CN106116160A - A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering - Google Patents
A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering Download PDFInfo
- Publication number
- CN106116160A CN106116160A CN201610455100.2A CN201610455100A CN106116160A CN 106116160 A CN106116160 A CN 106116160A CN 201610455100 A CN201610455100 A CN 201610455100A CN 106116160 A CN106116160 A CN 106116160A
- Authority
- CN
- China
- Prior art keywords
- parts
- glass
- tempering
- oxide
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
- C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/06—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals
- C03C17/09—Surface treatment of glass, not in the form of fibres or filaments, by coating with metals by deposition from the vapour phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/20—Materials for coating a single layer on glass
- C03C2217/25—Metals
- C03C2217/251—Al, Cu, Mg or noble metals
- C03C2217/254—Noble metals
- C03C2217/256—Ag
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/70—Properties of coatings
- C03C2217/73—Anti-reflective coatings with specific characteristics
- C03C2217/732—Anti-reflective coatings with specific characteristics made of a single layer
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/10—Deposition methods
- C03C2218/15—Deposition methods from the vapour phase
- C03C2218/154—Deposition methods from the vapour phase by sputtering
- C03C2218/156—Deposition methods from the vapour phase by sputtering by magnetron sputtering
Abstract
The invention discloses a kind of can the off-line gold list silver LOW E glass of tempering, be made up of following raw material according to parts by weight: borax decahydrate 36 parts, 15 parts of potassium chloride, potassium dichromate 24 parts, zirconium carbonate ammonium 59 parts, quartz sand 36 parts, cobalt powder 25 parts, aluminium sesquioxide 57 parts, Cs2O 13 parts, tungsten oxide 12 points, beryllium oxide 24 points, iron sesquioxide 46 parts, lithium oxide 12 parts, silver 13 parts, zinc oxide 24 parts, silicon nitride 24 parts, NiCrO213 parts, AlSiOx1 3 parts; moved with uniform velocity in the plane constant with the spacing distance of bare glass by multiple magnetic control targets and realize the uniform of plating oxide layer; oxide layer is allowed to form, at the glass surface of plated film, the protection that thick layer is thick; LOW E glass film layers will not be destroyed; before and after tempering, aberration is little, and after tempering, radiance is less.
Description
Technical field
The present invention relates to LOW-E field of glass production technology, be specifically related to a kind of can the off-line gold list silver LOW-E of tempering
Glass and preparation method thereof.
Background technology
Glass is important construction material, and along with improving constantly decorating building requirement, glass is in building trade
In usage amount also constantly increasing.But people are when selecting the glass door and window of building now, except considering that it is aesthstic
Outside with external appearance characteristic, more focus on the problem such as the control of its heat, refrigeration cost, thus allow low-E glass become focus of attention.
Nowadays, the glass surface after this kind of glass production is easy to oxidation, and usually hands contact firmly will allow
The film layer of glass is oxidized, then during producing, how doing can strengthen protecting becomes a problem to be solved.
Summary of the invention
For problem above, the invention provides a kind of can the off-line gold list silver LOW-E glass of tempering and preparation side thereof
Method, is moved with uniform velocity in the plane constant with the spacing distance of bare glass by multiple magnetic control targets and realizes the equal of plating oxide layer
Even, allow oxide layer form, at the glass surface of plated film, the protection that thick layer is thick, LOW-E glass film layers will not be destroyed, tempering
Front and back aberration is little, and after tempering, radiance is less.
To achieve these goals, the technical solution used in the present invention is as follows: a kind of can off-line gold Dan Yin of tempering
LOW-E glass, is made up of following raw material according to parts by weight:
Borax decahydrate 3-6 part, potassium chloride 1-5 part, potassium dichromate 2-4 part, zirconium carbonate ammonium 5-9 part, quartz sand 3-6 part, cobalt powder 2-5
Part, aluminium sesquioxide 5-7 part, Cs2O 1-3 part, tungsten oxide 1-2 divides, beryllium oxide 2-4 divides, iron sesquioxide 4-6 part, lithium oxide
1-2 part, silver 1-3 part, zinc oxide 2-4 part, silicon nitride 2-4 part, NiCrO21-3 part, AlSiOx1-3 part.
