CN106088369B - 一种无机有机材料复合隔热的保温板及制备方法与应用 - Google Patents

一种无机有机材料复合隔热的保温板及制备方法与应用 Download PDF

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CN106088369B
CN106088369B CN201610400956.XA CN201610400956A CN106088369B CN 106088369 B CN106088369 B CN 106088369B CN 201610400956 A CN201610400956 A CN 201610400956A CN 106088369 B CN106088369 B CN 106088369B
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叶道林
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    • E04B—GENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
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    • B32B37/06—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the heating method
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    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
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    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/30—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing magnesium cements or similar cements
    • C04B28/32—Magnesium oxychloride cements, e.g. Sorel cement
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
    • E04D—ROOF COVERINGS; SKY-LIGHTS; GUTTERS; ROOF-WORKING TOOLS
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    • E04D13/16—Insulating devices or arrangements in so far as the roof covering is concerned, e.g. characterised by the material or composition of the roof insulating material or its integration in the roof structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
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    • B32—LAYERED PRODUCTS
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
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    • B32B2311/00—Metals, their alloys or their compounds
    • B32B2311/24—Aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B32B2419/06—Roofs, roof membranes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/30—Mortars, concrete or artificial stone characterised by specific physical values for heat transfer properties such as thermal insulation values, e.g. R-values
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    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/91—Use of waste materials as fillers for mortars or concrete

Abstract

本发明公开一种无机有机材料复合隔热的保温板及制备方法与应用，其中，所述保温板自下而上依次包括：无机材料基板、高分子贴合膜、深层铝箔和高分子保护膜，所述无机材料基板为增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板。本发明利用深层铝箔对阳光的反射和无机材料基板的保温效果，用于屋面隔热保温和工业厂房内隔断隔热保温。另外，本发明无机材料基板耐水，物理性能稳定，长期在楼顶复杂温度条件下应用不腐蚀，同时还具备防火阻燃功能。

