CN105385123A - Flame-retardant modified degradable plastic - Google Patents
Flame-retardant modified degradable plastic Download PDFInfo
- Publication number
- CN105385123A CN105385123A CN201510782975.9A CN201510782975A CN105385123A CN 105385123 A CN105385123 A CN 105385123A CN 201510782975 A CN201510782975 A CN 201510782975A CN 105385123 A CN105385123 A CN 105385123A
- Authority
- CN
- China
- Prior art keywords
- parts
- flame
- poly
- retardant
- retardant modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a flame-retardant modified degradable plastic prepared from the following raw materials in parts by weight: 10-20 parts of antimony trioxide, 4-8 parts of modified montmorillonite, 5-10 parts of epoxy chloropropane, 5-15 parts of polyamide, 5-15 parts of polyhydroxybutyrate, 2-10 parts of furfuran resin, 4-12 parts of glass fiber, 4-8 parts of zinc stearate, 5-10 parts of acetic acid, 3-5 parts of lower alcohol, 1-2 parts of methacrylic ester, 1-5 parts of polyethylene, 1-5 parts of epoxidized plant oil, 5-15 parts of corn starch, 2-8 parts of vegetable protein cellulose, 1-9 parts of woody fiber powder, 4-8 parts of poly-beta-hydroxybutyric acid, 1-3 parts of a dispersant, 2-5 parts of a plasticizer, 3-6 parts of a coupling agent and 2-6 parts of a halogen-free flame retardant. The flame-retardant modified degradable plastic disclosed by the invention is excellent in flame-retardant property.
Description
Technical field
The present invention relates to a kind of degradable plastics, particularly relate to a kind of flame-retardant modified degradable plastics.
Background technology
Plastics are seen everywhere in our daily life, and the life for people provides greatly convenient, but waste plastic point to solve very slow in nature, decompose completely and want decades, even go up a century, cause environmental pollution, thus the degraded of plastics is urgent problems; And the flame retardant properties of degradable plastics of the prior art cannot meet the demand that actual production uses, therefore inventing a kind of degradable high flame retardant plastics is problems that currently available technology needs solution badly.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of flame-retardant modified degradable plastics, has excellent flame retardant properties, and can degrade.
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 10-20 part, modified montmorillonoid 4-8 part, epoxy chloropropane 5-10 part, polymeric amide 5-15 part, poly butyric ester 5-15 part, furfuryl alcohol resin 2-10 part, glass fibre 4-12 part, Zinic stearas 4-8 part, acetic acid 5-10 part, low-carbon alcohol 3-5 part, methacrylic ester 1-2 part, polyethylene 1-5 part, epoxidized vegetable oil 1-5 part, W-Gum 5-15 part, artificial beef plant element 2-8 part, wood fiber powder 1-9 part, poly-β-hydroxybutyric acid 4-8 part, dispersion agent 1-3 part, softening agent 2-5 part, coupling agent 3-6 part, halogen-free flame retardants 2-6 part.
Preferably, modified montmorillonoid is prepared by following technique: be scattered in by the vitriol oil in water, and stir to obtain acid compound aqueous intercalation solution, polynite joined in acid compound aqueous intercalation solution, 80-90 DEG C of high-speed stirring 2-4h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 150-250 mesh sieve and obtains material a, then material a is dispersed in aqueous ethanolic solution, ultrasonic in 45-55 DEG C of water-bath-mechanical stirring dispersion 2-4h obtains material b, then in material b, Silane coupling reagent KH-570 and methyl methacrylate monomer is added, be warming up to 75-85 DEG C, insulation 5-7h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 750-850 DEG C of vacuum-drying is to constant weight, grinding, cross 150-250 mesh sieve, namely modified montmorillonoid is obtained.
Preferably, the weight ratio of the vitriol oil, water, polynite, aqueous ethanolic solution, Silane coupling reagent KH-570, methyl methacrylate monomer is 80-120:40-60:5-15:8-16:2-8:1-5.
Preferably, the concentration of aqueous ethanolic solution is 20-40%.
Preferably, the weight ratio of antimonous oxide, modified montmorillonoid, epoxy chloropropane, polymeric amide and poly butyric ester is 12-18:5-7:6-9:8-12:8-12.
