CN106087546A - A kind of film coating and preparation method thereof - Google Patents

A kind of film coating and preparation method thereof Download PDF

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Publication number
CN106087546A
CN106087546A CN201610462183.8A CN201610462183A CN106087546A CN 106087546 A CN106087546 A CN 106087546A CN 201610462183 A CN201610462183 A CN 201610462183A CN 106087546 A CN106087546 A CN 106087546A
Authority
CN
China
Prior art keywords
film coating
raw material
preparation
stilbene
block copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610462183.8A
Other languages
Chinese (zh)
Inventor
曹长显
田世昌
潘海舰
朱义兵
孙京科
陈华徳
孙振林
史东景
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henan Xin Chang New Material Science And Technology Co Ltd
Original Assignee
Henan Xin Chang New Material Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henan Xin Chang New Material Science And Technology Co Ltd filed Critical Henan Xin Chang New Material Science And Technology Co Ltd
Priority to CN201610462183.8A priority Critical patent/CN106087546A/en
Publication of CN106087546A publication Critical patent/CN106087546A/en
Pending legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/46—Non-macromolecular organic compounds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/36—Coatings with pigments
    • D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
    • D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/143—Agents preventing ageing of paper, e.g. radiation absorbing substances
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38—Corrosion-inhibiting agents or anti-oxidants

Abstract

The present invention relates to a kind of film coating and preparation method thereof, it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water 500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid ester compounded thing defoamer 0.2 ~ 1；The preparation method of described film coating, it comprises the following steps: the raw material of composition described above mixed, and is placed in closed reactor in 150～400 DEG C of melting reactions 0.5～2h, is taken out by reactant liquor and be cooled to room temperature, coat on base stock, i.e. can get described film coating.Film coating prepared by the method for photograph can make photomap as having height anti-corrosive properties and anti-ultraviolet erosion, for a long time Chang Xin, will never fade, do not turn yellow, more can increase strong third dimension, produce beyond thought effect.

Description

A kind of film coating and preparation method thereof
Technical field
The present invention relates to a kind of protective film, particularly to a kind of film coating and preparation method thereof.
Background technology
Along with improving constantly of people's living standard, people are more and more higher to the requirement of some advertisements, photograph, due to extensively Accusing, particularly outdoor advertising is affected by the weather such as rainforest of exposing to the weather, and easily causes pollution or drenches so that the outdoor advertising longevity Life is affected, and arise that after the article storage time length such as similar photograph fade, the phenomenon such as yellowing.In order to be able to make open air wide It is longer to accuse the life-span, and photograph can have height anti-corrosive properties and anti-ultraviolet erosion, and for a long time Chang Xin is colour-fast, does not turns yellow, people Starting with transparent protective film to cover on picture, the covering of current protective film mostly uses the mode that thermoplastic seals, and needs Equipment is wanted to heat, operation inconvenience；But existing thin film light transmittance is low, covers and can obscure picture on picture.
Summary of the invention
It is an object of the invention to provide a kind of film coating and preparation method thereof, film coating prepared by the present invention for Photograph can make photomap as having height anti-corrosive properties and anti-ultraviolet erosion, for a long time Chang Xin, will never fade, do not turn yellow, more can Increase strong third dimension, produce beyond thought effect.
For achieving the above object, the technical solution used in the present invention is as follows:
The invention provides a kind of film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water 500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid Ester complexes defoamer 0.2 ~ 1.
According to above-mentioned film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 100, pure water 550 ~ 600, Stilbene-based Fluorescent Brighteners 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~ 1.5 and higher alcohols fatty acid ester Complex defoamer 0.2 ~ 0.6.
According to above-mentioned film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, hexichol Ethylene type fluorescent whitening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fatty acid ester compounded thing defoamer 0.5。
According to the preparation method of above-mentioned film coating, it comprises the following steps: is mixed by the raw material of composition described above, is placed in Reactant liquor, in 150～400 DEG C of melting reactions 0.5～2h, is taken out and is cooled to room temperature, coat on base stock, i.e. by closed reactor Available described film coating.
Compared with prior art, beneficial effects of the present invention:
Film coating adhesive force of the present invention is good, water-fast and light transmittance is high, and film coating prepared by the present invention can make phase for photograph Sheet image has height anti-corrosive properties and anti-ultraviolet erosion, and for a long time Chang Xin is will never fade, do not turn yellow, more can increase strong Third dimension, produces beyond thought effect.
Detailed description of the invention
By the following examples present disclosure is further described, but be not limited to these embodiments.
Raw material used in following example is commercially available.
Embodiment 1
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80 ~ 100, pure water 550 ~ 600, hexichol second Ene-type fluorescent whitening agent 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~ 1.5 and higher alcohols fatty acid ester compounded thing froth breaking Agent 0.2 ~ 0.6.
The preparation method of described film coating, it comprises the following steps: is mixed by the raw material of composition described above, is placed in airtight Reactant liquor, in 150～400 DEG C of melting reactions 0.5～2h, is taken out and is cooled to room temperature, coat on base stock by reactor, To described film coating.
Embodiment 2
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, Stilbene-based fluorescence Brightening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 3
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80, pure water 550, Stilbene-based fluorescence Brightening agent 2.5, polyoxyethylene polyoxypropylene block copolymer 0.9 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 4
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 85, pure water 570, Stilbene-based fluorescence Brightening agent 2.5, polyoxyethylene polyoxypropylene block copolymer 1.2 and higher alcohols fatty acid ester compounded thing defoamer 0.4.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 5
A kind of film coating, it is made up of following raw material: polyvinyl alcohol: 120, pure water 700, Stilbene-based are glimmering Optical brightener 4, polyoxyethylene polyoxypropylene block copolymer 2 and higher alcohols fatty acid ester compounded thing defoamer 0.7.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 6
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 110, pure water 620, Stilbene-based are glimmering Optical brightener 3.6, polyoxyethylene polyoxypropylene block copolymer 1.8 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 7
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 95, pure water 560, Stilbene-based fluorescence Brightening agent 2.2, polyoxyethylene polyoxypropylene block copolymer 0.6 and higher alcohols fatty acid ester compounded thing defoamer 0.9.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 8
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 105, pure water 540, Stilbene-based are glimmering Optical brightener 2.7, polyoxyethylene polyoxypropylene block copolymer 0.5 and higher alcohols fatty acid ester compounded thing defoamer 0.7.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 9
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 115, pure water 650, Stilbene-based are glimmering Optical brightener 4.5, polyoxyethylene polyoxypropylene block copolymer 1.6 and higher alcohols fatty acid ester compounded thing defoamer 0.5.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 10
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 95, pure water 510, Stilbene-based fluorescence Brightening agent 3, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 11
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 80, pure water 590, Stilbene-based fluorescence Brightening agent 2.8, polyoxyethylene polyoxypropylene block copolymer 2.2 and higher alcohols fatty acid ester compounded thing defoamer 0.4.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 12
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 86, pure water 530, Stilbene-based fluorescence Brightening agent 4.1, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 13
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 94, pure water 620, Stilbene-based fluorescence Brightening agent 4.4, polyoxyethylene polyoxypropylene block copolymer 1.9 and higher alcohols fatty acid ester compounded thing defoamer 0.6.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 14
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 103, pure water 640, Stilbene-based are glimmering Optical brightener 2.5, polyoxyethylene polyoxypropylene block copolymer 1.5 and higher alcohols fatty acid ester compounded thing defoamer 0.9.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 15
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 90, pure water 600, Stilbene-based fluorescence Brightening agent 2.2, polyoxyethylene polyoxypropylene block copolymer 1.4 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Embodiment 16
A kind of film coating, it is made up of following raw material: polyvinyl alcohol 106, pure water 680, Stilbene-based are glimmering Optical brightener 4.3, polyoxyethylene polyoxypropylene block copolymer 1.3 and higher alcohols fatty acid ester compounded thing defoamer 0.3.
The preparation method of the present embodiment is same as in Example 1.
Above-mentioned for the preferred embodiment of the present invention, in the present invention limited without departing from claims appended by the present invention In scope, any the change in form and details present invention done, broadly fall into protection scope of the present invention.

