CN106117586A - 镜像多功能弱溶剂打印材料、打印材料的制备方法及证卡 - Google Patents

镜像多功能弱溶剂打印材料、打印材料的制备方法及证卡 Download PDF

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CN106117586A
CN106117586A CN201610692233.1A CN201610692233A CN106117586A CN 106117586 A CN106117586 A CN 106117586A CN 201610692233 A CN201610692233 A CN 201610692233A CN 106117586 A CN106117586 A CN 106117586A
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weak solvent
printed material
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coating
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陈武
吕晓莉
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Shanghai Valley Digital Technology Co Ltd
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Abstract

一种镜像多功能弱溶剂打印材料，包括承载层和粘贴于所述承载层上的着墨层，所述承载层由透明的塑料制成，所述着墨层由多功能弱溶剂涂料制成，着墨层透明或半透明；镜像多功能弱溶剂打印材料的制备方法，包括：先将形成所述打底层的打底涂料以干重3～15g/m2的涂布量涂于所述承载层上，然后将所述承载层烘干收卷；再将所述着墨层的多功能弱溶剂涂料以干重10～25g/m2的涂布量涂于所述打底层上，待涂层完全烘干后收卷、分切即可。本发明镜像多功能弱溶剂打印材料及证卡，具有打印输出色彩还原准确、输出精度高、耐水能力强、抗紫外线性能好、剥离强度高、制作工艺简单、成本低、操作简便。

Description

镜像多功能弱溶剂打印材料、打印材料的制备方法及证卡
技术领域
本发明涉及一种镜像打印材料及证卡的制备方法，特别指一种镜像多功能弱溶剂打印材料、打印材料的制备方法及其证卡。
背景技术
现行的个性化证卡输出方式大多采用水性喷墨和数码印刷(HP indigo)进行输出打印。水性喷墨打印具有成本低廉，设备投入小等多种优势，但致命之处是图文色彩保存时间短，防水性能差，且输出速度慢，难以批量加工制作；数码印刷(HP indigo)具有输出速度快，图文色彩保存时间长，耐水性能好等特点，但其昂贵的设备投入与制作成本使众多制卡厂望而兴叹。另外，由于制卡工艺及卡片本身性能要求的特殊性，要求卡片层间剥离强度必须达到6N/cm(国家标准)以上，而以以上输出方式制成的卡片是很难达到国家标准所要求的。因此，寻求一种完美解决上述问题的数码输出方案是目前证卡输出的首要问题。
发明内容
本发明的目的在于提供一种镜像多功能弱溶剂打印材料、打印材料的的制备方法及证卡，该打印材料制作的证卡打印输出色彩还原准确、输出精度高、耐水能力强、抗紫外线性能好、剥离强度高、制作工艺简单、成本低、操作简便。
为了达到上述目的，本发明提供一种镜像多功能弱溶剂打印材料，包括承载层和附着于所述承载层上的着墨层，所述承载层由透明的塑料制成，所述着墨层由多功能弱溶剂涂料制成，并且所述着墨层透明。
