CN104167546A - Lead paste for battery starting/stopping, and preparation method thereof - Google Patents
Lead paste for battery starting/stopping, and preparation method thereof Download PDFInfo
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- CN104167546A CN104167546A CN201410215352.9A CN201410215352A CN104167546A CN 104167546 A CN104167546 A CN 104167546A CN 201410215352 A CN201410215352 A CN 201410215352A CN 104167546 A CN104167546 A CN 104167546A
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- lead
- sulfuric acid
- lead plaster
- water
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 108
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000000835 fiber Substances 0.000 claims abstract description 40
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 claims abstract description 37
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004021 humic acid Substances 0.000 claims abstract description 21
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 19
- 239000010439 graphite Substances 0.000 claims abstract description 19
- 229920005610 lignin Polymers 0.000 claims abstract description 19
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 claims abstract description 18
- RCIVOBGSMSSVTR-UHFFFAOYSA-L stannous sulfate Chemical compound [SnH2+2].[O-]S([O-])(=O)=O RCIVOBGSMSSVTR-UHFFFAOYSA-L 0.000 claims abstract description 18
- 229910000375 tin(II) sulfate Inorganic materials 0.000 claims abstract description 18
- 239000006230 acetylene black Substances 0.000 claims abstract description 8
- 239000011505 plaster Substances 0.000 claims description 63
- 239000000203 mixture Substances 0.000 claims description 34
- -1 2.5~3.5 parts Substances 0.000 claims description 33
- 238000003756 stirring Methods 0.000 claims description 32
- 239000000126 substance Substances 0.000 claims description 22
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 239000006071 cream Substances 0.000 claims description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- 238000009472 formulation Methods 0.000 claims description 12
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 claims description 11
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000002347 injection Methods 0.000 claims description 6
- 239000007924 injection Substances 0.000 claims description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- 238000010521 absorption reaction Methods 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000008367 deionised water Substances 0.000 claims description 3
- 229910021641 deionized water Inorganic materials 0.000 claims description 3
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 3
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 239000011630 iodine Substances 0.000 claims description 2
- 229910052740 iodine Inorganic materials 0.000 claims description 2
- XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(ii,iv) oxide Chemical compound O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 claims description 2
- 238000007254 oxidation reaction Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 claims description 2
- WUOBERCRSABHOT-UHFFFAOYSA-N diantimony Chemical compound [Sb]#[Sb] WUOBERCRSABHOT-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 7
- 230000009286 beneficial effect Effects 0.000 description 5
- 229910000464 lead oxide Inorganic materials 0.000 description 4
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/56—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead
- H01M4/57—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of lead of "grey lead", i.e. powders containing lead and lead oxide
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
- H01M4/625—Carbon or graphite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention relates to a lead paste for battery starting/stopping, and a preparation method thereof. The lead paste is composed of a positive lead paste and a negative lead paste, and the positive lead paste comprises, by weight, 990-1010 parts of lead powder, 40-60 parts of red lead, 0.6-1.0 part of a conductive fiber, 2.5-3.5 parts of graphite, 1.5-2.5 parts of diantimony trioxide, 0.5-1.5 parts of stannous sulfate, 110-130 parts of water and 80-90 parts of sulfuric acid; and the negative lead paste comprises, by weight, 990-1010 parts of the lead powder, 0.4-0.8 parts of the conductive fiber, 2.5-3.5 parts of acetylene black, 8-12 parts of barium sulfate, 0.5-1.5 parts of humic acid, 1.5 -2.5 parts of lignin, 100-120 parts of water, 85-95 parts of sulfuric acid. The lead paste for battery starting/stopping and the preparation method thereof effectively solve the problems of poor battery performance, low electrode plate strength, easy loosening and softening, and short battery life.
Description
Technical field
The present invention relates to a kind of lead plaster of battery, particularly lead plaster and preparation method thereof for a kind of start and stop battery.
