CN106117689A - A kind of preparation method of toy train square block - Google Patents

A kind of preparation method of toy train square block Download PDF

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Publication number
CN106117689A
CN106117689A CN201610493216.5A CN201610493216A CN106117689A CN 106117689 A CN106117689 A CN 106117689A CN 201610493216 A CN201610493216 A CN 201610493216A CN 106117689 A CN106117689 A CN 106117689A
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CN
China
Prior art keywords
preparation
parts
square block
surface layer
transition surface
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Granted
Application number
CN201610493216.5A
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Chinese (zh)
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CN106117689B (en
Inventor
王慧高
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Zhejiang Qifeng Toys Co., Ltd
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Ningbo Gelin Arts & Crafts Toy Co Ltd
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Priority to CN201610493216.5A priority Critical patent/CN106117689B/en
Publication of CN106117689A publication Critical patent/CN106117689A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63HTOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H19/00Model railways
    • A63H19/16Parts for model railway vehicles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The preparation method of toy train square block disclosed by the invention, including body preparation, prime, mend ash, priming paint is polished, finish paint spraying and test package, wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, get through hole, apical pore and polishing, preparation method also includes prepared by transition surface layer, transition surface layer is formed on the base substrate top layer that body preparation obtains, priming paint is formed on transition surface layer by prime, transition surface layer includes according to the raw material of weight portion: rubber 100 120 parts, high-dispersion white carbon black 50 80 parts, coupling agent 10 20 parts, stearic acid 58 parts, activating agent 58 parts, microwax 13 parts, Polyethylene Glycol 13 parts.The technique of the present invention program is simple, and product structure good stability, brushing interlayer is firmly combined with, and is effectively improved quality and the antiseptic property of toy train square block, extends its service life.

Description

A kind of preparation method of toy train square block
Technical field
The present invention relates to the preparation method of a kind of toy, the preparation method of a kind of toy train square block.
Background technology
The wooden toy in ancient times generation, is single wooden toy, modern wooden toy practical difference the most in various degree The contact of material technique and process, reach the variation of play function, multifunction.
One main kind of in toy classification of wooden toy, history is of long standing and well established, and wooden toy is in European and American developed countries Each each stage of historical development, at unique culture and realization configuration of being had of America and Europe, respective country in history, the wood of Germany Toy processed is the most also to be most notable.In the ancient times of Germany, just having the appearance of belt driven lathe, wooden toy is exactly belt driven lathe Processing, polish the most by hand, the size of this kind of wooden toy has to the biggest toy from the least several feet, this kind of object for appreciation Tool has most the works entering the coffin-die Asia Noah's ark of representative.
Have a people being A Erbai in U.S. Philadelphia, he is German, within 1872, migrates the U.S. arrived, and he starts as circus Group makes wooden horse toy, and his made wooden saddlery has nimbly and freely, lifelike feature, by a lot of circus troupe in locality Used, the most still can be seen its trace, be the most popular wooden horse.Later, circus troupe was mounted with four at wooden horse Wheel, has reformed into the blank of carriage in ancient times.
Because the inspiration of wooden horse, during wooden toy afterwards manufactures, wooden train, wooden vehicle, wooden steamer, wood Tractors processed etc. occur in succession, by now till, wooden aircraft has become favorite in children's toy, from this point can be seen that Come, the existing long history of wooden toy and cultural connotation, have the breath in imparting epoch.
In other wooden toy, stilt and gyro are also the toys that children are delithted with, and stilt are very simple wood Toy processed, teaches through lively activities, and gyro is the practical simplest wooden toy of processing technology, but in the middle of child, application is at most, little Time make gyro on ice, when gyro rotates when, therefrom acquired the knowledge such as mechanics principle, acceleration, it may be said that wooden Toy is performed meritorious deeds never to be obliterated in people's intellectual development.
In China, wooden toy history is the longest, famous ' Huarongdao ' in ancient times, the most always plays, and understands every The effect of individual personage, power and the skill mutually fought are all critically important, afterwards, occur in that again wooden toy building blocks, are taking During building building blocks, having understood the reason of building, put up and would not fall, the not science built is fallen down exactly, and this is perhaps Developing a lot of building designers, thus, toy is the intelligence teacher that the mankind impart rudimentary knowledge to beginners, and the good children's intelligence of object for appreciation will be obvious Outstanding, this also gives the glorious responsibility of toy manufacturing enterprise.