Description

一种无机有机材料复合隔热的保温板及制备方法与应用
技术领域
本发明涉及化工建材领域，尤其涉及一种无机有机材料复合隔热的保温板及制备方法与应用。
背景技术
现有的无机与有机材料复合只能在常温工况条件下成型，所以必须使用各种胶料完成无机与有机材料的界面粘合，界面这种方式的粘合存在着 抗拉强度低，不耐水，不耐老化的明显缺陷，使这两种材料的复合材料只能应用于室内等温度较为稳定的环境中，不能用于室外，特别是屋顶的隔热保温，因屋顶除阳光长期照射以外，常有雨水浸泡和积雪履盖，其应用条件更加复杂多变，需有物化性能均为稳定的材料才能满足其使用要求。
因此，现有技术还有待于改进和发展。
发明内容
鉴于上述现有技术的不足，本发明的目的在于提供一种无机有机材料复合隔热的保温板及制备方法与应用，旨在解决现有无机有机的复合材料只能应用于室内等温度较为稳定的环境中的问题。
本发明的技术方案如下：
一种无机有机材料复合隔热的保温板，其中，所述保温板自下而上依次包括：无机材料基板、高分子贴合膜、深层铝箔和高分子保护膜，所述无机材料基板为增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板。
所述的无机有机材料复合隔热的保温板，其中，按重量份计，所述氯氧镁板由以下组分组成：轻烧氧化镁80~120份、氯化镁水溶液100~130份、磷酸三钠1~5份、高铝水泥10~20份、10~20目石英砂或ф1.0~1.5陶粒80~120份、长8~12毫米玻璃纤维2~3份和玻璃纤维布1~3层。
所述的无机有机材料复合隔热的保温板，其中，按重量份计，所述氯氧镁板由以下组分组成：轻烧氧化镁100份、氯化镁水溶液115份、磷酸三钠3份、高铝水泥15份、10~20目石英砂或ф1.0~1.5陶粒100份、长8~12毫米玻璃纤维3份和玻璃纤维布2层。
所述的无机有机材料复合隔热的保温板，其中，按重量份计，所述硫氧镁板由以下组分组成：轻烧氧化镁80~120份、硫酸镁水溶液80~120份、柠檬酸0.2~0.6份、磷酸0.15~0.2份、硅灰10~20份、粉煤灰45~55份、长度为10~15毫米玻璃纤维1~3份和玻璃纤维布1~3层。
所述的无机有机材料复合隔热的保温板，其中，按重量份计，所述硫氧镁板由以下组分组成：轻烧氧化镁100份、硫酸镁水溶液100份、柠檬酸0.4份、磷酸0.15份、硅灰15份、粉煤灰50份、长度为10~15毫米玻璃纤维2份和玻璃纤维布2层。
所述的无机有机材料复合隔热的保温板，其中，所述高分子贴合膜由聚乙烯层及贴合于聚乙烯层上下表面的马来酚共挤而成。
所述的无机有机材料复合隔热的保温板，其中，所述深层铝箔由铝箔和贴合于铝箔一表面的聚脂深层共挤而成。
所述的无机有机材料复合隔热的保温板，其中，所述高分子保护膜由聚乙烯层及贴合于聚乙烯层一表面的马来酚共挤而成。
一种如上任一所述的无机有机材料复合隔热的保温板的制备方法，其中，包括步骤：
A、将氯氧镁板或硫氧镁板放入铝箔中升温至180~200℃；其中，所述氯氧镁板为增加了高铝水泥的氯氧镁板，所述硫氧镁板为增加了硅灰的硫氧镁板；
B、然后将依次贴合排列的高分子贴合膜、深层铝箔和高分子保护膜放置于氯氧镁板或硫氧镁板上，热压复合为保温板。
一种如上任一所述的无机有机材料复合隔热的保温板的应用，其中，将所述保温板用于屋顶隔热保温和工业厂房内隔热保温。
有益效果：本发明增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板可与有机材料采用热合的工艺进行复合，通过热合热压工艺复合得到无机有机材料复合隔热的保温板。本发明保温板中的铝箔具有反射阳光的功能，从而降低屋顶积累热，并连同无机材料基板的隔热保温性能，达到隔热保温，减小屋顶冷热膨胀系数，延长建筑物使用寿命。
具体实施方式
本发明提供一种无机有机材料复合隔热的保温板及制备方法与应用，为使本发明的目的、技术方案及效果更加清楚、明确，以下对本发明进一步详细说明。应当理解，此处所描述的具体实施例仅仅用以解释本发明，并不用于限定本发明。
本发明提供一种无机有机材料复合隔热的保温板，其中，所述保温板自下而上依次包括：无机材料基板、高分子贴合膜、深层铝箔和高分子保护膜，所述无机材料基板为增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板。
本发明所指的有机材料是指上述的高分子贴合膜、深层铝箔和高分子保护膜。其中，高分子贴合膜由三层膜共挤而成，具体为，所述高分子贴合膜由聚乙烯层及贴合于聚乙烯层上下表面的马来酚共挤而成。即三层膜分别为：中层的聚乙烯，外两层的马来酚，由该三层膜共挤而成的高分子贴合膜可起到粘贴作用，并可增强防腐作用。所述深层铝箔由铝箔和贴合于铝箔一表面的聚脂深层共挤而成。聚脂深层透明，又可对铝箔起到保护作用；且铝箔可以达到93%的阳光反射率，从而有效起到隔热和降低积累热的作用。高分子保护膜由二层膜共挤而成，具体为，所述高分子保护膜由聚乙烯层及贴合于聚乙烯层一表面的马来酚共挤而成。所述高分子保护膜可有效粘贴深层铝箔，是用于保护中层的深层铝箔。
现有无机材料基板包括氯氧镁板或硫氧镁板，按照现有配方制成的氯氧镁板或硫氧镁板不耐高温，在温度为200℃左右时这两种无机材料基板的强度衰减严重，不适合与有机材料通过热合的工艺进行复合。因此，本发明对现有无机材料基板的配方进行改进。与现有技术相比，本发明所述无机材料基板为增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板。按照本发明配方制成的无机材料基板可与有机材料采用热合的工艺进行复合。下面对本发明增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板的配方进行详细说明。
本发明所述氯氧镁板由以下组分组成：轻烧氧化镁80~120份、氯化镁水溶液100~130份、磷酸三钠1~5份、高铝水泥10~20份、10~20目石英砂或ф1.0~1.5陶粒80~120份、长8~12毫米玻璃纤维2~3份和玻璃纤维布1~3层。 采用上述配方，按照现行氯氧镁板制板经养护15天后，即可得到本发明的氯氧镁板。
优选地，按重量份计，所述氯氧镁板由以下组分组成：轻烧氧化镁100份、氯化镁水溶液115份、磷酸三钠3份、高铝水泥15份、10~20目石英砂或ф1.0~1.5陶粒100份、长8~12毫米玻璃纤维3份和玻璃纤维布2层。采用该配方制成的氯氧镁板能与有机材料较好地复合成型。
优选地，所述氯化镁水溶液的温度为25℃。
具体地，本发明所述硫氧镁板由以下组分组成：轻烧氧化镁80~120份、硫酸镁水溶液80~120份、柠檬酸0.2~0.6份、磷酸0.15~0.2份、硅灰10~20份、粉煤灰45~55份、长度为10~15毫米玻璃纤维1~3份和玻璃纤维布1~3层。采用上述配方，按照现行硫氧镁板工艺制板，养护15天后，即可得到本发明的硫氧镁板。
优选地，按重量份计，所述硫氧镁板由以下组分组成：轻烧氧化镁100份、硫酸镁水溶液100份、柠檬酸0.4份、磷酸0.15份、硅灰15份、粉煤灰50份、长度为10~15毫米玻璃纤维2份和玻璃纤维布2层。
优选地，所述硫酸镁水溶液的温度为30℃。
基于上述无机有机材料复合隔热的保温板，本发明还提供一种如上任一所述的无机有机材料复合隔热的保温板的制备方法，其包括步骤：
A、将氯氧镁板或硫氧镁板放入铝箔中升温至180~200℃；其中，所述氯氧镁板为增加了高铝水泥的氯氧镁板，所述硫氧镁板为增加了硅灰的硫氧镁板；
B、然后将依次贴合排列的高分子贴合膜、深层铝箔和高分子保护膜放置于氯氧镁板或硫氧镁板上，热压复合为保温板。
本发明无机材料基板和有机材料（高分子贴合膜、深层铝箔和高分子保护膜）通过高压热合成型。本发明是将增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板，通过热合热压工艺复合高分子贴合膜、深层铝箔和高分子保护膜，得到无机有机材料复合隔热的保温板。本发明保温板中的铝箔具有反射阳光的功能，从而降低屋顶积累热，并连同无机材料基板的隔热保温性能，达到隔热保温，减小屋顶冷热膨胀系数，延长建筑物使用寿命。
本发明还提供一种如上任一所述的无机有机材料复合隔热的保温板的应用，其中，将所述保温板用于屋顶隔热保温和工业厂房内隔热保温。本发明保温板用于屋顶隔热保温和工业厂房内隔热保温时，能有效降低屋顶积累热，并连同无机材料基板的隔热保温性能，达到隔热保温，减小屋顶冷热膨胀系数，延长建筑物使用寿命。
综上所述，本发明提供的无机有机材料复合隔热的保温板及制备方法与应用，通过将增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板，通过热合热压工艺复合高分子贴合膜、深层铝箔和高分子保护膜，得到无机有机材料复合隔热的保温板。本发明利用深层铝箔对阳光的反射和无机材料基板的保温效果，用于屋面隔热保温和工业厂房内隔断隔热保温。另外，本发明无机材料基板耐水，物理性能稳定，长期在楼顶复杂温度条件下应用不腐蚀，同时还具备防火阻燃功能。
应当理解的是，本发明的应用不限于上述的举例，对本领域普通技术人员来说，可以根据上述说明加以改进或变换，所有这些改进和变换都应属于本发明所附权利要求的保护范围。