Preferably, the weight ratio of furfuryl alcohol resin, glass fibre, Zinic stearas, acetic acid, low-carbon alcohol, methacrylic ester, polyethylene, epoxidized vegetable oil, W-Gum, artificial beef plant element, wood fiber powder, poly-β-hydroxybutyric acid, dispersion agent, softening agent, coupling agent and halogen-free flame retardants is 3-9:5-11:5-7:6-9:3.5-4.5:1.2-1.8:2-4:2-4:8-12:3-7:2-7:5-7:1.5-2.5:3-4:4-5:3-5.
Preferably, its raw material comprises by weight: antimonous oxide 12-18 part, modified montmorillonoid 5-7 part, epoxy chloropropane 6-9 part, polymeric amide 8-12 part, poly butyric ester 8-12 part, furfuryl alcohol resin 3-9 part, glass fibre 5-11 part, Zinic stearas 5-7 part, acetic acid 6-9 part, low-carbon alcohol 3.5-4.5 part, methacrylic ester 1.2-1.8 part, polyethylene 2-4 part, epoxidized vegetable oil 2-4 part, W-Gum 8-12 part, artificial beef plant element 3-7 part, wood fiber powder 2-8 part, poly-β-hydroxybutyric acid 5-7 part, dispersion agent 1.5-2.5 part, softening agent 3-4 part, coupling agent 4-5 part, halogen-free flame retardants 3-5 part.
The flame-retardant modified degradable plastics of one of the present invention, its raw material comprises antimonous oxide, modified montmorillonoid, epoxy chloropropane, polymeric amide, poly butyric ester, furfuryl alcohol resin, glass fibre, Zinic stearas, acetic acid, low-carbon alcohol, methacrylic ester, polyethylene, epoxidized vegetable oil, W-Gum, artificial beef plant element, wood fiber powder, poly-β-hydroxybutyric acid, dispersion agent, softening agent, coupling agent and halogen-free flame retardants, wherein using ANTIMONY TRIOXIDE SB 203 99.8 PCT as major ingredient, auxiliary interpolation modified montmorillonoid, epoxy chloropropane, polymeric amide, poly butyric ester, furfuryl alcohol resin, glass fibre, Zinic stearas, acetic acid, low-carbon alcohol, methacrylic ester, polyethylene, epoxidized vegetable oil, W-Gum, artificial beef plant element, wood fiber powder, poly-β-hydroxybutyric acid, dispersion agent, softening agent, coupling agent and halogen-free flame retardants are as auxiliary material, the proportioning of conservative control major ingredient and auxiliary material, effectively improve the flame retardant properties of flame-retardant modified degradable plastics of the present invention, wherein the ANTIMONY TRIOXIDE SB 203 99.8 PCT of major ingredient effectively can improve the flame retardant properties of flame-retardant modified degradable plastics of the present invention, in auxiliary material, by modified montmorillonoid, the consistency of polynite and structure are changed, itself and unclassified stores of the present invention can be compatible more fully, as packing material, also further increase flame retardant properties of the present invention, the epoxidized vegetable oil wherein added, W-Gum, artificial beef plant element, wood fiber powder and poly-β-hydroxybutyric acid, as the degradable composition in auxiliary material, ensure that flame-retardant modified degradable plastics of the present invention has degradability.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In embodiment, the weight part of antimonous oxide can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts; The weight part of modified montmorillonoid can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of epoxy chloropropane can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts; The weight part of polymeric amide can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of poly butyric ester can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of furfuryl alcohol resin can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts; The weight part of glass fibre can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts; The weight part of Zinic stearas can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of acetic acid can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts; The weight part of low-carbon alcohol can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of methacrylic ester can be 1 part, 1.1 parts, 1.2 parts, 1.3 parts, 1.4 parts, 1.5 parts, 1.6 parts, 1.7 parts, 1.8 parts, 1.9 parts, 2 parts; Poly weight part can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of epoxidized vegetable oil can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of W-Gum can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of artificial beef plant element can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of wood fiber powder can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of poly-β-hydroxybutyric acid can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of dispersion agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts; The weight part of softening agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of coupling agent can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of halogen-free flame retardants can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts.
Embodiment 1
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 15 parts, modified montmorillonoid 6 parts, epoxy chloropropane 7.5 parts, polymeric amide 10 parts, poly butyric ester 10 parts, furfuryl alcohol resin 6 parts, 8 parts, glass fibre, Zinic stearas 6 parts, acetic acid 7.5 parts, low-carbon alcohol 4 parts, methacrylic ester 1.5 parts, polyethylene 3 parts, epoxidized vegetable oil 3 parts, W-Gum 10 parts, artificial beef plant element 5 parts, wood fiber powder 5 parts, poly-β-hydroxybutyric acid 6 parts, dispersion agent 2 parts, 3.5 parts, softening agent, coupling agent 4.5 parts, halogen-free flame retardants 4 parts.
