CN106117983A - A kind of novel solar battery degradable environment-friendly type photoelectric material - Google Patents
A kind of novel solar battery degradable environment-friendly type photoelectric material Download PDFInfo
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Abstract
The invention discloses a kind of novel solar battery degradable environment-friendly type photoelectric material, in units of weight, it is made up of following raw material: hydroxy polyester resin 34 54 parts, hydracrylic acid valeric acid copolyesters 20 32 parts, acrylic carbazole 12 18 parts, alkalescence hargil 10 18 parts, sodium stearate 8 15 parts, sodium silicate 8 12 parts, corn stalk fiber 69 parts, polylactic acid 7 12 parts, dehydroactic acid 68 parts, degradation agent 57 parts, synthetics 6 10 parts, starch adesive 46 parts, antibacterial 23 parts, stabilizer I 12 parts, ultraviolet absorber 12 parts.The novel solar battery degradable environment-friendly type photoelectric material toxicity of the present invention is little, and environmental pollution is little, degradable, and photoelectric transformation efficiency is high, and production cost is low, beneficially popularization and application.
Description
[technical field]
The invention belongs to technical field of new energies and solar cell material lead for technology, be specifically related to a kind of new type solar energy electricity
Pond degradable environment-friendly type photoelectric material.
[background technology]
The energy of shortage has had a strong impact on life and the development of restriction society of people.Abundant solar energy is important cleaning energy
Source, is the energy that can freely utilize of inexhaustible, nexhaustible, pollution-free, cheap, the mankind.The first oil crisis it
After, various countries competitively carry out answering of cleaning and the applied researcies of regenerative resource, especially solar energy such as solar energy, water energy, wind energy
The most extensive with research.
Solar energy does not has any nonstaining property as a kind of green energy resource to environment, and its source is simple, it may be said that
It is that it is inexhaustible in the existence time limit of the mankind.Solar energy is not only the disposable energy, or cleaning energy
Source, its aboundresources, generally exist, without transporting, also can freely use, the most important thing is environment is not had any pollution.Too
Sun also can have the advantage not available for other generation modes many because of the particularity of solar energy by battery: without geographical restrictions, no
Consume fuel, scale is changeable, motility is big, pollution-free, noiselessness, safe and reliable, the construction period is short, safeguard simply,
There is the probability of large-scale application.So a lot of experts go solar energy to exploitation as the alternative energy, it is desirable to too
Sun can be brought benefit to the mankind.Nowadays the solar energy used have greatly by solar cell conversion get.Because
Solaode has sensing to light, it is possible to the luminous energy being radiated at its surface is converted to electric energy.At present, in the effort of relevant expert
Under, solaode is own through having moved towards commercialization and industrialization.
Solaode is the important device realizing opto-electronic conversion, and the most important principle wherein used is exactly photoproduction volt
Specially good effect is answered, so solaode is also referred to as photovoltaic cell.When sunlight or other light good fortune are mapped on semi-conducting material,
Valence-band electrons can absorb the photon energy of a part, and electronics is stimulated after obtaining energy and transits to conduction band, thus can be in valence band
Form a hole, and conduction band has more an electronics, form electron hole pair.Due to when P-type semiconductor and N type quasiconductor phase
Forming P-N junction during contact, the diffusion of many sons in P-type semiconductor and formation space-charge region, N-type semiconductor contact position, and can go out
The built in field being pointed to p-type by N-type of an existing continuous enhancing, thus produce the drift current of few son.Diffusion electricity when many sons
When the drift current of stream and few son is equal, form dynamic equilibrium.Therefore solaode plays the photoelectric material of pivotal role
Decide the efficiency of solar energy.More and more deep for solar cell material research at present, mostly it is devoted to improve solar energy
The photoelectric transformation efficiency of battery, but the various motor material serious environment pollution containing the heavy metal element such as chromium, stannum, the discarded sun
The recovery of energy battery is good problem to study, is therefore badly in need of exploitation novel degradable photoelectric material.
[summary of the invention]
The present invention provides a kind of novel solar battery degradable environment-friendly type photoelectric material, is difficult to solving existing photoelectric material
Degraded, containing the heavy metal element serious environment pollution such as chromium, stannum, and the recycling high in cost of production of discarded solaode is asked
Topic.The novel solar battery degradable environment-friendly type photoelectric material toxicity of the present invention is little, and environmental pollution is little, degradable, photoelectricity
Conversion efficiency is high, and production cost is low, beneficially popularization and application.
