CN106085319A - A kind of dual cure transfer film, then glue composition and preparation method thereof - Google Patents
A kind of dual cure transfer film, then glue composition and preparation method thereof Download PDFInfo
- Publication number
- CN106085319A CN106085319A CN201610415084.4A CN201610415084A CN106085319A CN 106085319 A CN106085319 A CN 106085319A CN 201610415084 A CN201610415084 A CN 201610415084A CN 106085319 A CN106085319 A CN 106085319A
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- China
- Prior art keywords
- transfer film
- dual cure
- resin
- glue composition
- glue
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
- C09J163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
- C09J175/04—Polyurethanes
- C09J175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Adhesive Tapes (AREA)
Abstract
The invention discloses a kind of dual cure transfer film, then glue composition and preparation method.It is configured to 40% resin solution with solvent, remixes 5 45 parts of activated monomers and 0.1 5 parts of light triggers, be eventually adding 0.1 3 parts of auxiliary agents and be uniformly mixing to obtain then glue composition.Then glue composition is coated on the carrier PET film layer containing functional layer, obtain dual cure transfer film.The transfer film of the present invention compares heat cure and single photocuring transfer film, has the advantages such as the saving energy, low VOC emission, curing rate be fast, and former hot stamping process and roasting plant can be kept constant, have useful technique effect.
Description
Technical field
The present invention relates to printing technology, be specifically related to a kind of can the silicate product surface such as thermoprint glass and pottery
Dual cure transfer film, the then glue composition and preparation method thereof on transfer film.
Background technology
The trailing on the silicate product surfaces such as glass and pottery is a lot, such as, and direct silk bat printing, spraying, printer
Print, plating or vacuum sputtering is aluminized, the spray on surface or stamp then after glue reheating turn thermoprint method, water transfer or heat sublimation side
Method, etc..In these methods, the method for direct silk bat printing is to obtain that picture and text are the simplest and the best approach, but is difficult to stamp thin
The level picture and text of small photo effect, for the adhesion obtained after printing, it is necessary to be heating and curing；Decoration side by spraying
The picture and text that method obtains, are largely used to decoration industry, but spray coating process cause to people's pollution to environment, picture and text are difficult to
Unified sizing, is weak point；The method printed by printer, the goods being suitable for plane or almost plane moulding obtain exquisiteness
Unified picture and text, but speed is slow, cost is high, be difficult to industrialized production；The method aluminized by plating or vacuum sputtering, Quan Mianfu
Cover metal color, get the favour of people, but express picture and text and have the biggest difficulty；By the spray on surface or stamp then after glue
Reheating turns thermoprint method, such as anodized aluminium golden in thermoprint, obtains metal color picture and text, particularly clear glass product surface and uses gold
The pattern decoration of silver color anodized aluminium, is exactly always a kind of trailings of liking of people.Picture and text periphery after this method thermoprint is the most not
There will be vestige, but this technique is the most complicated but also is difficult to reach exquisite fine and smooth pattern decoration effect.
The patent of invention of Patent No.: ZL200410015590.1, it is proposed that glass article surface is directly transferred
New trailing, efficiently solve being beautifully printed and save energy the two technical barrier, but also needing to through one
The high temperature (200 DEG C) of section time processes.If energy consumption can be reduced further, that will more meet the requirement of energy-saving, emission-reducing, environment friendly.
Summary of the invention
It is an object of the invention to overcome the deficiencies in the prior art, it is provided that one both can directly thermoprint in glass table
The dual cure transfer film in face, under keeping the constant premise of former hot stamping process and roasting plant, as long as increasing ultraviolet curing
The problem that equipment just can reach more energy efficient environmental protection.Another object of the present invention also resides in provides the then glue preparing this transfer film
Compositions and preparation method thereof.
The present invention solves the problems referred to above and be the technical scheme is that
The present invention provides the then glue composition of a kind of dual cure transfer film, it is characterised in that include following weight portion
Component:
Wherein, resin is epoxy resin, acrylic resin, acrylic modified epoxy resin, polyurethane resin, polyester tree
At least one in fat, and the softening point of resin is less than the solid of 160 DEG C or thick liquid thermoplastic resin；Resin has been adjusted to
After effect composition 40wt% resin, independent or mixing content is 40-70 weight portion, and preferred content is 45-65 weight portion.