Claims (4)

1. a film coating, it is characterised in that it is made up of following raw material: polyvinyl alcohol 80 ~ 120, pure water 500 ~ 700, Stilbene-based Fluorescent Brighteners 2 ~ 5, polyoxyethylene polyoxypropylene block copolymer 0.5 ~ 2 and higher alcohols fatty acid Ester complexes defoamer 0.2 ~ 1.
Film coating the most according to claim 1, it is characterised in that it is made up of following raw material: polyvinyl alcohol 80 ~ 100, pure water 550 ~ 600, Stilbene-based Fluorescent Brighteners 2 ~ 3, polyoxyethylene polyoxypropylene block copolymer 0.8 ~ 1.5 and higher alcohols fatty acid ester compounded thing defoamer 0.2 ~ 0.6.
Film coating the most according to claim 1, it is characterised in that it is made up of following raw material: polyvinyl alcohol 90, pure water 600, Stilbene-based Fluorescent Brighteners 3, polyoxyethylene polyoxypropylene block copolymer 1.0 and higher alcohols fat Acid esters complex defoamer 0.5.
The preparation method of film coating the most according to claim 1, it is characterised in that it comprises the following steps: by above group The raw material mixing become, is placed in closed reactor in 150～400 DEG C of melting reactions 0.5～2h, is taken out by reactant liquor and be cooled to room Temperature, coats on base stock, i.e. can get described film coating.
CN201610462183.8A 2016-06-23 2016-06-23 A kind of film coating and preparation method thereof Pending CN106087546A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610462183.8A CN106087546A (en) 2016-06-23 2016-06-23 A kind of film coating and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610462183.8A CN106087546A (en) 2016-06-23 2016-06-23 A kind of film coating and preparation method thereof

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Publication Number Publication Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106638139A (en) * 2016-12-09 2017-05-10 苏州艾博迈尔新材料有限公司 Compound oil-proofing agent for paper and preparation method of compound oil-proofing agent

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1890312A (en) * 2003-12-09 2007-01-03 塞拉尼斯国际公司 Optical brightener and method of preparing it
CN101068982A (en) * 2004-11-29 2007-11-07 集伟纸业化工股份有限公司 Sheet of high whiteness degree
CN101155962A (en) * 2005-04-08 2008-04-02 克莱里安特财务(Bvi)有限公司 Aqueous solutions of optical brighteners
CN102729682A (en) * 2012-07-16 2012-10-17 江苏泰特尔化工有限公司 Anti-aging, highlight and waterproof ahead-spraying lamp-house piece

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1890312A (en) * 2003-12-09 2007-01-03 塞拉尼斯国际公司 Optical brightener and method of preparing it
CN101068982A (en) * 2004-11-29 2007-11-07 集伟纸业化工股份有限公司 Sheet of high whiteness degree
CN101155962A (en) * 2005-04-08 2008-04-02 克莱里安特财务(Bvi)有限公司 Aqueous solutions of optical brighteners
CN102729682A (en) * 2012-07-16 2012-10-17 江苏泰特尔化工有限公司 Anti-aging, highlight and waterproof ahead-spraying lamp-house piece

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106638139A (en) * 2016-12-09 2017-05-10 苏州艾博迈尔新材料有限公司 Compound oil-proofing agent for paper and preparation method of compound oil-proofing agent

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Application publication date: 20161109