For solve above technical problem, the present invention by the following technical solutions:
A kind of novel solar battery degradable environment-friendly type photoelectric material, in units of weight, is made up of following raw material: hydroxyl
Polyester resin 34-54 part, hydracrylic acid valeric acid copolyesters 20-32 part, acrylic carbazole 12-18 part, alkalescence hargil 10-18 part,
Sodium stearate 8-15 part, sodium silicate 8-12 part, corn stalk fiber 6-9 part, polylactic acid 7-12 part, dehydroactic acid 6-8 part, degraded
Agent 5-7 part, synthetics 6-10 part, starch adesive 4-6 part, antibacterial 2-3 part, stabilizer I 1-2 part, ultraviolet absorber 1-2
Part；
Described degradation agent, in units of weight, is made up of following raw material: ammonium phosphate 2-2.4 part, amino trimethylene ethylphosphonic acid 1.2-
1.6 parts, ethylenediamine tetramethylenephosphonic acid 1-1.4 part, dodecyl dimethyl benzyl ammonium bromide 0.6-1.2 part, titanium dioxide 0.2-0.4
Part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 0.6-1.2 part, coupling agent 1-1.8 part, phase
Hold agent 0.8-1.4 part, regulator 0.6-1 part, hardening agent 0.6-1 part, flocculation agent 1-1.5 part, plasticizer 1-1.4 part, stabilizer
II 0.2-0.4 part, terminator 0.2-0.3 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.2-1.8 part, dimethyl adipate 1-
1.6 parts, amide dimethyl butyrate 0.8-1.2 part, barium hydroxide 0.4-0.6 part, epoxychloropropane 0.6-0.8 part；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 80-150r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 3-by 80-150r/min
5min, prepares suspension；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Control temperature and be 135-150 DEG C, under rotating speed is 100-200r/min, stirs 1-3h, prepares miscible fluid I；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 120-135 DEG C, react under rotating speed is 200-300r/min
40-60 min, prepares material I；
S22: be warming up to 150-160 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares,
Under rotating speed is 300-400r/min, reacts 150-180 min, prepares material II；
S23: be cooled to 110-120 after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares
DEG C, under rotating speed is 200-300r/min, reacts 60-90 min, prepares synthetics；
S3: add degradation agent, starch adesive, antibacterial after the miscible fluid I that step S2 prepares is cooled to 42-45 DEG C, stablize
Agent I, ultraviolet absorber, be placed in ultrasonic response still, reacts 20-30min under power 100-300W, and warp is 65-in temperature
It is dried at 78 DEG C, prepares the novel solar battery degradable environment-friendly type photoelectric material of moisture content≤7%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 30-35Be '；
S32: it is the dimethyl adipate of 3%-5%, amide dimethyl butyrate that the para arrowroot slurry I in step S31 adds concentration, so
After be 35-38 DEG C in temperature, speed of agitator be carry out under 60-80r/min cross-linked graft reaction 1-1.5h, prepare slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, be then 40-45 DEG C in temperature, stirring
Rotating speed is to carry out cross-linking reaction 0.4-0.6h under 60-80r/min, prepares slurry III；
S34: the slurry III of step S33 carried out pre-gelatinized and is dried at temperature is 105-125 DEG C, preparing moisture content≤8%
Material IV；
S35: the material IV of step S34 is pulverized, crosses 100-120 mesh sieve, prepare starch adesive.
Further, described plasticizer is dioctyl adipate.
Further, described stabilizer II is fat acids stabilizer.
Further, described terminator is styrene.
Further, described antibacterial is isothiazolone derivative.
Further, described stabilizer I is light stabilizer 783.
Further, described ultraviolet absorber is ESCALOL 567.
The method have the advantages that
(1) the novel solar battery degradable environment-friendly type photoelectric material toxicity of the present invention is little, and environmental pollution is little, degradable,
It it is a kind of environment-friendly type photoelectric material；
(2) novel solar battery of the present invention is high with the heat decomposition temperature of degradable environment-friendly type photoelectric material, reach 560 DEG C with
On, use soil-burial method to bury the novel solar battery degradable environment-friendly type photoelectric material of the present invention, degrade after 1 year
Rate reaches more than 89%；
(3) the novel solar battery degradable environment-friendly type photoelectric material of the present invention has dual electric conductivity, opto-electronic conversion
Efficiency is high, and weight is relatively light, and production cost is low.