Background technology
Automobile is in shutdown process, multiplex to storage battery, be generally lead-acid battery, starting sparking effect is provided, run into red light or other road conditions, automobile phase down engine, when green light, automobile is restarted, start frequently and stop, reduce the useful life of battery, how to extend the useful life of battery, and vehicle starting is struck sparks, in brake deceleration process, energy reclaims, store in battery and go, it is the difficult problem in battery research and development, in current lead acid accumulator lead paste formula, for example Chinese Patent Application No. is 201310296767.9, patent name is " a kind of lead-acid accumulator anode diachylon formula ", application number is 201210552186.2, patent name is " in a kind of storage battery that is applicable to high temperature area, turning to lead plaster ", battery and lead plaster compound method that the start and stop technology that is not all reported as Fraquent start and stop is used.
Summary of the invention
The invention provides a kind of start and stop battery lead plaster and preparation method thereof, effectively solve battery performance poor, pole plate intensity is low, easily loose softening, the problem that battery life is short.
In order to solve the problems of the technologies described above, the present invention adopts following technical scheme:
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster:
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 990～1010 parts, lead powder, 40～60 parts of red lead, 0.6～1.0 part of conductive fiber, 2.5～3.5 parts, graphite, 1.5～2.5 parts of antimonous oxides, 0.5～1.5 part of stannous sulfate, 110～130 parts, water, 80～90 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 990～1010 parts, lead powder, 0.4～0.8 part of conductive fiber, 2.5～3.5 parts of acetylene blacks, 8～12 parts, barium sulfate, 0.5～1.5 part of humic acid, 1.5～2.5 parts, lignin, 100～120 parts, water, 85～95 parts, sulfuric acid.
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster:
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 990 parts, lead powder, 40 parts of red lead, 0.6 part of conductive fiber, 2.5 parts, graphite, 1.5 parts of antimonous oxides, 0.5 part of stannous sulfate, 110 parts, water, 80 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 990 parts, lead powder, 0.4 part of conductive fiber, 2.5 parts of acetylene blacks, 8 parts, barium sulfate, 0.5 part of humic acid, 1.5 parts, lignin, 100 parts, water, 85 parts, sulfuric acid.
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster:
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1010 parts, lead powder, 60 parts of red lead, 1.0 parts of conductive fibers, 3.5 parts, graphite, 2.5 parts of antimonous oxides, 1.5 parts of stannous sulfates, 130 parts, water, 90 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1010 parts, lead powder, 0.8 part of conductive fiber, 3.5 parts of acetylene blacks, 12 parts, barium sulfate, 1.5 parts of humic acids, 2.5 parts, lignin, 120 parts, water, 95 parts, sulfuric acid.
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster:
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1000 parts, lead powder, 50 parts of red lead, 0.8 part of conductive fiber, 3 parts, graphite, 2 parts of antimonous oxides, 1 part of stannous sulfate, 120 parts, water, 85 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1000 parts, lead powder, 0.6 part of conductive fiber, 3 parts of acetylene blacks, 10 parts, barium sulfate, 1 part of humic acid, 2 parts, lignin, 110 parts, water, 90 parts, sulfuric acid.
Described degree of oxidation of lead powder is 75 ± 5%, and bulk density is 1.35 ± 0.05g/cm
3, lead powder impurity content Fe≤0.0008%, Sb≤0.001%;
Lead orthoplumbate content > 97% in described red lead, Fe≤0.0008%;
Described conductive fiber is length 2～4 ㎜, and resistance to sulfuric acid performance is: in the sulfuric acid solution that conductive fiber is 50%～60% at sulfuric acid mass percent concentration, soak 2h, the conductive fiber that weightlessness is less than 5%;
The purity > 99.5% of described graphite, granularity is average≤30um;
Described stannous sulfate is content > 99%, the stannous sulfate of Fe≤0.005%;
Described antimonous oxide is content > 99.5%, the antimonous oxide of Fe≤0.005%;
Described water is deionized water, conductance≤2 μ s/cm;
Described sulfuric acid density is 1.40g/cm
3, chloride≤0.00003%, iron≤0.00005%;
Described acetylene black: coarse grain divides≤and 0.02%, be 14～17 ml/g depending on specific volume, iodine absorption value >=90～105g/ ㎏, hydrochloric acid liquid absorption >=4.0ml/g, resistivity≤2.5 Ω .m;
Described barium sulfate: barium sulfate content >=98.0%, particle diameter is distributed as barium sulfate >=80% that is less than 10um, is less than barium sulfate >=60% of 5um, is less than barium sulfate >=25% of 2um;
Described humic acid: humic acid content >=80%, iron content≤0.10%, chlorinity≤0.10%, fineness is 0.125 ㎜ sieve >=99% by diameter;
Described lignin: ash is 30%, moisture content is 9%, sodium lignin sulfonate is 60%.
