CN106099119A - A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof - Google Patents
A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof Download PDFInfo
- Publication number
- CN106099119A CN106099119A CN201610548236.8A CN201610548236A CN106099119A CN 106099119 A CN106099119 A CN 106099119A CN 201610548236 A CN201610548236 A CN 201610548236A CN 106099119 A CN106099119 A CN 106099119A
- Authority
- CN
- China
- Prior art keywords
- parts
- acid
- lead
- plate
- ceruse
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/70—Carriers or collectors characterised by shape or form
- H01M4/72—Grids
- H01M4/73—Grids for lead-acid accumulators, e.g. frame plates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/82—Multi-step processes for manufacturing carriers for lead-acid accumulators
- H01M4/84—Multi-step processes for manufacturing carriers for lead-acid accumulators involving casting
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a kind of long-life pole plate for lead-acid storage battery and manufacture method thereof, belong to battery technology field.Its positive plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), graphite 0.25～0.4 part, plumbic acid barium 0.4～0.8 part, stannous sulfate 0.06～0.1 part, antimony oxide 0.08～0.15 part, dilute sulfuric acid 8～10 parts, fiber 0.08～0.12 part and pure water 9～11 parts；Negative plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6～0.9 part, graphite 0.2～0.5 part, acetylene black 0.2～0.4 part, humic acid 0.2～0.4 part, bismuth oxide 0.03～0.06 part, fiber 0.08～0.12 part, lignosulphonic acid sodium sulphosuccinate 0.18～0.2 part, dilute sulfuric acid 7～9 parts and pure water 9～11 parts.The present invention has the advantages such as low temperature capacity is good, large current discharging capability is strong.
Description
Technical field
The present invention relates to a kind of long-life pole plate for lead-acid storage battery and manufacture method thereof, belong to battery technology field.
Background technology
Technology for manufacturing lead is as it is shown in figure 1, its master operation is: pulverizing, cast panel and cream, coated plate, solidification
Be dried, be melted into, clean, be dried, burst.In the Pb-Sb-Cd alloy that wherein cast panel operation uses the most always containing 1.7%～
1.8% harmful hypertoxic element cadmium, according to the requirement in national environmental protection portion, within 2013, December contains cadmium element after 31 days
Lead-acid accumulator more than 0.002% (mass percent) does not meets national requirements for environmental protection, forbids producing, therefore in December, 2013
Later each electric boosted automobile-used lead-acid storage battery production producer the most all uses the Pb-Ca-Sn-Al alloy without cadmium instead.Lead calcium stannum aluminum closes
Production process easily operates, little to human injury, and the accumulator percentage of water loss produced is little, is suitable for analysing valve control type lead-acid accumulator battery and produces
Using, but compare with Pb-Sb-Cd alloy, battery cycle life is decreased obviously, and charge acceptance and low temperature discharge ability are the most too late
The lead antimony cadmium originally used closes battery, and the appearance of these shortcomings makes accumulator for electric cycle return of goods amount dramatically increase, user
Satisfaction substantially reduces, and in the face of this situation, researches and develops a kind of active material formula being suitable for Pb-Ca-Sn-Al alloy imperative.
Summary of the invention
An object of the present invention, is to provide a kind of long-life pole plate for lead-acid storage battery.The lead acid accumulator pole of the present invention
Plate, compared with prior art, has that low temperature capacity is good, large current discharging capability is strong, charge acceptance good, active material utilization rate
Advantage high, that have extended cycle life.
The technical scheme is that a kind of long-life pole plate for lead-acid storage battery, including just
Pole plate and negative plate, positive plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), graphite 0.25～0.4 part, plumbic acid barium
0.4～0.8 part, stannous sulfate 0.06～0.1 part, antimony oxide 0.08～0.15 part, dilute sulfuric acid 8～10 parts, fiber 0.08
～0.12 part and pure water 9～11 parts；Negative plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6～0.9
Part, graphite 0.2～0.5 part, acetylene black 0.2～0.4 part, humic acid 0.2～0.4 part, bismuth oxide 0.03～0.06 part, fiber
0.08～0.12 part, lignosulphonic acid sodium sulphosuccinate 0.18～0.2 part, dilute sulfuric acid 7～9 parts and pure water 9～11 parts.
The polar plate of lead acid storage battery of the present invention, adds plumbic acid barium, antimony oxide and stannous sulfate in positive plate, these are three years old
The effectively fall that adds planting raw material improves the electric conductivity of pole plate, eliminates the non-antimony effect of pole plate, not only substantially increases pole
The formation efficiency of plate also solves lead calcium stannum pole plate in early days capacitance loss (PCL) phenomenon, make pole plate chemical conversion electricity consumption reduce 9～
11%, battery cycle life is brought up to 450～500 times by about 300 times.Adding graphite and bismuth oxide in negative plate, these are two years old
The addition planting raw material is effectively increased negative plate charge acceptance, large current discharging capability and low temperature discharge ability, improves
Negative plate active material utilization rate, also plays certain effect to improving battery cycle life.
