CN106120382B - A kind of natural dye environment-friendly type mordant and preparation method thereof - Google Patents
A kind of natural dye environment-friendly type mordant and preparation method thereof Download PDFInfo
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- CN106120382B CN106120382B CN201610468058.8A CN201610468058A CN106120382B CN 106120382 B CN106120382 B CN 106120382B CN 201610468058 A CN201610468058 A CN 201610468058A CN 106120382 B CN106120382 B CN 106120382B
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- Prior art keywords
- natural dye
- cerine
- friendly type
- environment
- organic acid
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/34—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using natural dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
Abstract
A kind of natural dye environment-friendly type mordant and preparation method thereof, by the way of cerine, organic acid and cooperation graphene, it is prepared for the mordant with good result, it can effectively improve the colour fixation of natural dye, simultaneously in preparation process, chemical extraction need not be carried out to the rare earth element that cerine contains, greatly reduce the usage amount of various chemical reagent, reduce environmental pollution, meets requirement of the country to textile industry health environment-friendly.
Description
Technical field
The present invention relates to technical field of textile printing more particularly to a kind of natural dye environment-friendly type mordant and its preparations
Method.
Background technology
With the continuous enhancing of mankind's environmental consciousness and to the growing interest of own health, partially synthetic dyestuff is to the mankind
Harm caused by health and ecological environment is more and more noticeable.Existing result of study is it has been shown that there is 23 kinds of causes
Cancer aromatic amine, more than 100 synthetic dyestuffs are possible to generate carcinogen, and more than 20 synthetic dyestuffs generate allergy to skin.Cause
This, the textile of synthetic dyestuffs and its dyeing makes consumer suspect.Moreover, on the earth petroleum resources it is continuous
Consumption, the raw material problem of synthetic dyestuffs be becoming tight by day.
Natural dye refers to being extracted in the root from plant, leaf, bark, trunk, shell, flower or animal secretions, minerals
, preparation process will not cause environmental pollution；Fabric dress safety, has unlike some synthetic dyestuffs textiles after dyeing
Carcinogenic, teratogenesis causes allergic reaction, and natural dye and ecological environment compatibility are good, biodegradable；Except dyeing
Outside function, part natural dye also has the function of medicinal health-care.In the case where current people advocate the tide impact of green consumption product,
Possess vast potential for future development in the fields such as high grade true silk product, health care underwear, home textile product, adornment.
Natural dye is nontoxic, ecological, environmental protective, and application on the textile is increasing.But natural dye, which exists, to be stablized
Poor, the disadvantage of dyeing and printing fabric fastness difference of property.
Invention content
In order to solve the problems in background technology, the present invention provides a kind of natural dye environment-friendly type mordant and its preparation
Method.
A kind of natural dye environment-friendly type mordant, includes the main component of following weight percent：
Cerine 75-85%
Organic acid 8-12%
Graphene 0.05-0.3%
Dispersant surplus.
Preferably, the organic acid is citric acid.
Preferably, the dispersant is Sodium Polyacrylate.
A kind of natural dye preparation method of environment-friendly type mordant, includes the following steps：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to 500- using ball milling method
1200nm；
Step 3：Organic acid is added, under 800-1000rpm speed, stirs 15-20min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant.
The present invention is fully divided in water by the way of cerine and dispersant and graphene co-ground, by cerine powder
It dissipates, modified with organic acids is then added, obtains natural dye environment-friendly type mordant.
Cerine is a kind of zoisite race mineral containing higher rare earth component.Wherein cerium may be up to 11%, additionally often contain
Yttrium, thorium, lanthanum etc., also up to 3.8%, magnesium, manganese etc. are mixed into beryllium sometimes.Its rare earth is mainly utilized in the preparation process of the present invention
Ingredient, and it is modified, achieve the effect that mordant.
The two dimensional crystal for only one layer of atomic thickness that graphene is made of carbon atom.2004, Manchester, England
Graphene is isolated in College Physics scholar An Deliegaimu and Constantine's Nuo Woxiao loves, success from graphite, it was demonstrated that
Therefore it can also obtain Nobel Prize in physics in 2010 jointly with individualism, two people.
Before the discovery of 2015 year end boron alkene, graphene is both most thin material, and most tough material, fracture strength
200 times more taller than best steel.It has good elasticity, stretch range that can reach the 20% of own dimensions again simultaneously.It is
Nature is most thin at present, the highest material of intensity.
Graphene with organic acid can react providing place in preparation process for the active ingredient in cerine, carry
High reaction efficiency and reaction effect.
The present invention is in preparation process, after only carrying out simple physical grinding processing to cerine, add organic acid into
Row is modified, and need not be carried out chemical extraction to the rare earth element that it contains, be greatly reduced the usage amount of various chemical reagent, subtract
Lack environmental pollution, matched with natural dye, meets requirement of the country to textile industry health environment-friendly.
Natural dye of the present invention environment-friendly type mordant, using cerine, organic acid and cooperation graphene
Mode is prepared for the mordant with good result, can effectively improve the colour fixation of natural dye, while in preparation process
In, chemical extraction need not be carried out to the rare earth element that cerine contains, greatly reduce the usage amount of various chemical reagent, subtract
Lack environmental pollution, meets requirement of the country to textile industry health environment-friendly.