Modified montmorillonoid is prepared by following technique: be scattered in 50 parts of water by 100 parts of vitriol oils by weight, and stir to obtain acid compound aqueous intercalation solution, 10 parts of polynites joined in acid compound aqueous intercalation solution, 85 DEG C of high-speed stirring 3h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 200 mesh sieves and obtains material a, then material a being dispersed in 12 parts of concentration is in the aqueous ethanolic solution of 30%, ultrasonic in 50 DEG C of water-baths-mechanical stirring dispersion 3h obtains material b, then in material b, 5 parts of Silane coupling reagent KH-570s and 3 parts of methyl methacrylate monomers are added, be warming up to 80 DEG C, insulation 6h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 800 DEG C of vacuum-dryings are to constant weight, grinding, cross 200 mesh sieves, namely modified montmorillonoid is obtained.
Embodiment 2
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 10 parts, modified montmorillonoid 8 parts, epoxy chloropropane 5 parts, polymeric amide 15 parts, poly butyric ester 5 parts, furfuryl alcohol resin 10 parts, 4 parts, glass fibre, Zinic stearas 8 parts, acetic acid 5 parts, low-carbon alcohol 5 parts, methacrylic ester 1 part, polyethylene 5 parts, epoxidized vegetable oil 1 part, W-Gum 15 parts, artificial beef plant element 2 parts, wood fiber powder 9 parts, poly-β-hydroxybutyric acid 4 parts, dispersion agent 3 parts, 2 parts, softening agent, coupling agent 6 parts, halogen-free flame retardants 2 parts.
Modified montmorillonoid is prepared by following technique: be scattered in 40 parts of water by 120 parts of vitriol oils by weight, and stir to obtain acid compound aqueous intercalation solution, 15 parts of polynites joined in acid compound aqueous intercalation solution, 90 DEG C of high-speed stirring 2h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 250 mesh sieves and obtains material a, then material a being dispersed in 8 parts of concentration is in the aqueous ethanolic solution of 40%, ultrasonic in 45 DEG C of water-baths-mechanical stirring dispersion 4h obtains material b, then in material b, 2 parts of Silane coupling reagent KH-570s and 5 parts of methyl methacrylate monomers are added, be warming up to 75 DEG C, insulation 7h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 750 DEG C of vacuum-dryings are to constant weight, grinding, cross 250 mesh sieves, namely modified montmorillonoid is obtained.
Embodiment 3
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 20 parts, modified montmorillonoid 4 parts, epoxy chloropropane 10 parts, polymeric amide 5 parts, poly butyric ester 15 parts, furfuryl alcohol resin 2 parts, 12 parts, glass fibre, Zinic stearas 4 parts, acetic acid 10 parts, low-carbon alcohol 3 parts, methacrylic ester 2 parts, polyethylene 1 part, epoxidized vegetable oil 5 parts, W-Gum 5 parts, artificial beef plant element 8 parts, wood fiber powder 1 part, poly-β-hydroxybutyric acid 8 parts, dispersion agent 1 part, 5 parts, softening agent, coupling agent 3 parts, halogen-free flame retardants 6 parts.
Modified montmorillonoid is prepared by following technique: be scattered in 60 parts of water by 80 parts of vitriol oils by weight, and stir to obtain acid compound aqueous intercalation solution, 5 parts of polynites joined in acid compound aqueous intercalation solution, 90 DEG C of high-speed stirring 2h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 250 mesh sieves and obtains material a, then material a being dispersed in 8 parts of concentration is in the aqueous ethanolic solution of 40%, ultrasonic in 45 DEG C of water-baths-mechanical stirring dispersion 4h obtains material b, then in material b, 2 parts of Silane coupling reagent KH-570s and 5 parts of methyl methacrylate monomers are added, be warming up to 75 DEG C, insulation 7h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 750 DEG C of vacuum-dryings are to constant weight, grinding, cross 250 mesh sieves, namely modified montmorillonoid is obtained.