On the basis of technique scheme, the present invention can also do following improvement.
Positive plate described further is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.3 part of graphite, plumbic acid barium
0.6 part, stannous sulfate 0.08 part, antimony oxide 0.12 part, dilute sulfuric acid 9 parts, fiber 0.10 part and pure water 10 parts；Described negative pole
Plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.8 part of barium sulfate, 0.3 part of graphite, acetylene black 0.3 part, humic acid
0.3 part, bismuth oxide 0.04 part, fiber 0.10 part, lignosulphonic acid sodium sulphosuccinate 0.19 part, dilute sulfuric acid 8 parts and pure water 10 parts.
Use and above-mentioned further provide the benefit that: battery cycle life can reach more than 450 times, charge acceptance
And heavy-current discharge performance reaches optimum condition, each performance indications all meet GB/T22199-2008 standard-required.
Further, the oxidizability of described positive plate Hydrocerussitum (Ceruse) is 73～78%, the oxidizability of described negative plate Hydrocerussitum (Ceruse) be 70～
75%.
Use and above-mentioned further provide the benefit that: pole plate production process is easily operated, and procedure quality is easily controllable, pole plate
Performance reaches optimum state.
Further, the density of described dilute sulfuric acid is 1.4g/cm3。
Use and above-mentioned further provide the benefit that: lead plaster coating character is good, and cream temperature is easily controllable.
Further, described fiber is the acidproof terylene of length 3～4mm.
Use and above-mentioned further provide the benefit that: the requirement of strength that can meet pole plate nor affects on the coating character of lead plaster
Energy.
In the present invention, active material formula is the key element of battery performance, and its weight must strictly control, and Hydrocerussitum (Ceruse) weight is by mistake
Difference need to control below 0.5%, and each weight of additive error need to control below 0.3%；Close when dilute sulfuric acid density is 25 DEG C
Degree, the height of its density directly influences lead plaster acid content, and very big with battery performance relation, error must strictly control, and it is close
Degree error need to control at ± 0.01g/cm3In the range of.Lignosulphonic acid sodium sulphosuccinate of the present invention uses Norway to produce HT-I, and it is plumbic acid
The high performance cathodes extender that battery industry is generally admitted.
The two of the purpose of the present invention, are to provide the manufacture method of above-mentioned long-life pole plate for lead-acid storage battery.
The technical scheme is that the manufacturer of a kind of long-life pole plate for lead-acid storage battery
Method, comprise the steps: electrolytic lead cold cut, pulverizing, alloy lead cast panel and cream, coated plate, solidification be dried, be melted into, rinsing, drying,
Dividing brushing piece, packaging, described and cream positive plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), graphite 0.25～0.4
Part, plumbic acid barium 0.4～0.8 part, stannous sulfate 0.06～0.1 part, antimony oxide 0.08～0.15 part, dilute sulfuric acid 8～10 parts,
Fiber 0.08～0.12 part and pure water 9～11 parts, add Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, antimony oxide, fiber
Paste mixing machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid, stir 15 minutes to apparent density 4.35～
4.40g/cm3, and cream process control temp reaches 60 DEG C～65 DEG C, when lead plaster temperature is down to less than 45 DEG C, goes out cream coated plate, obtains
Positive plate；Negative plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6～0.9 part, graphite 0.2～0.5
Part, acetylene black 0.2～0.4 part, humic acid 0.2～0.4 part, bismuth oxide 0.03～0.06 part, fiber 0.08～0.12 part, lignin
Sodium sulfonate sodium sulfonate 0.18～0.2 part, dilute sulfuric acid 7～9 parts and pure water 9～11 parts, by Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid,
Bismuth oxide, fiber, lignosulphonic acid sodium sulphosuccinate, addition paste mixing machine, be dry mixed 5 minutes, add pure water, wet mixing 3 minutes, be slowly added into
Dilute sulfuric acid, stirs 15 minutes to apparent density 4.40～4.45g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, works as lead
Cream temperature is down to less than 45 DEG C, goes out cream coated plate, obtains negative plate.
The manufacture method of the polar plate of lead acid storage battery of the present invention, adds plumbic acid barium, antimony oxide and sulfur in positive plate
Acid stannous, the effectively fall that adds of these three kinds of raw materials improves the electric conductivity of pole plate, eliminates the non-antimony effect of pole plate, the most greatly
The formation efficiency that improve greatly pole plate also solves lead calcium stannum pole plate capacitance loss (PCL) phenomenon in early days, makes pole plate be melted into electricity consumption
Reducing 9～11%, battery cycle life is brought up to 450～500 times by about 300 times.Negative plate adds graphite and oxygen
Changing bismuth, the addition of these two kinds of raw materials is effectively increased negative plate charge acceptance, large current discharging capability and low temperature discharge energy
Power, improves negative plate active material utilization rate, also plays certain effect to improving battery cycle life.And, the present invention
Do not change original production technology, simple to operate, it is easy to batch production, improve battery performance effect obvious.
On the basis of technique scheme, the present invention can also do following improvement.
