CN106135207A - A kind of Fungicidal composition - Google Patents
A kind of Fungicidal composition Download PDFInfo
- Publication number
- CN106135207A CN106135207A CN201510162113.6A CN201510162113A CN106135207A CN 106135207 A CN106135207 A CN 106135207A CN 201510162113 A CN201510162113 A CN 201510162113A CN 106135207 A CN106135207 A CN 106135207A
- Authority
- CN
- China
- Prior art keywords
- syp
- boscalid
- fungicidal composition
- composition according
- kinds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- NEDIPFILZHFIPP-UHFFFAOYSA-N O=C(c1c(C2[IH]C2)nccc1)Nc(cccc1)c1-c(cn1)ccc1Cl Chemical compound O=C(c1c(C2[IH]C2)nccc1)Nc(cccc1)c1-c(cn1)ccc1Cl NEDIPFILZHFIPP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to disinfectant use in agriculture field, be specifically related to the Fungicidal composition of a kind of SYP-3375 and Boscalid.Composition active component is SYP-3375 and Boscalid, and the ratio of weight and number between two kinds of active components is 1:100 to 100:1.The present invention be by detailed research draw SYP-3375 and Boscalid composition to multiple pathogens, especially prevent and treat stalk rot more typically during various crop produces there is good synergistic effect.
Description
Technical field
The invention belongs to disinfectant use in agriculture field, be specifically related to killing of a kind of SYP-3375 and Boscalid
Epiphyte composition.
Background technology
SYP-3375 (ISO adopted name coumoxystrobin) is Shenyang Chemical Engineering Inst. Co., Ltd
The novel methoxy acrylic ester compounds of independent development, has the bactericidal activity of wide spectrum, can be used for
Preventing and treating is drawn by multiple germs such as Oomycete, Basidiomycetes, sac fungus and Fungi Imperfectis on various crops
The disease rising.To Disease of Apple Trees (rot, spot defoliation, ring spot etc.), rice disease (line
Rot, rice blast, bakanae disease etc.), wheat diseases (head blight, powdery mildew, banded sclerotial blight, root-rot
Sick etc.), cucumber disease (downy mildew, powdery mildew, gray mold, droop, scab etc.), tomato
Disease (late blight, leaf mold, anthracnose), grape disease (downy mildew, powdery mildew, anthracnose,
White rot), sigatoka, the late blight of potato, sclerotinia rot of colza, corn southern leaf blight, cotton yellow
Droops etc. all have good prevention effect.Chemical name is: (E)-2-{2-[(3-butyl-4-methyl
-2-oxo-2H-coumarin-7-yl) epoxide methyl] phenyl }-3-methoxy-methyl acrylate, structure is such as
Under:
Boscalid (boscalid) is the picolinamide series bactericidal agent developed by BASF AG, mainly uses
In preventing and treating sclerotiniose, rust, target and gray mold etc..For prevent and treat rape, beans,
Corm vegetable, leaf mustard, carrot, dish fruit, lettuce, peanut, the frankincense coptis, potato, drupe,
Strawberry, nut, wild cabbage, cucumber, peppermint, pea, roots vegetable, sunflower, grape, lawn,
Powdery mildew on other fruit trees, vegetables, field crop etc., gray mold, various rots, brown rot
With root rot etc..Chemical name is: the chloro-N-of 2-(4 '-chlordiphenyl-2-base) niacinamide, structure is such as
Under:
Paddy rice Rice sheath blight (Rice sclerotial stem rots), is to remove paddy rice in Rice Production
Rice blast, rice sheath blight disease, the another important disease of the big disease of bacterial blight of rice three.In China,
Mostly occur in the rice workspace of the Yangtze river basin and southwest, the southeast and south China, Jilin, northeast, Heilungkiang etc.
There are generation, and the trend that this disease has area progressively to expand, the extent of injury increases the weight of year by year in ground.
