CN103881386A - Novel organic/inorganic expanded type fireproof elastomer plate and preparation method thereof - Google Patents
Novel organic/inorganic expanded type fireproof elastomer plate and preparation method thereof Download PDFInfo
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- CN103881386A CN103881386A CN201410123532.4A CN201410123532A CN103881386A CN 103881386 A CN103881386 A CN 103881386A CN 201410123532 A CN201410123532 A CN 201410123532A CN 103881386 A CN103881386 A CN 103881386A
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Abstract
The invention discloses a novel organic/inorganic expanded type fireproof elastomer plate which comprises the following raw materials in percentage by weight: 10-35% of hydroxyl silicone oil, 5-30% of polymethylvinylsiloxane, 5-20% of hydrogen-containing silicone oil, 0-40% of inorganic flame-retardant fireproof filler, 15-50% of organic flame-retardant fireproof filler, 9-30% of other fillers, 0.1-0.5% of catalyst and 0.1-0.5% of inhibitor. The novel organic/inorganic expanded type fireproof elastomer plate is used for plugging an electrical panel cabinet, a cable shaft, a cable bridge and other large holes, and has the characteristics of long fireproof time, good smoke airtightness, attractive appearance, resistance against the shock of fire-fighting water, easy expansion, long fireproof service life and the like.
Description
Technical field:
The present invention relates to a kind of novel organic/inorganic expansion fire-proof elastomeric plates and preparation method thereof.
Background technology:
At seam, opening or the hole place of electric panel cabinet, cable shaft and buildings, often electric wire, cable and all kinds of communication cable are many and mix.Once presence of fire, the intensity of a fire will be by these places and rapid spread, also rapid diffusion thereupon of toxic gas.Therefore, utilize fire-proof board to carry out effective shutoff to these places, just can be effectively by fire control in certain scope, reduce the loss, thereby try to gain time precious to one for fire extinguishing.
The general plugging material such as anti-chamotte, back-fire relief bag can meet easy dilatation needs, but the performances such as fire prevention life-span, fire prevention timeliness, aesthetic property, anti-fire water stampability, flue gas resistance to air loss are all poor; Though general silicate plugging material can attractive in appearance, anti-fire water impact, the better performance such as flue gas resistance to air loss, passes through the aspects such as dilatation, fire prevention timeliness, fire prevention life-span be quite short of for the secondary of electric wire.
Summary of the invention:
The object of the present invention is to provide a kind of novel organic/inorganic expansion fire-proof elastomeric plates, as the shutoff of the large holes such as electric panel cabinet, cable shaft, cable testing bridge, have that fire prevention timeliness is long, flue gas resistance to air loss is good, attractive in appearance, can resist fire water to impact, the features such as easily dilatation, fire prevention life-span length.
For achieving the above object, the present invention has adopted following technical scheme:
A kind of novel organic/inorganic expansion fire-proof elastomeric plates, its composition of raw materials is:
Above-mentioned per-cent is mass percent, and the mass percent sum of described each composition is 100%.
Described inorganic combustion inhibitor is the mixture of zinc borate, magnesium hydroxide, aluminium hydroxide, hollow glass micropearl, wherein one or more of pearl sand.
Described organic fire-resisting fire-proof packing is the mixture of ammonium polyphosphate, trimeric cyanamide, dipentaerythritol, wherein one or more of N-P composite flame retardant system.
Described catalyzer is metal platinum series catalysts.
Described inhibitor is any one or several mixture in vinyl ring body, phenyl inhibitor or acetylene alcohol, and preferably, inhibitor is vinyl ring body.
Described other fillers are mainly the use of reinforcement regulating density, are one or more the mixture in pearlstone, mica powder of wet process, needle shape wollastonite powder, light calcium carbonate, aerosil, kaolin.