本发明镜像多功能弱溶剂打印材料，其中，所述承载层的厚度为0.012-0.15mm。。
本发明镜像多功能弱溶剂打印材料，其中，所述承载层由PVC、PET、PETG、PC或PP制成。
本发明镜像多功能弱溶剂打印材料，其中，所述承载层和着墨层之间还设置有打底层，所述打底层由胶粘胶制成。
本发明镜像多功能弱溶剂打印材料，其中，所述打底层为水性聚氨酯乳液或VAE乳液。
一种镜像多功能弱溶剂打印材料的制备方法，将所述着墨层的多功能弱溶剂涂料以干重10～25g/m2的涂布量直接涂于所述承载层上，然后将多功能弱溶剂涂料烘干收卷、分切即可。
一种镜像多功能弱溶剂打印材料的制备方法，该方法包括下述步骤：
A、将形成所述打底层的打底涂料以干重3～15g/m2的涂布量涂于所述承载层上，然后将所述承载层烘干收卷；
B、将所述着墨层的多功能弱溶剂涂料以干重10～25g/m2的涂布量涂于所述打底层上，待涂层完全烘干后收卷、分切即可。
本发明镜像多功能弱溶剂打印材料的制备方法，其中，在所述步骤B中，所述着墨层的多功能弱溶剂涂料采用涂布机涂布。
一种证卡，包括两层上述任一所述的多功能弱溶剂打印材料及一层PVC中料，所述两层多功能弱溶剂打印材料的着墨层分别贴合于所述PVC中料两侧，所述各层压为一体。
采用上述方案后，本发明镜像多功能弱溶剂打印材料、打印材料的制备方法及证卡的有益效果是：
1、本发明镜像多功能弱溶剂打印材料及证卡具有耐水性能好、抗紫外线能力强、色彩还原准确、输出精度高、剥离强度好、成本低廉等特点，由于该工艺为个性化输出技术，其输出图文整体质量接近传统印刷质量，并且制证卡层压时无需带胶膜，直接与中料热压贴合即可，因此，不但解决了传统个性化证卡制作的诸多弊端，而且解决了批量印刷中补卡成本高、周期长的问题，更适合小批量印刷卡的制作。
2、本发明镜像多功能弱溶剂打印材料的制备方法工艺简单、加工效率高。
附图说明
图1为本发明镜像多功能弱溶剂打印材料实施例一的结构示意图；
图2为本发明镜像多功能弱溶剂打印材料实施例二的结构示意图；
图3为本发明证卡的结构示意图。
具体实施方式
下面结合附图和具体实施例对本发明作进一步说明，以使本领域的技术人员可以更好的理解本发明并能予以实施，但所举实施例不作为对本发明的限定。
实施例一：如图1所示本发明镜像多功能弱溶剂打印材料包括承载层11和着墨层12，承载层11为基材，采用透明的PVC、PET、PETG、PC或PP等塑料材料制成，承载层11的厚度为0.012mm；着墨层12由多功能弱溶剂涂料制成，着墨层12具有较高透明度，多功能弱溶剂涂料按重量份数的配方是：
水性聚氨脂乳液：10～25份；
纯丙乳液：20～30份；
二氧化硅：1～3份；
苯酮类抗紫外线剂：0.2～0.6份；
有机硅表面活性剂：0.1～0.5份；
荧光增白剂：0.05～0.3份；
去离子水：5～30份。
多功能弱溶剂涂料的制备方法是：
(1)将1-3份二氧化硅在300转/分钟的搅拌状态下逐步加入5～30份去离子水中，再加入0.1-0.5份有机硅表面活性剂，然后将搅拌速度逐步提升到1500转/分钟，搅拌20～30分钟，待二氧化硅完全分散后备用；
(2)将步骤(1)所得的混合溶液与水性聚氨脂乳液、纯丙乳液、苯酮类抗紫外线剂、荧光增白剂按上述配方次序在200～300转/分钟的搅拌状态下逐步混合在一起，在1000～2000转/分钟的状态下搅拌10～20分钟；
(3)待步骤(2)所得乳液完全混合均匀后，用200～300目网布过滤后放置4小时以上，待完全消泡后即可上机涂布。
其技术指标如下：
涂料指标：
固含量：20～30％； 黏度：500～5000；