The difficulty of prevention and cure of current phytopathogen is increasing, and the resistance of pathogen selects at lasting medicament
Rising year by year under pressure, the prevention effect of single dose is had a greatly reduced quality, and control of plant disease is faced with great choosing
War.It is therefore desirable to reach both to reduce optionally dangerous, the prolongation of refractory fungal bacterial strain by mixture
In the service life of active component, expand again range of application (this point is even more important), increase for agricultural
Product increases income service.So far, SYP-3375 and Boscalid composition and for stalk rot preventing and treating not
See that document is reported.
Content of the invention
It is an object of the invention to provide the Fungicidal composition of a kind of SYP-3375 and Boscalid.
The present invention is to draw SYP-3375 and Boscalid composition to multiple cause of diseases by detailed research
Bacterium, especially good synergistic effect is had to paddy rice Rice sheath blight.
For achieving the above object, technical scheme is as follows:
A kind of Fungicidal composition, composition active component is SYP-3375 and Boscalid, two kinds of work
Ratio of weight and number between property component is 1:100 to 100:1.
Ratio of weight and number between described SYP-3375 and two kinds of active components of Boscalid be 1:20 extremely
20:1。
Ratio of weight and number between described SYP-3375 and two kinds of active components of Boscalid be 1:10 extremely
10:1。
Ratio of weight and number between described SYP-3375 and two kinds of active components of Boscalid be 1:1 extremely
1:10。
Ratio of weight and number between described SYP-3375 and two kinds of active components of Boscalid be 1:1 extremely
1:5。
Active component weight percentage in described composition is 0.5-95%.Wherein, fungicide group
The amount of application when amount containing active component depends on that every kind of component is used alone in compound, also depends on
The ratio of a kind of component and another kind of component and the degree of synergistic effect.
At least containing two kinds of carriers in described composition, wherein carrier is at least a kind of surfactant.
Carrier can be solid or liquid, and the carrier being generally used for preparing microbicide compositions all can use.
The application of a kind of Fungicidal composition, described composition is used for preparing in agricultural or other field
The preparation of preventing and treating fungi.Preparation can be configured to missible oil, suspending agent, aqueous emulsion, wettable powder, water
Dispersible granule, pulvis, granule or ultra-low-volume formulation.
Described composition be used for preparing in agricultural or other field preventing and treating field crop, gourd, fruit and vegetable,
The preparation of stalk rot in flowers, medicinal material or tobacco.
Especially, for preparing the preparation of preventing and treating paddy rice Rice sheath blight.
The present composition is used as the purposes of fungicide, is particularly used for preventing and treating field crop, melon and fruit
The purposes of stalk rot in vegetables, flowers, medicinal material or tobacco.Especially, the composition of the present invention is to water
Rice Rice sheath blight has special efficacy.The composition of the present invention is used for prepare preventing and treating paddy rice Rice sheath blight bacterium
Medicine, the prevention effect of corps diseases can be significantly improved, expand fungicidal spectrum, delay pathogen
The resistance to the action of a drug occurs.
When preparing the Fungicidal composition of the present invention, pure SYP-3375 and Boscalid are preferably used,
Can be added thereto to other to harmful pathogen or the effective active material of other insects, or have and remove
The reactive compound of grass effect and growth regulating effect or fertilizer.
The invention further relates to the using method of this Fungicidal composition.SYP-3375 and Boscalid according to
The appropriate proportioning that the present invention provides prepare in advance or use extemporaneous preparation (i.e. simultaneously use) or
Individually occupation mode all presents the increase of significant controlling disease scope and puies forward the preventive effect of some disease successively
Height, including the plurality of plant diseases that oomycetes, sac fungus, basidiomycetes, Fungi Imperfecti etc. are caused.Here
The concentration of SYP-3375 is 1-1000g/hm2, preferably 20-500g/hm2.Accordingly, pyridine acyl
The concentration of bacterium amine is 1-1000g/hm2, preferably 20-500g/hm2。
According to the occurrence degree of corps diseases, the concentration of the present composition is at proportion of crop planting
Region is 5-1500g/hm2, preferably 20-500g/hm2。
During preventing and treating fungal diseases of plants, the Dressing date of composition can select at plant seeding
Before or after, or before or after plant emergence, carry out spraying or dissipating to seed, plant or soil
The modes such as powder.