[detailed description of the invention]
For ease of being more fully understood that the present invention, being illustrated by following example, these embodiments belong to the protection of the present invention
Scope, but it is not intended to protection scope of the present invention.
In an embodiment, described novel solar battery degradable environment-friendly type photoelectric material, in units of weight, by with
Lower raw material is made: hydroxy polyester resin 34-54 part, hydracrylic acid valeric acid copolyesters 20-32 part, acrylic carbazole 12-18 part, alkali
Property hargil 10-18 part, sodium stearate 8-15 part, sodium silicate 8-12 part, corn stalk fiber 6-9 part, polylactic acid 7-12 part, dehydrogenation
Acetic acid 6-8 part, degradation agent 5-7 part, synthetics 6-10 part, starch adesive 4-6 part, antibacterial 2-3 part, stabilizer I 1-2 part,
Ultraviolet absorber 1-2 part；
Described degradation agent, in units of weight, is made up of following raw material: ammonium phosphate 2-2.4 part, amino trimethylene ethylphosphonic acid 1.2-
1.6 parts, ethylenediamine tetramethylenephosphonic acid 1-1.4 part, dodecyl dimethyl benzyl ammonium bromide 0.6-1.2 part, titanium dioxide 0.2-0.4
Part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 0.6-1.2 part, coupling agent 1-1.8 part, phase
Hold agent 0.8-1.4 part, regulator 0.6-1 part, hardening agent 0.6-1 part, flocculation agent 1-1.5 part, plasticizer 1-1.4 part, stabilizer
II 0.2-0.4 part, terminator 0.2-0.3 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid, and described plasticizer is dioctyl adipate, and described stabilizer II is fat acids stabilizer, described terminator
For styrene；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.2-1.8 part, dimethyl adipate 1-
1.6 parts, amide dimethyl butyrate 0.8-1.2 part, barium hydroxide 0.4-0.6 part, epoxychloropropane 0.6-0.8 part；
Described antibacterial is isothiazolone derivative；
Described stabilizer I is light stabilizer 783；
Described ultraviolet absorber is ESCALOL 567；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 80-150r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 3-by 80-150r/min
5min, prepares suspension；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Control temperature and be 135-150 DEG C, under rotating speed is 100-200r/min, stirs 1-3h, prepares miscible fluid I；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 120-135 DEG C, react under rotating speed is 200-300r/min
40-60 min, prepares material I；
S22: be warming up to 150-160 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares,
Under rotating speed is 300-400r/min, reacts 150-180 min, prepares material II；
S23: be cooled to 110-120 after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares
DEG C, under rotating speed is 200-300r/min, reacts 60-90 min, prepares synthetics；
S3: add degradation agent, starch adesive, antibacterial after the miscible fluid I that step S2 prepares is cooled to 42-45 DEG C, stablize
Agent I, ultraviolet absorber, be placed in ultrasonic response still, reacts 20-30min under power 100-300W, and warp is 65-in temperature
It is dried at 78 DEG C, prepares the novel solar battery degradable environment-friendly type photoelectric material of moisture content≤7%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 30-35Be '；
S32: it is the dimethyl adipate of 3%-5%, amide dimethyl butyrate that the para arrowroot slurry I in step S31 adds concentration, so
After be 35-38 DEG C in temperature, speed of agitator be carry out under 60-80r/min cross-linked graft reaction 1-1.5h, prepare slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, be then 40-45 DEG C in temperature, stirring
Rotating speed is to carry out cross-linking reaction 0.4-0.6h under 60-80r/min, prepares slurry III；
S34: the slurry III of step S33 carried out pre-gelatinized and is dried at temperature is 105-125 DEG C, preparing moisture content≤8%
Material IV；
S35: the material IV of step S34 is pulverized, crosses 100-120 mesh sieve, prepare starch adesive.