玻璃化温度：-20～0℃； 热活化温度：135～150℃。
成膜后指标：
涂膜厚度：15～30um； 耐水性：25℃，>72小时；
层间附着力：>6(N/cm)； 层压牢度：>6(N/cm)；
色密度：Dc>1.8、Dm>1.5、Dy>1.4、Dk>2.0；
耐黄变性：3～5年。
本发明镜像多功能弱溶剂打印材料的制备方法是：
将着墨层12的多功能弱溶剂涂料以干重10～25g/m2的涂布量直接涂于承载层11上，将多功能弱溶剂涂料烘干收卷、分切即可，以这种涂布方式制成的承载层11在图案打印时须镜像打印，可使打印材料与带胶膜二合为一，制证层压时无需带胶膜，直接与证卡中料镜像热压粘合，简化了制作工艺，降低了制作成本。
本发明镜像多功能弱溶剂打印材料制成的证卡，如图3所示，包括镜像打印有图文的第一多功能弱溶剂打印材料21、镜像打印有图文的第二多功能弱溶剂打印材料22及PVC中料23，第一、第二多功能弱溶剂打印材料的着墨层分别贴合于PVC中料23的两侧，第一、第二多功能弱溶剂打印材料及PVC中料热压粘合为一体。
用此配方制成得多功能弱溶剂涂料具备良好的着色性、耐水性、抗黄变性、固化速度、内聚强度和层间附着力等特点，用该涂料为现代制卡工艺技术提供一种新型图文输出技术；通过该涂料制成的镜像多功能弱溶剂打印材料及证卡具有耐水性能好、抗紫外线能力强、色彩还原准确、输出精度高、剥离强度好、成本低廉等特点，由于该工艺为个性化输出技术，其输出图文整体质量接近传统印刷质量，因此，不但解决了传统个性化证卡制作的诸多弊端，而且解决了批量印刷中补卡成本高、周期长的问题，更适合小批量印刷卡的制作；该镜像多功能弱溶剂打印材料的制备方法工艺简单、加工效率高。
实施例二：如图2所示本发明镜像多功能弱溶剂打印材料包括承载层11、着墨层12及打底层13，承载层11为基材，采用透明的PVC、PET、PETG、PC或PP等材料制成，承载层11的厚度为0.15mm；打底层13选用水性聚氨酯乳液、VAE乳液或其他胶粘胶，打底层13的设置提高了承载层11与着墨层12之间的层间剥离力；着墨层12由多功能弱溶剂涂料制成，着墨层12具有较高的透明度，多功能弱溶剂涂料按重量份数的配方是：
乙烯-醋酸乙烯共聚乳液：10～20份；
丙烯酸乳液：25～30份；
二氧化硅：1～6份；
碳酸氢钙：2～6份；
水性蜡乳液：1～3份；
荧光增白剂：0.05～0.3份；
纳米二氧化钛类抗紫外线剂：0.3～2份；
有机硅表面活性剂：0.1～0.5份；
去离子水：10～30份。
制备方法是：
(1)将1-6份二氧化硅和2-6份碳酸氢钙在300转/分钟的搅拌状态下逐步加入10～30份去离子水中，再加入0.1～0.5份有机硅表面活性剂，然后将搅拌速度逐步提升到1500转/分钟，搅拌20～30分钟，待二氧化硅和碳酸氢钙完全分散后备用；
(2)将步骤(1)所得的混合溶液与乙烯-醋酸乙烯共聚乳液、丙烯酸乳液、荧光增白剂、纳米二氧化钛类抗紫外线剂、水性蜡按上述配方次序在200～300转/分钟的搅拌状态下逐步混合在一起，在1000～2000转/分钟的状态下搅拌10～20分钟；
(3)待步骤(2)所得乳液完全混合均匀后，用200～300目网布过滤后放置4小时以上，待完全消泡后即可上机涂布。
其具体技术指标如下：
涂料指标：
固含量：15～30％； 黏度：500～3000；
玻璃化温度：-30～0℃； 热活化温度：135～150℃。
成膜后指标：
涂膜厚度：15～30um； 耐水性：25℃，>48小时；
层间附着力：>8(N/cm)； 层压牢度：>8(N/cm)；
色密度：Dc>1.7、Dm>1.4、Dy>1.4、Dk>1.9；
耐黄变性：3～5年。
本发明镜像多功能弱溶剂打印材料的制备方法是：