Use the present composition (or its suitable preparaton) the preventing and treating harmful fungoid of applicable dosage,
Impose on harmful fungoid habitat or to prevent and treat plant, seed, soil, region that they are infected,
Material or space.The administration of composition can be carried out before or after infected by harmful fungi, and emphasis should be
Before infecting or the initial stage of infecting is administered.
Can be formulated as the antifungal cooperative compositions of the present invention can Direct spraying solution, powder, suspension
Liquid, aqueous, the oiliness of high enrichment or other suspension, dispersion, emulsion, oil dispersion, paste,
Pulvis, broadcast sowing with composition or particle, and can by spraying, atomization, dusting, broadcast sowing or topple over
Apply etc. mode.Administration form depends on specific purpose；In all cases, it should be ensured that of the present invention group
Compound is fine and is uniformly distributed.
The composition of the present invention can be configured to missible oil, suspending agent, aqueous emulsion, wettable powder, water
Multiple formulations such as dispersible granule, pulvis, granule or ultra-low-volume formulation.
Above-mentioned various preparation all can be prepared in a known manner.For example by by active component and solvent and/or
Carrier (at least one of which surfactant) mixes and prepares, and if desired can add emulsifying agent and divide
The auxiliary agents such as powder.
Suitable solvent/auxiliary agent is mainly: water；Benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and
Chlorinated aromatic hydrocarbons；Chlorinated aliphatic hydrocarbons, such as chlorobenzene, vinyl chloride, trichloroethanes, dichloromethane, chlorine
Imitative, carbon tetrachloride and many chloroethanes；Aliphatic hydrocarbon, such as petroleum distillate, hexamethylene, light mineral oil,
Paraffin and coal.But, particularly suitable is polar solvent, i.e. alcohols, for example isopropanol, butanol,
Ethylene glycol, propane diols, glycerine, sorbierite, phenmethylol, furfuryl alcohol and cyclohexanol, and they
Ether and ester；Ketone, such as acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone, butyrolactone, with
And dimethylformamide, dimethyl sulfoxide (DMSO) and 1-METHYLPYRROLIDONE；Also have vegetable oil and the molten fibre of methyl
Dimension.Meanwhile, the mixture of different liquids is also applicable.
Suitable surfactant is lignosulphonic acid, naphthalene sulfonic acids, phenolsulfonic acid, dibutyl naphthalenesulfonic acid
Alkali metal salt, alkali salt and ammonium salt, alkylaryl sulfonates, alkyl sulfate, alkyl sulfonic acid
Salt, aliphatic alcohol sulfate, aliphatic acid and sulphated fatty alcohol glycol ether, also sulfonated naphthalene and naphthalene spread out
The biological condensation product with formaldehyde, the condensation product of naphthalene or naphthalene sulfonic acids and phenol and formaldehyde, polyoxethylene octylphenyl
Phenyl ether, ethoxylated isooctyl-phenol, octyl phenol, nonyl phenol, alkyl phenyl polyglycol ether, three
Butyl phenyl polyglycol ether, three stearyl phenyl polyglycol ethers, alkyl aryl polyether alcohol, alcohol/alcohol
With fatty alcohol/ethylene oxide condensation product, ethoxylated castor oil, polyoxyethylene alkyl ether, ethoxylation
Polyoxypropylene, laruyl alcohol polyglycol ether acetal, sorbitol ester, lignin sulfite waste liquor and methyl
Cellulose.
Be suitable to preparation can Direct spraying solution, emulsion, the material of paste or oil dispersion be in higher boiling
Mineral oil fractions such as kerosene or diesel oil, the also oil of coal tar and plant or animal origin, aliphatic series,
Ring-type and aromatic hydrocarbon such as toluene, dimethylbenzene, paraffin, tetrahydronaphthalene, alkylated naphthalene or derivatives thereof,
Methyl alcohol, ethanol, propyl alcohol, butanol, cyclohexanol, cyclohexanone, isophorone, intensive polar solvent such as two
First sulfoxide, 1-METHYLPYRROLIDONE or water.