Further, described and cream positive plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.3 part of graphite,
Plumbic acid barium 0.6 part, stannous sulfate 0.08 part, antimony oxide 0.12 part, dilute sulfuric acid 9 parts, fiber 0.10 part and pure water 10 parts；Institute
State the negative plate with cream to be made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.7 part of barium sulfate, 0.3 part of graphite, acetylene black
0.3 part, humic acid 0.3 part, bismuth oxide 0.04 part, fiber 0.10 part, lignosulphonic acid sodium sulphosuccinate 0.19 part, dilute sulfuric acid 8 parts and
Pure water 10 parts.
Use and above-mentioned further provide the benefit that: above for optimal parameter, use the lead-acid accumulator that this parameter prepares
The effect of pole plate is best.
Further, the oxidizability of described positive plate Hydrocerussitum (Ceruse) is 73～78%, the oxidizability of described negative plate Hydrocerussitum (Ceruse) be 70～
75%.
Use and above-mentioned further provide the benefit that: pole plate production process is easily operated, and pole plate outward appearance is without exception, process matter
Measuring easily controllable, pole plate performance reaches optimum state.
Further, the density of described dilute sulfuric acid is 1.4g/cm3。
Use and above-mentioned further provide the benefit that: lead plaster coating character is good, and cream temperature is easily controllable.
Further, described fiber is the acidproof terylene of length 3～4mm.
Use and above-mentioned further provide the benefit that: the requirement of strength that can meet pole plate nor affects on the coating character of lead plaster
Energy.
The invention has the beneficial effects as follows:
1. the polar plate of lead acid storage battery of the present invention, adds plumbic acid barium, antimony oxide and stannous sulfate in positive plate, this
The effectively fall that adds of three kinds of raw materials improves the electric conductivity of pole plate, eliminates the non-antimony effect of pole plate, not only substantially increases
The formation efficiency of pole plate also solves lead calcium stannum pole plate in early days capacitance loss (PCL) phenomenon, make pole plate chemical conversion electricity consumption reduce 9～
11%, battery cycle life is brought up to 450～500 times by about 300 times.Adding graphite and bismuth oxide in negative plate, these are two years old
The addition planting raw material is effectively increased negative plate charge acceptance, large current discharging capability and low temperature discharge ability, improves
Negative plate active material utilization rate, also plays certain effect to improving battery cycle life.
Manufacture method the most of the present invention is simple, wide market, is suitable for scale application.
3. the present invention efficiently solve the battery life that Pb-Ca-Sn-Al alloy produces in electric moped storage batteries short,
Charge acceptance difference and the defect of low temperature performance difference, for lead acid storage battery of electric booster car to environment-protecting long-life type battery
Development has stepped significantly one step.
Accompanying drawing explanation
Fig. 1 is technology for manufacturing lead flow chart in prior art.
Detailed description of the invention
Being described principle and the feature of the present invention below in conjunction with concrete accompanying drawing, example is served only for explaining this
Bright, it is not intended to limit the scope of the present invention.
Embodiment 1
The long-life pole plate for lead-acid storage battery of the present embodiment, including positive plate and negative plate, positive plate is by following weight
Raw material forms: Hydrocerussitum (Ceruse) 100kg, graphite 0.25kg, plumbic acid barium 0.8kg, stannous sulfate 0.06kg, antimony oxide 0.15kg, dilute
Sulphuric acid 8kg, fiber 0.12kg and pure water 9kg；Negative plate is made up of the raw material of following weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6kg,
Graphite 0.5kg, acetylene black 0.2kg, humic acid 0.4kg, bismuth oxide 0.03kg, fiber 0.12kg, lignosulphonic acid sodium sulphosuccinate
0.18kg, dilute sulfuric acid 7kg and pure water 11kg.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 73%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is
70%, the density of dilute sulfuric acid is 1.4g/cm3, fiber is the acidproof terylene of length 3mm.
The manufacture method of the long-life pole plate for lead-acid storage battery of above-described embodiment, comprises the steps: electrolytic lead cold cut, mill
Powder, alloy lead cast panel and cream, coated plate, solidification are dried, are melted into, rinsing, drying, point brushing piece, packaging, the described and positive plate of cream
It is made up of the raw material of following weight: Hydrocerussitum (Ceruse) 100kg, graphite 0.25kg, plumbic acid barium 0.8kg, stannous sulfate 0.06kg, three oxidations two
Antimony 0.15kg, dilute sulfuric acid 8kg, fiber 0.12kg and pure water 9kg, first by Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, three oxidations two
Antimony, fiber add paste mixing machine, are dry mixed 5 minutes, add pure water, wet mixing 3 minutes, are slowly added into dilute sulfuric acid and (added at 15～18 minutes
Complete), stir 15 minutes to apparent density 4.40g/cm3, and cream process control temp reaches 60 DEG C～65 DEG C, when lead plaster temperature is down to
Less than 45 DEG C, go out cream coated plate, obtain positive plate；It is made up of the raw material of following weight with the negative plate of cream: Hydrocerussitum (Ceruse) 100kg, sulphuric acid
Barium 0.6kg, graphite 0.5kg, acetylene black 0.2kg, humic acid 0.4kg, bismuth oxide 0.03kg, fiber 0.12kg, sodium lignosulfonate
Sodium sulfonate 0.18kg, dilute sulfuric acid 7kg and pure water 11kg, by Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid, bismuth oxide, fiber add and
Cream machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid (adding at 18～20 minutes), stirs 15 minutes
To apparent density to 4.40g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, when lead plaster temperature is down to less than 45 DEG C, goes out
Cream coated plate, obtains negative plate.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 73%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is 70%, dilute sulfur
The density of acid is 1.4g/cm3, fiber is the acidproof terylene of length 3mm.