Described monomer is at least one in bifunctional acrylate's class monomer, trifunctional group acrylate's class monomer,
Independent or mixing content is 5-45 weight portion, and preferred content is 10-40 weight portion.
Described light trigger is free radical photo-initiation and cation light initiator, and described free radical photo-initiation is
At least one in lrgacure-1173, lrgacure-184, lrgacure-369；Described cation light initiator is
At least one in Omnicat-440, Omnicat-445.Independent or mixing content is 0.1-5 weight portion, preferred content
For 0.5-1.0 weight portion.
Described auxiliary agent is levelling agent, defoamer.
Present invention additionally comprises the preparation method of the then glue composition of a kind of above-mentioned dual cure transfer film, specifically, use
Described solvent is configured to 40% resin solution, remixes described activated monomer and described light trigger, is eventually adding described auxiliary agent
It is uniformly mixing to obtain the then glue composition of dual cure transfer film.
Present invention additionally comprises the dual cure transfer film containing above-mentioned then glue, its cross section structure includes successively:
The one carrier PET film layer with release performance；
One posts the functional layer investing carrier PET film layer, and this functional layer includes sealer and or thermostability ergosphere and
Or color rendering properties ergosphere and or three-dimensional coating；
One aforementioned then glue-line, the described adhesive property of ultra-violet curing again after then glue has transfer.
Wherein, described UV curing method is under the ultraviolet lamp tube that power is 1000W, distance 10cm, illumination 10-20s.
Compared with prior art, the invention has the beneficial effects as follows: the transfer film of the present invention compares heat cure and single light
Curing transfer film, has the advantages such as the saving energy, low VOC emission, curing rate be fast, and can keep former hot stamping process and baking
Roasting equipment is constant, has useful technique effect.
Detailed description of the invention
Embodiment 1
Weighing 5g bisphenol A epoxide resin, 5g urethane acrylate is put in beaker as matrix resin, and wherein
Add acetone and the butanone mixed solvent of the mixing of 15g 1:1 ratio, system is stirred on heat collecting type constant-temperature heating magnetic stirring apparatus
Mix uniformly, be configured to the solution 25g of solid content 40%；
Weigh in TPGDA (two degree of functionality activated monomers) 6g, TMPTA (three-functionality-degree activated monomer) 6.5g addition system and stir
Mix uniformly；
Weigh free radical photo-initiation lrgacure-184 0.4g, lrgacure-651 0.5g, cation light initiator
Omnicat-440 0.25g joins in system, stirs；
Weigh levelling agent 0.2g, defoamer 0.2g to join in system, stir；
Mixed solution stands 10min, utilizes bar spreader to be coated on uniformly in the PET film luring picture and text；100℃
Hot blast removes solvent, is dried；Clean glass surface, it is ensured that surface does not has dust greasy dirt, dry；Pattern is transferred by transfer interpreter
On sheet glass, dry 5min for 100 DEG C；In the UV curing of 1000W, lamp, away from 10cm, illumination 20s, i.e. obtains end product.
Carrying out adhesive force test according to GB/T 9,286 1998 " cross cut test of paint and varnish-paint film ", paint film is from drawing
The area come off on the ground of lattice region to judge adhesive force grade for 1, adhesive force is excellent；
Recording according to GB/T 6739-1996 " hardness of film pencil algoscopy ", the hardness of film layer is 2H；
According to GB/T 1733-93 " paint film resistance to water algoscopy ", immersion 24h film layer does not falls off.