Powder, broadcasting sowing can be by mixing active material with solid carrier or one with composition and pulvis
Prepared by grinding.
Particle (such as coating particle, impregnated granules and homogeneous particle) can be by making active component and consolidating
Body carrier adheres to and prepares.Solid carrier be ore deposit soil, silicate, talcum, kaolin, activated clay,
Lime stone, lime, chalk, bole, loess, clay, dolomite, diatomite, calcium sulfate,
Magnesia, the synthetic material grinding；Fertilizer such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea；Plant
The product such as flour in source, bark powder, wood powder and shuck powder, cellulose powder and other solid carriers.
The present composition usually contains the active component of 0.5～95% (weight), preferably comprises 1～80%
The active component of (weight).
Part preparaton to prepare example as follows, it is true that wherein said active component is killing of the present invention
SYP-3375 in bacteria composition and Boscalid, the proportioning of two components as previously mentioned in the range of can do
Arbitrarily adjust.
First, the product of dilute with water, by weight percentage:
Example the 1st, 10% aqueous emulsion (EW) reactive compound 10%, agriculture breast 0201B 5%, dimethyl sulfoxide 12%,
Dimethylformamide 8%, agriculture breast 22016%, agriculture breast 16011.5%, ethylene glycol 5%, water complements to
100%.
Example the 2nd, 20% wettable powder (WP) reactive compound 20%, sodium lignin sulfonate 5%, ten
Dialkyl benzene sulfonic acids sodium 1%, alkyl naphthalene formaldehyde condensation product 5%, White Carbon black 5%, precipitated calcium carbonate is supplied
To 100%.
Example the 3rd, 10% missible oil (EC) reactive compound 10%, agriculture breast 0201B 5%, agriculture breast 0203B 5%,
Methyl alcohol 5%, dimethylformamide 10%, dimethylbenzene complements to 100%.
Example the 4th, 10% aqueous emulsion (EW) reactive compound 10%, alkylaryl formaldehyde resin polyoxy second
Alkene ether 10.5%, agriculture breast 507#8.5%, tetradecanol 0.6%, dimethylformamide 15%, the third two
Alcohol 5%, water complements to 100%.
Example the 5th, 20% suspending agent (SC) reactive compound 20%, methyl naphthalene sulfonate formaldehyde condensate
2.5%, sodium lignin sulfonate 3.5%, White Carbon black 0.2%, ethylene glycol 4%, defoamer is a little, water
Complement to 100%.
Example the 6th, 36% water dispersible granules (WG) reactive compound 36%, neopelex 1%,
Naphtholsulfonic acid formaldehyde condensation products 16%, calcium dodecyl benzene sulfonate 5%, bentonite 15%, kaolin is mended
Foot is to 100%.
Example the 7th, 60% wettable powder (WP) reactive compound 60%, lauryl sodium sulfate 2%,
White Carbon black 5%, sodium lignin sulfonate 8%, methyl naphthalene sulfonate formaldehyde condensate 5%, lightweight carbonic acid
Calcium complements to 100%.
Example the 8th, 60% water dispersible granules (WG) reactive compound 60%, methyl naphthalene sulfonic acid sodium formaldehyde is condensed
Thing 15%, sodium alginate 5%, PEG 8000 5%, sodium sulphate 15%, bentonite complements to 100%.
2nd, without the i.e. spendable product of dilution, meter by weight:
Example the 9th, 5% pulvis (DP) grinds in small, broken bits for 5 parts of active components and the kaolin in small, broken bits with 95%
It is sufficiently mixed and obtain pulvis.
Example the 10th, 0.5 granule (GR) grinds and combines 99.5% by small, broken bits for 0.5 part of active component
Carrier, current methods be extrusion, be spray-dried or fluid bed, obtain without dilution i.e. spendable
Particle.
10 parts of active compounds are dissolved in organic solvent such as by example the 11st, 10% ultra-low-volume formulation (ULV)
In dimethylbenzene, obtain without the i.e. spendable product of dilution.