Embodiment 4
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 12 parts, modified montmorillonoid 7 parts, epoxy chloropropane 6 parts, polymeric amide 12 parts, poly butyric ester 8 parts, furfuryl alcohol resin 9 parts, 5 parts, glass fibre, Zinic stearas 7 parts, acetic acid 6 parts, low-carbon alcohol 4.5 parts, methacrylic ester 1.2 parts, polyethylene 4 parts, epoxidized vegetable oil 2 parts, W-Gum 12 parts, artificial beef plant element 3 parts, wood fiber powder 8 parts, poly-β-hydroxybutyric acid 5 parts, dispersion agent 2.5 parts, 3 parts, softening agent, coupling agent 5 parts, halogen-free flame retardants 3 parts.
Modified montmorillonoid is prepared by following technique: be scattered in 45 parts of water by 115 parts of vitriol oils by weight, and stir to obtain acid compound aqueous intercalation solution, 12 parts of polynites joined in acid compound aqueous intercalation solution, 82 DEG C of high-speed stirring 3.5h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 180 mesh sieves and obtains material a, then material a being dispersed in 15 parts of concentration is in the aqueous ethanolic solution of 25%, ultrasonic in 52 DEG C of water-baths-mechanical stirring dispersion 2.5h obtains material b, then in material b, 7 parts of Silane coupling reagent KH-570s and 2 parts of methyl methacrylate monomers are added, be warming up to 82 DEG C, insulation 5.5h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 820 DEG C of vacuum-dryings are to constant weight, grinding, cross 180 mesh sieves, namely modified montmorillonoid is obtained.
Embodiment 5
The flame-retardant modified degradable plastics of one that the present invention proposes, its raw material comprises by weight: antimonous oxide 18 parts, modified montmorillonoid 5 parts, epoxy chloropropane 9 parts, polymeric amide 8 parts, poly butyric ester 12 parts, furfuryl alcohol resin 3 parts, 11 parts, glass fibre, Zinic stearas 5 parts, acetic acid 9 parts, low-carbon alcohol 3.5 parts, methacrylic ester 1.8 parts, polyethylene 2 parts, epoxidized vegetable oil 4 parts, W-Gum 8 parts, artificial beef plant element 7 parts, wood fiber powder 2 parts, poly-β-hydroxybutyric acid 7 parts, dispersion agent 1.5 parts, 4 parts, softening agent, coupling agent 4 parts, halogen-free flame retardants 5 parts.
Modified montmorillonoid is prepared by following technique: be scattered in 55 parts of water by 85 parts of vitriol oils by weight, and stir to obtain acid compound aqueous intercalation solution, 8 parts of polynites joined in acid compound aqueous intercalation solution, 88 DEG C of high-speed stirring 2.5h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 220 mesh sieves and obtains material a, then material a being dispersed in 9 parts of concentration is in the aqueous ethanolic solution of 35%, ultrasonic in 48 DEG C of water-baths-mechanical stirring dispersion 3.5h obtains material b, then in material b, 3 parts of Silane coupling reagent KH-570s and 4 parts of methyl methacrylate monomers are added, be warming up to 78 DEG C, insulation 6.5h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 780 DEG C of vacuum-dryings are to constant weight, grinding, cross 220 mesh sieves, namely modified montmorillonoid is obtained.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. a flame-retardant modified degradable plastics, it is characterized in that, its raw material comprises by weight: antimonous oxide 10-20 part, modified montmorillonoid 4-8 part, epoxy chloropropane 5-10 part, polymeric amide 5-15 part, poly butyric ester 5-15 part, furfuryl alcohol resin 2-10 part, glass fibre 4-12 part, Zinic stearas 4-8 part, acetic acid 5-10 part, low-carbon alcohol 3-5 part, methacrylic ester 1-2 part, polyethylene 1-5 part, epoxidized vegetable oil 1-5 part, W-Gum 5-15 part, artificial beef plant element 2-8 part, wood fiber powder 1-9 part, poly-β-hydroxybutyric acid 4-8 part, dispersion agent 1-3 part, softening agent 2-5 part, coupling agent 3-6 part, halogen-free flame retardants 2-6 part.
