CN106118666A - One is checked winds and fixed drifting sand nutrition whitewashing and preparation method thereof - Google Patents
One is checked winds and fixed drifting sand nutrition whitewashing and preparation method thereof Download PDFInfo
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- CN106118666A CN106118666A CN201610467527.4A CN201610467527A CN106118666A CN 106118666 A CN106118666 A CN 106118666A CN 201610467527 A CN201610467527 A CN 201610467527A CN 106118666 A CN106118666 A CN 106118666A
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- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
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- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
- C09K17/20—Vinyl polymers
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- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
- C09K17/18—Prepolymers; Macromolecular compounds
- C09K17/20—Vinyl polymers
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- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/14—Soil-conditioning materials or soil-stabilising materials containing organic compounds only
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- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
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Abstract
The invention provides one to check winds and fix drifting sand nutrition whitewashing and preparation method thereof.Nutrition whitewashing for checking winds and fixing drifting sand is made up of paper pulp, furfural dregs, furfural mud, polyacrylate dispersion, vinyl acetate ethylene copolymer (VAE) emulsion, six kinds of components of urea-formaldehyde resin adhesive;Wherein, the siccative parts by weight after the removing aqueous solvent of raw material are: paper pulp: 1 part;Furfural dregs: 0.15 0.3 parts;Furfural mud: 0.15 0.45 parts;Polyacrylate dispersion: 0.02 0.05 parts;Vinyl acetate ethylene copolymer (VAE) emulsion: 0.6 1.5 parts;Urea-formaldehyde resin adhesive: 0.1 0.5 parts.This nutrition whitewashing uses paper pulp to be main raw material(s), has good toughness and freezing and thawing performance.It is simultaneously introduced the furfural dregs after fermentation maturity, it is possible to take organic fertilizer efficiency for desertification, sandy land, improve soil environment.
Description
Technical field
Term environmental technology field of the present invention, more particularly, to nutrition whitewashing and preparation method thereof of checking winds and fixing drifting sand.
Background technology
Engineering of checking winds and fixing drifting sand is a worldwide ecological environment engineering, and soil desertification and desertification seriously constrain national warp
The sustainable development of Ji.Implement the ecological engineering checked winds and fixed drifting sand, check soil desertification and desertification process, to economic development, certainly
So ecological environmental protection and work etc. of preventing and reducing natural disasters are respectively provided with important realistic meaning.
Engineering sand control, chemistry sand control and sand control with biological measures are more technology of checking winds and fixing drifting sand of promoting at present.Engineering sand control is main
Reach to reduce the purpose that desert migrates by the engineering construction means such as windbreak, straw checkerboard barrier;Chemistry sand control is by by Colophonium, resin
It is sprayed at sandy soil surface formation bonding course to reach the purpose of fixing soil Deng sand-consolidating agent;Sand control with biological measures is by planting drought-resistant sand
The modes such as unconcerned plant are checked winds and fixed drifting sand.But, there is cost of checking winds and fixing drifting sand high in above-mentioned technological means, service life is shorter, two
The drawbacks such as secondary pollution environment, so engineering of checking winds and fixing drifting sand at present is still made slow progress.
Summary of the invention
It is an object of the invention to produce one check winds and fix drifting sand nutrition whitewashing, this whitewashing can reduce Radix Saposhnikoviae after promoting the use of solid
Husky cost, accelerates desertification or sandy land ecological recovery.This whitewashing uses paper pulp as primary raw material, and interpolation simultaneously processed
Furfural dregs, the industrial waste such as aldehyde mud as organic and reinforcing agent, in conjunction with the chemicals of other nonhazardouss, add after water through
Stirring, is prepared as the nutrition whitewashing that can be used in checking winds and fixing drifting sand.This whitewashing can by spraying by the way of uniform fold at sand ground
Surface, slurry can be formed with the bonding course of intensity after drying at sandy land surface, it is possible to weatherproof, freeze thawing resistance, stand rainwater punching
Brush.Can be while cost be checked winds and fixed drifting sand in reduction, it is ensured that good effect of checking winds and fixing drifting sand, environment does not cause secondary dirty simultaneously
Dye.
