CN106117500A - A kind of preparation method of the sneaker sole material of ventilative damping - Google Patents

A kind of preparation method of the sneaker sole material of ventilative damping Download PDF

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Publication number
CN106117500A
CN106117500A CN201610571908.7A CN201610571908A CN106117500A CN 106117500 A CN106117500 A CN 106117500A CN 201610571908 A CN201610571908 A CN 201610571908A CN 106117500 A CN106117500 A CN 106117500A
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CN
China
Prior art keywords
parts
component
polyether polyol
sole
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610571908.7A
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Chinese (zh)
Inventor
葛胜超
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
East Asia Nanjing Product Of Rubber And Plastic Co Ltd
Original Assignee
East Asia Nanjing Product Of Rubber And Plastic Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by East Asia Nanjing Product Of Rubber And Plastic Co Ltd filed Critical East Asia Nanjing Product Of Rubber And Plastic Co Ltd
Priority to CN201610571908.7A priority Critical patent/CN106117500A/en
Publication of CN106117500A publication Critical patent/CN106117500A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A43FOOTWEAR
    • A43BCHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00Soles; Sole-and-heel integral units
    • A43B13/02Soles; Sole-and-heel integral units characterised by the material
    • A43B13/04Plastics, rubber or vulcanised fibre
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/28Glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)

Abstract

The preparation method of the sneaker sole material of a kind of ventilative damping that the present invention provides, its raw material includes mass ratio (2 4): the component A and component B of 1;Wherein, described component A is made up of the component of following weight ratio: polyether polyol 30 60 parts, glycerol 20 30 parts, isocyanates 10 20 parts, sodium lauryl sulphate 46 parts, chain extender 46 parts;Described component B is made up of the component of following weight portion: china-hemp fibers 20 30 parts, polyether polyol 30 50 parts, polyacrylate 10 20 parts, polyether polyol 10 20 parts, triethylamine 0.5 1.5 parts, hollow glass micropearl 12 parts, foaming agent 12 parts, activating agent 23 parts, accelerator 0.5 1 parts, vulcanizing agent 0.5 1.5 parts.This material for sole of shoe preparation technology is simple, with low cost, good permeability, elasticity is good, damping performance good, is applicable to athletic shoe sole.

Description

A kind of preparation method of the sneaker sole material of ventilative damping
Technical field
The invention belongs to daily necessities field, particularly to the sneaker sole material and preparation method thereof of a kind of ventilative damping.
Background technology
The kind of material for sole of shoe is a lot, is generally divided into natural class material for sole of shoe and synthesis class material for sole of shoe two kinds.Natural class Material for sole of shoe includes that natural bottom leather, bamboo and wood material etc., synthesis class material for sole of shoe include rubber, PU material, PVC synthetic resin etc..Footwear The common characteristic of bottom material possesses wear-resisting, water-fast, good springiness, be easily suitable for foot type, sizing after be unlikely to deform etc. condition.At present Synthesis class material for sole of shoe is a most widely used class footwear material.
Many material for sole of shoe the most on the market have aesthetic appearances, but have just worn and can produce stink, and this is due to this The ventilative difference of a little shoes, it is impossible to discharge the perspiration of secretion on foot in time, forms the environment of humidity, breed bacteria in footwear, produces Frowst, for a long time, also can cause the step disease of tinea pedis.
Wear shoes is walked or motion not only can protect the foot of people to exempt from injury, and can also play cushioning effect.Owing to people exists When walking or move, human body is produced vibrations reason and mainly comes from sole, so, want that human body is alleviated or avoided and produced Shaking force, unique solution is to increase the elasticity of sole.
Sport shoes is more for ventilative higher with aeroelastic requirements due to user motion.
Summary of the invention
Technical problem: in order to solve the defect of prior art, the invention provides the sport shoes ground of a kind of ventilative damping Material.
Technical scheme: the sneaker sole material of a kind of ventilative damping that the present invention provides, including mass ratio (2-4): the group of 1 Part A and component B;Wherein, described component A is made up of the component of following weight ratio: polyether polyol 30-60 part, glycerol 20-30 Part, isocyanates 10-20 part, sodium lauryl sulphate 4-6 part, chain extender 4-6 part;Described component B is by the group of following weight portion Part is made: china-hemp fibers 20-30 part, polyether polyol 30-50 part, polyacrylate 10-20 part, polyether polyol 10-20 part, Triethylamine 0.5-1.5 part, hollow glass micropearl 1-2 part, foaming agent 1-2 part, activating agent 2-3 part, accelerator 0.5-1 part, sulfuration Agent 0.5-1.5 part.
As improvement, the sneaker sole material of described ventilative damping includes the component A and component B of mass ratio 3:1;Wherein, Described component A is made up of the component of following weight ratio: polyether polyol 45 parts, glycerol 25 parts, isocyanates 15 parts, dodecane 5 parts of base sodium sulfate, chain extender 5 parts;Described component B is made up of the component of following weight portion: china-hemp fibers 15 parts, polyether polyol 40 parts, polyacrylate 15 parts, polyether polyol 15 parts, triethylamine 1 part, hollow glass micropearl 1.5 parts, foaming agent 1.5 parts, live Property agent 2.5 parts, accelerator 0.75 part, vulcanizing agent 1.0 parts.
Present invention also offers the preparation method of the sneaker sole material of above-mentioned a kind of ventilative damping, comprise the following steps:
(1) each component of component A is weighed in proportion, mixes;Each component of component B is weighed in proportion, mixes;
(2) each component in component A is added in autoclave, at 80-90 DEG C, react 1-2h, be cooled to room temperature, obtain pre-polymerization Body;
(3) by performed polymer and the component B mix homogeneously of 2/3;Add in sole casting machine batch can, be warming up to 80-90 DEG C, constant temperature 5- 10min;It is cooled to 60-70 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min;
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Beneficial effect: the present invention provide material for sole of shoe preparation technology is simple, with low cost, good permeability, elastic good, subtract Pinking is good, is applicable to athletic shoe sole.
Detailed description of the invention
The sneaker sole material of damping of breathing freely the present invention below further illustrates.
The sneaker sole material of ventilative damping, including the component A and component B of mass ratio 3:1;Wherein, described component A by with The component of lower weight ratio is made: polyether polyol 45 parts, glycerol 25 parts, isocyanates 15 parts, sodium lauryl sulphate 5 parts, Chain extender 5 parts;Described component B is made up of the component of following weight portion: china-hemp fibers 15 parts, polyether polyol 40 parts, polypropylene Acid esters 15 parts, polyether polyol 15 parts, triethylamine 1 part, hollow glass micropearl 1.5 parts, foaming agent 1.5 parts, activating agent 2.5 parts, Accelerator 0.75 part, vulcanizing agent 1.0 parts.
Its preparation method, comprises the following steps:
(1) each component of component A is weighed in proportion, mixes;Each component of component B is weighed in proportion, mixes;
(2) each component in component A is added in autoclave, at 80-90 DEG C, react 1-2h, be cooled to room temperature, obtain pre-polymerization Body;
(3) by performed polymer and the component B mix homogeneously of 2/3;Add in sole casting machine batch can, be warming up to 80-90 DEG C, constant temperature 5- 10min;It is cooled to 60-70 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min;
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.