The product that the present invention describes provides with finished product preparation form, and i.e. in composition, each material is blended,
Meanwhile, the composition of composition also can provide with the form of independent preparation, straight in bucket (tank) before using
Connect mixing.The concentrate of the present invention is generally and water is mixed to get the concentration of required active material, by spray
Mist, atomization, dusting, broadcast sowing or pour into a mould and use.Type of service depends entirely on mesh to be reached
, guarantee most preferably may being distributed of active compound of the present invention in all cases.
Aqueous type of service can be by adding water (sprayable by emulsion concentrates, paste or wettable powder
Powder, oil dispersion) prepare.For preparing emulsion, paste or oil dispersion, can be by wetting agent, increasing
This material directly or is homogenized after being dissolved in oil or solvent in water by stick, dispersant or emulsifying agent.Or
Person, can prepare and be suitable to dilute with water and by active material, wetting agent, tackifier, dispersant or breast
The concentrate of agent, solvent or oil composition.
Various types of oil, wetting agent, adjuvant, herbicide, fungicide, other agricultural chemicals or kill true
Microbial inoculum all can add in the present composition；If suitable, just before next-door neighbour uses, add (bucket mixing).
These reagent generally mix with the weight ratio of 1:30-30:1 with the present composition.
The Fungicidal composition of the present invention has the advantage that Synergistic, improves the anti-of corps diseases
Control effect, expand fungicidal spectrum, delay the pathogen resistance to the action of a drug to occur.
Detailed description of the invention
Following example are used for further describing the present invention, but the present invention is limited to absolutely not these examples.
The synergistic function to harmful fungoid for the composition of the present invention can be illustrated by the following example.
Measure the composition of SYP-3375 and Boscalid at indoor employing growth rate method to paddy rice sclerotium
The prevention effect of stalk rot.
Reagent agent: the 96% former medicine of Boscalid, BASF AG of Germany；96% SYP-3375
Former medicine, Bada Pesticide Co., Ltd., Jilin Province.
For examination bacterial classification and culture medium: paddy rice Rice sheath blight bacterium Nakataea
Sigmoidea (Cavara) Hava, is separated by agricultural chemicals teaching and research room of Jilin Agriculture University, is identified.
Method of testing:
Test medicine screening and concentration determine: by reagent agent respectively with a small amount of organic solvent (e.g., acetone)
Dissolving, adding sterilized water, empirically needing to be configured to mass concentration is that 1000mg/L mother liquor is standby,
It is diluted to different concentration during use.The mass concentration of SYP-3375 is the 10th, the 2nd, the 0.4th, the 0.08th, 0.016
mg/L；Boscalid mass concentration is the 1st, the 0.2nd, the 0.04th, the 0.008th, 0.0016mg/L；Carbendazim
The mass concentration of (comparison medicament) is the 25th, the 5th, the 1st, the 0.2nd, 0.4mg/L.
Single dose Toxicity Determination: the PDA culture medium having melted is cooled to 60～70 DEG C, by set concentration
Add quantitative pharmacy, make variable concentrations pastille culture medium, after cooling, access the paddy rice bacterium of diameter 5mm
Core stalk rot bacterium bacterium cake, separately sets not adding medicine blank, often processes 3 times and repeat.Inoculation rear plate
It is placed in incubator (25 DEG C) and cultivates 48h, rear employing right-angled intersection method measurement colony growth diameter, press
Equation below calculates the inhibiting rate to bacterium colony for this drug concentrations.Evaluate system with DPS to be analyzed, meter
Calculate regression equation, EC50Value and coefficient correlation (seeing table 1).
Fungicide compounding is to paddy rice Rice sheath blight bacterium toxicity test: according to single dose toxicity test result and
Its mechanism of action, selects the preferable SYP-3375 of fungistatic effect and Boscalid to carry out joint toxicity measuring,
If mixture mass ratio is 5:1,3:1,1:1,1:3,1:5, adding same volume sterilized water is comparison, often
Individual process is repeated 3 times, and experimental technique, calculating are identical with indoor single dose toxicity test method.Use Wadley
Method calculates the co-toxicity effect to paddy rice Rice sheath blight for the compound drug.According to coefficient of synergism (SR)
Evaluate the synergistic effect of pharmacy mix, i.e. SR < 0.5 is antagonism, 0.5≤SR≤1.5
For summation action, SR > 1.5 be synergistic effect (seeing table 2).