Embodiment 1
A kind of novel solar battery degradable environment-friendly type photoelectric material, in units of weight, is made up of following raw material: hydroxyl
45 parts of polyester resin, hydracrylic acid valeric acid copolyesters 25 parts, acrylic carbazole 16 parts, alkalescence hargil 15 parts, sodium stearate 12 parts,
Sodium silicate 10 parts, corn stalk fiber 8 parts, polylactic acid 10 parts, dehydroactic acid 7 parts, degradation agent 6 parts, synthetics 8 parts, starch are viscous
Knot agent 5 parts, antibacterial 2.5 parts, stabilizer I 1.5 parts, ultraviolet absorber 1.5 parts；
Described degradation agent, in units of weight, is made up of following raw material: 2.2 parts of ammonium phosphate, amino trimethylene ethylphosphonic acid 1.4 parts,
Ethylenediamine tetramethylenephosphonic acid 1.2 parts, dodecyl dimethyl benzyl ammonium bromide 0.9 part, titanium dioxide 0.3 part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 0.9 part, coupling agent 1.4 parts, compatilizer 1.2
Part, regulator 0.8 part, hardening agent 0.8 part, flocculation agent 1.2 parts, plasticizer 1.2 parts, stabilizer II 0.3 parts, terminator 0.2 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid, and described plasticizer is dioctyl adipate, and described stabilizer II is fat acids stabilizer, described terminator
For styrene；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.5 parts, dimethyl adipate 1.3 parts,
Amide dimethyl butyrate 1 part, barium hydroxide 0.5 part, epoxychloropropane 0.7 part；
Described antibacterial is isothiazolone derivative；
Described stabilizer I is light stabilizer 783；
Described ultraviolet absorber is ESCALOL 567；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 120r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 4min by 120r/min, prepares outstanding
Turbid liquid；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Controlling temperature is 140 DEG C, stirs 2h, prepare miscible fluid I under rotating speed is 150r/min；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 128 DEG C, react 50 min under rotating speed is 250r/min, system
Obtain material I；
S22: be warming up to 155 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares, turning
Speed, for reacting 170 min under 350r/min, prepares material II；
S23: be cooled to 115 DEG C after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares,
Rotating speed is to react 75 min under 50r/min, prepares synthetics；
S3: by step S2 prepare miscible fluid I be cooled to 43 DEG C after add degradation agent, starch adesive, antibacterial, stabilizer I,
Ultraviolet absorber, is placed in ultrasonic response still, reacts 25min under power 200W, through being dried at temperature is 72 DEG C, prepares
Moisture content is the novel solar battery degradable environment-friendly type photoelectric material of 7%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 32Be '；
S32: the para arrowroot slurry I in step S31 adds dimethyl adipate, the amide dimethyl butyrate that concentration is 4%, then
Being 36 DEG C in temperature, speed of agitator is to carry out cross-linked graft reaction 1.2h under 70r/min, prepares slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, is then 42 DEG C in temperature, speed of agitator
For carrying out cross-linking reaction 0.5h under 70r/min, prepare slurry III；
S34: the slurry III of step S33 carrying out pre-gelatinized and is dried at temperature is 115 DEG C, prepared moisture content is the material of 8%
Ⅳ；
S35: the material IV of step S34 is pulverized, crosses 110 mesh sieve, prepare starch adesive.
Embodiment 2
A kind of novel solar battery degradable environment-friendly type photoelectric material, in units of weight, is made up of following raw material: hydroxyl
34 parts of polyester resin, hydracrylic acid valeric acid copolyesters 20 parts, acrylic carbazole 12 parts, alkalescence hargil 10 parts, sodium stearate 8 parts,
Sodium silicate 8 parts, corn stalk fiber 6 parts, polylactic acid 7 parts, dehydroactic acid 6 parts, degradation agent 5 parts, synthetics 6 parts, starch bond
Agent 4 parts, antibacterial 2 parts, stabilizer I 1 parts, ultraviolet absorber 1 part；
Described degradation agent, in units of weight, is made up of following raw material: 2 parts of ammonium phosphate, amino trimethylene ethylphosphonic acid 1.2 parts, second
Diamidogen tetracarboxylic acid 1 part, dodecyl dimethyl benzyl ammonium bromide 0.6 part, titanium dioxide 0.2 part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 0.6 part, coupling agent 1 part, compatilizer 0.8
Part, regulator 0.6 part, hardening agent 0.6 part, flocculation agent 1 part, plasticizer 1 part, stabilizer II 0.2 parts, terminator 0.2 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid, and described plasticizer is dioctyl adipate, and described stabilizer II is fat acids stabilizer, described terminator
For styrene；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.2 parts, dimethyl adipate 1 part, two
Methylbutyryl amine 0.8 part, barium hydroxide 0.4 part, epoxychloropropane 0.6 part；
Described antibacterial is isothiazolone derivative；
Described stabilizer I is light stabilizer 783；
Described ultraviolet absorber is ESCALOL 567；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 80r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 5min by 80r/min, prepares suspended
