CN105968556A - Deodorant basketball shoe sole material with high rebound resilience - Google Patents
Deodorant basketball shoe sole material with high rebound resilience Download PDFInfo
- Publication number
- CN105968556A CN105968556A CN201610572010.1A CN201610572010A CN105968556A CN 105968556 A CN105968556 A CN 105968556A CN 201610572010 A CN201610572010 A CN 201610572010A CN 105968556 A CN105968556 A CN 105968556A
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- Prior art keywords
- parts
- component
- nano
- shoe sole
- deodorant
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a deodorant basketball shoe sole material with high rebound resilience, which comprises a component A and a component B in a mass ratio of (2-4):1, wherein the component A is prepared from the following components in parts by weight: 20-25 parts of EVA of which the VA content is 25%, 15-25 parts of EVA of which the VA content is 40%, 10-20 parts of ethylene propylene diene copolymer, 10-20 parts of thermoplastic rubber SEBS, 1-3 parts of KH 560, and 1-3 parts of triethylenediamine; and the component B is prepared from the following components in parts by weight: 4-6 parts of nano silver particles, 10-20 parts of nano zinc oxide, 0.5-1.5 parts of nano titanium oxide, 0.5-5 parts of carboxylated polybutadiene, 1-3 parts of a coupling agent, 20-35 parts of a plasticizing agent, 2-5 parts of a reinforcing agent and 3-5 parts of stearic acid. The shoe sole material is simple in preparation process, low in cost, good in air permeability, good in elasticity, and applicable to a basketball shoe sole.
Description
Technical field
The invention belongs to daily necessities field, particularly to basketball shoe sole material and the preparation side thereof of a kind of high resilience deodorant
Method.
Background technology
The kind of material for sole of shoe is a lot, is generally divided into natural class material for sole of shoe and synthesis class material for sole of shoe two kinds.Natural class
Material for sole of shoe includes that natural bottom leather, bamboo and wood material etc., synthesis class material for sole of shoe include rubber, PU material, PVC synthetic resin etc..Footwear
The common characteristic of bottom material possesses wear-resisting, water-fast, good springiness, be easily suitable for foot type, sizing after be unlikely to deform etc. condition.At present
Synthesis class material for sole of shoe is a most widely used class footwear material.
When walking, the sweat gland on foot can secret out of secretions to people, and these secretions can produce under antibacterial, mycete are decomposed
Raw abnormal flavour, and after strenuous exercise, particularly evident after substantial amounts of perspiration, improve it is thought that often change shoe pad, imitate in a short time
Fruit is it is also possible that the most still can recur, so this way simply cured the symptoms, not the disease.If this problem not solved
If, not only have abnormal flavour, allow people become estranged, also can produce the disease of tinea pedis, the health of harm people.
Basketball movement needs have extraordinary spring, and athletic spring is except relevant with self body constitution, and basket
The elasticity of sneakers is also correlated with.Basketball is more higher for deodorant and aeroelastic requirements due to user basketball.
Summary of the invention
Technical problem: in order to solve the defect of prior art, the invention provides the basketball shoes of a kind of high resilience deodorant
Bottom material.
Technical scheme: the basketball shoe sole material of a kind of high resilience deodorant that the present invention provides, including mass ratio (2-4): 1
Component A and component B；Wherein, described component A is made up of the component of following weight ratio: VA content be 25% EVA20-25 part,
VA content be 40% EVA15-25 part, ethylene propylene diene rubber 10-20 part, thermoplastic elastomer SEBS10-20 part, KH560 1-3
Part, triethylene diamine 1-3 part；Described component B is made up of the component of following weight portion: nano-Ag particles 4-6 part, nano zine oxide
10-20 part, nano titanium oxide 0.5～1.5 parts, carboxylated polybutadiene 0.5～5 parts, coupling agent 1～3 parts, plasticizer 20～
35 parts, reinforcing agent 2～5 parts, stearic acid 3～5 parts.
As improvement, the basketball shoe sole material of described high resilience deodorant includes the component A and component B of mass ratio 3:1；Its
In, described component A is made up of the component of following weight ratio: VA content be 25% EVA22.5 part, VA content be 40%
EVA20 part, ethylene propylene diene rubber 15 parts, thermoplastic elastomer SEBS15 part, KH560 2 parts, triethylene diamine 2 parts；Described component B
It is made up of the component of following weight portion: nano-Ag particles 5 parts, nano zine oxide 15 parts, nano titanium oxide 1.0 parts, carboxylated
Polybutadiene 2.5 parts, coupling agent 2 parts, plasticizer 25 parts, reinforcing agent 3.5 parts, stearic acid 4 parts.