Specific implementation mode
Embodiment 1
A kind of natural dye environment-friendly type mordant, includes the main component of following weight percent：
Cerine 82%
Organic acid 10%
Graphene 0.2%
Dispersant surplus；
The organic acid is citric acid；
The dispersant is Sodium Polyacrylate；
A kind of natural dye preparation method of environment-friendly type mordant, includes the following steps：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to 800- using ball milling method
1000nm；
Step 3：Organic acid is added, under 850rpm speed, stirs 18min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant.
Embodiment 2
A kind of natural dye environment-friendly type mordant, includes the main component of following weight percent：
Cerine 75%
Organic acid 12%
Graphene 0.3%
Dispersant surplus；
The organic acid is citric acid；
The dispersant is Sodium Polyacrylate；
A kind of natural dye preparation method of environment-friendly type mordant, includes the following steps：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to using ball milling method
1000-1200nm；
Step 3：Organic acid is added, under 1000rpm speed, stirs 20min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant.
Embodiment 3
A kind of natural dye environment-friendly type mordant, includes the main component of following weight percent：
Cerine 85%
Organic acid 8%
Graphene 0.05%
Dispersant surplus；
The organic acid is citric acid；
The dispersant is Sodium Polyacrylate；
A kind of natural dye preparation method of environment-friendly type mordant, includes the following steps：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to 500- using ball milling method
700nm；
Step 3：Organic acid is added, under 800rpm speed, stirs 15min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (2)
1. a kind of natural dye preparation method of environment-friendly type mordant, which is characterized in that include the following steps：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to 500- using ball milling method
1200nm；
Step 3：Organic acid is added, under 800-1000rpm speed, stirs 15-20min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant；
Natural dye environment-friendly type mordant, includes the ingredient of following weight percent：
Cerine 75-85%
Organic acid 8-12%
Graphene 0.05-0.3%
Dispersant surplus；
The organic acid is citric acid；
The dispersant is Sodium Polyacrylate.
2. the natural dye according to claim 1 preparation method of environment-friendly type mordant, which is characterized in that including following
Step：
Step 1：Cerine is crushed, and crosses 120 mesh sieve, extracting screen underflow；
Step 2：By cerine powder, it is added to the water, graphene is added and dispersant is ground to 800- using ball milling method
1000nm；
Step 3：Organic acid is added, under 850rpm speed, stirs 18min；
Step 4：It by the way of spray drying, is dried, obtains natural dye environment-friendly type mordant；
Natural dye environment-friendly type mordant, includes the ingredient of following weight percent：
Cerine 82%
Organic acid 10%
Graphene 0.2%
Dispersant surplus；
The organic acid is citric acid；
The dispersant is Sodium Polyacrylate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201610468058.8A CN106120382B (en) | 2016-06-24 | 2016-06-24 | A kind of natural dye environment-friendly type mordant and preparation method thereof |
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| CN201610468058.8A CN106120382B (en) | 2016-06-24 | 2016-06-24 | A kind of natural dye environment-friendly type mordant and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN106120382A CN106120382A (en) | 2016-11-16 |
| CN106120382B true CN106120382B (en) | 2018-09-14 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| DK3628773T3 (en) | 2018-09-27 | 2024-02-26 | Sanko Tekstil Isletmeleri San Ve Tic As | PROCEDURE FOR TEXTILE DYEING AND COLORED TEXTILES |
| CN110424169A (en) * | 2019-08-06 | 2019-11-08 | 安徽恒益纺织科技有限公司 | A kind of textile fabric environmentally friendly coloring agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102182078A (en) * | 2011-04-06 | 2011-09-14 | 绍兴文理学院 | Monascorubrin mordant dyeing method of silk textile |
| CN102561063A (en) * | 2012-02-08 | 2012-07-11 | 上海工程技术大学 | Rare earth mordant dyeing method for kapok fiber and textile thereof |
| CN102605652A (en) * | 2011-12-13 | 2012-07-25 | 营口朗时多丝绸有限责任公司 | Method for dyeing pure silk by regarding rare earth material as mordant |
-
2016
- 2016-06-24 CN CN201610468058.8A patent/CN106120382B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102182078A (en) * | 2011-04-06 | 2011-09-14 | 绍兴文理学院 | Monascorubrin mordant dyeing method of silk textile |
| CN102605652A (en) * | 2011-12-13 | 2012-07-25 | 营口朗时多丝绸有限责任公司 | Method for dyeing pure silk by regarding rare earth material as mordant |
| CN102561063A (en) * | 2012-02-08 | 2012-07-11 | 上海工程技术大学 | Rare earth mordant dyeing method for kapok fiber and textile thereof |
Non-Patent Citations (1)
| Title |
|---|
| 稀土作为媒染剂对茶多酚上染真丝绸的影响;陈国华等;《印染助剂》;20131220;第35-38页 * |
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Denomination of invention: The invention relates to an environmental friendly mordant for natural dyes and a preparation method thereof Effective date of registration: 20210729 Granted publication date: 20180914 Pledgee: Zhejiang Deqing Rural Commercial Bank Co.,Ltd. Xinshi sub branch Pledgor: HUZHOU XINJIAYI SILK WEAVING PRINTING Co.,Ltd. Registration number: Y2021330001033 |
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