Liquid；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Controlling temperature is 135 DEG C, stirs 3h, prepare miscible fluid I under rotating speed is 100r/min；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 120 DEG C, react 60 min under rotating speed is 200r/min, system
Obtain material I；
S22: be warming up to 150 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares, turning
Speed, for reacting 180 min under 300r/min, prepares material II；
S23: be cooled to 110 DEG C after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares,
Rotating speed is to react 90 min under 200r/min, prepares synthetics；
S3: by step S2 prepare miscible fluid I be cooled to 42 DEG C after add degradation agent, starch adesive, antibacterial, stabilizer I,
Ultraviolet absorber, is placed in ultrasonic response still, reacts 30min under power 100W, through being dried at temperature is 65 DEG C, prepares
Moisture content is the novel solar battery degradable environment-friendly type photoelectric material of 6%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 30Be '；
S32: the para arrowroot slurry I in step S31 adds dimethyl adipate, the amide dimethyl butyrate that concentration is 3%, then
Being 35 DEG C in temperature, speed of agitator is to carry out cross-linked graft reaction 1.5h under 60r/min, prepares slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, is then 40 DEG C in temperature, speed of agitator
For carrying out cross-linking reaction 0.6h under 60r/min, prepare slurry III；
S34: the slurry III of step S33 carrying out pre-gelatinized and is dried at temperature is 105 DEG C, prepared moisture content is the material of 7%
Ⅳ；
S35: the material IV of step S34 is pulverized, crosses 100 mesh sieve, prepare starch adesive.
Embodiment 3
A kind of novel solar battery degradable environment-friendly type photoelectric material, in units of weight, is made up of following raw material: hydroxyl
54 parts of polyester resin, hydracrylic acid valeric acid copolyesters 32 parts, acrylic carbazole 18 parts, alkalescence hargil 18 parts, sodium stearate 15 parts,
Sodium silicate 12 parts, corn stalk fiber 9 parts, polylactic acid 12 parts, dehydroactic acid 8 parts, degradation agent 7 parts, synthetics 10 parts, starch are viscous
Knot agent 6 parts, antibacterial 3 parts, stabilizer I 2 parts, ultraviolet absorber 2 parts；
Described degradation agent, in units of weight, is made up of following raw material: 2.4 parts of ammonium phosphate, amino trimethylene ethylphosphonic acid 1.6 parts,
Ethylenediamine tetramethylenephosphonic acid 1.4 parts, dodecyl dimethyl benzyl ammonium bromide 1.2 parts, titanium dioxide 0.4 part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 1.2 parts, coupling agent 1.8 parts, compatilizer 1.4
Part, regulator 1 part, hardening agent 1 part, flocculation agent 1.5 parts, plasticizer 1.4 parts, stabilizer II 0.4 parts, terminator 0.3 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid, and described plasticizer is dioctyl adipate, and described stabilizer II is fat acids stabilizer, described terminator
For styrene；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.8 parts, dimethyl adipate 1.6 parts,
Amide dimethyl butyrate 1.2 parts, barium hydroxide 0.6 part, epoxychloropropane 0.8 part；
Described antibacterial is isothiazolone derivative；
Described stabilizer I is light stabilizer 783；
Described ultraviolet absorber is ESCALOL 567；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 150r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 3min by 150r/min, prepares outstanding
Turbid liquid；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Controlling temperature is 150 DEG C, stirs 1h, prepare miscible fluid I under rotating speed is 200r/min；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 135 DEG C, react 60 min under rotating speed is 300r/min, system
Obtain material I；
S22: be warming up to 160 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares, turning
Speed is reaction 150min under 400r/min, prepares material II；
S23: be cooled to 120 DEG C after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares,
Rotating speed is to react 60 min under 300r/min, prepares synthetics；
S3: by step S2 prepare miscible fluid I be cooled to 45 DEG C after add degradation agent, starch adesive, antibacterial, stabilizer I,
Ultraviolet absorber, is placed in ultrasonic response still, reacts 20min under power 300W, through being dried at temperature is 78 DEG C, prepares
Moisture content is the novel solar battery degradable environment-friendly type photoelectric material of 5%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 35Be '；
S32: the para arrowroot slurry I in step S31 adds dimethyl adipate, the amide dimethyl butyrate that concentration is 5%, then
Being 38 DEG C in temperature, speed of agitator is to carry out cross-linked graft reaction 1h under 80r/min, prepares slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, is then 45 DEG C in temperature, speed of agitator
For carrying out cross-linking reaction 0.4h under 80r/min, prepare slurry III；
S34: the slurry III of step S33 carrying out pre-gelatinized and is dried at temperature is 125 DEG C, prepared moisture content is the material of 5%
Ⅳ；
S35: the material IV of step S34 is pulverized, crosses 120 mesh sieve, prepare starch adesive.