2. flame-retardant modified degradable plastics according to claim 1, is characterized in that, it is characterized in that, modified montmorillonoid is prepared by following technique: be scattered in by the vitriol oil in water, and stir to obtain acid compound aqueous intercalation solution, polynite joined in acid compound aqueous intercalation solution, 80-90 DEG C of high-speed stirring 2-4h, filtered while hot, is washed with distilled water to neutrality, suction filtration, dries, grinding, crosses 150-250 mesh sieve and obtains material a, then material a is dispersed in aqueous ethanolic solution, ultrasonic in 45-55 DEG C of water-bath-mechanical stirring dispersion 2-4h obtains material b, then in material b, Silane coupling reagent KH-570 and methyl methacrylate monomer is added, be warming up to 75-85 DEG C, insulation 5-7h, logical nitrogen in the process of insulation, and be slowly added dropwise to Diisopropyl azodicarboxylate solution, finally reaction product is poured out, add distilled water, stir, stratification, remove supernatant liquid, lower reaction product layer is carried out suction filtration, washing, 750-850 DEG C of vacuum-drying is to constant weight, grinding, cross 150-250 mesh sieve, namely modified montmorillonoid is obtained.
3. flame-retardant modified degradable plastics according to claim 1, it is characterized in that, it is characterized in that, the weight ratio of the vitriol oil, water, polynite, aqueous ethanolic solution, Silane coupling reagent KH-570 and base methacrylate monomer is 80-120:40-60:5-15:8-16:2-8:1-5.
4. flame-retardant modified degradable plastics according to claim 1, is characterized in that, it is characterized in that, the concentration of aqueous ethanolic solution is 20-40%.
5. flame-retardant modified degradable plastics according to claim 1, is characterized in that, it is characterized in that, the weight ratio of antimonous oxide, modified montmorillonoid, epoxy chloropropane, polymeric amide and poly butyric ester is 12-18:5-7:6-9:8-12:8-12.
6. flame-retardant modified degradable plastics according to claim 1, it is characterized in that, it is characterized in that, the weight ratio of furfuryl alcohol resin, glass fibre, Zinic stearas, acetic acid, low-carbon alcohol, methacrylic ester, polyethylene, epoxidized vegetable oil, W-Gum, artificial beef plant element, wood fiber powder, poly-β-hydroxybutyric acid, dispersion agent, softening agent, coupling agent and halogen-free flame retardants is 3-9:5-11:5-7:6-9:3.5-4.5:1.2-1.8:2-4:2-4:8-12:3-7:2-7:5-7:1.5-2.5:3-4:4-5:3-5.
7. flame-retardant modified degradable plastics according to claim 1, it is characterized in that, it is characterized in that, its raw material comprises by weight: antimonous oxide 12-18 part, modified montmorillonoid 5-7 part, epoxy chloropropane 6-9 part, polymeric amide 8-12 part, poly butyric ester 8-12 part, furfuryl alcohol resin 3-9 part, glass fibre 5-11 part, Zinic stearas 5-7 part, acetic acid 6-9 part, low-carbon alcohol 3.5-4.5 part, methacrylic ester 1.2-1.8 part, polyethylene 2-4 part, epoxidized vegetable oil 2-4 part, W-Gum 8-12 part, artificial beef plant element 3-7 part, wood fiber powder 2-8 part, poly-β-hydroxybutyric acid 5-7 part, dispersion agent 1.5-2.5 part, softening agent 3-4 part, coupling agent 4-5 part, halogen-free flame retardants 3-5 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510782975.9A CN105385123A (en) | 2015-11-13 | 2015-11-13 | Flame-retardant modified degradable plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510782975.9A CN105385123A (en) | 2015-11-13 | 2015-11-13 | Flame-retardant modified degradable plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105385123A true CN105385123A (en) | 2016-03-09 |
Family
ID=55417926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510782975.9A Pending CN105385123A (en) | 2015-11-13 | 2015-11-13 | Flame-retardant modified degradable plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105385123A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105820559A (en) * | 2016-05-20 | 2016-08-03 | 苏州倍力特物流设备有限公司 | Enhanced composite packing box material and preparing method thereof |
| CN106144192A (en) * | 2016-08-31 | 2016-11-23 | 曹蓉蓉 | The cylindrical plastic bottle cap of a kind of band soup ladle and manufacture the plastics of this bottle cap |
| CN106188640A (en) * | 2016-08-31 | 2016-12-07 | 曹俪馨 | A kind of sealed plastic bottle cap and manufacture the plastics of this bottle cap |
| CN106243405A (en) * | 2016-08-31 | 2016-12-21 | 曹文岭 | A kind of hexagon plastic bottle closure and manufacture the plastics of this bottle cap |