Additionally the present invention have also been devised a kind of can the preparation method of off-line gold list silver LOW-E glass of tempering, including such as
Lower step:
(1), after raw material is pressed formula mixing, add a certain amount of Nucleating Agent, put into mix homogeneously in ball mill together, by 5%
Liquid glass pelletize；
(2) granule after being dried loads in graphite crucible, at a temperature of 1400-1600 DEG C, keeps temperature to found 60-
800min, stirs in melting process always；
(3) vitreous humour after being founded by graphite crucible is poured intermediate frequency furnace into and is relayed temperature of continuing rising, continues at a temperature of 2000-2100 DEG C
Continue and found 20-30min；Obtain glass crystalline substance plate；
(4) thermal treatment zone that the LOW-E film face of glass crystalline substance plate is put into annealing furnace down preheats, and preheating temperature is
370 520 DEG C, preheating time is 150 260s；
(5) it is in vacuum environment interval for 0.5-0.6Pa that glass crystalline substance plate is vertically arranged at pressure；
(6) in vacuum environment, it is passed through process gas, and keeps the pressure of vacuum environment within 0.5-0.6Pa interval；
(7) magnetic control target is placed in vacuum environment, and is electrically connected to high-tension negative electrode；
(8) multiple magnetic control targets move with uniform velocity in the plane constant with the spacing distance of bare glass.
According to technique scheme, the glass crystalline substance plate obtained in described step (3) is first cut into the size of regulation as requested；
And carry out edging process.
Beneficial effects of the present invention:
The present invention is moved with uniform velocity in the plane constant with the spacing distance of bare glass by multiple magnetic control targets and realizes plating oxidation
Layer uniform, allows oxide layer form, at the glass surface of plated film, the protection that thick layer is thick, and LOW-E glass film layers will not be broken
Bad, before and after tempering, aberration is little, and after tempering, radiance is less.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to
Limit the present invention.
Embodiment 1:
A kind of can the off-line gold list silver LOW-E glass of tempering, be made up of following raw material according to parts by weight:
Borax decahydrate 3 parts, 1 part of potassium chloride, potassium dichromate 2 parts, zirconium carbonate ammonium 5 parts, quartz sand 3 parts, cobalt powder 2 parts, three oxidations two
5 parts of aluminum, Cs2O 1 part, tungsten oxide 1 point, beryllium oxide 2 points, iron sesquioxide 4 parts, lithium oxide 1 part, silver 1 part, zinc oxide 2 parts,
Silicon nitride 2 parts, NiCrO21 part, AlSiOx1 part.
Additionally the present invention have also been devised a kind of can the preparation method of off-line gold list silver LOW-E glass of tempering, including such as
Lower step:
(1), after raw material is pressed formula mixing, add a certain amount of Nucleating Agent, put into mix homogeneously in ball mill together, by 5%
Liquid glass pelletize；
(2) granule after being dried loads in graphite crucible, at a temperature of 1400 DEG C, keeps temperature to found 60min, molten
Stir during system always；
(3) vitreous humour after being founded by graphite crucible is poured intermediate frequency furnace into and is relayed temperature of continuing rising, continues molten at a temperature of 2000 DEG C
20min processed；Obtain glass crystalline substance plate；
(4) thermal treatment zone that the LOW-E film face of glass crystalline substance plate is put into annealing furnace down preheats, and preheating temperature is 370
DEG C, preheating time is 150s；
(5) it is in vacuum environment interval for 0.5Pa that glass crystalline substance plate is vertically arranged at pressure；
(6) in vacuum environment, it is passed through process gas, and keeps the pressure of vacuum environment within 0.5Pa interval；
(7) magnetic control target is placed in vacuum environment, and is electrically connected to high-tension negative electrode；
(8) multiple magnetic control targets move with uniform velocity in the plane constant with the spacing distance of bare glass.
According to technique scheme, the glass crystalline substance plate obtained in described step (3) is first cut into the size of regulation as requested；
And carry out edging process.