This nutrition whitewashing uses paper pulp to be main raw material(s), has good toughness and freezing and thawing performance.It is simultaneously introduced and sends out
Ferment become thoroughly decomposed after furfural dregs, it is possible to take organic fertilizer efficiency for desertification, sandy land, improve soil environment.Furfural mud conduct
Technical furfural produces garbage, there is severe contamination problem etc., through acid-base neutralization and salt divisional processing in subsequent processes
After, it is added in slurry dispersion stirring, there is good intensity and hardness, it is possible to weatherproof after solidification, stand rain drop erosion.
The invention provides a kind of nutrition whitewashing for checking winds and fixing drifting sand, by paper pulp, furfural dregs, furfural mud, polyacrylic acid
Ester emulsion, vinyl acetate-ethylene copolymer (VAE) emulsion, six kinds of component compositions of urea-formaldehyde resin adhesive;Wherein, the removing of raw material is molten
Siccative parts by weight after agent water are: paper pulp: 1 part;Furfural dregs: 0.15-0.3 part;Furfural mud: 0.15-0.45 part;Polyacrylic acid
Ester emulsion: 0.02-0.05 part;Vinyl acetate-ethylene copolymer (VAE) emulsion: 0.6-1.5 part;Urea-formaldehyde resin adhesive: 0.1-0.5
Part.
In above-mentioned nutrition is whitewashed, wherein, described paper pulp is to be added water pulverizing by old and useless newspaper, paper, paperboard grade (stock) pulper
The rear paper pulp prepared.
In above-mentioned nutrition is whitewashed, wherein, described furfural dregs is the furfural dregs after fermentation maturity, and being exposed to the sun in the sun is carried out
Fermentation maturity.
In above-mentioned nutrition is whitewashed, wherein, the screening mesh number scope of described furfural dregs is 50-150 mesh.
In above-mentioned nutrition is whitewashed, wherein, described furfural mud is the furfural mud after processing with acidic materials.
In above-mentioned nutrition is whitewashed, wherein, described polyacrylate dispersion is the homopolymer with esters of acrylic acid as monomer
Or copolymer is at the water-soluble emulsion after emulsifying.
In above-mentioned nutrition is whitewashed, wherein, described urea-formaldehyde resin adhesive is with starch, lignin, tripolycyanamide or polyethylene
The urea-formaldehyde resin adhesive that alcohol is modified.
Present invention also offers a kind of method preparing whitewashing of checking winds and fixing drifting sand, comprise the following steps: waste and old by 1 part under room temperature
Paper adds pulper slurrying with water;After obtaining paper pulp, it is sequentially added into 0.15-0.3 part furfural dregs and 0.15-0.45 part furfural
Mud, fully dissolves dispersion;After furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.02-0.05 part polyacrylate dispersion
With 0.6-1.5 part vinyl acetate-ethylene copolymer (VAE) emulsion, it is sufficiently stirred for dispersion;0.1-0.5 part urea-formaldehyde resin adhesive is used
Hot water adds slurry after fully dissolving, and is sufficiently stirred for;After making slurry entirety be uniformly dispersed, whitewash with spouting plant, make slurry
Expecting to form uniform coating at sandy land surface, wherein, raw material number refers both to the siccative parts by weight after removing solvent.
In the above-mentioned methods, wherein, 1 part of waste and old paper and water are added pulper slurrying include by 1 part of waste and old paper with
10-15 part water adds pulper slurrying.
In the above-mentioned methods, wherein, the thickness of coating is not less than 3mm or 4mm.
The whitewashing of checking winds and fixing drifting sand of the present invention has the advantages that
(1) this nutrition whitewashing of checking winds and fixing drifting sand uses furfural production garbage furfural dregs and furfural mud as raw material components, does
Utilizing to garbage secondary, effectively solve furfural waste gurry and process problem, make full use of in furfural dregs and furfural mud is residual simultaneously
Staying organic matter, product price is cheap and environmental protection.
