CN106117691A - A kind of rubber and processing method thereof - Google Patents

A kind of rubber and processing method thereof Download PDF

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Publication number
CN106117691A
CN106117691A CN201610774529.8A CN201610774529A CN106117691A CN 106117691 A CN106117691 A CN 106117691A CN 201610774529 A CN201610774529 A CN 201610774529A CN 106117691 A CN106117691 A CN 106117691A
Authority
CN
China
Prior art keywords
rubber
parts
accelerator
banbury
mixing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610774529.8A
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Chinese (zh)
Inventor
林英强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tiantai Xin Kai Rubber & Plastic Co Ltd
Original Assignee
Tiantai Xin Kai Rubber & Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tiantai Xin Kai Rubber & Plastic Co Ltd filed Critical Tiantai Xin Kai Rubber & Plastic Co Ltd
Priority to CN201610774529.8A priority Critical patent/CN106117691A/en
Publication of CN106117691A publication Critical patent/CN106117691A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/09Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Braking Arrangements (AREA)

Abstract

nullThe present invention relates to the field of rubber,It relates to rubber and the processing method thereof of a kind of brake pipe sheath,Rubber 100g is put into and carries out moulding white silk to banbury,Zinc oxide 5g is added the most again in banbury、Stearic acid 1g、Age resistor 2g、White carbon black 50g、Accelerator ZBX 0.5g is put in banbury、Accelerator ZDMC0.5g、Urotropinum 0.5g、Accelerant CZ 1g carries out mixed melting binder removal at a temperature of 120 DEG C and becomes film,Finally place into softening agent 20g to mix with film,Finished product is obtained after placing mill removing from mould after mixing and cooling down 3 hours,The present invention can overcome in prior art the most aging、The high defect with poor stability of maintenance cost,It is difficult to aging with realization、The advantage that maintenance cost is low and safety is good,And wearability is good,Resistance to pressure is strong,Anti-ozone performance is strong.

