CN106085220A - A kind of preparation method and applications of organic silicon flame-retardant fireproof coating - Google Patents
A kind of preparation method and applications of organic silicon flame-retardant fireproof coating Download PDFInfo
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- CN106085220A CN106085220A CN201610315736.7A CN201610315736A CN106085220A CN 106085220 A CN106085220 A CN 106085220A CN 201610315736 A CN201610315736 A CN 201610315736A CN 106085220 A CN106085220 A CN 106085220A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to fireproof coating technical field, poor for solving the combustible material fire saveties such as architecture exterior wall insulating materials, problem the most aging, incendive, the present invention proposes the preparation method and applications of a kind of organic silicon flame-retardant fireproof coating, a kind of organic silicon flame-retardant fireproof coating is made up of following component, and the weight portion of each component is: organic siliconresin 40 70, auxiliary agent: 20 40, fire-retardant filler: 0 15, catalyst: 4 x10‑4‑50 x10‑4.With organic siliconresin for matrix be prepared for no-solvent type low viscosity and can the organosilicon coating of room temperature fast-curing, be possible not only to combustible material is realized the effect of fire-retardant fireproof, and there is preferable non-deformability and adhesive property.
Description
Technical field
The present invention relates to fireproof coating technical field, specifically design the preparation method and applications of a kind of no-solvent type cold curing organic silicon flame-retardant fireproof coating.
Background technology
At present, architecture exterior wall insulating materials is the main material of insulation, is widely used.The organic insulation material used mainly includes styrofoam (EPS), extruded sheet (XPS) and polyurethane (PU) three kinds, and the advantage of its maximum is that light weight, insulation, thermal insulation are good.But it is poor that the defect of maximum is fire savety, the most aging, easy firing.Such as, CCTV's building fire just comes from and have employed the most fire-retardant organic insulation material.These materials, while causing extensive fire, because of imperfect combustion and pyrolysis, can produce more flue dust and toxic gas, and in fire incident, majority suck cigarette just and toxic gas is died of asphyxiation.Therefore, architecture exterior wall insulating materials fire risk is high, easily causes major casualties.
Containing " silicon-oxygen-silicon " structure in the backbone structure of organic siliconresin, side chain contains a small amount of organic group, thus it has the organic and two-fold advantage of inorganic material concurrently, resistance to elevated temperatures, resistance to irradiation and weather-proof ability, in combustion process, heat is little, the amount of being fuming is little, do not discharge toxic gas and have self-extinguishment in release.Therefore, the fire resistant flame retardant performance of organic siliconresin is much better than carbon back macromolecular material such as polypropylene, polyurethane, epoxy resin etc..Utilizing silicone resin coating can realize while conventional carbon base polymer foam fire resistance and will not produce a large amount of harmful gas, meet environmental requirement, display has market prospect widely.
Traditional method mainly utilizes fire retardant to add in foam of polymers and realizes flame retardant effect.As patent CN104974527A discloses the preparation method and applications of a kind of organic siliconresin polymer-modified foam flame-proof composite material, the method uses solid content to be the machine silicon resin solution of 30-80%, and combines filler and achieve the fire retardation to polyurethane foam；But the method uses organic solvent, and needs low-temperature setting in use, to a certain degree limit its application.In order to be pushed further into the application of environment-friendly type organosilicon fire retardant, the organic silicon flame-retardant fireproof coating of exploitation no-solvent type and ambient temperature curable is imperative.
Summary of the invention
Poor for solving the combustible material fire saveties such as architecture exterior wall insulating materials, problem the most aging, incendive, the present invention proposes the preparation method and applications of a kind of organic silicon flame-retardant fireproof coating, it is prepared for no-solvent type low viscosity and can the organosilicon coating of room temperature fast-curing for matrix with organic siliconresin, it is possible not only to combustible material is realized the effect of fire-retardant fireproof, and there is preferable non-deformability and adhesive property.
The present invention is achieved by the following technical solutions: a kind of organic silicon flame-retardant fireproof coating is made up of following component, and the weight portion of each component is: organic siliconresin 40-70, auxiliary agent: 20-40, fire-retardant filler: 0-15, catalyst: 4 x10-4-50 x10-4。
Organic siliconresin is selected from having one or more in different side chain and molecular weight.As preferably, organic siliconresin is selected from MQ resin, phenyl polysiloxane, vinyl polysiloxane, Silicon Containing Hydrogen resin, in methyl silicon resin one or more.
