CN106106571A - A kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture - Google Patents
A kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture Download PDFInfo
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- CN106106571A CN106106571A CN201610462035.6A CN201610462035A CN106106571A CN 106106571 A CN106106571 A CN 106106571A CN 201610462035 A CN201610462035 A CN 201610462035A CN 106106571 A CN106106571 A CN 106106571A
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N65/00—Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
- A01N65/40—Liliopsida [monocotyledons]
- A01N65/42—Aloeaceae [Aloe family] or Liliaceae [Lily family], e.g. aloe, veratrum, onion, garlic or chives
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- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Wood Science & Technology (AREA)
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- Agronomy & Crop Science (AREA)
- Biotechnology (AREA)
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- Mycology (AREA)
- Natural Medicines & Medicinal Plants (AREA)
- Pest Control & Pesticides (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture, belong to antibacterial preparing technical field.With Gourmet Powder Factory's waste liquid, for raw material, through deproteinization pretreatment, also and metal ion-chelant reaction obtains amino-acid metal chelate to the present invention, after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli mixing homogenizing is processed, steam reflux, extract, vegetable oil, can be prepared by composite aqueous emulsion disinfectant use in agriculture by titrimetry.Example proves, the present invention is with Gourmet Powder Factory's waste liquid as raw material, generate stable amino-acid metal chelate, the pathogenic fungi in plant or the liquid protein in antibacterial is made to produce deposition modification by metal ion, enzyme is made to lose activity, reach the purpose that sterilizes, itself and vegetable oil are compounded, solve conventional disinfectant use in agriculture and mostly be chloride, organic iodine mixture or the chemical bactericide of phenols, also exist that acid-base value is high, corrosivity strong and bacterial resistance sex chromosome mosaicism, and plant material turn avoid conventional sterilants and easily remains environmentally hazardous deficiency.
Description
Technical field
The invention discloses a kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture, belong to sterilization
Agent preparing technical field.
Background technology
The aminoacid not waited containing 16 kinds of content based on glutamic acid in monosodium glutamate waste liquid, and wherein remaining NH4+、K+、
Mg2+、Ca2+、Fe2+Plasma, is again the macro-and trace-element required for plant growing.Aminoacid contains amino and carboxyl.
Nitrogen therein, oxygen atom are provided that lone pair electrons respectively, are a kind of well trilons.It with add in monosodium glutamate waste liquid
The metal ion of other positive bivalence such as copper ion, under certain process conditions, carries out chelatropic reaction, generates stable aminoacid
Metallo-chelate, soluble copper salt is the antibacterial of a kind of plant disease.But after being dissolved in water, formed free state metallic copper from
Son, hardly enters inside plant organ, is only attracted to the epidermis of plant, forms the antibacterial of a protectiveness.But above-mentioned amino
Acid metallo-chelate and metal complex, can make the high nutrient required for plant growing, together with copper ion by plant
Absorb inside plant.Due to the continuous absorption of copper ion, cause accumulation, make to exist in which the disease causing the various disease of plant
Liquid protein in fungal pathogens or antibacterial produces deposition modification, makes enzyme lose activity, so that pathogenic fungi or bacterial death,
I.e. play the effect preventing and treating various plant diseases.Meanwhile, aminoacid and derivant thereof also have the antibacterial activity that degree is different, example
As glycine can suppress the growth and breeding of bacillus subtilis etc., antimicrbial power is stronger；Methionine can prevent and treat rice root pestilence and Semen Maydis, Fructus Cucumidis sativi
On multiple pathogenic bacteria etc..
Oleum Caryophylli is yellowish or colourless clear oil thing, has the special aroma of Flos Caryophylli, water insoluble, be soluble in alcohol,
In ether or glacial acetic acid, its main Fungicidal substance is eugenol.Oleum Bulbus Allii is the particular matter in Bulbus Allii, weak yellow liquid, tool
There is strong garlic smell, water insoluble, it is partially soluble in ethanol, play bactericidal action is garlicin therein.Oleum Cinnamomi is yellow
Color or the supernatant liquid of yellowish-brown, have the special fragrance of Cortex Cinnamomi, and readily soluble in ethanol or glacial acetic acid, cinnamic aldehyde therein plays sterilization
Effect.Owing to volatile oil has preferable biological activity, frequently as the effective ingredient of medicine, but owing to its character is unstable,
Volatile, it is insoluble in water, when preparing liquid preparation, various surfactants need to be added and carry out solubilising formation microemulsion, make system
Agent stability improves.