A、将形成打底层13的打底涂料以干重3～15g/m2的涂布量涂于承载层11上，然后将承载层11烘干收卷；
B、利用涂布机将着墨层12的多功能弱溶剂涂料以干重10～25g/m2的涂布量涂于打底层13上，待涂层完全烘干后收卷、分切即可。
以这种涂布方式制成的承载层11在图案打印时须镜像打印，可使打印材料与带胶膜二合为一，制证层压时无需带胶膜，直接与证卡中料镜像热压粘合，简化了制作工艺，降低了制作成本。
本发明镜像多功能弱溶剂打印材料制成的证卡，与实施例一中的证卡不同之处在于，第一多功能弱溶剂打印材料21、第二多功能弱溶剂打印材料22均包括承载层11、打底层13及着墨层12。
用此配方制成得多功能弱溶剂涂料具备良好的着色性、耐水性、抗黄变性、固化速度、内聚强度和层间附着力等特点，用该涂料为现代制卡工艺技术提供一种新型图文输出技术；通过该涂料制成的镜像多功能弱溶剂打印材料及证卡具有耐水性能好、抗紫外线能力强、色彩还原准确、输出精度高、剥离强度好、成本低廉等特点，由于该工艺为个性化输出技术，其输出图文整体质量接近传统印刷质量，因此，不但解决了传统个性化证卡制作的诸多弊端，而且解决了批量印刷中补卡成本高、周期长的问题，更适合小批量印刷卡的制作；该镜像多功能弱溶剂打印材料的制备方法工艺简单、加工效率高。
实施例三，如图2所示本发明镜像多功能弱溶剂打印材料包括承载层11、着墨层12及打底层13，承载层11为基材，采用透明的PVC、PET、PETG、PC或PP等材料制成，承载层11的厚度为0.09mm；打底层13选用水性聚氨酯乳液、VAE乳液或其他胶粘胶，打底层13的设置提高了承载层11与着墨层12之间的层间剥离力；着墨层12由多功能弱溶剂涂料制成，着墨层12具有较高的透明度，多功能弱溶剂涂料按重量份数的配方是：
水性聚氨脂乳液：5～10份；
乙烯－醋酸乙烯共聚乳液：5～20份；
丙烯酸乳液：20～30份；
二氧化硅：2～5份；
荧光增白剂：0.05～0.3份；
苯并三唑类抗紫外线剂：0.3～0.6份；
氟表面活性剂：0.01～0.03份；
有机硅表面活性剂：0.1～0.3份；
去离子水：10～30份。
制备方法是：
(1)将2-5份二氧化硅在300转/分钟的搅拌状态下逐步加入10～30份去离子水中，再加入0.1～0.3份有机硅表面活性剂，然后将搅拌速度逐步提升到1500转/分钟，搅拌20～30分钟，待二氧化硅完全分散后备用；
(2)将步骤(1)所得的混合溶液与水性聚氨脂乳液、乙烯-醋酸乙烯共聚乳液、丙烯酸乳液、荧光增白剂、苯并三唑类抗紫外线剂、氟表面活性剂、按上述配方次序在200～300转/分钟的搅拌状态下逐步混合在一起，在1000～2000转/分钟的状态下搅拌10～20分钟；
(3)待步骤(2)所得乳液完全混合均匀后，用200～300目网布过滤后放置4小时以上，待完全消泡后即可上机涂布。
其具体技术指标如下：
涂料指标：
固含量：20～35％； 黏度：500～5000；
玻璃化温度：-40～0℃； 热活化温度：125～145℃。
成膜后指标：
涂膜厚度：15～30um； 耐水性：25℃，>48小时；
层间附着力：>6(N/cm)； 层压牢度：>6(N/cm)；
色密度：Dc>1.8、Dm>1.5、Dy>1.4、Dk>2.0；
耐黄变性：3～5年。
本发明镜像多功能弱溶剂打印材料的制备方法是：
A、将形成打底层13的打底涂料以干重3～15g/m2的涂布量涂于承载层11上，然后将承载层11烘干收卷；
B、利用涂布机将着墨层12的多功能弱溶剂涂料以干重10～25g/m2的涂布量涂于打底层13上，待涂层完全烘干后收卷、分切即可。
