CN106120382A - A kind of natural dye environment-friendly type mordant and preparation method thereof - Google Patents

A kind of natural dye environment-friendly type mordant and preparation method thereof Download PDF

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Publication number
CN106120382A
CN106120382A CN201610468058.8A CN201610468058A CN106120382A CN 106120382 A CN106120382 A CN 106120382A CN 201610468058 A CN201610468058 A CN 201610468058A CN 106120382 A CN106120382 A CN 106120382A
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China
Prior art keywords
natural dye
friendly type
cerine
environment
organic acid
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CN201610468058.8A
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Chinese (zh)
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CN106120382B (en
Inventor
何时荣
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Huzhou New Jiayi Silk Printing Co Ltd
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Huzhou New Jiayi Silk Printing Co Ltd
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Priority to CN201610468058.8A priority Critical patent/CN106120382B/en
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67383—Inorganic compounds containing silicon
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
    • D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/653—Nitrogen-free carboxylic acids or their salts
    • D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

A kind of natural dye environment-friendly type mordant and preparation method thereof, use cerine, organic acid and coordinate the mode of Graphene, it is prepared for the mordant with good result, the colour fixation of natural dye can be effectively improved, simultaneously in preparation process, it is not necessary to the rare earth element containing cerine carries out chemical extraction, greatly reduces the usage amount of various chemical reagent, decrease environmental pollution, meet country's requirement to textile industry health environment-friendly.