Currently used antibacterial be typically all chemical bactericide such as hydrogen peroxide, peracetic acid, chlorine-containing agent, formaldehyde,
, all there is penetrating odor in glutaraldehydes etc., corrosivity is strong, has the shortcoming irritated to respiratory tract, also has certain pollution to environment.
Herbaceous plant wide material sources, toxic and side effects is low, environmental protection.Therefore, highly desirable can the developing from natural herb of people is killed
Bacterium effect is strong, have no adverse reaction, herbaceous plant antibacterial easy to use.
Summary of the invention
The technical problem that present invention mainly solves: mostly be chloride, organic for disinfectant use in agriculture the most conventional
Iodine mixture or the chemical bactericide of phenols, also exist that acid-base value is high, corrosivity strong and the problem such as bacterial drug resistance, make for a long time
By corrosion both hands and irritant abnormal smells from the patient, the environmentally hazardous defect of antibacterial of residual, it is provided that one utilizes Gourmet Powder Factory's waste liquid
The method of disinfectant use in agriculture prepared by compound botanical oil.The method with Gourmet Powder Factory's waste liquid for raw material through deproteinization pretreatment and and metal
Ion chelating reaction obtains amino-acid metal chelate, and after being processed by Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli mixing homogenizing, steam backflow carries
Take vegetable oil, can be prepared by composite aqueous emulsion disinfectant use in agriculture by titrimetry.The present invention is easy and simple to handle, twice laid, with taste
Essence factory waste liquid is raw material, generates stable amino-acid metal chelate, makes the pathogenic fungi in plant or thin by metal ion
Liquid protein in bacterium produces deposition modification, makes enzyme lose activity, and reaches the purpose that sterilizes, by it with have planting of bactericidal action
Thing oil compounds, and had both solved conventional disinfectant use in agriculture and mostly has been chloride, organic iodine mixture or the chemical bactericide of phenols, and had existed
That acid-base value is high, corrosivity strong and the problem such as bacterial drug resistance, and material of vegetable origin to turn avoid conventional sterilants the most residual
Stay thus environmentally hazardous deficiency.
In order to solve above-mentioned technical problem, the technical solution adopted in the present invention is:
(1) collect the glutamic acid monosodium glutamate waste liquid of 3～5L Gourmet Powder Factories discharge, be loaded in glass, heated and boiled 20～30min
After put in 4～6 DEG C of ice-water baths, after staticly settling 5～6h filter remove precipitation, obtain filtrate, then it is dense that filtrate is moved into vacuum
In contracting tank, reduction pressure inside the tank is to 1.3～1.4kPa, and concentrating under reduced pressure, until becoming the 1/5 of original volume, obtains pretreatment and concentrates
Liquid；
(2) it is that 1:10 adds manganese sulphate powder in above-mentioned pretreatment concentrated solution by solid-to-liquid ratio, turns after stirring by stirring rod
Enter in the there-necked flask with agitator, and flask is moved in 90～100 DEG C of oil bath pans, start agitator insulated and stirred and carry out
Chelatropic reaction 45～60min, chelatropic reaction adds appropriate barium hydroxide powder until precipitating in mixed liquor and not being further added by after completing
Till, separate with centrifuge and remove precipitation, obtain supernatant, standby；
(3) by weight putting in sonic oscillation instrument after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli being mixed for 8:5:1, three's cumulative volume 2 is added
～3 times of deionized waters, to be filtrated to get filtering residue after 200～300W power ultrasonic vibration washings 20～30min；
(4) filtering residue obtained above is put in high pressure homogenizer, add filtering residue volume 3～4 times of distilled water, in 3～5MPa pressures
Under power, homogenizing process 30～40min obtains uniform homogeneous blend, then is proceeded to by uniform homogeneous blend in the distilling apparatus with return duct,
It is heated to 80～90 DEG C, isolated mixed vegetable oil after reflux, extract, 1～2h；
(5) above-mentioned vegetable oil is proceeded in conical flask, add its quality 3～the polyethenoxy sorbitan monoglyceride of 5% and
1～the glycerol of 3%, it is placed on magnetic stirrer and obtains oil phase with 300～400r/min rotating speeds stirrings 15～20min；
(6) under the water bath condition of 40～60 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill stirring
Under oil phase in, control rate of addition make its in 20～30min dropping complete, hold with 200～300r/min rotating speeds with blender
Continuous stirring, till mixed liquor is become clarification by muddiness, i.e. obtains disinfectant use in agriculture after tinning.