Embodiment 2:
A kind of can the off-line gold list silver LOW-E glass of tempering, be made up of following raw material according to parts by weight:
Borax decahydrate 2 parts, 3 parts of potassium chloride, potassium dichromate 3 parts, zirconium carbonate ammonium 6 parts, quartz sand 4 parts, cobalt powder 4 parts, three oxidations two
6 parts of aluminum, Cs2O 2 parts, tungsten oxide 1.5 points, beryllium oxide 3 points, iron sesquioxide 5 parts, lithium oxide 1.5 parts, silver 2 parts, zinc oxide 3
Part, silicon nitride 3 parts, NiCrO22 parts, AlSiOx2 part.
Additionally the present invention have also been devised a kind of can the preparation method of off-line gold list silver LOW-E glass of tempering, including such as
Lower step:
(1), after raw material is pressed formula mixing, add a certain amount of Nucleating Agent, put into mix homogeneously in ball mill together, by 5%
Liquid glass pelletize；
(2) granule after being dried loads in graphite crucible, at a temperature of 1500 DEG C, keeps temperature to found 70min, molten
Stir during system always；
(3) vitreous humour after being founded by graphite crucible is poured intermediate frequency furnace into and is relayed temperature of continuing rising, continues molten at a temperature of 2050 DEG C
25min processed；Obtain glass crystalline substance plate；
(4) thermal treatment zone that the LOW-E film face of glass crystalline substance plate is put into annealing furnace down preheats, and preheating temperature is 450
DEG C, preheating time is 180s；
(5) it is in vacuum environment interval for 0.5-0.6Pa that glass crystalline substance plate is vertically arranged at pressure；
(6) in vacuum environment, it is passed through process gas, and keeps the pressure of vacuum environment within 0.5-0.6Pa interval；
(7) magnetic control target is placed in vacuum environment, and is electrically connected to high-tension negative electrode；
(8) multiple magnetic control targets move with uniform velocity in the plane constant with the spacing distance of bare glass.
According to technique scheme, the glass crystalline substance plate obtained in described step (3) is first cut into the size of regulation as requested；
And carry out edging process.
Embodiment 3:
A kind of can the off-line gold list silver LOW-E glass of tempering, be made up of following raw material according to parts by weight:
Borax decahydrate 6 parts, 5 parts of potassium chloride, potassium dichromate 4 parts, zirconium carbonate ammonium 9 parts, quartz sand 6 parts, cobalt powder 5 parts, three oxidations two
7 parts of aluminum, Cs2O 3 parts, tungsten oxide 2 points, beryllium oxide 4 points, iron sesquioxide 6 parts, lithium oxide 2 parts, silver 3 parts, zinc oxide 4 parts,
Silicon nitride 4 parts, NiCrO23 parts, AlSiOx3 part.
Additionally the present invention have also been devised a kind of can the preparation method of off-line gold list silver LOW-E glass of tempering, including such as
Lower step:
(1), after raw material is pressed formula mixing, add a certain amount of Nucleating Agent, put into mix homogeneously in ball mill together, by 5%
Liquid glass pelletize；
(2) granule after being dried loads in graphite crucible, at a temperature of 1600 DEG C, keeps temperature to found 80min, molten
Stir during system always；
(3) vitreous humour after being founded by graphite crucible is poured intermediate frequency furnace into and is relayed temperature of continuing rising, continues molten at a temperature of 2100 DEG C
30min processed；Obtain glass crystalline substance plate；
(4) thermal treatment zone that the LOW-E film face of glass crystalline substance plate is put into annealing furnace down preheats, and preheating temperature is 520
DEG C, preheating time is 260s；
(5) it is in vacuum environment interval for 0.6Pa that glass crystalline substance plate is vertically arranged at pressure；
(6) in vacuum environment, it is passed through process gas, and keeps the pressure of vacuum environment within 0.6Pa interval；
(7) magnetic control target is placed in vacuum environment, and is electrically connected to high-tension negative electrode；
(8) multiple magnetic control targets move with uniform velocity in the plane constant with the spacing distance of bare glass.
According to technique scheme, the glass crystalline substance plate obtained in described step (3) is first cut into the size of regulation as requested；
And carry out edging process.