Start and stop battery by the preparation method of lead plaster is:
A, positive medical paste preparing process:
The first step: the lead powder in positive paste formulation is added to paste mixing machine;
Second step: again the red lead in positive paste formulation, conductive fiber, graphite, antimonous oxide, stannous sulfate are added and lead plaster machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain positive cream.
B, negative medical paste preparing process
The first step: the lead powder in negative paste formulation is added to paste mixing machine;
Second step: again conductive fiber, acetylene black, barium sulfate, humic acid, lignin in negative paste formulation are added to paste mixing machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain negative cream.
The invention has the beneficial effects as follows:
Lead powder is lead plaster main material; Red lead is beneficial to lead oxide and in charging process, converts brown lead oxide to, reduces the formation charging amount of battery; Conductive fiber: effect is that plumbous being conducting fiber is caught, increases being bonding strength; The effect of graphite, stannous sulfate is: due to anodal brown lead oxide being poorly conductive, add and increase conductivity so anodal; The positive electrode potential of antimonous oxide adjustment, widens the potential difference between both positive and negative polarity, is beneficial to raising charge acceptance; Density is 1.40g/cm
3effect of sulfuric acid is to make lead oxide generate lead sulfate, and the shutdown of lead sulfate increases, and paints the dry setting of pole plate, after the lead sulfate that it's time to charge conversion, shut down and reduce, and be also the porosity that increases being in fact.Make sulfuric acid in follow-up use procedure have enough apertures to enter reaction.The effect of the water in positive cream is to make lead powder (just the siccative in cream refers to red lead with each siccative, conductive fiber, graphite, antimonous oxide and stannous sulfate) stir into paste, after moisture loss, be micropore, the electrolyte that is beneficial to battery fully enters to react with lead and stores electric weight.The effect of acetylene black, barium sulfate, humic acid lignin: be all the porosity that increases negative plate being, improve cryogenic property, because negative plate is to exist with plumbous state after overcharging, inner hole is fewer and feweri, sulfuric acid cannot enter reaction, so increase into macroporous additive, particularly at low temperature season, sulfuric acid denseness strengthens more difficult to get access; Water in negative cream is that deionized water effect is to make lead powder and each siccative (bear siccative in cream and refer to conductive fiber, acetylene black, barium sulfate, humic acid and lignin) stir into paste, after moisture loss, be micropore, the electrolyte that is beneficial to battery fully enters to react with lead and stores electric weight.
The present invention is simple to operate; Battery performance improves greatly, improves pole plate intensity, and pole plate is not easy loose softening, and through inferior tests up to a hundred, has all obtained good effect, improves battery life 15%, and dark charge and discharge cycles improves 20%; Improve pole plate porosity, good electrolyte passage is provided, battery discharge capacity in early stage carries 10%, and heavy current discharging time improves 30%, efficiently solves and starts frequently and stop, and reduces the problem of battery.
Embodiment
Be that the specific embodiment of the present invention elaborates below in conjunction with actual conditions.