Wooden toy the most morphologically have nature, abstract, artistic form point.Natural morphologic appearance toy Essence, to the comfort of people's soul, the mental factor of abstract morphologic appearance toy, to the unlimited reverie of people.The morphologic appearance of art The appreciation factor of toy, to the sensation that people is beautiful.When people is mood is gloomy when, if he is appreciating a object for appreciation the most stupid very greatly Tool, then he is more painful, at this time, he appreciate one in bright gay color, profile is graceful, it appears that the most happy toy, the heart Feelings can be different.
Wooden toy is not only to have unique charm in intellectual development, has good feature the most in other respects, real It is first by safety, owing to wooden toy is all processed with timber, nonpoisonous and tasteless, the physical and mental health of child there is is side very much Helping, then have and fall not bad exactly, wear-resisting, the resistance to advantage such as beat, this is also the factor abroad hankering after buying Chinese wooden.
Although existing wooden toy has aforesaid advantage, but it is as natural organic, difficult without doubt To avoid to make moist, to go mouldy, corruption, the problem of the aspect such as deformation, bring difficulty for life-time service, cause the highest pushing away Wide application cost.
Summary of the invention
For solving the problems referred to above, the invention discloses the preparation method of a kind of toy train square block, technique is simple, cost Controllability is good, product structure good stability, and brushing interlayer is firmly combined with, and is effectively improved quality and the anti-corrosive properties of wooden toy Can, extend its service life.
The preparation method of toy train square block disclosed by the invention, including body preparation, prepared by transition surface layer, priming paint is coated with Brush, benefit ash, priming paint polishing, finish paint spraying form top coat layer and test package, and wherein body preparation includes sawing sheet, shape sand Light, fracture, chamfering, getting through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, priming paint Being formed on transition surface layer by prime, transition surface layer includes according to the raw material of weight portion: rubber 100-120 part, high score Dissipate white carbon 50-80 part, coupling agent 10-20 part, stearic acid 5-8 part, activating agent 5-8 part, microwax 1-3 part, Polyethylene Glycol 1-3 Part.Coupling agent (such as silane coupler etc.), activating agent etc. are the material that this area is commonly commonly used, and have the present invention program Universal adaptability.The transition surface layer arranged by employing in this programme, forms cambic structure by it in billet surface, The binding ability of wooden structures with skin of paint to strengthen base substrate, reduces in the base substrate renovation process of toy mending ash work simultaneously The dependency of skill, reduces benefit mortar and has influence on the binding ability of skin of paint on surface or the larger amount of use of local, Thus improve overall structure performance and the quality stability of toy.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, mends ash for ash material is prepared as slurry After, it is coated on workpiece, through polishing.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, ash material includes the former of following weight portion Material: Portland cement 30~60 parts, Gypsum Fibrosum 10~30 parts, penetrant crystalline material 1~4 parts, rubber powder 1~4 parts, water-retaining agent 0 ~0.3 part and fiber 0.1~0.3 part.By using special ash material to form in this programme, form hardness at surface of the work higher Structure sheaf, be beneficial to processing and post-processing operation, simultaneously by simple grinding process after, its add fiber can pass through beat Mill its prominent surface of strength control is formed and is similar to the structure of " burr " and controls this structure highlight the length on surface, thus rear Continuous process forms interlaminar improvement attachment structure, thus strengthens the fastness of Coating combination so that the surface structure of toy is more Stable firm, processability is more preferable, and abrasion resistance is higher.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, penetrant crystalline material is that activated silica oozes Crystallization master batch thoroughly.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, rubber powder is good with the cement compatibility Redispersable latex powder.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, redispersable latex powder is selected from second One or more in alkene-vinylacetate, acrylate and styrene-acrylate.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, water-retaining agent is cellulose ether.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, cellulose ether is selected from Methyl cellulose One or more in element ether, hydroxypropyl methyl cellulose ether, ethoxyl methyl cellulose ether, hydroxyethyl ether cellulose.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, fiber is selected from polypropylene fibre, gathers One or more in alcohol fibers and carbon fiber.
A kind of improvement of the preparation method of toy train square block disclosed by the invention, finish paint outer layer is also formed with glass and sinks Lamination, glass sedimentary is formed on finish paint outer layer.This glass sedimentary is that sodium silicate alkaline aqueous solution brushing is to dried Coat of paint surface obtains, and it is 0.5-0.8 micron that glass sedimentary forms thickness.In the technical program, the glass by being formed deposits Layer, is formed with one layer of comparatively dense glass structure layer with the outermost layer structure of toy, thus plays effective oxygen barrier, water proof very To the effect playing fire protection flame retarding to a certain extent, (other parts of wooden toy are respectively provided with combustibility, and this glass deposits Layer then serves certain mitigation, and is difficult to simply be lighted), simultaneously facilitate and surface is polished or frosted, change The outward appearance of kind product, has good case hardness and wearability.