The application process of the present invention is: adds clear water in the disinfectant use in agriculture present invention prepared and dilutes 5～10 times, loads
In agricultural watering can, spray Tanaka with the dose uniformity of every mu 8～10L, wherein sprayed once every 5～7 days, altogether spray 2～4
It is secondary,.After using, not only antibiotic rate is relatively strong, plays the effect preventing and treating various plant diseases, and can enter in plant organ
Portion, it is provided that the high nutrient required for plant growing.
The invention has the beneficial effects as follows:
(1) present invention is easy and simple to handle, with Gourmet Powder Factory's waste liquid as raw material, generates stable amino-acid metal chelate, passes through metal
Ion makes the pathogenic fungi in plant or the liquid protein in antibacterial produce deposition modification, makes enzyme lose activity, reaches sterilization
Purpose；
(2) amino-acid metal chelate and vegetable oil are compounded by the present invention, solve conventional disinfectant use in agriculture and mostly are chloride, have
Machine iodine mixture or the chemical bactericide of phenols, also exist that acid-base value is high, corrosivity strong and bacterial resistance sex chromosome mosaicism；
(3) the disinfectant use in agriculture raw material that the present invention prepares is natural, and safety and sanitation use rear noresidue, for environment without any danger
Evil produces.
Detailed description of the invention
First collect 3～5L Gourmet Powder Factories discharge glutamic acid monosodium glutamate waste liquid, be loaded in glass, heated and boiled 20～
Put in 4～6 DEG C of ice-water baths after 30min, filter after staticly settling 5～6h and remove precipitation, obtain filtrate, then filtrate is moved into true
In empty concentration tank, reduction pressure inside the tank is to 1.3～1.4kPa, and concentrating under reduced pressure, until becoming the 1/5 of original volume, obtains pretreatment dense
Contracting liquid；Then it is that 1:10 adds manganese sulphate powder, after stirring by stirring rod in above-mentioned pretreatment concentrated solution by solid-to-liquid ratio
Proceed in the there-necked flask with agitator, and flask is moved in 90～100 DEG C of oil bath pans, start agitator insulated and stirred and enter
Row chelatropic reaction 45～60min, chelatropic reaction adds appropriate barium hydroxide powder until precipitating in mixed liquor and no longer increasing after completing
Till adding, separate with centrifuge and remove precipitation, obtain supernatant, standby；Subsequently by weight for 8:5:1 by Bulbus Allii, Cortex Cinnamomi and fourth
Put in sonic oscillation instrument after fragrant mixing, add three's cumulative volume 2～3 times of deionized waters, with 200～300W power ultrasonic vibrations
It is filtrated to get filtering residue after washing 20～30min；Afterwards filtering residue obtained above is put in high pressure homogenizer, add filtering residue volume
3～4 times of distilled water, under 3～5MPa pressure, homogenizing process 30～40min obtains uniform homogeneous blend, then is turned by uniform homogeneous blend
Enter in the distilling apparatus with return duct, be heated to 80～90 DEG C, isolated mixed plant after reflux, extract, 1～2h
Oil；Next above-mentioned vegetable oil is proceeded in conical flask, add its quality 3～polyethenoxy sorbitan monoglyceride of 5%
With 1～the glycerol of 3%, it is placed on magnetic stirrer and obtains oil phase with 300～400r/min rotating speeds stirrings 15～20min；Finally
Under the water bath condition of 40～60 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill the oil under stirring
Xiang Zhong, controls rate of addition and makes its 20～30min interior dropping complete, continuously stirred with 200～300r/min rotating speeds with blender
Till mixed liquor is become clarification by muddiness, after tinning, i.e. obtain disinfectant use in agriculture.