The preparation method of described a kind of novel organic/inorganic expansion fire-proof elastomeric plates, comprises the following steps:
1. take each component raw material according to composition of raw materials;
2. hydroxy silicon oil, inhibitor, containing hydrogen silicone oil, poly-ethylene methacrylic radical siloxane, catalyzer are placed in to stirring tank, be to stir 5～20 minutes under the condition of 15～45 ℃ in temperature, then add successively inorganic fire-retarded fire-proof packing, other filler of half amount, stir 30～60 minutes, in the time that material body viscosity reaches 500000～700000cs, stop stirring, make paste;
3. by step 2. made paste be placed in kneader, add successively organic fire-resisting fire-proof packing, the inorganic fire-retarded fire-proof packing of residual content and other filler, mediate 20～50 minutes, makes colloid compound;
4. by step 3. made colloid compound be placed in hydropress mould, carry out shaped by fluid pressure, the demoulding after pressurize 10s, be placed in 15～40 ℃ of environment solidify, make a kind of novel organic/inorganic expansion fire-proof elastomeric plates.
The novel a kind of novel organic/inorganic expansion fire-proof elastomeric plates of the present invention adopts the effect of poly-ethylene methacrylic radical siloxane, containing hydrogen silicone oil, zinc borate, aluminium hydroxide, N-P composite flame retardant system, makes it have good fire resistance; Again because the array mode of its hydroxy silicon oil, containing hydrogen silicone oil and aerosil makes it have flue gas resistance to air loss effect better.Organic/inorganic expansion fire-proof elastomeric plates of the present invention possesses that fire prevention timeliness reaches 3 hours, flue gas resistance to air loss is good, and 2m hydraulic pressure does not leak, attractive in appearance, can resist fire water to impact, and easily dilatation, fire prevention life-span reach 60 years effectively, excellent performance.
Embodiment
Below in conjunction with example to further detailed, complete explanation of the present invention.
In the present embodiment, described N-P composite flame retardant system is purchased from Sichuan Zhuo An fire-fighting quipment company limited.
Case study on implementation 1
A. take each component raw material according to following formula:
B. the hydroxy silicon oil, inhibitor, containing hydrogen silicone oil, poly-ethylene methacrylic radical siloxane, the catalyzer that step a are weighed are placed in stirring tank, at 15～45 ℃ of temperature, stir 5～20 minutes, then add appropriate stirring 35 minutes, now expect that body viscosity reaches 770000cs, stop stirring the paste of system;
C. made step b paste is placed in to kneader, adds successively the organic fire-resisting fire-proof packing of residual content, inorganic fire-retarded fire-proof packing and other filler, mediate the colloid compound of system 20～50 minutes;
Made step c colloid compound is placed in to hydropress mould, carries out shaped by fluid pressure, the demoulding after pressurize 10s, is placed in 15～0 ℃ of environment and solidifies, and makes a kind of novel organic/inorganic expansion fire-proof elastomeric plates.
Embodiment 2
A. take each component raw material according to following formula:
All the other steps are with described in embodiment 1.
Embodiment 3
A. take each component raw material according to following formula:
All the other steps are with described in embodiment 1.
Embodiment 4
A. take each component raw material according to following formula:
All the other steps are with described in embodiment 1.
Embodiment 5
A. take each component raw material according to following formula:
All the other steps are with described in embodiment 1.
The main performance index of fire prevention elastomeric plates prepared by each embodiment and testing standard thereof are as table 1:
Table 1
By the visible embodiment 5 property indices optimums of table one, it is scheme most preferably.
Above embodiment is only for being described in further detail the present invention; can not be interpreted as limiting the scope of the invention, some nonessential improvement that those skilled in the art's foregoing according to the present invention is made and adjustment all belong to protection scope of the present invention.
Claims (6)
1. a novel organic/inorganic expansion fire-proof elastomeric plates, is characterized in that, its composition of raw materials is:
Hydroxy silicon oil 10～35%
Poly-ethylene methacrylic radical siloxane 5～30%
Containing hydrogen silicone oil 5～20%
Inorganic fire-retarded fire-proof packing 10～40%
Organic fire-resisting fire-proof packing 15～50%
Other fillers 9～30%
Catalyzer 0.1～0.5%
Inhibitor 0.1～0.5%
Above-mentioned per-cent is mass percent, and the mass percent sum of described each composition is 100%.
2. the novel organic/inorganic expansion fire-proof of one as claimed in claim 1 elastomeric plates, is characterized in that, described inorganic combustion inhibitor is the mixture of zinc borate, magnesium hydroxide, aluminium hydroxide, hollow glass micropearl, wherein one or more of pearl sand.