| CN106835854A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of fire-proof and water-proof wallpaper and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102485805A (en) * | 2010-12-02 | 2012-06-06 | 广东高科达科技实业有限公司 | Method for preparing modified nano montmorillonite |
| CN102924888A (en) * | 2012-10-09 | 2013-02-13 | 山东省意可曼科技有限公司 | Full-biodegradation polyhydroxyalkanoate material with flame retardance |
| CN104893006A (en) * | 2015-06-11 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Degradable plastic |
-
2015
- 2015-11-13 CN CN201510782975.9A patent/CN105385123A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102485805A (en) * | 2010-12-02 | 2012-06-06 | 广东高科达科技实业有限公司 | Method for preparing modified nano montmorillonite |
| CN102924888A (en) * | 2012-10-09 | 2013-02-13 | 山东省意可曼科技有限公司 | Full-biodegradation polyhydroxyalkanoate material with flame retardance |
| CN104893006A (en) * | 2015-06-11 | 2015-09-09 | 张家港市山牧新材料技术开发有限公司 | Degradable plastic |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105820559A (en) * | 2016-05-20 | 2016-08-03 | 苏州倍力特物流设备有限公司 | Enhanced composite packing box material and preparing method thereof |
| CN106144192A (en) * | 2016-08-31 | 2016-11-23 | 曹蓉蓉 | The cylindrical plastic bottle cap of a kind of band soup ladle and manufacture the plastics of this bottle cap |
| CN106188640A (en) * | 2016-08-31 | 2016-12-07 | 曹俪馨 | A kind of sealed plastic bottle cap and manufacture the plastics of this bottle cap |
| CN106243405A (en) * | 2016-08-31 | 2016-12-21 | 曹文岭 | A kind of hexagon plastic bottle closure and manufacture the plastics of this bottle cap |
| CN106188640B (en) * | 2016-08-31 | 2019-02-05 | 曹俪馨 | A kind of sealed plastic bottle cap and the plastics for manufacturing the bottle cap |
| CN106835854A (en) * | 2016-12-22 | 2017-06-13 | 安徽易有墙纸有限公司 | A kind of fire-proof and water-proof wallpaper and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105385123A (en) | Flame-retardant modified degradable plastic | |
| CN103122228B (en) | Bio-oil starch adhesive for wood and preparation method | |
| CN105968743A (en) | Antibacterial polylactic acid and starch compound fully-degradable plastic film and manufacturing method thereof | |
| CN101538401A (en) | High temperature resistance binary fiber/polylactic acid based composite material and preparation method thereof | |
| CN102229750A (en) | Modified polypropylene composite material and preparation technology thereof | |
| CN108359229B (en) | Enhanced polylactic acid-based composite material and preparation method thereof | |
| CN103382315A (en) | Modified calcium carbonate used for papermaking | |
| CN105968749A (en) | Fully-degradable plastic film with excellent thermal stability for color printing packaging and manufacturing method of fully-degradable plastic film | |
| CN105968746A (en) | Oxidized graphene fully-degradable plastic film with good barrier property and manufacturing method of plastic film | |
| CN104629127A (en) | Sheathing material for modified cables and preparation method thereof | |
| CN103333410A (en) | Reinforced flame-retardant bamboo-plastic composite material and preparation method thereof | |
| CN105061924A (en) | Montmorillonite modified wood-plastic composite material plate | |
| CN103709773B (en) | The preparation method of alkali urea disentanglement stalk/resin composite plates | |
| CN105128180A (en) | Continuous extrusion type process technology for environmentally friendly biomass material | |
| CN105968745A (en) | Hydrophobic polylactic acid and starch compound fully-degradable plastic film and manufacturing method thereof | |
| CN105968748A (en) | Flame-retardant polylactic acid and starch compound fully-degradable plastic film and manufacturing method thereof | |
| CN106987148B (en) | A kind of high-strength fire-retarding wood plastic composite and preparation method thereof | |
| CN103205023A (en) | Preparation method of bamboo powder/white carbon black composite reinforced starch-based degradable plastic | |
| CN102417687B (en) | Modified impact-resistant polystyrene composite material and preparation technique thereof | |
| CN105968747A (en) | Novel polylactic acid and starch compound fully-degradable plastic film and manufacturing method thereof | |
| CN104130512A (en) | Green biodegradable composite plastic | |
| CN104387683A (en) | Preparation method of biodegradable composite plastic | |
| CN105924747A (en) | Protein-based degradable plastic sheet | |
| CN105968744A (en) | Fully-degradable plastic film with enhanced mechanical property and manufacturing method of fully-degradable plastic film | |
| CN105462203A (en) | PHB based degradable 3D printing material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160309 |