The present invention is to embodiment 1 to embodiment 3 gained finished product detection transmitance and reflectance, and the data obtained are as follows:
| Sample number | Standard substance | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Transmitance/% | 55 | 68 | 69 | 68 |
| Reflectance/% | 35 | 49 | 51 | 50 |
As seen from the above table, transmitance and the reflectance of embodiment 1 to embodiment 3 gained finished product is superior to standard substance.
Based on above-mentioned, it is an advantage of the current invention that the present invention passes through multiple magnetic control target at the spacing distance with bare glass not
Move with uniform velocity in the plane become and realize the uniform of plating oxide layer, allow oxide layer form thick layer thickness at the glass surface of plated film
Protection, LOW-E glass film layers will not be destroyed, and before and after tempering, aberration is little, and after tempering, radiance is less.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (3)
1. one kind can the off-line gold list silver LOW-E glass of tempering, it is characterised in that according to parts by weight by following raw material group
Become: borax decahydrate 3-6 part, potassium chloride 1-5 part, potassium dichromate 2-4 part, zirconium carbonate ammonium 5-9 part, quartz sand 3-6 part, cobalt powder 2-5
Part, aluminium sesquioxide 5-7 part, Cs2O 1-3 part, tungsten oxide 1-2 divides, beryllium oxide 2-4 divides, iron sesquioxide 4-6 part, lithium oxide
1-2 part, silver 1-3 part, zinc oxide 2-4 part, silicon nitride 2-4 part, NiCrO21-3 part, AlSiOx1-3 part.
2. one kind can the preparation method of off-line gold list silver LOW-E glass of tempering, it is characterised in that comprise the steps:
(1), after raw material is pressed formula mixing, add a certain amount of Nucleating Agent, put into mix homogeneously in ball mill together, by 5%
Liquid glass pelletize；
(2) granule after being dried loads in graphite crucible, at a temperature of 1400-1600 DEG C, keeps temperature to found 60-
800min, stirs in melting process always；
(3) vitreous humour after being founded by graphite crucible is poured intermediate frequency furnace into and is relayed temperature of continuing rising, continues at a temperature of 2000-2100 DEG C
Continue and found 20-30min；Obtain glass crystalline substance plate；
(4) thermal treatment zone that the LOW-E film face of glass crystalline substance plate is put into annealing furnace down preheats, and preheating temperature is
370 520 DEG C, preheating time is 150 260s；
(5) it is in vacuum environment interval for 0.5-0.6Pa that glass crystalline substance plate is vertically arranged at pressure；
(6) in vacuum environment, it is passed through process gas, and keeps the pressure of vacuum environment within 0.5-0.6Pa interval；
(7) magnetic control target is placed in vacuum environment, and is electrically connected to high-tension negative electrode；
(8) multiple magnetic control targets move with uniform velocity in the plane constant with the spacing distance of bare glass.