Example 1
First collect the glutamic acid monosodium glutamate waste liquid of 3L Gourmet Powder Factory discharge, be loaded in glass, put into after heated and boiled 20min
In 4 DEG C of ice-water baths, filter after staticly settling 5h and remove precipitation, obtain filtrate, then filtrate is moved in vacuum concentration pot, reduce tank
Interior pressure until becoming the 1/5 of original volume, obtains pretreatment concentrated solution to 1.3kPa, concentrating under reduced pressure；Then it is 1 by solid-to-liquid ratio:
10 add manganese sulphate powder in above-mentioned pretreatment concentrated solution, proceed to three mouthfuls of burnings with agitator by stirring rod after stirring
In Ping, and being moved into by flask in 90 DEG C of oil bath pans, start agitator insulated and stirred and carry out chelatropic reaction 45min, chelatropic reaction is complete
Add after one-tenth appropriate barium hydroxide powder precipitate in mixed liquor no longer increase till, with centrifuge separate remove precipitation,
Supernatant, standby；Subsequently by weight putting in sonic oscillation instrument after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli being mixed for 8:5:1, add three
2 times of deionized waters of person's cumulative volume, to be filtrated to get filtering residue after 200W power ultrasonic vibration washing 20min；Obtain above-mentioned afterwards
Filtering residue put in high pressure homogenizer, add 3 times of distilled water of filtering residue volume, under 3MPa pressure homogenizing process 30min obtain all
Matter mixture, then uniform homogeneous blend is proceeded in the distilling apparatus with return duct, it is heated to 80 DEG C, after reflux, extract, 1h
Isolated mixed vegetable oil；Next above-mentioned vegetable oil is proceeded in conical flask, add the polyoxyethylene of its quality 3%
Sorbitol monoglyceride and the glycerol of 1%, be placed on magnetic stirrer and obtain oil phase with 300r/min rotating speed stirring 15min；?
After under the water bath condition of 40 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill the oil phase under stirring
In, control rate of addition and make dropping in its 20min complete, with blender with 200r/min rotating speed be stirred continuously until mixed liquor by
Till muddy change clarification, after tinning, i.e. obtain disinfectant use in agriculture.
This example operation is simple, adds clear water and dilutes 5 times, load agricultural in the disinfectant use in agriculture present invention prepared
In watering can, spray Tanaka with the dose uniformity of every mu of 8L, wherein sprayed once every 5 days, altogether spray 2 times,.Use
After, not only antibiotic rate is relatively strong, plays the effect preventing and treating various plant diseases, and can enter inside plant organ, it is provided that plant
High nutrient required for growth.
Example 2
First collect the glutamic acid monosodium glutamate waste liquid of 4L Gourmet Powder Factory discharge, be loaded in glass, put into after heated and boiled 25min
In 5 DEG C of ice-water baths, filter after staticly settling 5.5h and remove precipitation, obtain filtrate, then filtrate is moved in vacuum concentration pot, reduce
Pressure inside the tank until becoming the 1/5 of original volume, obtains pretreatment concentrated solution to 1.35kPa, concentrating under reduced pressure；Then by solid-to-liquid ratio it is
1:10 adds manganese sulphate powder in above-mentioned pretreatment concentrated solution, proceeds to three mouthfuls with agitator by stirring rod after stirring
In flask, and flask is moved in 95 DEG C of oil bath pans, start agitator insulated and stirred and carry out chelatropic reaction 55min, chelatropic reaction
Add after completing appropriate barium hydroxide powder precipitate in mixed liquor no longer increase till, with centrifuge separate remove precipitation,
Obtain supernatant, standby；Subsequently by weight putting in sonic oscillation instrument after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli being mixed for 8:5:1, add
2.5 times of deionized waters of three's cumulative volume, to be filtrated to get filtering residue after 250W power ultrasonic vibration washing 25min；Afterwards by above-mentioned
The filtering residue obtained is put in high pressure homogenizer, adds 3.5 times of distilled water of filtering residue volume, and under 4MPa pressure, homogenizing processes 35min
Obtaining uniform homogeneous blend, then proceeded to by uniform homogeneous blend in the distilling apparatus with return duct, be heated to 85 DEG C, backflow carries
Take isolated mixed vegetable oil after 1.5h；Next above-mentioned vegetable oil is proceeded in conical flask, add the polyoxy of its quality 4%
Ethylene anhydro sorbitol monoglyceride and the glycerol of 2%, be placed on magnetic stirrer and obtain with 350r/min rotating speed stirring 18min
To oil phase；Last under the water bath condition of 50 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill stirring
Under oil phase in, control rate of addition and make dropping in its 25min complete, be stirred continuously until with 250r/min rotating speed with blender
Till mixed liquor is become clarification by muddiness, after tinning, i.e. obtain disinfectant use in agriculture.
