CN106085672A - A kind of scavenger - Google Patents

A kind of scavenger Download PDF

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Publication number
CN106085672A
CN106085672A CN201610447578.0A CN201610447578A CN106085672A CN 106085672 A CN106085672 A CN 106085672A CN 201610447578 A CN201610447578 A CN 201610447578A CN 106085672 A CN106085672 A CN 106085672A
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CN
China
Prior art keywords
scavenger
ethanol
solvent
butyl ether
alkene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610447578.0A
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Chinese (zh)
Inventor
刘祥
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610447578.0A priority Critical patent/CN106085672A/en
Publication of CN106085672A publication Critical patent/CN106085672A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/825—Mixtures of compounds all of which are non-ionic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/12—Water-insoluble compounds
    • C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
    • C11D3/1246—Silicates, e.g. diatomaceous earth
    • C11D3/128—Aluminium silicates, e.g. zeolites
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/18—Hydrocarbons
    • C11D3/188—Terpenes
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2003—Alcohols; Phenols
    • C11D3/2006—Monohydric alcohols
    • C11D3/201—Monohydric alcohols linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/667—Neutral esters, e.g. sorbitan esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D1/721—End blocked ethers

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a kind of scavenger, its formula consists of by weight percentage: D alkene 20 40wt.%, emulsifying agent 10 30wt.%, solvent 10 30wt.%, penetrating agent 5 10wt.%, chelating agen 1 5wt.%, deionized water surplus, wherein, described emulsifying agent is sorbitan fatty ester, polyoxyethylene sorbitan monooleate dehydration, fatty alcohol-polyoxyethylene ether, in triethanolamine the most compounding, solvent is ethanol and propandiol butyl ether mixed solvent, penetrating agent is fatty alcohol-polyoxyethylene ether, chelating agen is 4A zeolite, poly-aspartate, one in sodium citrate.The scavenger cleaning performance of the present invention is excellent, had both reduced usage amount, and had also substantially increased cleaning efficiency, and formula is nontoxic, and biological degradability is good, nonirritant volatilization gas.