Toy disclosed by the invention, has good surface texture, has good Surface Machining performance and serviceability, And technique is simple, and cost controllability is good, product structure good stability, and brushing interlayer is firmly combined with, and is effectively improved wooden The quality of toy and antiseptic property, extend its service life, and has good safety in utilization.
Detailed description of the invention
Below in conjunction with detailed description of the invention, it is further elucidated with the present invention, it should be understood that following detailed description of the invention is only used for The bright present invention rather than restriction the scope of the present invention.
Embodiment 1
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 100 parts, high-dispersion white carbon black 70 parts, coupling agent 20 Part, stearic acid 6.4 parts, activating agent 5.8 parts, microwax 1.6 parts, Polyethylene Glycol 2.3 parts.
Embodiment 2
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 103 parts, high-dispersion white carbon black 73 parts, coupling agent 10 Part, stearic acid 7.2 parts, activating agent 8 parts, microwax 2.7 parts, Polyethylene Glycol 3 parts.
Embodiment 3
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 109 parts, high-dispersion white carbon black 50 parts, coupling agent 15 Part, stearic acid 5.5 parts, activating agent 5 parts, microwax 2 parts, Polyethylene Glycol 1 part.
Embodiment 4
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 110 parts, high-dispersion white carbon black 80 parts, coupling agent 12 Part, stearic acid 8 parts, activating agent 6.2 parts, microwax 3 parts, Polyethylene Glycol 1.8 parts.
Embodiment 5
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 113 parts, high-dispersion white carbon black 60 parts, coupling agent 17 Part, stearic acid 7 parts, activating agent 7 parts, microwax 1 part, Polyethylene Glycol 2 parts.
Embodiment 6
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 116 parts, high-dispersion white carbon black 70 parts, coupling agent 16 Part, stearic acid 6 parts, activating agent 6 parts, microwax 2.4 parts, Polyethylene Glycol 1.2 parts.
Embodiment 7
The preparation method of the present embodiment toy, including body preparation, prepared by transition surface layer, prime, benefit ash, priming paint are beaten The spraying of mill, finish paint forms top coat layer and test package, and wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, beats Through hole, apical pore and polishing, transition surface layer is formed on the base substrate top layer that body preparation obtains, and priming paint is formed by prime On transition surface layer, transition surface layer includes according to the raw material of weight portion: rubber 120 parts, high-dispersion white carbon black 56 parts, coupling agent 13 Part, stearic acid 5 parts, activating agent 7.8 parts, microwax 1.3 parts, Polyethylene Glycol 2.6 parts.
Distinguish with above-described embodiment, mend ash for ash material is prepared as slurry after, be coated on workpiece, through polishing i.e. Can.
Distinguishing with above-described embodiment, the composition of ash material is illustrated by following PART, and not as The restriction of claimed range, and all can be suitable in the present invention program:
The composition embodiment 1 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 30 parts, 12 parts of Gypsum Fibrosum, penetrant crystalline Material 3 parts, rubber powder 3.3 parts and fiber 0.22 part.
The composition embodiment 2 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 40 parts, 30 parts of Gypsum Fibrosum, penetrant crystalline Material 1 part, rubber powder 2.5 parts, water-retaining agent 0.3 part and fiber 0.2 part.
The composition embodiment 3 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 50 parts, 26 parts of Gypsum Fibrosum, penetrant crystalline Material 2 parts, rubber powder 3 parts, water-retaining agent 0.1 part and fiber 0.3 part.
The composition embodiment 4 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 60 parts, 20 parts of Gypsum Fibrosum, penetrant crystalline Material 4 parts, rubber powder 2 parts, water-retaining agent 0.2 part and fiber 0.1 part.
The composition embodiment 5 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 38 parts, 17 parts of Gypsum Fibrosum, penetrant crystalline Material 1.8 parts, rubber powder 4 parts, water-retaining agent 0.15 part and fiber 0.28 part.
The composition embodiment 6 of ash material
In this enforcement, ash material includes the raw material of following weight portion: Portland cement 52 parts, 10 parts of Gypsum Fibrosum, penetrant crystalline Material 3.2 parts, rubber powder 1 part, water-retaining agent 0.23 part and fiber 0.13 part.