This example operation is simple, adds clear water and dilutes 8 times, load agricultural in the disinfectant use in agriculture present invention prepared
In watering can, spray Tanaka with the dose uniformity of every mu of 9L, wherein sprayed once every 6 days, altogether spray 3 times,.Use
After, not only antibiotic rate is relatively strong, plays the effect preventing and treating various plant diseases, and can enter inside plant organ, it is provided that plant
High nutrient required for growth.
Example 3
First collect the glutamic acid monosodium glutamate waste liquid of 5L Gourmet Powder Factory discharge, be loaded in glass, put into after heated and boiled 30min
In 6 DEG C of ice-water baths, filter after staticly settling 6h and remove precipitation, obtain filtrate, then filtrate is moved in vacuum concentration pot, reduce tank
Interior pressure until becoming the 1/5 of original volume, obtains pretreatment concentrated solution to 1.4kPa, concentrating under reduced pressure；Then it is 1 by solid-to-liquid ratio:
10 add manganese sulphate powder in above-mentioned pretreatment concentrated solution, proceed to three mouthfuls of burnings with agitator by stirring rod after stirring
In Ping, and being moved into by flask in 100 DEG C of oil bath pans, start agitator insulated and stirred and carry out chelatropic reaction 60min, chelatropic reaction is complete
Add after one-tenth appropriate barium hydroxide powder precipitate in mixed liquor no longer increase till, with centrifuge separate remove precipitation,
Supernatant, standby；Subsequently by weight putting in sonic oscillation instrument after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli being mixed for 8:5:1, add three
3 times of deionized waters of person's cumulative volume, to be filtrated to get filtering residue after 300W power ultrasonic vibration washing 30min；Obtain above-mentioned afterwards
Filtering residue put in high pressure homogenizer, add 4 times of distilled water of filtering residue volume, under 5MPa pressure homogenizing process 40min obtain all
Matter mixture, then uniform homogeneous blend is proceeded in the distilling apparatus with return duct, it is heated to 90 DEG C, after reflux, extract, 2h
Isolated mixed vegetable oil；Next above-mentioned vegetable oil is proceeded in conical flask, add the polyoxyethylene of its quality 5%
Sorbitol monoglyceride and the glycerol of 3%, be placed on magnetic stirrer and obtain oil phase with 400r/min rotating speed stirring 20min；?
After under the water bath condition of 60 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill the oil phase under stirring
In, control rate of addition and make dropping in its 30min complete, with blender with 300r/min rotating speed be stirred continuously until mixed liquor by
Till muddy change clarification, after tinning, i.e. obtain disinfectant use in agriculture.
This example operation is simple, adds clear water and dilutes 10 times, load agriculture in the disinfectant use in agriculture present invention prepared
With in watering can, spray Tanaka with the dose uniformity of every mu of 10L, wherein sprayed once every 7 days, altogether spray 4 times,.Make
With rear, not only antibiotic rate is relatively strong, plays the effect preventing and treating various plant diseases, and can enter inside plant organ, it is provided that plants
High nutrient required for thing growth.