3. the novel organic/inorganic expansion fire-proof of one as claimed in claim 1 elastomeric plates, is characterized in that, described catalyzer is metal platinum series catalysts.
4. the novel organic/inorganic expansion fire-proof of one as claimed in claim 1 elastomeric plates, is characterized in that, described inhibitor is any one or several mixture in vinyl ring body, phenyl inhibitor or acetylene alcohol, and preferably, inhibitor is vinyl ring body.
5. the novel organic/inorganic expansion fire-proof of one as claimed in claim 1 elastomeric plates, it is characterized in that, described other fillers are mainly the use of reinforcement regulating density, are one or more the mixture in pearlstone, mica powder of wet process, needle shape wollastonite powder, light calcium carbonate, aerosil, kaolin.
6. a preparation method for novel organic/inorganic expansion fire-proof elastomeric plates, is characterized in that, comprises the following steps:
(1) take each component raw material according to composition of raw materials;
(2) hydroxy silicon oil, inhibitor, containing hydrogen silicone oil, poly-ethylene methacrylic radical siloxane, catalyzer are placed in to stirring tank, be to stir 5～20 minutes under the condition of 15～45 ℃ in temperature, then add successively inorganic fire-retarded fire-proof packing, other filler of half amount, stir 30～60 minutes, in the time that material body viscosity reaches 500000～700000cs, stop stirring, make paste;
(3) the made paste of step (2) is placed in to kneader, adds successively organic fire-resisting fire-proof packing, the inorganic fire-retarded fire-proof packing of residual content and other filler, mediate 20～50 minutes, makes colloid compound;
(4) made step (3) colloid compound is placed in to hydropress mould, carries out shaped by fluid pressure, the demoulding after pressurize 10s, is placed in 15～40 ℃ of environment and solidifies, and makes a kind of novel organic/inorganic expansion fire-proof elastomeric plates.
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| CN201410123532.4A CN103881386B (en) | 2014-03-28 | 2014-03-28 | A kind of novel organic/inorganic expansion fire-proof elastomeric plates and preparation method thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726018A (en) * | 2014-09-28 | 2015-06-24 | 海龙核材科技（江苏）有限公司 | Preparation method of environment-friendly double-component high-temperature-resisting fireproof coating |
| CN105295380A (en) * | 2014-09-28 | 2016-02-03 | 海龙核材科技（江苏）有限公司 | Light fire-proof foaming brick and preparation method thereof |
| CN107663351A (en) * | 2017-09-23 | 2018-02-06 | 镇江市太浪新材料科技有限公司 | A kind of fireproof building material |
| CN107674441A (en) * | 2017-09-19 | 2018-02-09 | 信阳市华盈矿业有限公司 | Environment-friendly type expansible fireproof synthetic rubber, fireproof cable and rubber coated fire prevention pipeline |
| CN107722523A (en) * | 2017-09-23 | 2018-02-23 | 镇江市太浪新材料科技有限公司 | A kind of Building Fire Protection filler |
| CN107746207A (en) * | 2017-09-23 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of Building Fire Protection filler |
| CN107746713A (en) * | 2017-09-22 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of building materials specific complex fire-proof packing |
| CN107903631A (en) * | 2017-09-22 | 2018-04-13 | 镇江市太浪新材料科技有限公司 | A kind of preparation method for building specific complex refractory flexible material |
| CN110950625A (en) * | 2019-12-09 | 2020-04-03 | 江苏三安消防设备有限公司 | Preparation and application of novel expandable fireproof plugging material |
| CN111073298A (en) * | 2019-11-26 | 2020-04-28 | 国网湖南省电力有限公司 | Flame-retardant plugging agent for substation and preparation method and use method thereof |
| CN114891352A (en) * | 2022-05-13 | 2022-08-12 | 江苏中迪新材料技术有限公司 | Expansion type ceramic fireproof product and preparation method thereof |