Described auxiliary agent is low viscosity auxiliary agent, in silane coupler or silicone oil one or more.As preferably, silane coupler is selected from KH550, KH560, KH570 one or more；Described silicone oil is selected from the vinyl silicone oil of different viscosities, containing hydrogen silicone oil one or more, and silicone oil is more preferably phenyl silicone oil, containing hydrogen silicone oil etc., silicone rubber, alkynyl ring alcohol, 3,7,11-trimethyl dodecyne-3-alcohol, one or more in 1-ethynylcyclohexanol etc..
One or more in nano silicon, Graphene, magnesium hydroxide, sodium aluminosilicate, montmorillonite, aluminium hydroxide, expanded graphite alkene, laminar silicic acid hydrochlorate, boron nitride, antimonial, molybdenum compound etc. of described fire-retardant filler.
One or more in chloroplatinic acid, platinum catalyst and complex of described catalyst.
The preparation method of described a kind of organic silicon flame-retardant fireproof coating is following steps:
(1) first by organic siliconresin, fire-retardant filler, auxiliary agent mixing, the component A of organic silicon flame-retardant fireproof coating is prepared；Organic siliconresin is mixed with catalyst simultaneously, prepare the B component of organic silicon flame-retardant fireproof coating；
(2) when using, after AB part is mixed, by spraying or be stained with the physics painting methods such as painting to combustible material surface, solidify 15-120 minute at ambient temperature.
The present invention uses this method on the skeleton surface that organic siliconresin is wrapped in conventional urethane open-cell foam materials, good high temperature resistant of organic siliconresin is utilized to be prepared for low viscosity organic silicon flame-retardant fireproof coating, organic siliconresin consumption in A, B part is determined by the viscosity of required organic silicon flame-retardant fireproof coating, total amount in the range of just can reach the purpose of fire protection flame retarding, in A, B component, organic siliconresin may be the same or different kind.
The present invention is with organic siliconresin as matrix, in conjunction with low viscosity auxiliary agent and catalyst, being prepared for no-solvent type silicone resin coating, this coating not only can realize the performance such as room temperature fast-curing, fire-retardant fireproof, and has good adhesive property, hydrophobic performance and deformability.Based on the high temperature resistant and heat stability that organic siliconresin is good, described a kind of environment-friendly type organosilicon fire-retardant fireproof coating application on combustible material surface in the fields such as architecture exterior wall insulating materials, electric appliance and electronic, instrument and equipment, packaging material, fitting-up.
Compared with prior art, the invention has the beneficial effects as follows:
(1) there is the fire-retardant fireproof performance of excellence, there is good adhesive property, hydrophobic performance and deformability simultaneously；
(2) this preparation method for coating is easy, quick, can realize cold curing and no coupling product, be environmental-protection flame-retardant coating.
Accompanying drawing explanation
Fig. 1 is embodiment 2 polyurethane foam and organic silicon flame-retardant modified paint polyurethane foam combustion contrast test.
Detailed description of the invention
Below by embodiment, the present invention is described in further detail, raw materials used the most commercially available in embodiment.
Embodiment 1
By MQ resin 20g, add containing hydrogen silicone oil 20g, full and uniform in mechanical agitation, as component A；By vinyl polysiloxane 48g, add the platinum complex 20g containing 40ppm, full and uniform in mechanical agitation, as B component；After the mass mixings such as AB group meeting 5 minutes, obtain organic silicon flame-retardant fireproof coating.It is stained with painting or is sprayed on combustible material such as epoxy resin, after room temperature places solidification 120min, the organic silicon flame-retardant modified paint epoxy resin batten prepared.Burning comparing result shows: uncoated epoxy resin batten deflagrate, and period is with molten melt drop state comburant drippage and a large amount of harmful smokes.Comparatively speaking, the epoxy resin batten through organic silicon flame-retardant modified paint remove after remaining in that the basic configuration of foam, and burning 10s in 30s burning things which may cause a fire disaster can self-extinguishment, do not have droplet-like comburant to drip yet, do not have a large amount of flue gas to release；Visible, organic silicon flame-retardant coating has good fire-retardant fireproof performance.