以这种涂布方式制成的承载层11在图案打印时须镜像打印，可使打印材料与带胶膜二合为一，制证层压时无需带胶膜，直接与证卡中料镜像热压粘合，简化了制作工艺，降低了制作成本。
本发明镜像多功能弱溶剂打印材料制成的证卡，与实施例一中的证卡不同之处在于，第一多功能弱溶剂打印材料21、第二多功能弱溶剂打印材料22均包括承载层11、打底层13及着墨层12。
用此配方制成得多功能弱溶剂涂料具备良好的着色性、耐水性、抗黄变性、固化速度、内聚强度和层间附着力等特点，用该涂料为现代制卡工艺技术提供一种新型图文输出技术；通过该涂料制成的镜像多功能弱溶剂打印材料及证卡具有耐水性能好、抗紫外线能力强、色彩还原准确、输出精度高、剥离强度好、成本低廉等特点，由于该工艺为个性化输出技术，其输出图文整体质量接近传统印刷质量，因此，不但解决了传统个性化证卡制作的诸多弊端，而且解决了批量印刷中补卡成本高、周期长的问题，更适合小批量印刷卡的制作；该镜像多功能弱溶剂打印材料的制备方法工艺简单、加工效率高。
以上所述实施例仅是为充分说明本发明而所举的较佳的实施例，本发明的保护范围不限于此。本技术领域的技术人员在本发明基础上所作的等同替代或变换，均在本发明的保护范围之内。本发明的保护范围以权利要求书为准。

Claims (9)

1.一种镜像多功能弱溶剂打印材料，其特征在于：包括承载层(11)和附着于所述承载层(11)上的着墨层(12)，所述承载层(11)由透明的塑料制成，所述着墨层(12)由多功能弱溶剂涂料制成，并且所述着墨层(12)透明或半透明。
2.根据权利要求1所述的镜像多功能弱溶剂打印材料，其特征在于：所述承载层(11)的厚度为0.012-0.15mm。
3.根据权利要求1所述的镜像多功能弱溶剂打印材料，其特征在于：所述承载层(11)由PVC、PET、PETG、PC或PP制成。
4.根据权利要求1所述的镜像多功能弱溶剂打印材料，其特征在于：所述承载层(11)和着墨层(12)之间还设置有打底层(13)，所述打底层(13)由胶粘胶制成。
5.根据权利要求4所述的镜像多功能弱溶剂打印材料，其特征在于：所述打底层(13)为水性聚氨酯乳液或VAE乳液。
6.上述权利要求1至3任一所述镜像多功能弱溶剂打印材料的制备方法，其特征在于：将所述着墨层(12)的多功能弱溶剂涂料以干重10～25g/m2的涂布量直接涂于所述承载层(11)上，然后将多功能弱溶剂涂料烘干收卷、分切即可。
7.上述权利要求4或5所述镜像多功能弱溶剂打印材料的制备方法，其特征在于：该方法包括下述步骤：
A、将形成所述打底层(13)的打底涂料以干重3～15g/m2的涂布量涂于所述承载层(11)上，然后将所述承载层(11)烘干收卷；
B、将所述着墨层(12)的多功能弱溶剂涂料以干重10～25g/m2的涂布量涂于所述打底层(13)上，待涂层完全烘干后收卷、分切即可。
8.根据权利要求7所述镜像多功能弱溶剂打印材料的制备方法，其特征在于：在所述步骤B中，所述着墨层(12)的多功能弱溶剂涂料采用涂布机涂布。
9.一种证卡，其特征在于：包括两层镜像打印有图文的上述权利要求1-5任一所述的多功能弱溶剂打印材料(21、22)及一层PVC中料(23)，所述两层多功能弱溶剂打印材料(21、22)的着墨层分别贴合于所述PVC中料(23)两侧，所述各层热压粘合为一体。
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US11926747B2 (en) 2019-12-23 2024-03-12 Hid Global Cid Sas UV curable and heat sealable ink

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