Claims (6)

1.一种无机有机材料复合隔热的保温板，其特征在于，所述保温板自下而上依次包括：无机材料基板、高分子贴合膜、深层铝箔和高分子保护膜，
所述无机材料基板为增加了高铝水泥的氯氧镁板或增加了硅灰的硫氧镁板；
所述深层铝箔由铝箔和贴合于铝箔一表面的聚脂深层共挤而成；
所述高分子保护膜由聚乙烯层及贴合于聚乙烯层一表面的马来酚共挤而成；按重量份计，所述氯氧镁板由以下组分组成：轻烧氧化镁80~120份、氯化镁水溶液100~130份、磷酸三钠1~5份、高铝水泥10~20份、10~20目石英砂或ф1.0~1.5陶粒80~120份、长8~12毫米玻璃纤维2~3份和玻璃纤维布1~3层；
按重量份计，所述硫氧镁板由以下组分组成：轻烧氧化镁80~120份、硫酸镁水溶液80~120份、柠檬酸0.2~0.6份、磷酸0.15~0.2份、硅灰10~20份、粉煤灰45~55份、长度为10~15毫米玻璃纤维1~3份和玻璃纤维布1~3层；
所述保温板为所述无机材料基板、高分子贴合膜、深层铝箔和高分子保护膜依次叠加后通过热压工艺复合而成。
2.根据权利要求1所述的无机有机材料复合隔热的保温板，其特征在于，按重量份计，所述氯氧镁板由以下组分组成：轻烧氧化镁100份、氯化镁水溶液115份、磷酸三钠3份、高铝水泥15份、10~20目石英砂或ф1.0~1.5陶粒100份、长8~12毫米玻璃纤维3份和玻璃纤维布2层。
3.根据权利要求1所述的无机有机材料复合隔热的保温板，其特征在于，按重量份计，所述硫氧镁板由以下组分组成：轻烧氧化镁100份、硫酸镁水溶液100份、柠檬酸0.4份、磷酸0.15份、硅灰15份、粉煤灰50份、长度为10~15毫米玻璃纤维2份和玻璃纤维布2层。
4.根据权利要求1所述的无机有机材料复合隔热的保温板，其特征在于，所述高分子贴合膜由聚乙烯层及贴合于聚乙烯层上下表面的马来酚共挤而成。
5.一种如权利要求1~4任一所述的无机有机材料复合隔热的保温板的制备方法，其特征在于，包括步骤：
A、将氯氧镁板或硫氧镁板放入铝箔中升温至180~200℃；其中，所述氯氧镁板为增加了高铝水泥的氯氧镁板，所述硫氧镁板为增加了硅灰的硫氧镁板；
B、然后将依次贴合排列的高分子贴合膜、深层铝箔和高分子保护膜放置于氯氧镁板或硫氧镁板上，热压复合为保温板；
所述深层铝箔由铝箔和贴合于铝箔一表面的聚脂深层共挤而成；
所述高分子保护膜由聚乙烯层及贴合于聚乙烯层一表面的马来酚共挤而成。
6.一种如权利要求1~4任一所述的无机有机材料复合隔热的保温板的应用，其特征在于，将所述保温板用于屋顶隔热保温和工业厂房内隔热保温。
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