(2) other chemical reagent that this nutrition whitewashing of checking winds and fixing drifting sand is added belong to environmentally friendly chemistry product.Whole production
Process operation is simple, raw material composition environmental protection, will not produce secondary pollution.
(3) this checks winds and fixes drifting sand in nutrition whitewashing, and paper pulp fiber and other chemical addition agents can make to fix the sand to tie layer and have excellent
Different freezing and thawing performance and toughness, the coating of fixing the sand that addition furfural mud can make whitewashing be formed has excellent intensity and weatherproof
Performance.
(4) this nutrition whitewashing of checking winds and fixing drifting sand can be formed on the surface such as desertification or sandy land and fix the sand to tie layer, and this is solid simultaneously
Knot layer is rich in organic and slow release fertilizer efficiency, it is possible to promote plant growing.
Detailed description of the invention
The following examples can make those skilled in the art that the present invention is more fully understood, but limits never in any form
The present invention.
The invention provides a kind of for check winds and fix drifting sand nutrition whitewashing, mainly by paper pulp, furfural dregs, furfural mud, poly-third
Olefin(e) acid ester emulsion, VAE emulsion, six kinds of component compositions of urea-formaldehyde resin adhesive.
Siccative parts by weight after the removing aqueous solvent of raw material are:
Paper pulp: 1 part;Furfural dregs: 0.15-0.3 part;Furfural mud: 0.15-0.45 part;Polyacrylate dispersion: 0.02-
0.05 part;VAE emulsion: 0.6-1.5 part;Urea-formaldehyde resin adhesive: 0.1-0.5 part.
Wherein:
I. above-mentioned paper pulp refer to by the pulper such as old and useless newspaper, paper, cardboard add water pulverize after prepare paper pulp.
II. above-mentioned furfural dregs refers to the furfural dregs after fermentation maturity.Screening obtains the mesh number scope furfural dregs at 50-150 mesh,
It is exposed to the sun in the sun and carries out fermentation maturity.
III. above-mentioned furfural mud refers to the furfural mud after processing with acidic materials.
IV. above-mentioned polyacrylate dispersion refers to that the homopolymer with esters of acrylic acid as monomer or copolymer are through Over emulsfication
Water-soluble emulsion after process.
V. above-mentioned VAE emulsion refers to vinyl acetate-ethylene copolymer emulsion.
VI. above-mentioned urea-formaldehyde resin adhesive is known in the art to be reacted by addition-condensation with carbamide and formaldehyde for raw material
The water-soluble polymer arrived, the urea-formaldehyde resin adhesive of the present invention includes with modifications such as starch, lignin, tripolycyanamide or polyvinyl alcohol
Urea-formaldehyde resin adhesive.
The preparation method of whitewashing of checking winds and fixing drifting sand is described below in conjunction with specific embodiment.
Embodiment one:
A. under room temperature, 1 part of waste and old paper and 10 parts of water are added pulper slurrying;
B. after obtaining paper pulp, it is sequentially added into 0.25 part of furfural dregs and 0.25 part of furfural mud, adjusts blender rotating speed so that it is fill
Divide and dissolve dispersion;
C., after furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.04 part of polyacrylate dispersion and 1 part of VAE breast
Liquid, is sufficiently stirred for dispersion;
D. add slurry after fully being dissolved by 0.5 part of starch conversion urea-formaldehyde resin adhesive powder hot water, be sufficiently stirred for;
After the most all addO-on therapy all add, slurry is sufficiently stirred for, it is ensured that slurry entirety is uniformly dispersed
After, whitewash with spouting plant, make slurry form uniform coating at sandy land surface, it is ensured that coating layer thickness is not less than 3mm i.e.
Can.
Above-mentioned raw materials number refers both to the siccative parts by weight after removing solvent.