Embodiment 2
By vinyl polysiloxane 20g, add containing hydrogen silicone oil 15g, phenyl silicone oil 7g and nano silicon filler 3g, full and uniform in mechanical agitation, as component A；By vinyl polysiloxane 40g, add the platinum complex 50g containing 100ppm, full and uniform in mechanical agitation, as B component；After the mass mixings such as AB group meeting 5 minutes, obtain organic silicon flame-retardant fireproof coating.Sprayed or be coated to combustible material such as polyurethane foam, after room temperature places solidification 90min, the organic silicon flame-retardant coating surface modified polyurethane foam material prepared.
Burning comparative test result is as it is shown in figure 1, polyurethane (PU) foam is easily lighted, and combustion process can produce a large amount of harmful smoke, has substantially burnt in 10s.Under the conditions of same size, the polyurethane foam (Silicone@PU) through organic silicon flame-retardant modified paint cannot be lighted, even if still cannot light after placing 60s；According to UL testing standard, this organic silicon flame-retardant fireproof coating makes inflammable polyurethane foamed material reach V0 level flame-retardant standard.
Embodiment 3
By Silicon Containing Hydrogen resin 15g, add 15g silane KH550,5g silicone rubber and 15g laminar silicic acid hydrochlorate, full and uniform in mechanical agitation, as component A；By vinyl polysiloxane 45g, add the platinum complex 50g containing 50ppm, full and uniform in mechanical agitation, as B component；After the mass mixings such as AB group meeting 5 minutes, obtain organic silicon flame-retardant fireproof coating.Sprayed to combustible material such as EPS surface, after room temperature places solidification 15min, the organic silicon flame-retardant coating surface modified EPS material prepared.Burning comparative test result shows: EPS material is easily lighted, and can produce a large amount of toxic gas；And cannot light through the EPS material of organic silicon flame-retardant modified paint, according to UL testing standard, reach V0 level flame-retardant standard.
Embodiment 4
By phenyl polysiloxane 25g, add 10g containing hydrogen silicone oil, 8g KH570 and montmorillonite 10g, full and uniform in mechanical agitation, as component A；By vinyl polysiloxane 45g, add the chloroplatinic acid 20g containing 20ppm, full and uniform in mechanical agitation, as B component；After the mass mixings such as AB group meeting 5 minutes, obtain organic silicon flame-retardant fireproof coating.Sprayed to combustible material such as polyurethane foamed material surface, after room temperature places solidification 70min, the organic silicon flame-retardant coating surface modified polyurethane foam material prepared.Burning comparative test result shows: polyurethane foamed material is easily lighted, and can produce a large amount of gas；And cannot light through the polyurethane foamed material of organic silicon flame-retardant modified paint, according to UL testing standard, reach V0 level.
Embodiment 5
By vinyl polysiloxane 4g, add 20g Silicon Containing Hydrogen resin, alkynyl ring alcohol 0.5g, 19.5gKH560 and laminar silicic acid hydrochlorate 6g, full and uniform in mechanical agitation, as component A；By vinyl polysiloxane 46g, add the platinum complex 20g containing 60ppm, full and uniform in mechanical agitation, as B component；After the mass mixings such as AB group meeting 5 minutes, obtain organic silicon flame-retardant fireproof coating.Sprayed to combustible material such as polystyrene foam plate surface, after room temperature places solidification 45min, the organic silicon flame-retardant coating surface MPS cystosepiment prepared.Burning comparative test result shows: polystyrene foam plate is easily lighted, and can produce a large amount of flue gas；And cannot light through the polystyrene foam plate of organic silicon flame-retardant modified paint, according to UL testing standard, reach V0 level.
Claims (8)
1. an organic silicon flame-retardant fireproof coating, it is characterised in that described fireproof coating is made up of following component, the weight portion of each component is: organic siliconresin 40-70, auxiliary agent: 20-40, fire-retardant filler: 0-15, catalyst: 4 x10-4-50 x10-4。
A kind of organic silicon flame-retardant fireproof coating the most according to claim 1, it is characterised in that organic siliconresin is selected from having one or more in different side chain and molecular weight.
A kind of organic silicon flame-retardant fireproof coating the most according to claim 1, it is characterised in that described auxiliary agent is selected from silane coupler or silicone oil one or more.
A kind of organic silicon flame-retardant fireproof coating the most according to claim 3, it is characterised in that described silicone oil is selected from the vinyl silicone oil of different viscosities, containing hydrogen silicone oil one or more.
A kind of organic silicon flame-retardant fireproof coating the most according to claim 1, it is characterized in that, one or more in nano silicon, Graphene, magnesium hydroxide, sodium aluminosilicate, montmorillonite, aluminium hydroxide, expanded graphite alkene, laminar silicic acid hydrochlorate, boron nitride, antimonial, molybdenum compound etc. of described fire-retardant filler.