| WO2024000116A1 (en) * | 2022-06-27 | 2024-01-04 | Dow Silicones Corporation | Organopolysiloxane composition with expanded perlite |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101983989A (en) * | 2010-11-01 | 2011-03-09 | 深圳市森日有机硅材料有限公司 | Liquid silicon rubber composition and preparation method thereof |
| JP2012006986A (en) * | 2010-06-22 | 2012-01-12 | Shin-Etsu Chemical Co Ltd | Room-temperature curable organopolysiloxane composition, thermal foaming fire-resistant coating material, and fire-resistant structure |
| CN102504545A (en) * | 2011-12-02 | 2012-06-20 | 海龙核材科技（江苏）有限公司 | High-density fire-proof silicone rubber and preparation method thereof |
| CN102964836A (en) * | 2011-08-29 | 2013-03-13 | 深圳市沃尔核材股份有限公司 | Ceramicized silicon rubber, preparation method and application |
| CN103665891A (en) * | 2013-12-10 | 2014-03-26 | 海龙核材科技（江苏）有限公司 | Double-component fireproof silicone foamed material with ultra-low density and preparation technology thereof |
-
2014
- 2014-03-28 CN CN201410123532.4A patent/CN103881386B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012006986A (en) * | 2010-06-22 | 2012-01-12 | Shin-Etsu Chemical Co Ltd | Room-temperature curable organopolysiloxane composition, thermal foaming fire-resistant coating material, and fire-resistant structure |
| CN101983989A (en) * | 2010-11-01 | 2011-03-09 | 深圳市森日有机硅材料有限公司 | Liquid silicon rubber composition and preparation method thereof |
| CN102964836A (en) * | 2011-08-29 | 2013-03-13 | 深圳市沃尔核材股份有限公司 | Ceramicized silicon rubber, preparation method and application |
| CN102504545A (en) * | 2011-12-02 | 2012-06-20 | 海龙核材科技（江苏）有限公司 | High-density fire-proof silicone rubber and preparation method thereof |
| CN103665891A (en) * | 2013-12-10 | 2014-03-26 | 海龙核材科技（江苏）有限公司 | Double-component fireproof silicone foamed material with ultra-low density and preparation technology thereof |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104726018A (en) * | 2014-09-28 | 2015-06-24 | 海龙核材科技（江苏）有限公司 | Preparation method of environment-friendly double-component high-temperature-resisting fireproof coating |
| CN105295380A (en) * | 2014-09-28 | 2016-02-03 | 海龙核材科技（江苏）有限公司 | Light fire-proof foaming brick and preparation method thereof |
| CN107674441A (en) * | 2017-09-19 | 2018-02-09 | 信阳市华盈矿业有限公司 | Environment-friendly type expansible fireproof synthetic rubber, fireproof cable and rubber coated fire prevention pipeline |
| CN107746713A (en) * | 2017-09-22 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of building materials specific complex fire-proof packing |
| CN107903631A (en) * | 2017-09-22 | 2018-04-13 | 镇江市太浪新材料科技有限公司 | A kind of preparation method for building specific complex refractory flexible material |
| CN107663351A (en) * | 2017-09-23 | 2018-02-06 | 镇江市太浪新材料科技有限公司 | A kind of fireproof building material |
| CN107722523A (en) * | 2017-09-23 | 2018-02-23 | 镇江市太浪新材料科技有限公司 | A kind of Building Fire Protection filler |
| CN107746207A (en) * | 2017-09-23 | 2018-03-02 | 镇江市太浪新材料科技有限公司 | A kind of Building Fire Protection filler |
| CN111073298A (en) * | 2019-11-26 | 2020-04-28 | 国网湖南省电力有限公司 | Flame-retardant plugging agent for substation and preparation method and use method thereof |
| CN110950625A (en) * | 2019-12-09 | 2020-04-03 | 江苏三安消防设备有限公司 | Preparation and application of novel expandable fireproof plugging material |
| CN114891352A (en) * | 2022-05-13 | 2022-08-12 | 江苏中迪新材料技术有限公司 | Expansion type ceramic fireproof product and preparation method thereof |
| WO2024000116A1 (en) * | 2022-06-27 | 2024-01-04 | Dow Silicones Corporation | Organopolysiloxane composition with expanded perlite |
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| CN103881386B (en) | 2016-08-31 |
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