Embodiment two:
A. under room temperature, 1 part of waste and old paper and 15 parts of water are added pulper slurrying;
B. after obtaining paper pulp, it is sequentially added into 0.3 part of furfural dregs and 0.15 part of furfural mud, adjusts blender rotating speed so that it is fill
Divide and dissolve dispersion;
C., after furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.02 part of polyacrylate dispersion and 1.5 parts of VAE breasts
Liquid, is sufficiently stirred for dispersion;
D. add slurry after 0.45 part of cyanurotriamide modified urea resin glue powder with hot water fully being dissolved, fully stir
Mix;
After the most all addO-on therapy all add, slurry is sufficiently stirred for, it is ensured that slurry entirety is uniformly dispersed
After, whitewash with spouting plant, make slurry form uniform coating at sandy land surface, it is ensured that coating layer thickness is not less than 3mm i.e.
Can.
Above-mentioned raw materials number refers both to the siccative parts by weight after removing solvent.
Embodiment three:
A. under room temperature, 1 part of waste and old paper and 13 parts of water are added pulper slurrying;
B. after obtaining paper pulp, it is sequentially added into 0.15 part of furfural dregs and 0.45 part of furfural mud, adjusts blender rotating speed so that it is fill
Divide and dissolve dispersion;
C., after furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.04 part of polyacrylate dispersion and 0.85 part of VAE
Emulsion, is sufficiently stirred for dispersion;
D. add slurry after 0.25 part of lignin modified urea resin glue powder with hot water fully being dissolved, be sufficiently stirred for;
After the most all addO-on therapy all add, slurry is sufficiently stirred for, it is ensured that slurry entirety is uniformly dispersed
After, whitewash with spouting plant, make slurry form uniform coating at sandy land surface, it is ensured that coating layer thickness is not less than 4mm i.e.
Can.
Above-mentioned raw materials number refers both to the siccative parts by weight after removing solvent.
Embodiment four:
A. under room temperature, 1 part of waste and old paper and 10 parts of water are added pulper slurrying;
B. after obtaining paper pulp, it is sequentially added into 0.3 part of furfural dregs and 0.4 part of furfural mud, adjusts blender rotating speed so that it is fully
Dissolve dispersion;
C., after furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.02 part of polyacrylate dispersion and 0.6 part of VAE breast
Liquid, is sufficiently stirred for dispersion;
D. add slurry after 0.35 part of lignin modified urea resin glue powder with hot water fully being dissolved, be sufficiently stirred for;
After the most all addO-on therapy all add, slurry is sufficiently stirred for, it is ensured that slurry entirety is uniformly dispersed
After, whitewash with spouting plant, make slurry form uniform coating at sandy land surface, it is ensured that coating layer thickness is not less than 3mm i.e.
Can.
Above-mentioned raw materials number refers both to the siccative parts by weight after removing solvent.
Embodiment five:
A. under room temperature, 1 part of waste and old paper and 14 parts of water are added pulper slurrying;
B. after obtaining paper pulp, it is sequentially added into 0.2 part of furfural dregs and 0.35 part of furfural mud, adjusts blender rotating speed so that it is fill
Divide and dissolve dispersion;
C., after furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.03 part of polyacrylate dispersion and 0.8 part of VAE breast
Liquid, is sufficiently stirred for dispersion;
D. add slurry after 0.1 part of lignin modified urea resin glue powder with hot water fully being dissolved, be sufficiently stirred for;
After the most all addO-on therapy all add, slurry is sufficiently stirred for, it is ensured that slurry entirety is uniformly dispersed
After, whitewash with spouting plant, make slurry form uniform coating at sandy land surface, it is ensured that coating layer thickness is not less than 4mm i.e.
Can.
Above-mentioned raw materials number refers both to the siccative parts by weight after removing solvent.
It will be understood by those skilled in the art that above example is only exemplary embodiment, in the spirit without departing substantially from the present invention
In the case of scope, multiple change can be carried out, replace and change.