A kind of organic silicon flame-retardant fireproof coating the most according to claim 1, it is characterised in that one or more in chloroplatinic acid, platinum catalyst and complex of described catalyst.
7. the preparation method of a kind of organic silicon flame-retardant fireproof coating as according to any one of claim 1 to 6, it is characterised in that described preparation method is following steps:
(1) first by organic siliconresin, fire-retardant filler, auxiliary agent mixing, the component A of organic silicon flame-retardant fireproof coating is prepared；Organic siliconresin is mixed with catalyst simultaneously, prepare the B component of organic silicon flame-retardant fireproof coating；
(2) when using, after AB part is mixed, by spraying or be stained with the physics painting methods such as painting to combustible material surface, solidify 15-120 minute at ambient temperature.
8. a kind of environment-friendly type organosilicon fire-retardant fireproof coating application on combustible material surface in the fields such as architecture exterior wall insulating materials, electric appliance and electronic, instrument and equipment, packaging material, fitting-up as according to any one of claim 1 to 6.
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832389A (en) * | 2016-12-30 | 2017-06-13 | 杭州师范大学 | A kind of preparation method of organosilicon and graphene oxide cooperative flame retardant polymer composites |
| CN107556913A (en) * | 2017-09-26 | 2018-01-09 | 信和新材料股份有限公司 | A kind of solvent-free organic silicon high-temperature resistant anti-corrosive paint being modified based on graphene and preparation method thereof |
| CN108129066A (en) * | 2017-12-30 | 2018-06-08 | 常州新之雅装饰材料有限公司 | A kind of preparation method for carrying silver-colored palygorskite heat resistant type liquid wallpaper |
| CN108795201A (en) * | 2018-07-05 | 2018-11-13 | 温州北宸建设有限公司 | A kind of environment-friendly fireproof decorative panel |
| CN109468058A (en) * | 2018-09-30 | 2019-03-15 | 浙江凌志新材料有限公司 | A kind of weather-proof cracking resistance organosilicon fireproof coating of ultrathin type |
| CN110003693A (en) * | 2019-04-18 | 2019-07-12 | 安徽工业大学 | A kind of photocatalysis fireproof coating and preparation method thereof for degradation of formaldehyde gas |
| CN110894397A (en) * | 2019-12-10 | 2020-03-20 | 凯诗雷(上海)新材料有限公司 | Nano organic silicon protective coating |
| CN111019454A (en) * | 2019-11-26 | 2020-04-17 | 温州大学新材料与产业技术研究院 | Ultrathin water-based intumescent steel structure nano flame-retardant coating and preparation method thereof |
| CN111303739A (en) * | 2020-02-17 | 2020-06-19 | 陈家珺 | Hydrophobic flame-retardant coating and preparation process thereof |
| CN113265186A (en) * | 2021-05-26 | 2021-08-17 | 深圳市华必达科技有限公司 | Flame-retardant molecular chain grafted mesoporous silica modified epoxy resin coating and preparation method thereof |
| CN114634760A (en) * | 2022-04-07 | 2022-06-17 | 江苏世博设计研究院有限公司 | Novel solidified heat-insulating material |
| WO2022236519A1 (en) * | 2021-05-10 | 2022-11-17 | Allnex Resins (Shanghai) Co., Ltd. | Powder coating compostion blend |
| CN116463054A (en) * | 2023-04-14 | 2023-07-21 | 哈尔滨工业大学 | Preparation method of flame-retardant heat-insulating organosilicon foaming coating |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302396A (en) * | 2008-06-27 | 2008-11-12 | 中材高新材料股份有限公司 | High temperature-resistant flame-retardant insulating paint and preparation thereof |
| CN104694004A (en) * | 2015-02-17 | 2015-06-10 | 成都拓利化工实业有限公司 | Solvent-free anti-pollution flashover organic silicon coating and preparation method thereof |
| CN104726020A (en) * | 2014-09-28 | 2015-06-24 | 海龙核材科技（江苏）有限公司 | Nuclear-grade high-temperature-resistance fireproof coating and preparation method thereof |