Embodiment 1
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster, and in anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 990 parts, lead powder, 40 parts of red lead, 0.6 part of conductive fiber, 2.5 parts, graphite, 1.5 parts of antimonous oxides, 0.5 part of stannous sulfate, 110 parts, water, 80 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 990 parts, lead powder, 0.4 part of conductive fiber, 2.5 parts of acetylene blacks, 8 parts, barium sulfate, 0.5 part of humic acid, 1.5 parts, lignin, 100 parts, water, 85 parts, sulfuric acid.
Embodiment 2
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster, and in anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1010 parts, lead powder, 60 parts of red lead, 1.0 parts of conductive fibers, 3.5 parts, graphite, 2.5 parts of antimonous oxides, 1.5 parts of stannous sulfates, 130 parts, water, 90 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1010 parts, lead powder, 0.8 part of conductive fiber, 3.5 parts of acetylene blacks, 12 parts, barium sulfate, 1.5 parts of humic acids, 2.5 parts, lignin, 120 parts, water, 95 parts, sulfuric acid.
Embodiment 3
A kind of start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster, and in anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1000 parts, lead powder, 50 parts of red lead, 0.8 part of conductive fiber, 3 parts, graphite, 2 parts of antimonous oxides, 1 part of stannous sulfate, 120 parts, water, 85 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1000 parts, lead powder, 0.6 part of conductive fiber, 3 parts of acetylene blacks, 10 parts, barium sulfate, 1 part of humic acid, 2 parts, lignin, 110 parts, water, 90 parts, sulfuric acid.
Embodiment 4
The preparation method of embodiment 1～3:
A, positive medical paste preparing process:
The first step: the lead powder in positive paste formulation is added to paste mixing machine;
Second step: again the red lead in positive paste formulation, conductive fiber, graphite, antimonous oxide, stannous sulfate are added and lead plaster machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain positive cream.
B, negative medical paste preparing process
The first step: the lead powder in negative paste formulation is added to paste mixing machine;
Second step: again conductive fiber, acetylene black, barium sulfate, humic acid, lignin in negative paste formulation are added to paste mixing machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain negative cream.
Claims (6)
1. a start and stop battery lead plaster, is made up of anode diachylon and cathode lead plaster, it is characterized in that,
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 990～1010 parts, lead powder, 40～60 parts of red lead, 0.6～1.0 part of conductive fiber, 2.5～3.5 parts, graphite, 1.5～2.5 parts of antimonous oxides, 0.5～1.5 part of stannous sulfate, 110～130 parts, water, 80～90 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 990～1010 parts, lead powder, 0.4～0.8 part of conductive fiber, 2.5～3.5 parts of acetylene blacks, 8～12 parts, barium sulfate, 0.5～1.5 part of humic acid, 1.5～2.5 parts, lignin, 100～120 parts, water, 85～95 parts, sulfuric acid.
2. start and stop battery lead plaster according to claim 1, is made up of anode diachylon and cathode lead plaster, it is characterized in that,
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 990 parts, lead powder, 40 parts of red lead, 0.6 part of conductive fiber, 2.5 parts, graphite, 1.5 parts of antimonous oxides, 0.5 part of stannous sulfate, 110 parts, water, 80 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 990 parts, lead powder, 0.4 part of conductive fiber, 2.5 parts of acetylene blacks, 8 parts, barium sulfate, 0.5 part of humic acid, 1.5 parts, lignin, 100 parts, water, 85 parts, sulfuric acid.
3. start and stop battery lead plaster according to claim 1, is made up of anode diachylon and cathode lead plaster, it is characterized in that,
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1010 parts, lead powder, 60 parts of red lead, 1.0 parts of conductive fibers, 3.5 parts, graphite, 2.5 parts of antimonous oxides, 1.5 parts of stannous sulfates, 130 parts, water, 90 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1010 parts, lead powder, 0.8 part of conductive fiber, 3.5 parts of acetylene blacks, 12 parts, barium sulfate, 1.5 parts of humic acids, 2.5 parts, lignin, 120 parts, water, 95 parts, sulfuric acid.