The novel solar battery degradable environment-friendly type photoelectric material of embodiment 1-3 is carried out thermogravimetric analysis (TG) and poor
The test of heat scan thermometric analysis (DSC), the rate of heat addition is 20 DEG C/min, and thermogravimetric analysis (TG) heat decomposition temperature result sees below
Table.
Using soil-burial method, claim the degradable photoelectric material of certain mass and the soil mixing of certain mass, note is total
Quality；Then being placed in environment by the pedotheque being mixed with degradable photoelectric material, each a period of time claims its quality, records matter
Amount change, Mass lost amount obtains degradation rate than original degradable photoelectric material quality, when the degradation rate in following table is 1 year
Degradability.
As seen from the above table, the novel solar battery of the present invention heat decomposition temperature of degradable environment-friendly type photoelectric material
Height, reaches more than 560 DEG C, uses soil-burial method to bury the novel solar battery degradable environment-friendly type photoelectricity material of the present invention
Material, after 1 year, degradation rate reaches more than 89%.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanation, technology belonging to the present invention is led
For the those of ordinary skill in territory, without departing from the inventive concept of the premise, it is also possible to make some simple deduction or replace,
All should be considered as belonging to the scope of patent protection that the present invention is determined by the claims submitted to.
Claims (7)
1. a novel solar battery degradable environment-friendly type photoelectric material, it is characterised in that in units of weight, by following
Raw material is made: hydroxy polyester resin 34-54 part, hydracrylic acid valeric acid copolyesters 20-32 part, acrylic carbazole 12-18 part, alkalescence
Hargil 10-18 part, sodium stearate 8-15 part, sodium silicate 8-12 part, corn stalk fiber 6-9 part, polylactic acid 7-12 part, dehydrogenation second
Acid 6-8 part, degradation agent 5-7 part, synthetics 6-10 part, starch adesive 4-6 part, antibacterial 2-3 part, stabilizer I 1-2 part, purple
Outer absorbent 1-2 part；
Described degradation agent, in units of weight, is made up of following raw material: ammonium phosphate 2-2.4 part, amino trimethylene ethylphosphonic acid 1.2-
1.6 parts, ethylenediamine tetramethylenephosphonic acid 1-1.4 part, dodecyl dimethyl benzyl ammonium bromide 0.6-1.2 part, titanium dioxide 0.2-0.4
Part；
Described synthetics, in units of weight portion, is made up of following raw material: propellant 0.6-1.2 part, coupling agent 1-1.8 part, phase
Hold agent 0.8-1.4 part, regulator 0.6-1 part, hardening agent 0.6-1 part, flocculation agent 1-1.5 part, plasticizer 1-1.4 part, stabilizer
II 0.2-0.4 part, terminator 0.2-0.3 part；
Described propellant is aerogel generating agent, and described coupling agent is epoxy silane class coupling agent, and described compatilizer is maleic acid
Acid anhydride grafting compatilizer, described regulator is processing aids acrylic resin, and described hardening agent is 701 powder hardening agents, described coacervation
Agent is aluminium polychlorid；
Described starch adesive, in units of weight portion, is made up of following raw material: starch 1.2-1.8 part, dimethyl adipate 1-
1.6 parts, amide dimethyl butyrate 0.8-1.2 part, barium hydroxide 0.4-0.6 part, epoxychloropropane 0.6-0.8 part；
The preparation method of described novel solar battery degradable environment-friendly type photoelectric material, comprises the following steps:
S1: add polylactic acid, dehydroactic acid after hydroxy polyester resin, hydracrylic acid valeric acid copolyesters, the mixing of acrylic carbazole,
Under rotating speed is 80-150r/min, stirring is warming up to 78 DEG C, keeps temperature-resistant lower continuation to stir 3-by 80-150r/min
5min, prepares suspension；
S2: the suspension prepared to step S1 adds alkalescence hargil, sodium stearate, sodium silicate, corn stalk fiber, synthetics,