| CN104927647A (en) * | 2015-06-22 | 2015-09-23 | 青岛恩高运动控制技术有限公司 | Fireproof oil paint |
-
2016
- 2016-05-13 CN CN201610315736.7A patent/CN106085220A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101302396A (en) * | 2008-06-27 | 2008-11-12 | 中材高新材料股份有限公司 | High temperature-resistant flame-retardant insulating paint and preparation thereof |
| CN104726020A (en) * | 2014-09-28 | 2015-06-24 | 海龙核材科技（江苏）有限公司 | Nuclear-grade high-temperature-resistance fireproof coating and preparation method thereof |
| CN104694004A (en) * | 2015-02-17 | 2015-06-10 | 成都拓利化工实业有限公司 | Solvent-free anti-pollution flashover organic silicon coating and preparation method thereof |
| CN104927647A (en) * | 2015-06-22 | 2015-09-23 | 青岛恩高运动控制技术有限公司 | Fireproof oil paint |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832389A (en) * | 2016-12-30 | 2017-06-13 | 杭州师范大学 | A kind of preparation method of organosilicon and graphene oxide cooperative flame retardant polymer composites |
| CN106832389B (en) * | 2016-12-30 | 2019-07-23 | 杭州师范大学 | A kind of preparation method of organosilicon and graphene oxide cooperative flame retardant polymer composites |
| CN107556913A (en) * | 2017-09-26 | 2018-01-09 | 信和新材料股份有限公司 | A kind of solvent-free organic silicon high-temperature resistant anti-corrosive paint being modified based on graphene and preparation method thereof |
| CN108129066B (en) * | 2017-12-30 | 2020-12-01 | 义乌市君胜科技有限公司 | Preparation method of silver-loaded palygorskite heat-resistant liquid wallpaper |
| CN108129066A (en) * | 2017-12-30 | 2018-06-08 | 常州新之雅装饰材料有限公司 | A kind of preparation method for carrying silver-colored palygorskite heat resistant type liquid wallpaper |
| CN108795201A (en) * | 2018-07-05 | 2018-11-13 | 温州北宸建设有限公司 | A kind of environment-friendly fireproof decorative panel |
| CN109468058A (en) * | 2018-09-30 | 2019-03-15 | 浙江凌志新材料有限公司 | A kind of weather-proof cracking resistance organosilicon fireproof coating of ultrathin type |
| CN109468058B (en) * | 2018-09-30 | 2020-12-29 | 浙江凌志新材料有限公司 | Ultrathin weather-resistant anti-cracking organic silicon fireproof coating |
| CN110003693B (en) * | 2019-04-18 | 2021-01-01 | 安徽工业大学 | Photocatalytic fireproof coating for degrading formaldehyde gas and preparation method thereof |
| CN110003693A (en) * | 2019-04-18 | 2019-07-12 | 安徽工业大学 | A kind of photocatalysis fireproof coating and preparation method thereof for degradation of formaldehyde gas |
| CN111019454A (en) * | 2019-11-26 | 2020-04-17 | 温州大学新材料与产业技术研究院 | Ultrathin water-based intumescent steel structure nano flame-retardant coating and preparation method thereof |
| CN111019454B (en) * | 2019-11-26 | 2021-12-17 | 温州大学新材料与产业技术研究院 | Ultrathin water-based intumescent steel structure nano flame-retardant coating and preparation method thereof |
| CN110894397A (en) * | 2019-12-10 | 2020-03-20 | 凯诗雷(上海)新材料有限公司 | Nano organic silicon protective coating |
| CN111303739A (en) * | 2020-02-17 | 2020-06-19 | 陈家珺 | Hydrophobic flame-retardant coating and preparation process thereof |
| CN111303739B (en) * | 2020-02-17 | 2021-06-15 | 四川天道易科技有限公司 | Hydrophobic flame-retardant coating and preparation process thereof |
| WO2022236519A1 (en) * | 2021-05-10 | 2022-11-17 | Allnex Resins (Shanghai) Co., Ltd. | Powder coating compostion blend |
| CN113265186A (en) * | 2021-05-26 | 2021-08-17 | 深圳市华必达科技有限公司 | Flame-retardant molecular chain grafted mesoporous silica modified epoxy resin coating and preparation method thereof |
| CN114634760A (en) * | 2022-04-07 | 2022-06-17 | 江苏世博设计研究院有限公司 | Novel solidified heat-insulating material |
| CN116463054A (en) * | 2023-04-14 | 2023-07-21 | 哈尔滨工业大学 | Preparation method of flame-retardant heat-insulating organosilicon foaming coating |
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