Boscalid and the field efficiency test of SYP-3375 confection: test and enter in big An County, Jilin Province
OK, and on this ground select that physical features is smooth, fertility level uniformity, the normal field of field management.
By 36% SYP-3375 Boscalid water dispersible granules after processing (according to examples detailed above in experimentation
6 preparations, wherein between SYP-3375 and Boscalid mass fraction ratio for 1:1) according to the 200th, the 150th,
100g a.i./hm2Spray in rice plant of tillering stage, Boscalid, SYP-3375 and carbendazim are set
Single dose is comparison medicament.10d " Invest, Then Investigate " record field incidence, and calculate field efficacy and (see
Table 3).
Measurement result:
Boscalid, SYP-3375 and the toxicity test to paddy rice Rice sheath blight for the carbendazim, result is shown in
Table 1 below.
Table 1 Boscalid, SYP-3375 and the Toxicity Determination to paddy rice Rice sheath blight for the carbendazim
| Reagent agent | Virulence regression equation (y=) | EC50Value/(mg L-1) | Coefficient correlation (r) |
| Boscalid | 0.8197x+6.6542 | 0.0037 | 0.9531 |
| SYP-3375 | 0.3808x+5.4559 | 0.0079 | 0.9629 |
| Carbendazim | 0.8067x+5.2907 | 0.0113 | 0.9546 |
SYP-3375 and Boscalid joint toxicity measuring, result see table 2.
Table 2 SYP-3375 and the joint toxicity measuring to paddy rice Rice sheath blight bacterium for the Boscalid mixed agent
SYP-3375 Boscalid field plot trial, result see table 3.
Table 3 SYP-3375 Boscalid results of field plot
Claims (10)
1. a Fungicidal composition, it is characterised in that: composition active component is SYP-3375 and pyridine
Acyl bacterium amine, the ratio of weight and number between two kinds of active components is 1:100 to 100:1.
2. Fungicidal composition according to claim 1, it is characterised in that: described SYP-3375
With the ratio of weight and number between two kinds of active components of Boscalid is 1:20 to 20:1.
3. Fungicidal composition according to claim 2, it is characterised in that: described SYP-3375
With the ratio of weight and number between two kinds of active components of Boscalid is 1:10 to 10:1.
4. Fungicidal composition according to claim 3, it is characterised in that: described SYP-3375
With the ratio of weight and number between two kinds of active components of Boscalid is 1:1 to 1:10.
5. Fungicidal composition according to claim 4, it is characterised in that: described SYP-3375
With the ratio of weight and number between two kinds of active components of Boscalid is 1:1 to 1:5.
6. the Fungicidal composition according to any one of claim 1-5, it is characterised in that: combination
Active component weight percentage in thing is 0.5-95%.
7. Fungicidal composition according to claim 1, it is characterised in that: in composition at least
Containing two kinds of carriers, wherein, carrier is at least a kind of surfactant.
8. the application of a Fungicidal composition according to claim 7, it is characterised in that: institute
State composition in agricultural or other field for preparing the preparation of preventing and treating fungi.
9. the application of Fungicidal composition according to claim 8, it is characterised in that: described group
Compound is used for preparing preventing and treating field crop, gourd, fruit and vegetable, flowers, medicinal material in agricultural or other field
Or the preparation of stalk rot in tobacco.