The most according to claim 2 a kind of can the preparation method of off-line gold list silver LOW-E glass of tempering, its feature exists
In, the glass crystalline substance plate obtained in described step (3) is first cut into the size of regulation as requested；And carry out edging process.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610455100.2A CN106116160A (en) | 2016-06-20 | 2016-06-20 | A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610455100.2A CN106116160A (en) | 2016-06-20 | 2016-06-20 | A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106116160A true CN106116160A (en) | 2016-11-16 |
Family
ID=57268440
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610455100.2A Pending CN106116160A (en) | 2016-06-20 | 2016-06-20 | A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106116160A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107555806A (en) * | 2017-09-12 | 2018-01-09 | 成都新柯力化工科技有限公司 | A kind of heat-insulated Low E glass of individual layer durability building heat preservation and preparation method |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1201616A2 (en) * | 2000-10-30 | 2002-05-02 | Atofina Chemicals, Inc. | Solar control coated glass |
| CN1887760A (en) * | 2006-07-20 | 2007-01-03 | 杭州钱塘江特种玻璃技术有限公司 | Self-cleaning household appliance glass capable of shielding electromagnetic radiation and its prepn |
| CN103396010A (en) * | 2013-08-15 | 2013-11-20 | 蚌埠玻璃工业设计研究院 | Preparation method of light self-trapping AZO (aluminium-doped zinc oxide) film glass |
| CN104402224A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Toughened glass formula |
| CN105084774A (en) * | 2015-07-31 | 2015-11-25 | 芜湖真空科技有限公司 | Offline production method of low-E glass |
-
2016
- 2016-06-20 CN CN201610455100.2A patent/CN106116160A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1201616A2 (en) * | 2000-10-30 | 2002-05-02 | Atofina Chemicals, Inc. | Solar control coated glass |
| CN1887760A (en) * | 2006-07-20 | 2007-01-03 | 杭州钱塘江特种玻璃技术有限公司 | Self-cleaning household appliance glass capable of shielding electromagnetic radiation and its prepn |
| CN103396010A (en) * | 2013-08-15 | 2013-11-20 | 蚌埠玻璃工业设计研究院 | Preparation method of light self-trapping AZO (aluminium-doped zinc oxide) film glass |
| CN104402224A (en) * | 2014-10-26 | 2015-03-11 | 青岛智谷创新技术有限公司 | Toughened glass formula |
| CN105084774A (en) * | 2015-07-31 | 2015-11-25 | 芜湖真空科技有限公司 | Offline production method of low-E glass |
Non-Patent Citations (1)
| Title |
|---|
| 周琦等: "镍渣微晶玻璃制备及铁的回收利用", 《兰州理工大学学报》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107555806A (en) * | 2017-09-12 | 2018-01-09 | 成都新柯力化工科技有限公司 | A kind of heat-insulated Low E glass of individual layer durability building heat preservation and preparation method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102607934A (en) | X-ray fluorescence spectroscopy analysis fusion sample preparation method of aluminum, manganese, calcium and iron alloy | |
| CN106746726A (en) | It is a kind of offline can the transmitance low radiation coated glass of tempering 50 and preparation method thereof | |
| CN106430989B (en) | A kind of low melting point glass powder, preparation method and application and the method for preparing compound glass column using low melting point glass powder | |
| CN106746545A (en) | A kind of manufacturing process of safety glass | |
| CN103739189B (en) | A kind of preparation method of chemically toughened glass | |
| Gonella et al. | Diffusion behavior of transition metals in field-assisted ion-exchanged glasses | |
| CN104556649A (en) | Fused salt formula for chemical tempering of low-alkaline and low-aluminum glass and tempering technology of fused salt formula | |
| CN106116160A (en) | A kind of can the off-line gold list silver LOW E glass and preparation method thereof of tempering | |
| CN101862922A (en) | Binary alloy sealing solder wire | |
| CN106567048B (en) | A kind of manufacturing method of large size High-Purity Molybdenum alloy rotary target material | |
| CN104496185A (en) | Nano microcrystalline dielectric glass and preparation method thereof | |
| CN103866244B (en) | Niobium tubular target material and producing method thereof | |
| Fredericci et al. | Effect of TiO2 addition on the chemical durability of Bi2O3–SiO2–ZnO–B2O3 glass system | |
| CN110344011B (en) | Tin oxide-doped silver target material and preparation method and application thereof | |
| CN102503158B (en) | Inorganic nanometer transparent heat insulation coated glass online manufacturing device and production technology thereof | |
| CN114293158B (en) | Preparation method of tungsten-silicon alloy target | |
| CN109881172A (en) | A kind of metal composite oxide target material and its processing method | |
| CN102409147A (en) | Heat treatment method for target material | |
| CN105483626B (en) | A kind of production method of fine grain planar molybdenum target material | |
| CN107601900A (en) | A kind of photosensitive glass-ceramics shell and preparation method thereof | |
| CN103757592B (en) | Niobium target preparation method | |
| CN106808136A (en) | A kind of novel metal combination process | |
| CN111727175B (en) | Lead-free low-temperature sintered glass frit, slurry, and vacuum glass assembly using same | |
| CN114262874B (en) | Target material for building glass and preparation method thereof | |
| CN105088140A (en) | Copper aluminum alloy crystal oscillator chip coating process |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161116 |