Description

A kind of scavenger
Technical field
The present invention relates to the scavenger of a kind of environment-protecting asepsis safety, specifically, refer to a kind of " Corii Bovis seu Bubali for adhesive type Tinea " poster paper environment-protecting asepsis safety scavenger.
Background technology
It is the persistent ailment " psoriasis " in city that small advertisement is known as, and effecting a radical cure these persistent ailments becomes government and citizen's headache A great problem, the departments such as current number of ads is a lot, and cleaning gets up to waste time and energy, appearance of the city environmental sanitation have to output specially " little extensively Accuse and rinse special-purpose vehicle " Adlet cleaning machine of specialty, but cleaning machine is big to the waste of water resource, and cost is high；Directly use The mode that scraper is scraped is removed, and not only inconvenient operation but also the amount of labour of workman are big, the most arduously, also have damage to building.City The a little auxiliary cleaning agent cleaning performance occurred on face is inconspicuous, and abluent residue difficult degradation waving with virose Get angry body, as Chinese patent 201110310412.1 discloses a kind of outdoor small advertisement cleaning agent, by following component by weight Composition: dichloromethane 20-40 part, dichloroethanes 15-25 part, tributyl phosphate 15-25 part, phenol 15-20 part, N-methylpyrrole Alkanone 2-4 part, formic acid 15-25 part, NPE 2-6 part, ethylene glycol monobutyl ether 0.2-0.8 part.
Summary of the invention
It is an object of the invention to provide a kind of formula, preparation and application simplicity, the scavenger of environment-friendly type and system thereof Preparation Method, with the deficiency overcoming existing abluent to exist.
The present invention solves its technical problem and uses following technical scheme:
A kind of scavenger of the present invention, its formula consists of by weight percentage: D-alkene 20-40wt.%, emulsifying agent 10-30wt.%, solvent 10-30wt.%, penetrating agent 5-10wt.%, chelating agen 1-5wt.%, deionized water surplus.
Wherein, described emulsifying agent is sorbitan fatty ester (span 80), polyethenoxy sorbitan list In oleate (Tween 80), fatty alcohol-polyoxyethylene ether (AEO-9), triethanolamine the most compounding, solvent is ethanol and propylene glycol Butyl ether mixed solvent, penetrating agent is fatty alcohol-polyoxyethylene ether (JFC), and chelating agen is 4A zeolite, poly-aspartate, sodium citrate In one.
The preparation method of scavenger of the present invention:
1) first load weighted solvent, emulsifying agent, penetrating agent being added in load weighted D-alkene, stir to obtain mixed liquor A；
2) being added in deionized water by load weighted chelating agen, stir to obtain mixed liquid B；
3) step 1 gained mixed liquor A the most slowly being heated up, it is 30 DEG C-40 DEG C that temperature controls.By step 2 gained Mixed liquid B the most at the uniform velocity adds in A, after B is added completely into, stirs to clarify to obtain product.
This scavenger cleaning performance is excellent, has both reduced usage amount, has also substantially increased cleaning efficiency, and formula is nontoxic, raw Thing degradability is good, nonirritant volatilization gas.
Detailed description of the invention
The scavenger of the present invention presses D-alkene 20-40wt.%, emulsifying agent 10-30wt.%, solvent 10-30wt.%, infiltration Agent 5-10wt.%, chelating agen 1-5wt.%, deionized water surplus weighs, and is prepared as follows:
1) first load weighted solvent, emulsifying agent, penetrating agent being added in load weighted D-alkene, stir to obtain mixed liquor A；
2) being added in deionized water by load weighted chelating agen, stir to obtain mixed liquid B；
3) step 1 gained mixed liquor A the most slowly being heated up, it is 30 DEG C-40 DEG C that temperature controls.By step 2 gained Mixed liquid B the most at the uniform velocity adds in A, after B is added completely into, stirs to clarify to obtain product.
The raw material that the embodiment of the present invention is used is the commercially available raw material of industry.
Embodiment 1
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 40%, emulsifying agent 15% (wherein Tween 80, the mass ratio of AEO-9 are 1:1), solvent 30% (wherein ethanol, propandiol butyl ether mass ratio 1:2, penetrating agent 10% selects JFC, and chelating agen selects poly-aspartate 5%, deionized water surplus, is prepared as follows:
Load weighted solvent, emulsifying agent, penetrating agent, chelating agen are added in load weighted D-alkene, stirs to clarify Product.
The present embodiment is sprayed on advertisement or Sticker, soaks 15 seconds and is i.e. completely removed.
Embodiment 2
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 20%, emulsifying agent 20% (wherein AEO-9, the mass ratio of triethanolamine are 4:1), solvent 25% (wherein ethanol, propandiol butyl ether mass ratio are 1:4), oozes Agent 5% (JFC) thoroughly, chelating agen 5% (sodium citrate), deionized water surplus weighs, and is prepared as follows:
1) first load weighted solvent, emulsifying agent, penetrating agent being added in load weighted D-alkene, stir to obtain mixed liquor A；
2) being added in deionized water by load weighted chelating agen, stir to obtain mixed liquid B；
3) step 1 gained mixed liquor A the most slowly being heated up, it is 30 DEG C-40 DEG C that temperature controls.By step 2 gained Mixed liquid B the most at the uniform velocity adds in A, after B is added completely into, stirs to clarify to obtain product.
This reagent is sprayed on advertisement or Sticker, soaks 57 seconds and is i.e. completely removed.
Embodiment 3
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 25%, emulsifying agent 20% (wherein span 80, Tween 80 mass ratio are 1:2), solvent 30% (wherein ethanol, propandiol butyl ether mass ratio 1:1), penetrating agent (JFC) 8%, chelating agen (4A zeolite) 5%, deionized water surplus weighs, and preparation method is with embodiment 2.
The present embodiment is sprayed on advertisement or Sticker, soaks 53 seconds and is i.e. completely removed.
Embodiment 4
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 30%, emulsifying agent (this dish 80:AEO-9=2:5) 20%, solvent 30% (wherein ethanol, propandiol butyl ether mass ratio are 1:1), penetrating agent (JFC) 8%, chela Mixture (4A zeolite) 5%, deionized water surplus weighs, and preparation method is with embodiment 2.The present embodiment is sprayed at advertisement or business On label paster, soak 33 seconds and be i.e. completely removed.
Embodiment 5
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 30%, emulsifying agent 10% (wherein span 80, triethanolamine mass ratio are 1:3), solvent 20% (wherein ethanol, propandiol butyl ether mass ratio are 2:3), oozes Agent (JFC) 5% thoroughly, chelating agen (poly-aspartate) 5%, deionized water surplus weighs, and preparation method is with embodiment 2.This Embodiment is sprayed on advertisement or Sticker, soaks 41 seconds and is i.e. completely removed.
Embodiment 6
The scavenger of the present embodiment, by weight percentage, is made up of following raw material: D-alkene 20%, emulsifying agent 20% (wherein Tween 80, triethanolamine mass ratio are 1:1), solvent 25% (wherein ethanol, propandiol butyl ether mass ratio are 3:2), oozes Agent (JFC) 6% thoroughly, chelating agen (sodium citrate) 6%, deionized water surplus weighs, and preparation method is with embodiment 2.This reality Execute example to be sprayed on advertisement or Sticker, soak 52 seconds and be i.e. completely removed.
This product method of testing: with the poster paper of the band adhesive sticker of standard A7 size, be affixed on glass, metope, metal surface, Contrast checkout time by each embodiment, show that elimination effect, concrete data ask for an interview subordinate list 1:
Subordinate list 1
Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Embodiment 5 Embodiment 6 Commercially available
Glass 15s 57s 53s 39s 41s 67s 243s
Metope 20s 61s 58s 44s 49s 75s 262s
Metal 14s 53s 50s 37s 39s 62s 238s

Claims (5)