Present invention also offers the preparation method of the basketball shoe sole material of a kind of high resilience deodorant, comprise the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Beneficial effect: the material for sole of shoe preparation technology that the present invention provides is simple, with low cost, good permeability, elastic good, energy
Enough effective deodorant, are applicable to basketball shoes sole.
Detailed description of the invention
Below the basketball shoe sole material of high resilience deodorant of the present invention is further illustrated.
The basketball shoe sole material of high resilience deodorant, including the component A and component B of mass ratio 1:2；Wherein, described component A
It is made up of the component of following weight ratio: EVA20 part that EVA22.5 part that VA content is 25%, VA content are 40%, EPDM
Rubber 15 parts, thermoplastic elastomer SEBS15 part, KH560 2 parts, triethylene diamine 2 parts；Described component B is by the group of following weight portion
Part is made: nano-Ag particles 5 parts, nano zine oxide 15 parts, nano titanium oxide 1.0 parts, carboxylated polybutadiene 2.5 parts, even
Connection agent 2 parts, plasticizer 25 parts, reinforcing agent 3.5 parts, stearic acid 4 parts.
Its preparation method, comprises the following steps:
(1) each component of component A is weighed in proportion, mixes；Each component of component B is weighed in proportion, mixes；
(2) each component in component A is added in autoclave, at 60-70 DEG C, react 2-3h, be cooled to room temperature, obtain pre-polymerization
Body；
(3) by performed polymer and the component B mix homogeneously of 2/3；Add in sole casting machine batch can, be warming up to 60-70 DEG C, constant temperature 5-
10min；It is cooled to 55-60 DEG C, continuously adds the component B of remaining 1/3, constant temperature 10-20min；
(4) by step (3) product on die for shoe-sole coating release agent, dry up, pour into a mould, be incubated 10-12min, the demoulding, to obtain final product.
Claims (2)
1. the basketball shoe sole material of a high resilience deodorant, it is characterised in that: include mass ratio (2-4): the component A of 1 and group
Part B；Wherein, described component A is made up of the component of following weight ratio: VA content be 25% EVA20-25 part, VA content be
EVA15-25 part of 40%, ethylene propylene diene rubber 10-20 part, thermoplastic elastomer SEBS10-20 part, KH560 1-3 part, triethylene
Diamidogen 1-3 part；Described component B is made up of the component of following weight portion: nano-Ag particles 4-6 part, nano zine oxide 10-20 part,
Nano titanium oxide 0.5～1.5 parts, carboxylated polybutadiene 0.5～5 parts, coupling agent 1～3 parts, plasticizer 20～35 parts, mend
Strong agent 2～5 parts, stearic acid 3～5 parts.
The basketball shoe sole material of a kind of high resilience deodorant the most according to claim 1, it is characterised in that: include mass ratio
The component A and component B of 3:1；Wherein, described component A is made up of the component of following weight ratio: VA content is the EVA22.5 of 25%
Part, VA content be 40% EVA20 part, ethylene propylene diene rubber 15 parts, thermoplastic elastomer SEBS15 part, KH560 2 parts, triethylene
Diamidogen 2 parts；Described component B is made up of the component of following weight portion: nano-Ag particles 5 parts, nano zine oxide 15 parts, nano-silica
Change titanium 1.0 parts, carboxylated polybutadiene 2.5 parts, coupling agent 2 parts, plasticizer 25 parts, reinforcing agent 3.5 parts, stearic acid 4 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572010.1A CN105968556A (en) | 2016-07-20 | 2016-07-20 | Deodorant basketball shoe sole material with high rebound resilience |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610572010.1A CN105968556A (en) | 2016-07-20 | 2016-07-20 | Deodorant basketball shoe sole material with high rebound resilience |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105968556A true CN105968556A (en) | 2016-09-28 |
Family
ID=56953192
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610572010.1A Pending CN105968556A (en) | 2016-07-20 | 2016-07-20 | Deodorant basketball shoe sole material with high rebound resilience |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105968556A (en) |
-
2016
- 2016-07-20 CN CN201610572010.1A patent/CN105968556A/en active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160928 |
|
| WD01 | Invention patent application deemed withdrawn after publication |