Distinguishing with above-described embodiment, penetrant crystalline material is activated silica penetrant crystalline masterbatch.
Distinguishing with above-described embodiment, rubber powder is the redispersable latex powder good with the cement compatibility.
Distinguishing with above-described embodiment, redispersable latex powder is to include, without being limited to the one in following scheme: second Alkene-vinylacetate;Acrylate;Styrene-acrylate;Ethylene-vinyl acetate, acrylate;Ethene-vinyl acetate Ester, styrene-acrylate;Acrylate, styrene-acrylate and;Ethylene-vinyl acetate, acrylate, styrene Acrylate.When redispersable latex powder has plurality of raw materials, combine for any mass ratio.
Distinguishing with above-described embodiment, water-retaining agent is cellulose ether.
Distinguishing with above-described embodiment, cellulose ether is to include, without being limited to the one in following scheme: Methyl cellulose Element ether;Hydroxypropyl methyl cellulose ether;Ethoxyl methyl cellulose ether;Hydroxyethyl ether cellulose;Methyl cellulose ether, hydroxypropyl Methyl cellulose ether;Methyl cellulose ether, ethoxyl methyl cellulose ether;Hydroxypropyl methyl cellulose ether, hydroxyethyl methyl are fine Dimension element ether;Methyl cellulose ether, hydroxyethyl ether cellulose;Hydroxypropyl methyl cellulose ether, hydroxyethyl ether cellulose;Methyl cellulose Element ether, hydroxypropyl methyl cellulose ether;Hydroxypropyl methyl cellulose ether, ethoxyl methyl cellulose ether, hydroxyethyl ether cellulose; Methyl cellulose ether, ethoxyl methyl cellulose ether, hydroxyethyl ether cellulose;Methyl cellulose ether, hydroxypropyl methyl cellulose Ether, hydroxyethyl ether cellulose;Methyl cellulose ether, hydroxypropyl methyl cellulose ether, ethoxyl methyl cellulose ether;Methyl cellulose Element ether, hydroxypropyl methyl cellulose ether, ethoxyl methyl cellulose ether, hydroxyethyl ether cellulose.When cellulose ether has multiple During raw material, combine for any mass ratio.
Distinguishing with above-described embodiment, fiber is to include, without being limited to the one in following scheme: polypropylene fibre;Poly- Alcohol fibers;Carbon fiber;Vinal, carbon fiber;Polypropylene fibre, carbon fiber;Polypropylene fibre, polyvinyl alcohol are fine Dimension;Polypropylene fibre, vinal, carbon fiber.When fiber has plurality of raw materials, combine for any mass ratio.
Include, without being limited in embodiments above, the toy product obtained, through different batches sampling 10, carry out water Soak, oil immersion bubble, 1m height concrete floor base plate drop 3 times, the solid desktop 100 inferior tests that rub continuously all damage without obvious.
Distinguishing with above-described embodiment, finish paint outer layer is also formed with glass sedimentary, glass sedimentary is formed at finish paint On outer layer.
Distinguishing with above-described embodiment, glass sedimentary is that sodium silicate alkaline aqueous solution brushing is to the dried coat of paint Surface obtains, glass sedimentary formed thickness be 0.5 micron (glass sedimentary formed thickness can also for include, without being limited to as Under arbitrary: 0.54 micron, 0.6 micron, 0.62 micron, 0.7 micron, 0.78 micron, 0.8 micron and 0.5-0.8 micron).
Including, without being limited in embodiments above, the toy product with glass sedimentary obtained, through different batches Sampling 10, carries out water soaking, oil immersion bubble, 1m height concrete floor base plate drop 3 times, solid desktop rubs 100 inferior examinations continuously Test all without substantially damage, and under conventional chambers environment, with general flame calcination 3min without substantially peeling off and combustion phenomena.
This place embodiment is in place of the claimed non-limit of technical scope midrange and in embodiment technology Single or multiple technical characteristics are replaced the new technical scheme formed, the most all at application claims by scheme on an equal basis In the range of protection;Simultaneously in all embodiments enumerated or do not enumerate of the present invention program, in the same embodiment each Parameter is merely representative of an example (i.e. a kind of feasible scheme) of its technical scheme, and does not exist strict between parameters Cooperation and qualified relation, the most each parameter can mutually replace when stating ask without prejudice to axiom and the present invention, special declaration Except.