Description

A kind of natural dye environment-friendly type mordant and preparation method thereof
Technical field
The present invention relates to technical field of textile printing, particularly relate to a kind of natural dye environment-friendly type mordant and preparation thereof Method.
Background technology
Along with the constantly enhancing of mankind's environmental consciousness and the growing interest to own health, partial synthesis dyestuff is to the mankind The produced harm of healthy and ecological environment is the most noticeable.Existing result of study is it has been shown that there are 23 kinds of causes Cancer aromatic amine, more than 100 synthetic dyestuffs likely produce carcinogen, and more than 20 synthetic dyestuffs produce allergy to skin.Cause This, the textile of synthetic dyestuffs and dyeing thereof makes consumer suspect.Moreover, along with petroleum resources continuous on the earth Consume, be becoming tight the raw material problem day of synthetic dyestuffs.
Natural dye refers to extract from the root of plant, leaf, bark, trunk, shell, flower or animal secretions, mineral , preparation process does not results in environmental pollution；After dyeing, fabric wears safety, has unlike some synthetic dyestuffs textile Carcinogenic, teratogenesis or cause allergic reaction, and natural dye is good with the ecological environment compatibility, biodegradable；Except dyeing Outside function, part natural dye also has medicinal health-care function.Under the tide impact that current people advocate green consumption product, The fields such as high grade true silk goods, health care underwear, home textile product, adornment have vast potential for future development.
Natural dye is nontoxic, ecological, environmental protective, and application on the textile is increasing.But natural dye exists stable Property poor, dyeing and printing fabric fastness difference shortcoming.
Summary of the invention
In order to solve the problem in background technology, the present invention provides a kind of natural dye environment-friendly type mordant and preparation thereof Method.
A kind of natural dye environment-friendly type mordant, including the main component of following percentage by weight:
Cerine 75-85%
Organic acid 8-12%
Graphene 0.05-0.3%
Dispersant surplus.
Preferably, described organic acid is citric acid.
Preferably, described dispersant is sodium polyacrylate.
The preparation method of a kind of natural dye environment-friendly type mordant, comprises the following steps:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 500- 1200nm；
Step 3: add organic acid, under 800-1000rpm speed, stirs 15-20min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant.
The present invention uses cerine and dispersant and the mode of Graphene co-ground, is fully divided by cerine powder in water Dissipate, be subsequently adding modified with organic acids, obtain natural dye environment-friendly type mordant.
Cerine is a kind of zoisite race mineral containing higher rare earth component.Wherein cerium may be up to 11%, the most often contains Yttrium, thorium, lanthanum etc., the most also beryllium is up to 3.8%, being mixed into of magnesium, manganese etc..The preparation process of the present invention mainly utilizes its rare earth Composition, and it is modified, reach the effect of mordant.
The two dimensional crystal of only one layer of atomic thickness that Graphene is made up of carbon atom.2004, Manchester, England College Physics scholar An Deliegaimu and Constantine's Nuo Woxiao love, Graphene is isolated in success from graphite, it was demonstrated that It can be with individualism, and two people obtain Nobel Prize in physics in 2010 the most jointly.
Before at the end of 2015, boron alkene finds, Graphene is the thinnest material, is also the most tough material, fracture strength More taller than best steel 200 times.It has again good elasticity simultaneously, and stretch range can reach the 20% of own dimensions.It is The material that nature is the thinnest, intensity is the highest at present.
Graphene can be that the effective ingredient in cerine carries out reaction offer place with organic acid in preparation process, carries High reaction efficiency and reaction effect.
The present invention, in preparation process, after only cerine being carried out simple physical grinding process, adds organic acid and enters Row modification, it is not necessary to its rare earth element contained is carried out chemical extraction, greatly reduces the usage amount of various chemical reagent, subtract Lack environmental pollution, matched with natural dye, meet country's requirement to textile industry health environment-friendly.
Natural dye environment-friendly type mordant of the present invention, uses cerine, organic acid and coordinates Graphene Mode, is prepared for the mordant with good result, can be effectively improved the colour fixation of natural dye, simultaneously in preparation process In, it is not necessary to the rare earth element containing cerine carries out chemical extraction, greatly reduces the usage amount of various chemical reagent, subtracts Lack environmental pollution, meet country's requirement to textile industry health environment-friendly.
Detailed description of the invention
Embodiment 1
A kind of natural dye environment-friendly type mordant, including the main component of following percentage by weight:
Cerine 82%
Organic acid 10%
Graphene 0.2%
Dispersant surplus；
Described organic acid is citric acid；
Described dispersant is sodium polyacrylate；
The preparation method of a kind of natural dye environment-friendly type mordant, comprises the following steps:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 800- 1000nm；
Step 3: add organic acid, under 850rpm speed, stirs 18min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant.
Embodiment 2
A kind of natural dye environment-friendly type mordant, including the main component of following percentage by weight:
Cerine 75%
Organic acid 12%
Graphene 0.3%
Dispersant surplus；
Described organic acid is citric acid；
Described dispersant is sodium polyacrylate；
The preparation method of a kind of natural dye environment-friendly type mordant, comprises the following steps:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 1000- 1200nm；
Step 3: add organic acid, under 1000rpm speed, stirs 20min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant.
Embodiment 3
A kind of natural dye environment-friendly type mordant, including the main component of following percentage by weight:
Cerine 85%
Organic acid 8%
Graphene 0.05%
Dispersant surplus；
Described organic acid is citric acid；
Described dispersant is sodium polyacrylate；
The preparation method of a kind of natural dye environment-friendly type mordant, comprises the following steps:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 500- 700nm；
Step 3: add organic acid, under 800rpm speed, stirs 15min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto, Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.

Claims (5)