Claims (2)

1. the preparation method of the sneaker sole material of a ventilative damping, it is characterised in that: comprise the following steps:
(1) each component of component A is weighed in proportion, mixes;Each component of component B is weighed in proportion, mixes;
(2) each component in component A is added in autoclave, at 80-90 DEG C, react 1-2h, be cooled to room temperature, obtain pre-polymerization Body;
(3) by performed polymer and the component B mix homogeneously of 2/3;Add in sole casting machine batch can, be warming up to 80-90 DEG C, constant temperature 5- 10min;It is cooled to 60-70 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min;
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product;
Wherein, the mass ratio of component A and component B is (2-4): 1;Wherein, described component A is made up of the component of following weight ratio: Polyether polyol 30-60 part, glycerol 20-30 part, isocyanates 10-20 part, sodium lauryl sulphate 4-6 part, chain extender 4-6 Part;Described component B is made up of the component of following weight portion: china-hemp fibers 20-30 part, polyether polyol 30-50 part, polyacrylic acid Ester 10-20 part, polyether polyol 10-20 part, triethylamine 0.5-1.5 part, hollow glass micropearl 1-2 part, foaming agent 1-2 part, live Property agent 2-3 part, accelerator 0.5-1 part, vulcanizing agent 0.5-1.5 part.
The preparation method of the sneaker sole material of a kind of ventilative damping the most according to claim 1, it is characterised in that: include The component A and component B of mass ratio 3:1;Wherein, described component A is made up of the component of following weight ratio: polyether polyol 45 parts, Glycerol 25 parts, isocyanates 15 parts, sodium lauryl sulphate 5 parts, chain extender 5 parts;Described component B is by the group of following weight portion Part is made: china-hemp fibers 15 parts, polyether polyol 40 parts, polyacrylate 15 parts, polyether polyol 15 parts, triethylamine 1 part, empty Heart glass microballoon 1.5 parts, foaming agent 1.5 parts, activating agent 2.5 parts, accelerator 0.75 part, vulcanizing agent 1.0 parts.
CN201610571908.7A 2016-07-20 2016-07-20 A kind of preparation method of the sneaker sole material of ventilative damping Pending CN106117500A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610571908.7A CN106117500A (en) 2016-07-20 2016-07-20 A kind of preparation method of the sneaker sole material of ventilative damping

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610571908.7A CN106117500A (en) 2016-07-20 2016-07-20 A kind of preparation method of the sneaker sole material of ventilative damping

Publications (1)

Publication Number Publication Date
CN106117500A true CN106117500A (en) 2016-11-16

Family

ID=57289061

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610571908.7A Pending CN106117500A (en) 2016-07-20 2016-07-20 A kind of preparation method of the sneaker sole material of ventilative damping

Country Status (1)

Country Link
CN (1) CN106117500A (en)

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WD01 Invention patent application deemed withdrawn after publication
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Application publication date: 20161116