Technological means disclosed in the present invention program is not limited only to the technological means disclosed in above-mentioned technological means, also includes The technical scheme being made up of above technical characteristic combination in any.The above is the detailed description of the invention of the present invention, it should refer to Go out, for those skilled in the art, under the premise without departing from the principles of the invention, it is also possible to make some Improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.

Claims (9)

1. a preparation method for toy train square block, including body preparation, prime, benefit ash, priming paint polishing, finish paint spray Being coated with and test package, wherein body preparation includes sawing sheet, setting sanding, fracture, chamfering, gets through hole, apical pore and polishing, its Being characterised by: described preparation method also includes prepared by transition surface layer, described transition surface layer is formed at the base substrate that body preparation obtains On top layer, described priming paint is formed on transition surface layer by prime, and described transition surface layer includes according to the raw material of weight portion: Rubber 100-120 part, high-dispersion white carbon black 50-80 part, coupling agent 10-20 part, stearic acid 5-8 part, activating agent 5-8 part, crystallite Wax 1-3 part, Polyethylene Glycol 1-3 part.
The preparation method of toy train square block the most according to claim 1, it is characterised in that: described benefit ash is by ash material After being prepared as slurry, it is coated on workpiece, through polishing.
The preparation method of toy train square block the most according to claim 1, it is characterised in that: described ash material includes as follows The raw material of weight portion: Portland cement 30~60 parts, Gypsum Fibrosum 10~30 parts, penetrant crystalline material 1~4 parts, rubber powder 1~4 Part, water-retaining agent 0~0.3 part and fiber 0.1~0.3 part.
The preparation method of toy train square block the most according to claim 3, it is characterised in that: described penetrant crystalline material For activated silica penetrant crystalline masterbatch.
The preparation method of toy train square block the most according to claim 4, it is characterised in that: described rubber powder is and cement The redispersable latex powder that the compatibility is good.
The preparation method of toy train square block the most according to claim 5, it is characterised in that: described Redispersable latex One or more in ethylene-vinyl acetate, acrylate and styrene-acrylate of powder.
The preparation method of toy train square block the most according to claim 3, it is characterised in that: described water-retaining agent is fiber Element ether.
The preparation method of toy train square block the most according to claim 7, it is characterised in that: described cellulose ether is choosing One in methyl cellulose ether, hydroxypropyl methyl cellulose ether, ethoxyl methyl cellulose ether, hydroxyethyl ether cellulose or Multiple.
The preparation method of toy train square block the most according to claim 3, it is characterised in that: described fiber is selected from poly-third One or more in alkene fiber, vinal and carbon fiber.
CN201610493216.5A 2016-06-24 2016-06-24 A kind of preparation method of toy train square block Active CN106117689B (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106669377A (en) * 2016-12-28 2017-05-17 宁波兴光新能源投资有限公司 Landfill gas purification device
CN106731500A (en) * 2016-12-28 2017-05-31 宁波兴光新能源投资有限公司 A kind of landfill gas pretreatment unit

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2127056Y (en) * 1992-07-23 1993-02-17 温克义 Compound product with rigidity rubber face
CN1111572A (en) * 1995-03-29 1995-11-15 王振发 Making method for decorative art and craft articles
CN101670335A (en) * 2008-09-09 2010-03-17 莫有根 Paint coating process for wooden furniture
CN103304205A (en) * 2013-07-04 2013-09-18 重庆久圣成防水材料有限公司 Capillary crystalline patch plaster
CN104587678A (en) * 2015-01-20 2015-05-06 宁波宝笛工艺精机有限公司 Toy tire and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2127056Y (en) * 1992-07-23 1993-02-17 温克义 Compound product with rigidity rubber face
CN1111572A (en) * 1995-03-29 1995-11-15 王振发 Making method for decorative art and craft articles
CN101670335A (en) * 2008-09-09 2010-03-17 莫有根 Paint coating process for wooden furniture
CN103304205A (en) * 2013-07-04 2013-09-18 重庆久圣成防水材料有限公司 Capillary crystalline patch plaster
CN104587678A (en) * 2015-01-20 2015-05-06 宁波宝笛工艺精机有限公司 Toy tire and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106669377A (en) * 2016-12-28 2017-05-17 宁波兴光新能源投资有限公司 Landfill gas purification device
CN106731500A (en) * 2016-12-28 2017-05-31 宁波兴光新能源投资有限公司 A kind of landfill gas pretreatment unit

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