Claims (10)
1. whitewash, by paper pulp, furfural dregs, furfural mud, polyacrylate dispersion, acetic acid second for the nutrition checked winds and fixed drifting sand for one kind
Alkene-ethylene copolymer (VAE) emulsion, six kinds of component compositions of urea-formaldehyde resin adhesive;
Wherein, the siccative parts by weight after the removing aqueous solvent of raw material are:
Paper pulp: 1 part;Furfural dregs: 0.15-0.3 part;Furfural mud: 0.15-0.45 part;Polyacrylate dispersion: 0.02-0.05 part;
Vinyl acetate-ethylene copolymer (VAE) emulsion: 0.6-1.5 part;Urea-formaldehyde resin adhesive: 0.1-0.5 part.
Nutrition the most according to claim 1 is whitewashed, and wherein, described paper pulp is by old and useless newspaper, paper, paperboard grade (stock) pulper
Add water the paper pulp prepared after pulverizing.
Nutrition the most according to claim 1 is whitewashed, and wherein, described furfural dregs is the furfural dregs after fermentation maturity, at sunlight
Under be exposed to the sun and carry out fermentation maturity.
Nutrition the most according to claim 1 is whitewashed, and wherein, the screening mesh number scope of described furfural dregs is 50-150 mesh.
Nutrition the most according to claim 1 is whitewashed, and wherein, described furfural mud is the furfural mud after processing with acidic materials.
Nutrition the most according to claim 1 is whitewashed, and wherein, described polyacrylate dispersion is with esters of acrylic acid as monomer
Homopolymer or copolymer at the water-soluble emulsion after emulsifying.
Nutrition the most according to claim 1 is whitewashed, and wherein, described urea-formaldehyde resin adhesive is with starch, lignin, tripolycyanamide
Or the urea-formaldehyde resin adhesive of polyvinyl alcohol modification.
8. the method preparing whitewashing of checking winds and fixing drifting sand, comprises the following steps:
Under room temperature, 1 part of waste and old paper is added pulper slurrying with water;
After obtaining paper pulp, it is sequentially added into 0.15-0.3 part furfural dregs and 0.15-0.45 part furfural mud, fully dissolves dispersion;
After furfural dregs and furfural mud are fully dispersed, it is sequentially added into 0.02-0.05 part polyacrylate dispersion and 0.6-1.5 part vinegar
Acid ethylene-vinyl copolymer (VAE) emulsion, is sufficiently stirred for dispersion;
Add slurry after fully being dissolved by 0.1-0.5 part urea-formaldehyde resin adhesive hot water, be sufficiently stirred for;
After making slurry entirety be uniformly dispersed, whitewash with spouting plant, make slurry form uniform coating at sandy land surface,
Wherein, raw material number refers both to the siccative parts by weight after removing solvent.
Method the most according to claim 8, wherein, adds 1 part of waste and old paper and water pulper slurrying and includes giving up 1 part
Old paper adds pulper slurrying with 10-15 part water.
Method the most according to claim 8, wherein, the thickness of coating is not less than 3mm or 4mm.
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Cited By (5)
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CN107325820A (en) * | 2017-07-04 | 2017-11-07 | 江苏东珠景观股份有限公司 | A kind of soil-repairing agent suitable for landscape ecosystem |
CN109266357A (en) * | 2018-08-09 | 2019-01-25 | 钱兴 | A kind of preparation method of chemical sand fixing material |
CN109535353A (en) * | 2018-10-30 | 2019-03-29 | 王震勇 | Macromolecule dust suppression emulsion preparation method and dust suppression paper pulp |
CN110294656A (en) * | 2019-07-31 | 2019-10-01 | 郑州轻工业学院 | One kind check winds and fix drifting sand nutrition whitewashing and preparation method thereof |
CN114680018A (en) * | 2020-12-30 | 2022-07-01 | 青岛冠中生态股份有限公司 | Sand-fixing cultivation substrate for river hydro-fluctuation belt in alpine high-altitude area and use method thereof |
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