南万容包装有限公司 A convenient dustproof integrated cover

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