4. start and stop battery lead plaster according to claim 1, is made up of anode diachylon and cathode lead plaster, it is characterized in that,
In anode diachylon, each chemical composition accounts for the weight portion of anode diachylon and is: 1000 parts, lead powder, 50 parts of red lead, 0.8 part of conductive fiber, 3 parts, graphite, 2 parts of antimonous oxides, 1 part of stannous sulfate, 120 parts, water, 85 parts, sulfuric acid;
In cathode lead plaster, each chemical composition accounts for the weight portion of cathode lead plaster and is: 1000 parts, lead powder, 0.6 part of conductive fiber, 3 parts of acetylene blacks, 10 parts, barium sulfate, 1 part of humic acid, 2 parts, lignin, 110 parts, water, 90 parts, sulfuric acid.
5. according to the start and stop battery lead plaster described in any one in claim 1-4, it is characterized in that, described degree of oxidation of lead powder is 75 ± 5%, and bulk density is 1.35 ± 0.05g/cm
3, lead powder impurity content Fe≤0.0008%, Sb≤0.001%;
Lead orthoplumbate content > 97% in described red lead, Fe≤0.0008%;
Described conductive fiber is length 2～4 ㎜, and resistance to sulfuric acid performance is: in the sulfuric acid solution that conductive fiber is 50%～60% at sulfuric acid mass percent concentration, soak 2h, the conductive fiber that weightlessness is less than 5%;
The purity > 99.5% of described graphite, granularity is average≤30um;
Described stannous sulfate is content > 99%, the stannous sulfate of Fe≤0.005%;
Described antimonous oxide is content > 99.5%, the antimonous oxide of Fe≤0.005%;
Described water is deionized water, conductance≤2 μ s/cm;
Described sulfuric acid density is 1.40g/cm
3, chloride≤0.00003%, iron≤0.00005%;
Described acetylene black: coarse grain divides≤and 0.02%, be 14～17 ml/g depending on specific volume, iodine absorption value >=90～105g/ ㎏, hydrochloric acid liquid absorption >=4.0ml/g, resistivity≤2.5 Ω .m;
Described barium sulfate: barium sulfate content >=98.0%, particle diameter is distributed as barium sulfate >=80% that is less than 10um, is less than barium sulfate >=60% of 5um, is less than barium sulfate >=25% of 2um;
Described humic acid: humic acid content >=80%, iron content≤0.10%, chlorinity≤0.10%, fineness is 0.125 ㎜ sieve >=99% by diameter;
Described lignin: ash is 30%, moisture content is 9%, sodium lignin sulfonate is 60%.
6. the preparation method of lead plaster for the start and stop battery described in claim 1-4 any one, is characterized in that:
A, positive medical paste preparing process:
The first step: the lead powder in positive paste formulation is added to paste mixing machine;
Second step: again the red lead in positive paste formulation, conductive fiber, graphite, antimonous oxide, stannous sulfate are added and lead plaster machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain positive cream;
?b, negative medical paste preparing process
The first step: the lead powder in negative paste formulation is added to paste mixing machine;
Second step: again conductive fiber, acetylene black, barium sulfate, humic acid, lignin in negative paste formulation are added to paste mixing machine, stir 8 minutes;
The 3rd step: while stirring in 2 minutes after water injection, rewetting stir 8 minutes;
The 4th step: in 20 minutes, add sulfuric acid while stirring, in the process of interpolation sulfuric acid, lead plaster and sulfuric acid reaction, temperature progressively increases, and in the time that temperature reaches 55 DEG C, the recirculated water of open cycle wind and pot wall reduces temperature, keeps temperature not surpass 65 DEG C;
The 5th step: stir and go out cream after 8 minutes, obtain negative cream.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106099049A (en) * | 2016-06-30 | 2016-11-09 | 济源市万洋绿色能源有限公司 | A kind of positive pole and cream technique |