Embodiment 2
Weighing 5g bisphenol A epoxide resin, 5g epoxy acrylate is put in beaker as matrix resin, and is added wherein
Enter acetone and the butanone mixed solvent of the mixing of 15g 1:1 ratio, system is stirred on heat collecting type constant-temperature heating magnetic stirring apparatus
Uniformly, the solution 25g of solid content 40% it is configured to；
Weigh in TPGDA (two degree of functionality activated monomers) 10g, TMPTA (three-functionality-degree activated monomer) 10g addition system and stir
Mix uniformly；
Weigh free radical photo-initiation lrgacure-184 0.4g, lrgacure-651 0.5g, cation light initiator
Omnicat-440 0.5g joins in system, stirs；
Weigh levelling agent 0.2g, defoamer 0.2g to join in system, stir；
Mixed solution stands 10min, utilizes bar spreader to be coated on the PET film with thermostability ergosphere uniformly
On；100 DEG C of hot blasts remove solvent, are dried；Clean glass surface, it is ensured that surface does not has dust greasy dirt, dry；Will on transfer interpreter
Pattern is transferred on sheet glass, dries 5min for 100 DEG C；In the UV curing of 1000W, lamp, away from 10cm, illumination 15s, i.e. obtains
Rear finished product.
Carrying out adhesive force test according to GB/T 9,286 1998 " cross cut test of paint and varnish-paint film ", paint film is from drawing
The area come off on the ground of lattice region is to judge that adhesive force grade is 2 grades, and adhesive force is good；
Recording according to GB/T 6739-1996 " hardness of film pencil algoscopy ", the hardness of film layer is 3H；
According to GB/T 1733-93 " paint film resistance to water algoscopy ", immersion 24h film layer does not falls off.
Embodiment 3
Weighing 5g bisphenol A epoxide resin, 5g urethane acrylate, 5g epoxy acrylate is put into as matrix resin
In beaker, and it is added thereto to acetone and the butanone mixed solvent that 10g 1:1 ratio mixes, by system in heat collecting type heated at constant temperature
Stir on magnetic stirring apparatus, be configured to the solution 25g of solid content 40%；
Weigh in TPGDA (two degree of functionality activated monomers) 5g, TMPTA (three-functionality-degree activated monomer) 5g addition system and stir
Uniformly；
Weigh free radical photo-initiation lrgacure-184 0.5g, lrgacure-651 0.5g, cation light initiator
Omnicat-440 0.5g joins in system, stirs；
Weigh levelling agent 0.2g, defoamer 0.2g to join in system, stir；
Mixed solution stands 10min, utilizes bar spreader to be coated on the PET film with color rendering properties ergosphere uniformly
On；100 DEG C of hot blasts remove solvent, are dried；Clean glass surface, it is ensured that surface does not has dust greasy dirt, dry；Will on transfer interpreter
Pattern is transferred on glass, dries 5min for 100 DEG C；In the UV curing of 1000W, lamp, away from 10cm, illumination 10s, i.e. obtains
End product.
Carrying out adhesive force test according to GB/T 9,286 1998 " cross cut test of paint and varnish-paint film ", paint film is from drawing
The area come off on the ground of lattice region is to judge that adhesive force grade is 0 grade, and adhesive force is excellent；
Recording according to GB/T 6739-1996 " hardness of film pencil algoscopy ", the hardness of film layer is 3H；
According to GB/T 1733-93 " paint film resistance to water algoscopy ", immersion 24h film layer does not falls off.
Embodiment 4
Weighing 10g bisphenol A epoxide resin, 5g epoxy acrylate is put in beaker as matrix resin, and wherein
Add acetone and the butanone mixed solvent of the mixing of 10g 1:1 ratio, system is stirred on heat collecting type constant-temperature heating magnetic stirring apparatus
Mix uniformly, be configured to the solution 25g of solid content 40%；
Weigh in TPGDA (two degree of functionality activated monomers) 5g, TMPTA (three-functionality-degree activated monomer) 5g addition system and stir
Uniformly；
Weigh free radical photo-initiation lrgacure-184 0.3g, lrgacure-651 0.3g, cation light initiator
Omnicat-440 0.5g joins in system, stirs；
Weigh levelling agent 0.2g, defoamer 0.2g to join in system, stir；
Mixed solution stands 10min, utilize bar spreader be coated on uniformly there is sealer lure three-dimensional
In the PET film of picture and text；100 DEG C of hot blasts remove solvent, are dried；Clean glass surface, it is ensured that surface does not has dust greasy dirt, dry
Dry；Transfer interpreter transfers pattern on glass, dry 5min for 100 DEG C；In the UV curing of 1000W, lamp away from 10cm,
Illumination 20s, i.e. obtains end product.