Claims (1)
1. one kind utilizes the method that disinfectant use in agriculture prepared by Gourmet Powder Factory's waste liquid compound botanical oil, it is characterised in that concrete preparation process
For:
(1) collect the glutamic acid monosodium glutamate waste liquid of 3～5L Gourmet Powder Factories discharge, be loaded in glass, heated and boiled 20～30min
After put in 4～6 DEG C of ice-water baths, after staticly settling 5～6h filter remove precipitation, obtain filtrate, then it is dense that filtrate is moved into vacuum
In contracting tank, reduction pressure inside the tank is to 1.3～1.4kPa, and concentrating under reduced pressure, until becoming the 1/5 of original volume, obtains pretreatment and concentrates
Liquid；
(2) it is that 1:10 adds manganese sulphate powder in above-mentioned pretreatment concentrated solution by solid-to-liquid ratio, turns after stirring by stirring rod
Enter in the there-necked flask with agitator, and flask is moved in 90～100 DEG C of oil bath pans, start agitator insulated and stirred and carry out
Chelatropic reaction 45～60min, chelatropic reaction adds appropriate barium hydroxide powder until precipitating in mixed liquor and not being further added by after completing
Till, separate with centrifuge and remove precipitation, obtain supernatant, standby；
(3) by weight putting in sonic oscillation instrument after Bulbus Allii, Cortex Cinnamomi and Flos Caryophylli being mixed for 8:5:1, three's cumulative volume 2 is added
～3 times of deionized waters, to be filtrated to get filtering residue after 200～300W power ultrasonic vibration washings 20～30min；
(4) filtering residue obtained above is put in high pressure homogenizer, add filtering residue volume 3～4 times of distilled water, in 3～5MPa pressures
Under power, homogenizing process 30～40min obtains uniform homogeneous blend, then is proceeded to by uniform homogeneous blend in the distilling apparatus with return duct,
It is heated to 80～90 DEG C, isolated mixed vegetable oil after reflux, extract, 1～2h；
(5) above-mentioned vegetable oil is proceeded in conical flask, add its quality 3～the polyethenoxy sorbitan monoglyceride of 5% and
1～the glycerol of 3%, it is placed on magnetic stirrer and obtains oil phase with 300～400r/min rotating speeds stirrings 15～20min；
(6) under the water bath condition of 40～60 DEG C, measure the isopyknic standby supernatant of above-mentioned oil phase, dropwise instill stirring
Under oil phase in, control rate of addition make its in 20～30min dropping complete, hold with 200～300r/min rotating speeds with blender
Continuous stirring, till mixed liquor is become clarification by muddiness, i.e. obtains disinfectant use in agriculture after tinning.
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| CN201610462035.6A CN106106571A (en) | 2016-06-23 | 2016-06-23 | A kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture |
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| CN201610462035.6A CN106106571A (en) | 2016-06-23 | 2016-06-23 | A kind of method utilizing Gourmet Powder Factory's waste liquid compound botanical oil to prepare disinfectant use in agriculture |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054405A (en) * | 1991-04-16 | 1991-09-11 | 武汉化工学院 | A kind of method for treating waste liquid from gourmet powder plant and products thereof |
| CN101574093A (en) * | 2009-06-22 | 2009-11-11 | 吉林农业大学 | New preparation technology and new applications of syringa amurensis rupr bar volatile oil |
| CN101869122A (en) * | 2010-06-01 | 2010-10-27 | 刘志慧 | Garlicin plant growth promoting solution with insect disinfestation and sterilization functions |
| CN103783093A (en) * | 2014-03-13 | 2014-05-14 | 四川龙蟒福生科技有限责任公司 | Composition having functions of sterilization and nematode prevention and control |
-
2016
- 2016-06-23 CN CN201610462035.6A patent/CN106106571A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054405A (en) * | 1991-04-16 | 1991-09-11 | 武汉化工学院 | A kind of method for treating waste liquid from gourmet powder plant and products thereof |
| CN101574093A (en) * | 2009-06-22 | 2009-11-11 | 吉林农业大学 | New preparation technology and new applications of syringa amurensis rupr bar volatile oil |
| CN101869122A (en) * | 2010-06-01 | 2010-10-27 | 刘志慧 | Garlicin plant growth promoting solution with insect disinfestation and sterilization functions |
| CN103783093A (en) * | 2014-03-13 | 2014-05-14 | 四川龙蟒福生科技有限责任公司 | Composition having functions of sterilization and nematode prevention and control |
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Application publication date: 20161116 |
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