Control temperature and be 135-150 DEG C, under rotating speed is 100-200r/min, stirs 1-3h, prepares miscible fluid I；
The preparation method of described synthetics, comprises the following steps:
S21: propellant, coupling agent, compatilizer mixing are warming up to 120-135 DEG C, react under rotating speed is 200-300r/min
40-60 min, prepares material I；
S22: be warming up to 150-160 DEG C after adding regulator, hardening agent, flocculation agent mixing in the material I that step S21 prepares,
Under rotating speed is 300-400r/min, reacts 150-180 min, prepares material II；
S23: be cooled to 110-120 after adding plasticizer, stabilizer II, terminator mixing in the material II that step S22 prepares
DEG C, under rotating speed is 200-300r/min, reacts 60-90 min, prepares synthetics；
S3: add degradation agent, starch adesive, antibacterial after the miscible fluid I that step S2 prepares is cooled to 42-45 DEG C, stablize
Agent I, ultraviolet absorber, be placed in ultrasonic response still, reacts 20-30min under power 100-300W, and warp is 65-in temperature
It is dried at 78 DEG C, prepares the novel solar battery degradable environment-friendly type photoelectric material of moisture content≤7%；
The preparation method of described starch adesive, comprises the following steps:
S31: compound concentration is the starch slurry I of 30-35Be '；
S32: it is the dimethyl adipate of 3%-5%, amide dimethyl butyrate that the para arrowroot slurry I in step S31 adds concentration, so
After be 35-38 DEG C in temperature, speed of agitator be carry out under 60-80r/min cross-linked graft reaction 1-1.5h, prepare slurry II；
S33: add barium hydroxide and epoxychloropropane in the slurry II of step S32, be then 40-45 DEG C in temperature, stirring
Rotating speed is to carry out cross-linking reaction 0.4-0.6h under 60-80r/min, prepares slurry III；
S34: the slurry III of step S33 carried out pre-gelatinized and is dried at temperature is 105-125 DEG C, preparing moisture content≤8%
Material IV；
S35: the material IV of step S34 is pulverized, crosses 100-120 mesh sieve, prepare starch adesive.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described increasing
Moulding agent is dioctyl adipate.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described surely
Determine agent II for fat acids stabilizer.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described end
Only agent is styrene.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described anti-
Microbial inoculum is isothiazolone derivative.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described surely
Determine agent I for light stabilizer 783.
Novel solar battery degradable environment-friendly type photoelectric material the most according to claim 1, it is characterised in that described purple
Outer absorbent is ESCALOL 567.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405200A (en) * | 2002-11-07 | 2003-03-26 | 上海交通大学 | Terminal hydroxy superbranched polyester |
| US20130306151A1 (en) * | 2011-01-13 | 2013-11-21 | Basf Se | Organic photovoltaic device and manufacturing method thereof |
| CN104169285A (en) * | 2012-04-06 | 2014-11-26 | Dic株式会社 | Phthalocyanine nano-size structures, and electronic elements using said nano-size structures |
| CN104377305A (en) * | 2014-11-13 | 2015-02-25 | 无锡中洁能源技术有限公司 | Degradable photoelectric material and preparing method for degradable photoelectric material |
-
2016
- 2016-07-25 CN CN201610588842.2A patent/CN106117983A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1405200A (en) * | 2002-11-07 | 2003-03-26 | 上海交通大学 | Terminal hydroxy superbranched polyester |
| US20130306151A1 (en) * | 2011-01-13 | 2013-11-21 | Basf Se | Organic photovoltaic device and manufacturing method thereof |
| CN104169285A (en) * | 2012-04-06 | 2014-11-26 | Dic株式会社 | Phthalocyanine nano-size structures, and electronic elements using said nano-size structures |
| CN104377305A (en) * | 2014-11-13 | 2015-02-25 | 无锡中洁能源技术有限公司 | Degradable photoelectric material and preparing method for degradable photoelectric material |
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Application publication date: 20161116 |