CN106118555A - 一种防水耐蚀弹性胶 - Google Patents

一种防水耐蚀弹性胶 Download PDF

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Publication number
CN106118555A
CN106118555A CN201610563789.0A CN201610563789A CN106118555A CN 106118555 A CN106118555 A CN 106118555A CN 201610563789 A CN201610563789 A CN 201610563789A CN 106118555 A CN106118555 A CN 106118555A
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Prior art keywords
corrosion
elastic gum
azodiisobutyronitrile
methyl methacrylate
waterproof anti
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Pending
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CN201610563789.0A
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Inventor
李欢军
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Zhenjiang Dongfanghong Nanometer Technology Co Ltd
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Zhenjiang Dongfanghong Nanometer Technology Co Ltd
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Priority to CN201610563789.0A priority Critical patent/CN106118555A/zh
Publication of CN106118555A publication Critical patent/CN106118555A/zh
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04—Homopolymers or copolymers of esters
    • C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明公开了一种防水耐蚀弹性胶，包括甲基丙烯酸羟乙酯、丙烯酸乙酯、丙烯酸丁酯、偶氮二异丁腈、无水乙醇、甲基丙烯酸甲酯、过硫酸铵、采用乳化剂乳液聚合工艺合成；各组分的配比如下：甲基丙烯酸羟乙酯10~25%，丙烯酸乙酯12~30%，丙烯酸丁酯12~30%，偶氮二异丁腈1.0~2.0%，无水乙醇10~15%，甲基丙烯酸甲酯4~12%，过硫酸铵0.1~2.0%；本发明性能优越、粘结效果及耐腐蚀度高。

Description

一种防水耐蚀弹性胶
技术领域
本发明涉及纳米复合材料领域，具体涉及一种防水耐蚀弹性胶。
背景技术
目前国内纤维用胶均存在透明度低、定位效果差、光泽度差、柔韧性及抗粘连性均不理想，不能满足市场的需求和质量要求。
发明内容
本发明的目的是提供一种防水耐蚀弹性胶，其性能优越、粘结效果及耐腐蚀均很高的弹性胶。
本发明通过以下技术方案予以实现：
一种防水耐蚀弹性胶，包括甲基丙烯酸羟乙酯、丙烯酸乙酯、丙烯酸丁酯、偶氮二异丁腈、无水乙醇、甲基丙烯酸甲酯、过硫酸铵、采用乳化剂乳液聚合工艺合成；各组分的配比如下：甲基丙烯酸羟乙酯10 ~25%，丙烯酸乙酯12~30%，丙烯酸丁酯12 ~30%，偶氮二异丁腈1.0~2.0%，无水乙醇10~15%，甲基丙烯酸甲酯4~12%，过硫酸铵0.1~2.0%。
本发明采用特殊聚合工艺使得弹性胶与各种纤维有良好的结合力，渗透性好，涂层后定位性和回弹性好，赋有硬而韧的手感；而且耐蚀和防水性极好，具有广泛的应用前景。
具体实施方式
下面结合实施例对本发明作进一步说明。
实施例一：一种防水耐蚀弹性胶，各组分的配比如下：甲基丙烯酸羟乙酯10 %，丙烯酸乙酯12%，丙烯酸丁酯12 %，偶氮二异丁腈1.0%，无水乙醇10%，甲基丙烯酸甲酯4%，过硫酸铵0.1%。
实施例二：一种防水耐蚀弹性胶，各组分的配比如下：甲基丙烯酸羟乙酯25%，丙烯酸乙酯30%，丙烯酸丁酯30%，偶氮二异丁腈2.0%，无水乙醇15%，甲基丙烯酸甲酯12%，过硫酸铵2.0%。
实施例三：一种防水耐蚀弹性胶，各组分的配比如下：甲基丙烯酸羟乙酯20%，丙烯酸乙酯20%，丙烯酸丁酯20%，偶氮二异丁腈1.5%，无水乙醇12%，甲基丙烯酸甲酯8%，过硫酸铵1%。
实施例四：一种防水耐蚀弹性胶，各组分的配比如下：甲基丙烯酸羟乙酯10 %，丙烯酸乙酯30%，丙烯酸丁酯30%，偶氮二异丁腈1.0%，无水乙醇10%，甲基丙烯酸甲酯4%，过硫酸铵2.0%。
除上述实施例外，本发明还可以有其他实施方式，凡采用等同替换或等效变换形成的技术方案，均落在本发明要求的保护范围内。

Claims (1)

1.一种防水耐蚀弹性胶，其特征在于：包括甲基丙烯酸羟乙酯、丙烯酸乙酯、丙烯酸丁酯、偶氮二异丁腈、无水乙醇、甲基丙烯酸甲酯、过硫酸铵、采用乳化剂乳液聚合工艺合成；上述各组分的配比如下：甲基丙烯酸羟乙酯10~25%，丙烯酸乙酯12~30%，丙烯酸丁酯12 ~30%，偶氮二异丁腈1.0~2.0%，无水乙醇10~15%，甲基丙烯酸甲酯4~12%，过硫酸铵0.1~2.0%。
CN201610563789.0A 2016-07-18 2016-07-18 一种防水耐蚀弹性胶 Pending CN106118555A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659752A (zh) * 2018-04-11 2018-10-16 无锡海特新材料研究院有限公司 一种标签用水溶性聚丙烯酸酯压敏胶、其制备方法及应用

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533177A (zh) * 2011-12-26 2012-07-04 中国印刷科学技术研究所 高耐水性乳液型聚丙烯酸酯压敏胶粘剂及其制法和应用

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102533177A (zh) * 2011-12-26 2012-07-04 中国印刷科学技术研究所 高耐水性乳液型聚丙烯酸酯压敏胶粘剂及其制法和应用

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108659752A (zh) * 2018-04-11 2018-10-16 无锡海特新材料研究院有限公司 一种标签用水溶性聚丙烯酸酯压敏胶、其制备方法及应用
CN108659752B (zh) * 2018-04-11 2020-07-17 无锡海特新材料研究院有限公司 一种标签用水溶性聚丙烯酸酯压敏胶、其制备方法及应用

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Application publication date: 20161116