1. a natural dye environment-friendly type mordant, it is characterised in that include the composition of following percentage by weight:
Cerine 75-85%
Organic acid 8-12%
Graphene 0.05-0.3%
Dispersant surplus.
Natural dye environment-friendly type mordant the most according to claim 1, it is characterised in that described organic acid is Fructus Citri Limoniae Acid.
Natural dye environment-friendly type mordant the most according to claim 1, it is characterised in that described dispersant is poly-third Olefin(e) acid sodium.
4. the natural dye preparation method of environment-friendly type mordant, it is characterised in that comprise the following steps:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 500- 1200nm；
Step 3: add organic acid, under 800-1000rpm speed, stirs 15-20min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant.
The preparation method of natural dye environment-friendly type mordant the most according to claim 4, it is characterised in that include following Step:
Step one: cerine is pulverized, and cross 120 mesh sieves, extracting screen underflow；
Step 2: by cerine powder, be added to the water, adds Graphene and dispersant, uses ball milling method, is ground to 800- 1000nm；
Step 3: add organic acid, under 850rpm speed, stirs 18min；
Step 4: use the mode being spray-dried, be dried, obtain natural dye environment-friendly type mordant；
Described natural dye environment-friendly type mordant, including the composition of following percentage by weight:
Cerine 82%
Organic acid 10%
Graphene 0.2%
Dispersant surplus；
Described organic acid is citric acid；
Described dispersant is sodium polyacrylate.
CN201610468058.8A 2016-06-24 2016-06-24 A kind of natural dye environment-friendly type mordant and preparation method thereof Active CN106120382B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110424169A (en) * 2019-08-06 2019-11-08 安徽恒益纺织科技有限公司 A kind of textile fabric environmentally friendly coloring agent and preparation method thereof
EP3628773A1 (en) * 2018-09-27 2020-04-01 Sanko Tekstil Isletmeleri San. Ve Tic. A.S. A process of textile dyeing and dyed textiles

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102182078A (en) * 2011-04-06 2011-09-14 绍兴文理学院 Monascorubrin mordant dyeing method of silk textile
CN102561063A (en) * 2012-02-08 2012-07-11 上海工程技术大学 Rare earth mordant dyeing method for kapok fiber and textile thereof
CN102605652A (en) * 2011-12-13 2012-07-25 营口朗时多丝绸有限责任公司 Method for dyeing pure silk by regarding rare earth material as mordant

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102182078A (en) * 2011-04-06 2011-09-14 绍兴文理学院 Monascorubrin mordant dyeing method of silk textile
CN102605652A (en) * 2011-12-13 2012-07-25 营口朗时多丝绸有限责任公司 Method for dyeing pure silk by regarding rare earth material as mordant
CN102561063A (en) * 2012-02-08 2012-07-11 上海工程技术大学 Rare earth mordant dyeing method for kapok fiber and textile thereof

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Title
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3628773A1 (en) * 2018-09-27 2020-04-01 Sanko Tekstil Isletmeleri San. Ve Tic. A.S. A process of textile dyeing and dyed textiles
WO2020064845A1 (en) * 2018-09-27 2020-04-02 Sanko Tekstil Isletmeleri San. Ve Tic. A.S. A process of textile dyeing and dyed textiles
JP2020076188A (en) * 2018-09-27 2020-05-21 サンコ テキスタイル イスレットメレリ サン ベ ティク エーエスＳａｎｋｏ Ｔｅｋｓｔｉｌ Ｉｓｌｅｔｍｅｌｅｒｉ Ｓａｎ． Ｖｅ Ｔｉｃ． Ａ．Ｓ． Process of textile dyeing and dyed textiles
US10954628B2 (en) 2018-09-27 2021-03-23 Sanko Tekstil Isletmeleri San. Ve Tic. A.S. Process of textile dyeing and dyed textiles
JP7346197B2 (en) 2018-09-27 2023-09-19 サンコ テキスタイル イスレットメレリ サン ベ ティク エーエス Textile dyeing method and dyed textile products
CN110424169A (en) * 2019-08-06 2019-11-08 安徽恒益纺织科技有限公司 A kind of textile fabric environmentally friendly coloring agent and preparation method thereof

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Denomination of invention: The invention relates to an environmental friendly mordant for natural dyes and a preparation method thereof

Effective date of registration: 20210729

Granted publication date: 20180914

Pledgee: Zhejiang Deqing Rural Commercial Bank Co.,Ltd. Xinshi sub branch

Pledgor: HUZHOU XINJIAYI SILK WEAVING PRINTING Co.,Ltd.

Registration number: Y2021330001033