1. a scavenger, it is characterised in that mixed by weight percentage by following component: D-alkene 20-40%, emulsifying Agent 10-30%, solvent 10-30%, penetrating agent 5-10%, chelating agen 1-5%, deionized water surplus；
Wherein, described emulsifying agent is sorbitan fatty ester, polyoxyethylene sorbitan monooleate dehydration, fatty alcohol Arbitrarily compounding in polyoxyethylene ether, triethanolamine, solvent is the mixed solvent of ethanol and propandiol butyl ether, and penetrating agent is fat Polyoxyethylenated alcohol, chelating agen is any one in 4A zeolite, poly-aspartate, sodium citrate.
Scavenger the most according to claim 1, it is characterised in that above-mentioned scavenger is replaced with by following weight percentage ratio Component constitute: D-alkene 40%；Tween 80, AEO-9 blended emulsifier 15%, wherein Tween 80, the mixing ratio of AEO-9 are 1: 1；Ethanol, propandiol butyl ether mixing 30%, wherein ethanol, propandiol butyl ether mixing ratio 1:2；JFC10%；Poly-aspartate 5%, Deionized water surplus.
Scavenger the most according to claim 1, it is characterised in that above-mentioned scavenger is replaced with by following weight percentage ratio Component constitute: D-alkene 20%；AEO-9, triethanolamine blended emulsifier 20%, wherein AEO-9, triethanolamine mixing ratio are 4:1；Ethanol, propandiol butyl ether mixed solvent 25%, wherein ethanol, propandiol butyl ether mixing ratio are 1:4；JFC5%；Citric acid Sodium 5%；Deionized water surplus.
Scavenger the most according to claim 1, it is characterised in that above-mentioned scavenger is replaced with by following weight percentage ratio Component constitute: D-alkene 25%；Span 80, Tween 80 blended emulsifier 20%, wherein span 80, Tween 80 mixing ratio are 1: 2；Ethanol, propandiol butyl ether mixed solvent 30%；Wherein ethanol, propandiol butyl ether mixing ratio 1:1, JFC8%, 4A zeolite 5%, Deionized water surplus.
5. according to the scavenger described in claim 1-4, it is characterised in that the preparation method of described scavenger includes following step Rapid:
1) first load weighted solvent, emulsifying agent, penetrating agent being added in load weighted D-alkene, stir to obtain mixed liquor A；
2) being added in deionized water by load weighted chelating agen, stir to obtain mixed liquid B；
3) step 1 gained mixed liquor A the most slowly being heated up, it is 30 DEG C-40 DEG C that temperature controls.Step 2 gained is mixed Liquid B the most at the uniform velocity adds in A, after B is added completely into, stirs to clarify to obtain product.
CN201610447578.0A 2016-06-21 2016-06-21 A kind of scavenger Pending CN106085672A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610447578.0A CN106085672A (en) 2016-06-21 2016-06-21 A kind of scavenger

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Application Number Priority Date Filing Date Title
CN201610447578.0A CN106085672A (en) 2016-06-21 2016-06-21 A kind of scavenger

Publications (1)

Publication Number Publication Date
CN106085672A true CN106085672A (en) 2016-11-09

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Country Status (1)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108260799A (en) * 2018-01-17 2018-07-10 上海美农生物科技股份有限公司 Mixed emulsifier and its application
CN108624412A (en) * 2018-06-12 2018-10-09 上海申仰实业有限公司 A kind of oil greasy dirt detergent
CN108715775A (en) * 2018-06-12 2018-10-30 上海申仰实业有限公司 A kind of mechanical equipment detergent
CN111073768A (en) * 2019-12-15 2020-04-28 华中科技大学同济医学院附属协和医院 Medical sol and preparation method thereof
CN111979059A (en) * 2020-08-31 2020-11-24 上海申仰实业有限公司 Cleaning agent
CN115287126A (en) * 2022-07-15 2022-11-04 中山市天图精细化工有限公司 Low-VOC adhesive removing agent spray

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108260799A (en) * 2018-01-17 2018-07-10 上海美农生物科技股份有限公司 Mixed emulsifier and its application
CN108624412A (en) * 2018-06-12 2018-10-09 上海申仰实业有限公司 A kind of oil greasy dirt detergent
CN108715775A (en) * 2018-06-12 2018-10-30 上海申仰实业有限公司 A kind of mechanical equipment detergent
CN111073768A (en) * 2019-12-15 2020-04-28 华中科技大学同济医学院附属协和医院 Medical sol and preparation method thereof
CN111073768B (en) * 2019-12-15 2021-05-14 华中科技大学同济医学院附属协和医院 Medical sol and preparation method thereof
CN111979059A (en) * 2020-08-31 2020-11-24 上海申仰实业有限公司 Cleaning agent
CN115287126A (en) * 2022-07-15 2022-11-04 中山市天图精细化工有限公司 Low-VOC adhesive removing agent spray
CN115287126B (en) * 2022-07-15 2023-12-05 中山市天图精细化工有限公司 Low-VOC (volatile organic compound) adhesive removing agent spray

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Application publication date: 20161109

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