| CN106099119A (en) * | 2016-07-12 | 2016-11-09 | 河北金星电源有限公司 | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof |
| CN106486667A (en) * | 2015-11-25 | 2017-03-08 | 衡阳瑞达电源有限公司 | The solar energy lead accumulator used under a kind of high temperature and preparation method |
| CN106784642A (en) * | 2015-11-25 | 2017-05-31 | 衡阳瑞达电源有限公司 | A kind of tubular colloidal battery and preparation method |
| CN113394399A (en) * | 2021-05-21 | 2021-09-14 | 天能电池集团股份有限公司 | Positive electrode lead plaster and lead storage battery |
| CN113675397A (en) * | 2021-08-23 | 2021-11-19 | 浙江巨江电源制造有限公司 | Deep-cycle long-life lead-acid storage battery lead paste for parking, battery thereof and manufacturing process method of battery |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101694886A (en) * | 2009-10-16 | 2010-04-14 | 黄山市美达电器有限公司 | Preparation technique of silica gel battery used for solar photovoltaic and wind energy system |
| CN101937996A (en) * | 2010-08-26 | 2011-01-05 | 风帆股份有限公司 | Colloid lead-acid storage battery cathode lead plaster for electric power assisted vehicle and preparation method |
| CN103219523A (en) * | 2013-04-03 | 2013-07-24 | 江苏海德森能源有限公司 | Negative plate of lead-acid storage battery and preparation method of negative plate |
| CN103715425A (en) * | 2013-12-07 | 2014-04-09 | 河南超威电源有限公司 | Lead paste for battery of electric vehicle, and use method thereof |
-
2014
- 2014-05-21 CN CN201410215352.9A patent/CN104167546B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101694886A (en) * | 2009-10-16 | 2010-04-14 | 黄山市美达电器有限公司 | Preparation technique of silica gel battery used for solar photovoltaic and wind energy system |
| CN101937996A (en) * | 2010-08-26 | 2011-01-05 | 风帆股份有限公司 | Colloid lead-acid storage battery cathode lead plaster for electric power assisted vehicle and preparation method |
| CN103219523A (en) * | 2013-04-03 | 2013-07-24 | 江苏海德森能源有限公司 | Negative plate of lead-acid storage battery and preparation method of negative plate |
| CN103715425A (en) * | 2013-12-07 | 2014-04-09 | 河南超威电源有限公司 | Lead paste for battery of electric vehicle, and use method thereof |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106486667A (en) * | 2015-11-25 | 2017-03-08 | 衡阳瑞达电源有限公司 | The solar energy lead accumulator used under a kind of high temperature and preparation method |
| CN106784642A (en) * | 2015-11-25 | 2017-05-31 | 衡阳瑞达电源有限公司 | A kind of tubular colloidal battery and preparation method |
| CN106099049A (en) * | 2016-06-30 | 2016-11-09 | 济源市万洋绿色能源有限公司 | A kind of positive pole and cream technique |
| CN106099049B (en) * | 2016-06-30 | 2018-12-14 | 济源市万洋绿色能源有限公司 | A kind of anode mixing paste technology |
| CN106099119A (en) * | 2016-07-12 | 2016-11-09 | 河北金星电源有限公司 | A kind of long-life pole plate for lead-acid storage battery and manufacture method thereof |
| CN113394399A (en) * | 2021-05-21 | 2021-09-14 | 天能电池集团股份有限公司 | Positive electrode lead plaster and lead storage battery |
| CN113394399B (en) * | 2021-05-21 | 2022-07-26 | 天能电池集团股份有限公司 | Positive electrode lead plaster and lead storage battery |
| CN113675397A (en) * | 2021-08-23 | 2021-11-19 | 浙江巨江电源制造有限公司 | Deep-cycle long-life lead-acid storage battery lead paste for parking, battery thereof and manufacturing process method of battery |
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Address after: 454550 Qinnan Industrial Zone, Qinyang City, Jiaozuo City, Henan Province Patentee after: Henan Biaoxin Power Supply Co.,Ltd. Country or region after: China Address before: 454550 Qinnan Industrial Zone, Qinyang City, Jiaozuo City, Henan Province Patentee before: HENAN CHAOWEI POWER SUPPLY Co.,Ltd. Country or region before: China |