10. the application of Fungicidal composition according to claim 9, it is characterised in that: it is used for
The preparation of preparation preventing and treating paddy rice Rice sheath blight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510162113.6A CN106135207A (en) | 2015-04-07 | 2015-04-07 | A kind of Fungicidal composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510162113.6A CN106135207A (en) | 2015-04-07 | 2015-04-07 | A kind of Fungicidal composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106135207A true CN106135207A (en) | 2016-11-23 |
Family
ID=57335682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510162113.6A Pending CN106135207A (en) | 2015-04-07 | 2015-04-07 | A kind of Fungicidal composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106135207A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080293567A1 (en) * | 2005-11-10 | 2008-11-27 | Erich Birner | Fungicidal Mixtures Comprising Boscalid and Pyrimethanil |
| CN101485307A (en) * | 2009-02-09 | 2009-07-22 | 吉林省八达农药有限公司 | Agricultural fungicidal composition containing SYP-3375 and triazole fungicide |
| CN103210937A (en) * | 2013-02-06 | 2013-07-24 | 吉林省八达农药有限公司 | Composition comprising coumoxystrobin and other bactericides |
| CN104430357A (en) * | 2014-11-10 | 2015-03-25 | 吉林省八达农药有限公司 | Bactericide composition containing coumoxystrobin with synergistic effect |
-
2015
- 2015-04-07 CN CN201510162113.6A patent/CN106135207A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080293567A1 (en) * | 2005-11-10 | 2008-11-27 | Erich Birner | Fungicidal Mixtures Comprising Boscalid and Pyrimethanil |
| CN101485307A (en) * | 2009-02-09 | 2009-07-22 | 吉林省八达农药有限公司 | Agricultural fungicidal composition containing SYP-3375 and triazole fungicide |
| CN103210937A (en) * | 2013-02-06 | 2013-07-24 | 吉林省八达农药有限公司 | Composition comprising coumoxystrobin and other bactericides |
| CN104430357A (en) * | 2014-11-10 | 2015-03-25 | 吉林省八达农药有限公司 | Bactericide composition containing coumoxystrobin with synergistic effect |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102106349B (en) | Antifungal composition containing tebuconazole and pyrimidine compound | |
| CN102106355B (en) | Antifungal composition containing pyraoxystrobin | |
| CN101595882B (en) | Pesticide composition containing methoxyl acrylic ester bactericide | |
| CN101953352B (en) | Antifungal composition containing pyraclostrobin and pyrimidine compounds | |
| CN104839168B (en) | Bactericidal composition and its application | |
| CN102630679A (en) | Pesticide composition containing orysastrobin | |
| CN103120166B (en) | Hymexazol-containing sterilizing composition | |
| CN104542585A (en) | Fungicide composition and application thereof | |
| CN114617127B (en) | Pesticide sterilization composition and application thereof | |
| CN101669495A (en) | Bactericidal composition containing kresoxim-methyl phenylate | |
| CN103385249B (en) | Antifungal composition containing flumorph and prochloraz | |
| CN104522035A (en) | Compound composition containing 2-(p-fluorophenyl)-5-methanesulfonyl-1,3,4-oxadiazole and leasn and preparation | |
| CN104488930B (en) | A kind of complex composition and preparation of the azoles of bacterium containing methylsulfonyl and Zhongshengmycin | |
| CN103053606B (en) | Antifungal composition containing pyraoxystrobin | |
| CN102318626A (en) | Germicidal composition containing bupirimate and EBDC compounds | |
| CN106135207A (en) | A kind of Fungicidal composition | |
| CN104488963A (en) | Compound composition with methanesulphonyl myclobutanil and organic copper bactericide and preparation | |
| CN104365634A (en) | Fungicide composition containing amisulborum and mancozeb and application | |
| CN104430390A (en) | Amino-oligosaccharin and ethaboxam compounded agricultural fungicide | |
| CN104522030B (en) | A kind of containing methylsulfonyl bacterium azoles and the complex composition of imidazoles antibacterial and preparation | |
| CN103704237B (en) | A kind of Fungicidal composition containing pyrazole compound and glyoxaline compound | |
| CN107853309A (en) | A kind of composition pesticide comprising folpet and dimethomorph | |
| CN103053563B (en) | Antifungal composition containing pyraoxystrobin | |
| CN103053582B (en) | Antifungal composition containing pyraoxystrobin | |
| CN104365619B (en) | A kind of bactericidal composition and application containing amisulbrom and Acibenzolar |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161123 |
|
| RJ01 | Rejection of invention patent application after publication |