Embodiment 2
The long-life pole plate for lead-acid storage battery of the present embodiment, including positive plate and negative plate, positive plate is by following weight
Raw material forms: Hydrocerussitum (Ceruse) 100kg, graphite 0.3kg, plumbic acid barium 0.6kg, stannous sulfate 0.08kg, antimony oxide 0.12kg, dilute sulfur
Acid 9kg, fiber 0.10kg and pure water 10kg；Negative plate is made up of the raw material of following weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.8kg,
Graphite 0.3kg, acetylene black 0.3kg, humic acid 0.3kg, bismuth oxide 0.04kg, fiber 0.10kg, lignosulphonic acid sodium sulphosuccinate
0.19kg, dilute sulfuric acid 8kg and pure water 10kg.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 75%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is
72%, the density of dilute sulfuric acid is 1.4g/cm3, fiber is the acidproof terylene of length 4mm.
The manufacture method of the long-life pole plate for lead-acid storage battery of above-described embodiment, comprises the steps: electrolytic lead cold cut, mill
Powder, alloy lead cast panel and cream, coated plate, solidification are dried, are melted into, rinsing, drying, point brushing piece, packaging, the described and positive plate of cream
It is made up of the raw material of following weight: Hydrocerussitum (Ceruse) 100kg, graphite 0.3kg, plumbic acid barium 0.6kg, stannous sulfate 0.08kg, three oxidations two
Antimony 0.12kg, dilute sulfuric acid 9kg, fiber 0.10kg and pure water 10kg, first by Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, three oxidations
Two antimony, fiber add paste mixing machine, are dry mixed 5 minutes, add pure water, wet mixing 3 minutes, are slowly added into dilute sulfuric acid (at 15～18 minutes
Add), stir 15 minutes to apparent density 4.38g/cm3, and cream process control temp reaches 60 DEG C～65 DEG C, when lead plaster temperature drops
To less than 45 DEG C, go out cream coated plate, obtain positive plate；It is made up of the raw material of following weight with the negative plate of cream: Hydrocerussitum (Ceruse) 100kg, sulfur
Acid barium 0.8kg, graphite 0.3kg, acetylene black 0.3kg, humic acid 0.3kg, bismuth oxide 0.04kg, fiber 0.10kg, lignosulphonic acid
Sodium sulphosuccinate 0.19kg, dilute sulfuric acid 8kg and pure water 10kg, add Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid, bismuth oxide, fiber
Paste mixing machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid (adding at 18～20 minutes), stirs 15 points
Clock is to apparent density to 4.41g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, when lead plaster temperature is down to less than 45 DEG C,
Go out cream coated plate, obtain negative plate.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 75%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is 72%, dilute
The density of sulphuric acid is 1.4g/cm3, fiber is the acidproof terylene of length 4mm.
Embodiment 3
The long-life pole plate for lead-acid storage battery of the present embodiment, including positive plate and negative plate, positive plate is by following weight
Raw material forms: Hydrocerussitum (Ceruse) 100kg, graphite 0.4kg, plumbic acid barium 0.4kg, stannous sulfate 0.1kg, antimony oxide 0.08kg, dilute sulfur
Acid 10kg, fiber 0.08kg and pure water 11kg；Negative plate is made up of the raw material of following weight: Hydrocerussitum (Ceruse) 100kg, barium sulfate 0.9kg,
Graphite 0.2kg, acetylene black 0.4kg, humic acid 0.2kg, bismuth oxide 0.06kg, fiber 0.08kg, lignosulphonic acid sodium sulphosuccinate
0.2kg, dilute sulfuric acid 9kg and pure water 9kg.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 78%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is
75%, the density of dilute sulfuric acid is 1.4g/cm3, fiber is the acidproof terylene of length 4mm.