Carrying out adhesive force test according to GB/T 9,286 1998 " cross cut test of paint and varnish-paint film ", paint film is from drawing
The area come off on the ground of lattice region is to judge that adhesive force grade is 1 grade, and adhesive force is excellent；
Recording according to GB/T 6739-1996 " hardness of film pencil algoscopy ", the hardness of film layer is 2H；
According to GB/T 1733-93 " paint film resistance to water algoscopy ", immersion 24h film layer does not falls off.
It can be that professional and technical personnel in the field realize or use, to above-mentioned that above-mentioned embodiment is intended to illustrate the present invention
Embodiment is modified and be will be apparent from for those skilled in the art, therefore the present invention includes but not limited to
Above-mentioned embodiment, any the claims or description of meeting describes, meet with principles disclosed herein and novelty,
The method of inventive features, technique, product, within each falling within protection scope of the present invention.
Claims (6)
1. the then glue composition of a dual cure transfer film, it is characterised in that include the component of following weight portion:
Wherein, during resin is epoxy resin, acrylic resin, acrylic modified epoxy resin, polyurethane resin, polyester resin
At least one, and the softening point of resin is less than the solid of 160 DEG C or thick liquid thermoplastic resin；Described light trigger is certainly
By base light trigger and cation light initiator, described free radical photo-initiation is lrgacure-1173, lrgacure-184,
At least one in lrgacure-369；Described cation light initiator be in Omnicat-440, Omnicat-445 at least
A kind of.
Then the glue composition of dual cure transfer film the most according to claim 1, it is characterised in that described activated monomer
For at least one in bifunctional acrylate's class monomer, trifunctional group acrylate's class monomer.
Then the glue composition of dual cure transfer film the most according to claim 1, it is characterised in that described auxiliary agent is stream
Flat agent, defoamer.
4. the preparation method of the then glue composition of dual cure transfer film described in claim 1, it is characterised in that with described molten
Agent is configured to 40% resin solution, remixes described activated monomer and described light trigger, is eventually adding the stirring of described auxiliary agent all
The even then glue composition obtaining dual cure transfer film.
5. containing the dual cure transfer film of then glue described in claim 1, its cross section structure includes successively:
The one carrier PET film layer with release performance；
One posts the functional layer investing carrier PET film layer, and this functional layer includes sealer and or thermostability ergosphere and or aobvious
Color performance layer and or three-dimensional coating；
Then glue-line described in one claim 1；The described adhesive property of ultra-violet curing again after then glue has transfer.
Dual cure transfer film the most according to claim 5, it is characterised in that described UV curing method is at power to be
Under the ultraviolet lamp tube of 1000W, distance 10cm, illumination 10-20s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610415084.4A CN106085319A (en) | 2016-06-14 | 2016-06-14 | A kind of dual cure transfer film, then glue composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610415084.4A CN106085319A (en) | 2016-06-14 | 2016-06-14 | A kind of dual cure transfer film, then glue composition and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106085319A true CN106085319A (en) | 2016-11-09 |
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| CN201610415084.4A Pending CN106085319A (en) | 2016-06-14 | 2016-06-14 | A kind of dual cure transfer film, then glue composition and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109263388A (en) * | 2018-09-21 | 2019-01-25 | 中广核达胜加速器技术有限公司 | A kind of package material surface transfer processing method |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385372A (en) * | 2015-11-06 | 2016-03-09 | 东莞职业技术学院 | Sealing film and packaging product using sealing film |
-
2016
- 2016-06-14 CN CN201610415084.4A patent/CN106085319A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105385372A (en) * | 2015-11-06 | 2016-03-09 | 东莞职业技术学院 | Sealing film and packaging product using sealing film |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109263388A (en) * | 2018-09-21 | 2019-01-25 | 中广核达胜加速器技术有限公司 | A kind of package material surface transfer processing method |
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Application publication date: 20161109 |