Description

A kind of rubber and processing method thereof
Technical field
The present invention relates to the field of rubber, more specifically, it relates to the rubber of a kind of brake pipe sheath and adding Work method.
Background technology
Brake pipe in automobile is used in the parts in brake system of car, and its Main Function is in automobile brake Transmission braking medium, it is ensured that brake force is delivered to motor vehicle brake shoe or caliper produces brake force, so that braking is the most effective.
Brake pipe plays conveying brake fluid, the effect of transmission brake pressure in automobile brake system.Due in brake pipe Being filled with DOT class brake fluid for a long time, sebific duct internal layer raw material is easily extracted out and is crystallized or be deposited in brake pipe, and electromotor nacelle Causing using temperature to rise, can make sebific duct premature aging, service life is the highest.
Summary of the invention
The deficiency existed for prior art, it is an object of the invention to provide a kind of ageing resistace good, and wearability is good, Resistance to pressure is strong, the brake pipe sheath that anti-ozone performance is strong.
For achieving the above object, the technical scheme is that
A kind of rubber, described rubber part by weight is mixed by following component:
Rubber: 100 parts,
Zinc oxide: 2~7 parts,
Stearic acid: 0.3~1.8 part,
Age resistor: 1~5 part,
White carbon black: 30~70 parts,
Softening agent: 10~30 parts,
Accelerator: 1~5 part.
The present invention is further arranged to: described rubber peace weight meter part is mixed by following component:
Rubber: 100 parts,
Zinc oxide: 3~6 parts,
Stearic acid: 0.6~1.5 part,
Age resistor: 1.5~3 parts,
White carbon black: 45~60 parts,
Softening agent: 15~25 parts,
Accelerator: 2~3 parts.
Zinc oxide, is mainly used as the reinforcing agent of rubber or cable, so that rubber has good corrosion resistance, tear resistance And elasticity.
Stearic acid, stearic acid is wide variety of vulcanizing activator in natural gum, synthetic rubber and latex, it is possible to be used as to increase Mould agent and softening agent.During producing synthetic rubber, need to add stearic acid make emulsifying agent, it is also possible to be used as the demoulding of rubber Agent.
Age resistor, is used for delaying or suppressing elastomeric ageing process, extends rubber and the storage period of goods thereof and makes Use the life-span.The age resistor of the present invention uses antioxidant 4010NA or age resistor IPPD mixing to constitute.
Softening agent: can increase the plasticity of sizing material, reduce compound viscosity and mixing time temperature, improve dispersibility and mix Property, improve the hot strength of vulcanizate, percentage elongation and wearability.
Accelerator: can shorten the cure time of rubber or reduce curing temperature, reduces vulcanizing agent consumption and improves rubber Physical and mechanical properties.
The present invention is further arranged to: described by rubber peace weight based on part accelerator by accelerator ZBX 0.5-1 part, rush Enter agent ZDMC0.5-1, Urotropinum 0.5-1 part, accelerant CZ 1-2 part mixing composition.
Entering agent uses multiple special accelerator combination matching to form, and promotes that the time is different, works in coordination, promotes sulfuration and carry The high speed of sulfuration, it is ensured that product obtains excellent performance.
A kind of processing method of rubber, step is as follows,
A. rubber is put into banbury and carries out moulding white silk,
B., after step a processes, in banbury, put into zinc oxide, stearic acid, age resistor, accelerator and white carbon black carry out mixing Become raw material,
C. to the most mixing after the raw material interpolation softening agent synthesized through b step,
D. raw material after step c is mixing just takes out placement in banbury and begins to pratise machine, through the machine of beginning to pratise by raw material shaping finished product.
The step of contrast prior art, beneficial effects of the present invention:
Can overcome the most aging in prior art, maintenance cost is high and the defect of poor stability, with realize be difficult to aging, safeguard into This low and that safety is good advantage, and wearability is good, and resistance to pressure is strong, and anti-ozone performance is strong.
Detailed description of the invention
Embodiment 1:
Rubber 100g is put into banbury and carries out moulding white silk, add in banbury the most again zinc oxide 3g, stearic acid 0.6g, Accelerator ZBX 0.5g, accelerator ZDMC0.5g, Urotropinum 0.5g, rush is put in age resistor 1.5g, white carbon black 45g, banbury Enter agent CZ1g at a temperature of 120 DEG C, to carry out mixed melting binder removal become film, finally place into softening agent 15g and mix with film, Finished product is obtained after placing mill removing from mould after mixing and cooling down 3 hours.
Embodiment 2:
Rubber 100g is put into banbury and carries out moulding white silk, add in banbury the most again zinc oxide 6g, stearic acid 1.5g, Accelerator ZBX 1g, accelerator ZDMC0.5g, Urotropinum 1g, accelerator is put in age resistor 3g, white carbon black 60g, banbury CZ0.5g carries out mixed melting binder removal at a temperature of 120 DEG C and becomes film, finally places into softening agent 25g and mixes with film, mixed Finished product is obtained after placing mill removing from mould after refining and cooling down 3 hours.
Embodiment 3:
Rubber 100g is put into and carries out moulding white silk to banbury, in banbury, add zinc oxide 5g, stearic acid 1g the most again, prevent Accelerator ZBX 0.5g, accelerator ZDMC0.5g, Urotropinum 0.5g, accelerator is put in old agent 2g, white carbon black 50g, banbury CZ1g carries out mixed melting binder removal at a temperature of 120 DEG C and becomes film, finally places into softening agent 20g and mixes with film, mixing Rear placement mill removing from mould also obtains finished product after cooling down 3 hours.
The indices of the finished product obtained in the middle of above-mentioned three groups of embodiments is:
Embodiment 1: resisting fatigue degree >=1000h, hot strength > 3000N, pulse is more than 100,000 times.
Embodiment 2: resisting fatigue degree >=1100h, hot strength > 3100N, pulse is more than 150,000 times.
Embodiment 3: embodiment 1: resisting fatigue degree >=1300h, hot strength > 3600N, pulse is more than 200,000 times.
It is most preferred embodiment that above-mentioned experiment obtains embodiment three in indices.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, those skilled in the art exists Carry out common variations and alternatives in the range of technical solution of the present invention all should comprise within the scope of the present invention.