The manufacture method of the long-life pole plate for lead-acid storage battery of above-described embodiment, comprises the steps: electrolytic lead cold cut, mill
Powder, alloy lead cast panel and cream, coated plate, solidification are dried, are melted into, rinsing, drying, point brushing piece, packaging, the described and positive plate of cream
It is made up of the raw material of following weight: Hydrocerussitum (Ceruse) 100kg, graphite 0.4kg, plumbic acid barium 0.4kg, stannous sulfate 0.1kg, antimony oxide
0.08kg, dilute sulfuric acid 10kg, fiber 0.08kg and pure water 11kg, first by Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, three oxidations two
Antimony, fiber add paste mixing machine, are dry mixed 5 minutes, add pure water, wet mixing 3 minutes, are slowly added into dilute sulfuric acid and (added at 15～18 minutes
Complete), stir 15 minutes to apparent density 4.35g/cm3, and cream process control temp reaches 60 DEG C～65 DEG C, when lead plaster temperature is down to
Less than 45 DEG C, go out cream coated plate, obtain positive plate；It is made up of the raw material of following weight with the negative plate of cream: Hydrocerussitum (Ceruse) 100kg, sulphuric acid
Barium 0.9kg, graphite 0.2kg, acetylene black 0.4kg, humic acid 0.2kg, bismuth oxide 0.06kg, fiber 0.08kg, sodium lignosulfonate
Sodium sulfonate 0.2kg, dilute sulfuric acid 9kg and pure water 9kg, add Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid, bismuth oxide, fiber and cream
Machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid (adding at 18～20 minutes), stirs 15 minutes extremely
Apparent density is to 4.45g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, when lead plaster temperature is down to less than 45 DEG C, goes out cream
Coated plate, obtains negative plate.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 75%, and the oxidizability of negative plate Hydrocerussitum (Ceruse) is 72%, dilute sulfuric acid
Density be 1.4g/cm3, fiber is the acidproof terylene of length 4mm.
Embodiment 4
The long-life pole plate for lead-acid storage battery of the present embodiment, including positive plate and negative plate, positive plate is by following weight
Raw material forms: Hydrocerussitum (Ceruse) 100kg, graphite 0.3kg, plumbic acid barium 0.7kg, stannous sulfate 0.07kg, antimony oxide 0.1kg, dilute sulfur
Acid 9kg, fiber 0.09kg and pure water 11kg；Negative plate is made up of the raw material of following weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.8kg,
Graphite 0.4kg, acetylene black 0.25kg, humic acid 0.3kg, bismuth oxide 0.035kg, fiber 0.09kg, lignosulphonic acid sodium sulphosuccinate
0.19kg, dilute sulfuric acid 8.5kg and pure water 9.5kg.Wherein, the oxidizability of positive plate Hydrocerussitum (Ceruse) is 78%, the oxidation of negative plate Hydrocerussitum (Ceruse)
Degree is 75%, and the density of dilute sulfuric acid is 1.4g/cm3, fiber is the acidproof terylene of length 4mm.
The manufacture method of the long-life pole plate for lead-acid storage battery of above-described embodiment, comprises the steps: electrolytic lead cold cut, mill
Powder, alloy lead cast panel and cream, coated plate, solidification are dried, are melted into, rinsing, drying, point brushing piece, packaging, the described and positive plate of cream
Hydrocerussitum (Ceruse) 100kg, graphite 0.3kg, plumbic acid barium 0.7kg, stannous sulfate 0.07kg, antimony oxide is formed by the raw material of following weight
0.1kg, dilute sulfuric acid 9kg, fiber 0.09kg and pure water 11kg, first by Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, three oxidations two
Antimony, fiber add paste mixing machine, are dry mixed 5 minutes, add pure water, wet mixing 3 minutes, are slowly added into dilute sulfuric acid and (added at 15～18 minutes
Complete), stir 15 minutes to apparent density 4.35g/cm3, and cream process control temp reaches 60 DEG C～65 DEG C, when lead plaster temperature is down to
Less than 45 DEG C, go out cream coated plate, obtain positive plate；It is made up of the raw material of following weight with the negative plate of cream: Hydrocerussitum (Ceruse) 100kg, sulphuric acid
Barium 0.9kg, graphite 0.2kg, acetylene black 0.4kg, humic acid 0.2kg, bismuth oxide 0.06kg, fiber 0.08kg, dilute sulfuric acid 9kg,
Lignosulphonic acid sodium sulphosuccinate 0.19kg and pure water 9kg, by Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid, bismuth oxide, fiber, lignin sulphur
Acid sodium sulphosuccinate adds paste mixing machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid (at 18～20 minutes
Add), stir 15 minutes to apparent density to 4.42g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, when lead plaster temperature
It is down to less than 45 DEG C, goes out cream coated plate, obtain negative plate.
Comparative example
With long-life pole plate for lead-acid storage battery and the polar plate of lead acid storage battery of prior art of embodiment 4, carry out main property
Energy Experimental Comparison, as shown in table 1.
The polar plate of lead acid storage battery main performance test of the long-life pole plate for lead-acid storage battery of table 1 present invention and prior art
Contrast
As can be seen here, the long-life pole plate for lead-acid storage battery of the present invention, not only substantially increase the formation efficiency of pole plate also
Solve lead calcium stannum pole plate in early days capacitance loss (PCL) phenomenon, make pole plate chemical conversion electricity consumption reduce 9～11% (pole plate chemical conversion is filled
Electricity multiplying power can be by being reduced to about 2.0 times about the 2.3 of common pole plate times) battery cycle life brings up to 450 by about 300 times
～500 times.Adding graphite and bismuth oxide in negative plate, the addition of these two kinds of raw materials is effectively increased negative plate charging by energy
Power, large current discharging capability and low temperature discharge ability, improve negative plate active material utilization rate, to improving battery cycle life also
Serve certain effect.Battery charge acceptance rises to 3.1 from 2.2；Large current discharging capability brought up to from 20 minutes
30 minutes；Low temperature discharge ability brings up to about 105% from about 85%.Currently used Pb-Ca-Sn-Al alloy is by this effect
For the battery that grid raw material is produced, it is a new breakthrough technically.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (10)
1. a long-life pole plate for lead-acid storage battery, including positive plate and negative plate, it is characterised in that positive plate is by following weight
The raw material composition of number: 100 parts of Hydrocerussitum (Ceruse), graphite 0.25～0.4 part, plumbic acid barium 0.4～0.8 part, stannous sulfate 0.06～0.1
Part, antimony oxide 0.08～0.15 part, dilute sulfuric acid 8～10 parts, fiber 0.08～0.12 part and pure water 9～11 parts；Negative plate
It is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6～0.9 part, graphite 0.2～0.5 part, acetylene black 0.2
～0.4 part, humic acid 0.2～0.4 part, bismuth oxide 0.03～0.06 part, fiber 0.08～0.12 part, lignosulphonic acid sodium sulphosuccinate
0.18～0.2 part, dilute sulfuric acid 7～9 parts and pure water 9～11 parts.
A kind of long-life pole plate for lead-acid storage battery the most according to claim 1, it is characterised in that described positive plate is by as follows
The raw material composition of parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.3 part of graphite, plumbic acid barium 0.6 part, stannous sulfate 0.08 part, antimony oxide
0.12 part, dilute sulfuric acid 9 parts, fiber 0.10 part and pure water 10 parts；Described negative plate is made up of the raw material of following parts by weight: Hydrocerussitum (Ceruse)
100 parts, 0.8 part of barium sulfate, 0.3 part of graphite, acetylene black 0.3 part, humic acid 0.3 part, bismuth oxide 0.04 part, fiber 0.10 part,
Lignosulphonic acid sodium sulphosuccinate 0.19 part, dilute sulfuric acid 8 parts and pure water 10 parts.
A kind of long-life pole plate for lead-acid storage battery the most according to claim 1 and 2, it is characterised in that described positive plate lead
The oxidizability of powder is 73～78%, and the oxidizability of described negative plate Hydrocerussitum (Ceruse) is 70～75%.
A kind of long-life pole plate for lead-acid storage battery the most according to claim 1 and 2, it is characterised in that described dilute sulfuric acid
Density is 1.4g/cm3。
A kind of long-life pole plate for lead-acid storage battery the most according to claim 1 and 2, it is characterised in that described fiber is for long
The acidproof terylene of degree 3～4mm.
6. a manufacture method for long-life pole plate for lead-acid storage battery, comprises the steps: electrolytic lead cold cut, pulverizing, alloy lead
Cast panel and cream, coated plate, solidification are dried, are melted into, rinsing, drying, point brushing piece, packaging, it is characterised in that the described and positive pole of cream
Plate is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), graphite 0.25～0.4 part, plumbic acid barium 0.4～0.8 part, sulphuric acid Asia
Stannum 0.06～0.1 part, antimony oxide 0.08～0.15 part, dilute sulfuric acid 8～10 parts, fiber 0.08～0.12 part and pure water 9～
11 parts, Hydrocerussitum (Ceruse), graphite, plumbic acid barium, stannous sulfate, antimony oxide, fiber are added paste mixing machine, is dry mixed 5 minutes, adds pure
Water, wet mixing 3 minutes, it is slowly added into dilute sulfuric acid, stirs 15 minutes to apparent density 4.35～4.40g/cm3, and cream process control temperature
Degree reaches 60 DEG C～65 DEG C, when lead plaster temperature is down to less than 45 DEG C, goes out cream coated plate, obtains positive plate；Negative plate is by following weight
The raw material composition of number: 100 parts of Hydrocerussitum (Ceruse), barium sulfate 0.6～0.9 part, graphite 0.2～0.5 part, acetylene black 0.2～0.4 part, corruption
Grow acid 0.2～0.4 part, bismuth oxide 0.03～0.06 part, fiber 0.08～0.12 part, lignosulphonic acid sodium sulphosuccinate 0.18～0.2
Part, dilute sulfuric acid 7～9 parts and pure water 9～11 parts, by Hydrocerussitum (Ceruse), barium sulfate, graphite, humic acid, bismuth oxide, fiber, sodium lignosulfonate
Sodium sulfonate adds paste mixing machine, is dry mixed 5 minutes, adds pure water, wet mixing 3 minutes, is slowly added into dilute sulfuric acid, stirs 15 minutes to regarding close
Degree is to 4.40～4.45g/cm3, and cream process control and cream temperature be not higher than 60 DEG C, when lead plaster temperature is down to less than 45 DEG C, goes out
Cream coated plate, obtains negative plate.