Claims (4)

1. a rubber, is characterized in that: described rubber part by weight is mixed by following component:
Rubber: 100 parts,
Zinc oxide: 2~7 parts,
Stearic acid: 0.3~1.8 part,
Age resistor: 1~5 part,
White carbon black: 30~70 parts,
Softening agent: 10~30 parts,
Accelerator: 1~5 part.
A kind of rubber the most according to claim 1, is characterized in that: described rubber peace weight meter part is by following component mixing system Become:
Rubber: 100 parts,
Zinc oxide: 3~6 parts,
Stearic acid: 0.6~1.5 part,
Age resistor: 1.5~3 parts,
White carbon black: 45~60 parts,
Softening agent: 15~25 parts,
Accelerator: 2~3 parts.
A kind of rubber the most according to claim 1 and 2, is characterized in that: described based on rubber peace weight part accelerator by promoting Enter agent ZBX 0.5-1 part, accelerator ZDMC0.5-1, Urotropinum 0.5-1 part, accelerant CZ 1-2 part mixing composition.
The processing method of a kind of rubber, is characterized in that: step is as follows,
A. rubber is put into banbury and carries out moulding white silk,
B., after step a processes, in banbury, put into zinc oxide, stearic acid, age resistor, accelerator and white carbon black carry out mixing Become raw material,
C. to the most mixing after the raw material interpolation softening agent synthesized through b step,
D. the raw material after step c is mixing takes out placement in banbury and begins to pratise machine, through the machine of beginning to pratise by raw material shaping finished product.
CN201610774529.8A 2016-08-31 2016-08-31 A kind of rubber and processing method thereof Pending CN106117691A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610774529.8A CN106117691A (en) 2016-08-31 2016-08-31 A kind of rubber and processing method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610774529.8A CN106117691A (en) 2016-08-31 2016-08-31 A kind of rubber and processing method thereof

Publications (1)

Publication Number Publication Date
CN106117691A true CN106117691A (en) 2016-11-16

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370075A (en) * 2018-11-07 2019-02-22 太仓冠联高分子材料有限公司 A kind of low temperature resistant environment-friendly electric wire cable CPE rubber compound and preparation method thereof
CN110591238A (en) * 2019-09-27 2019-12-20 江苏冠联新材料科技股份有限公司 EP (ethylene-propylene-diene monomer) rubber compound for high-elasticity wear-resistant printing rubber roller and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558629A (en) * 2011-12-15 2012-07-11 常熟市新华化工有限公司 Ageing-resistant and cold-resistant rubber
CN103254479A (en) * 2013-05-21 2013-08-21 江苏福莱欧工业制带有限公司 Heat-resisting conveyor belt
CN105419120A (en) * 2015-12-21 2016-03-23 潍坊市宏源防水材料有限公司 Vulcanized ethylene propylene diene monomer waterproof roll capable of being subjected to hot-air welding construction and production process of vulcanized ethylene propylene diene monomer waterproof roll
CN105504423A (en) * 2015-11-24 2016-04-20 安徽欧耐橡塑工业有限公司 Rubber conveyor belt and preparation process thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102558629A (en) * 2011-12-15 2012-07-11 常熟市新华化工有限公司 Ageing-resistant and cold-resistant rubber
CN103254479A (en) * 2013-05-21 2013-08-21 江苏福莱欧工业制带有限公司 Heat-resisting conveyor belt
CN105504423A (en) * 2015-11-24 2016-04-20 安徽欧耐橡塑工业有限公司 Rubber conveyor belt and preparation process thereof
CN105419120A (en) * 2015-12-21 2016-03-23 潍坊市宏源防水材料有限公司 Vulcanized ethylene propylene diene monomer waterproof roll capable of being subjected to hot-air welding construction and production process of vulcanized ethylene propylene diene monomer waterproof roll

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
谭德征: "石蜡在橡胶制品中的应用", 《橡胶工业》 *
陈士朝 等: "《橡胶技术与制造概论》", 30 September 2002, 中国石化出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109370075A (en) * 2018-11-07 2019-02-22 太仓冠联高分子材料有限公司 A kind of low temperature resistant environment-friendly electric wire cable CPE rubber compound and preparation method thereof
CN110591238A (en) * 2019-09-27 2019-12-20 江苏冠联新材料科技股份有限公司 EP (ethylene-propylene-diene monomer) rubber compound for high-elasticity wear-resistant printing rubber roller and preparation method thereof

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SE01 Entry into force of request for substantive examination
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Application publication date: 20161116