The manufacture method of a kind of long-life pole plate for lead-acid storage battery the most according to claim 6, it is characterised in that described and
The positive plate of cream is made up of the raw material of following parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.3 part of graphite, plumbic acid barium 0.6 part, stannous sulfate
0.07 part, antimony oxide 0.12 part, dilute sulfuric acid 9 parts, fiber 0.10 part and pure water 10 parts；The negative plate of described and cream is by as follows
The raw material composition of parts by weight: 100 parts of Hydrocerussitum (Ceruse), 0.7 part of barium sulfate, 0.3 part of graphite, acetylene black 0.3 part, humic acid 0.3 part, oxygen
Change bismuth 0.04 part, fiber 0.10 part, lignosulphonic acid sodium sulphosuccinate 0.19 part, dilute sulfuric acid 8 parts and pure water 10 parts.
8. according to the manufacture method of a kind of long-life pole plate for lead-acid storage battery described in claim 6 or 7, it is characterised in that institute
The oxidizability stating positive plate Hydrocerussitum (Ceruse) is 73～78%, and the oxidizability of described negative plate Hydrocerussitum (Ceruse) is 70～75%.
9. according to the manufacture method of a kind of long-life pole plate for lead-acid storage battery described in claim 6 or 7, it is characterised in that institute
The density stating dilute sulfuric acid is 1.4g/cm3。
10. according to the manufacture method of a kind of long-life pole plate for lead-acid storage battery described in claim 6 or 7, it is characterised in that institute
State the acidproof terylene that fiber is length 3～4mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610548236.8A CN106099119A (en) | 2016-07-12 | 2016-07-12 | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610548236.8A CN106099119A (en) | 2016-07-12 | 2016-07-12 | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106099119A true CN106099119A (en) | 2016-11-09 |
Family
ID=57221252
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610548236.8A Pending CN106099119A (en) | 2016-07-12 | 2016-07-12 | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106099119A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106654217A (en) * | 2017-01-09 | 2017-05-10 | 江苏海宝电池科技有限公司 | Composite carbon negative-electrode active material for lead carbon power battery as well as preparation method and application of composite carbon negative-electrode active material |
| CN109830652A (en) * | 2018-12-25 | 2019-05-31 | 江苏理士电池有限公司 | A kind of lead-acid battery negative pole plate lead plaster, preparation method and lead-acid accumulator |
| CN110783639A (en) * | 2019-11-29 | 2020-02-11 | 湖南科舰能源发展有限公司 | EFB battery for starting and stopping of automobile and preparation method thereof |
| CN110854448A (en) * | 2019-11-29 | 2020-02-28 | 湖南科舰能源发展有限公司 | AGM storage battery for starting and stopping automobile and preparation method thereof |
| CN114068884A (en) * | 2021-10-19 | 2022-02-18 | 广东奥克莱集团有限公司 | Bipolar plate for lead-acid storage battery and preparation method thereof |
| CN114530600A (en) * | 2021-10-28 | 2022-05-24 | 安徽力普拉斯电源技术有限公司 | Formula and preparation method of positive lead paste of energy storage battery |
| CN116315144A (en) * | 2022-11-10 | 2023-06-23 | 骆驼集团襄阳蓄电池有限公司 | Low-voltage auxiliary battery for new energy vehicle |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03176965A (en) * | 1989-12-01 | 1991-07-31 | Yuasa Battery Co Ltd | Sealed lead-acid battery |
| CN103219523A (en) * | 2013-04-03 | 2013-07-24 | 江苏海德森能源有限公司 | Negative plate of lead-acid storage battery and preparation method of negative plate |
| CN104167546A (en) * | 2014-05-21 | 2014-11-26 | 河南超威电源有限公司 | Lead paste for battery starting/stopping, and preparation method thereof |
| CN105140573A (en) * | 2015-09-28 | 2015-12-09 | 骆驼集团蓄电池研究院有限公司 | Maintenance-free lead-acid storage battery and preparation method thereof |
| CN105280916A (en) * | 2015-02-11 | 2016-01-27 | 济源市万洋绿色能源有限公司 | Composite paste for inner formation of lead-acid storage battery |
| CN105336992A (en) * | 2015-10-26 | 2016-02-17 | 程艳青 | Manufacturing method for long-life barren liquor type valve control storage battery |
| CN105720266A (en) * | 2016-03-29 | 2016-06-29 | 安徽省华森电源有限公司 | Lead paste for high-performance lead-acid storage battery |
-
2016
- 2016-07-12 CN CN201610548236.8A patent/CN106099119A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03176965A (en) * | 1989-12-01 | 1991-07-31 | Yuasa Battery Co Ltd | Sealed lead-acid battery |
| CN103219523A (en) * | 2013-04-03 | 2013-07-24 | 江苏海德森能源有限公司 | Negative plate of lead-acid storage battery and preparation method of negative plate |
| CN104167546A (en) * | 2014-05-21 | 2014-11-26 | 河南超威电源有限公司 | Lead paste for battery starting/stopping, and preparation method thereof |
| CN105280916A (en) * | 2015-02-11 | 2016-01-27 | 济源市万洋绿色能源有限公司 | Composite paste for inner formation of lead-acid storage battery |
| CN105140573A (en) * | 2015-09-28 | 2015-12-09 | 骆驼集团蓄电池研究院有限公司 | Maintenance-free lead-acid storage battery and preparation method thereof |
| CN105336992A (en) * | 2015-10-26 | 2016-02-17 | 程艳青 | Manufacturing method for long-life barren liquor type valve control storage battery |
| CN105720266A (en) * | 2016-03-29 | 2016-06-29 | 安徽省华森电源有限公司 | Lead paste for high-performance lead-acid storage battery |
Non-Patent Citations (1)
| Title |
|---|
| 陈红雨等: "含铋铅粉对铅酸蓄电池的作用与机理的研究", 《第七届全国铅酸蓄电池学术年会论文全集》 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106654217A (en) * | 2017-01-09 | 2017-05-10 | 江苏海宝电池科技有限公司 | Composite carbon negative-electrode active material for lead carbon power battery as well as preparation method and application of composite carbon negative-electrode active material |
| CN109830652A (en) * | 2018-12-25 | 2019-05-31 | 江苏理士电池有限公司 | A kind of lead-acid battery negative pole plate lead plaster, preparation method and lead-acid accumulator |
| CN110783639A (en) * | 2019-11-29 | 2020-02-11 | 湖南科舰能源发展有限公司 | EFB battery for starting and stopping of automobile and preparation method thereof |
| CN110854448A (en) * | 2019-11-29 | 2020-02-28 | 湖南科舰能源发展有限公司 | AGM storage battery for starting and stopping automobile and preparation method thereof |
| CN114068884A (en) * | 2021-10-19 | 2022-02-18 | 广东奥克莱集团有限公司 | Bipolar plate for lead-acid storage battery and preparation method thereof |
| CN114530600A (en) * | 2021-10-28 | 2022-05-24 | 安徽力普拉斯电源技术有限公司 | Formula and preparation method of positive lead paste of energy storage battery |
| CN116315144A (en) * | 2022-11-10 | 2023-06-23 | 骆驼集团襄阳蓄电池有限公司 | Low-voltage auxiliary battery for new energy vehicle |
| CN116315144B (en) * | 2022-11-10 | 2023-09-26 | 骆驼集团襄阳蓄电池有限公司 | Low-voltage auxiliary battery for new energy vehicle |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106099119A (en) | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof | |
| CN102354751B (en) | Formula and preparation method of high energy storage lead-acid battery lead paste | |
| CN103337613B (en) | A kind of Si-C composite material and preparation method thereof, lithium ion battery | |
| CN101937996B (en) | Colloid lead-acid storage battery cathode lead plaster for electric power assisted vehicle and preparation method | |
| CN102664256A (en) | Anode lead plaster of power lead-acid storage battery polar plate | |
| CN105720266A (en) | Lead paste for high-performance lead-acid storage battery | |
| CN103682331B (en) | Positive lead paste of storage battery and preparation method thereof | |
| CN101916861A (en) | Cathode lead plaster capable of prolonging fast charge-discharge circulating life of battery and preparation method thereof | |
| CN105226342B (en) | A kind of method that active material of utilization waste lead acid battery prepares new lead-acid battery | |
| CN103413977B (en) | A kind of production technology of accumulator | |
| CN107302118B (en) | High-performance lead-acid storage battery with recovered lead oxide as active substance | |
| CN109755564A (en) | A kind of power type lead storage battery | |
| CN104167545A (en) | Lead-acid storage battery negative electrode lead paste and preparation method thereof | |
| CN109904448A (en) | A kind of super alkene macromolecule lead storage battery green plate lead plaster | |
| CN109994710A (en) | Composite negative electrode material, preparation method thereof, negative electrode plate and battery | |
| CN103855399A (en) | Lead storage battery positive electrode lead plaster | |
| WO2018121101A1 (en) | Method for preparing high-cycle and high-voltage modified lithium-rich lithium manganate positive electrode material | |
| CN105390763A (en) | Method for preparing tetrabasic lead sulfate from waste lead plaster | |
| CN102709549A (en) | Tubular lead-acid battery positive pole squeezing cream and preparation method thereof | |
| CN102163719B (en) | Formula and manufacturing method of lead plaster for lead-acid battery positive plate | |
| CN108306058A (en) | A kind of preparation method of lead-acid accumulator | |
| CN103762388B (en) | A kind of internal formation process of electric motor car valve-regulated lead-acid battery | |
| CN105206800A (en) | Lead-acid cell positive electrode with lead sulfate as active material and method for preparing lead-acid cell through positive electrode | |
| CN110993897B (en) | Positive electrode additive for prolonging service life of valve-controlled sealed lead-acid battery and application thereof | |
| CN103633331A (en) | Positive active material for lead-acid power battery and preparation method of positive active material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |
|
| RJ01 | Rejection of invention patent application after publication |