CN106085030A - A kind of preparation method of diatomite inner wall coating - Google Patents

A kind of preparation method of diatomite inner wall coating Download PDF

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Publication number
CN106085030A
CN106085030A CN201610693917.3A CN201610693917A CN106085030A CN 106085030 A CN106085030 A CN 106085030A CN 201610693917 A CN201610693917 A CN 201610693917A CN 106085030 A CN106085030 A CN 106085030A
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wall coating
slurry
preparation
diatomite
diatomite inner
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CN201610693917.3A
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陈军
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Wuhan Environmental Protection Technology Co Ltd
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Wuhan Environmental Protection Technology Co Ltd
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Priority to CN201610693917.3A priority Critical patent/CN106085030A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • C09D125/14Copolymers of styrene with unsaturated esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/02Flame or fire retardant/resistant
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses the preparation method of a kind of diatomite inner wall coating, including step in detail below: 1) weigh raw material;2) first ethylene glycol phenyl ether, antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, under stirring action add attapulgite and stir evenly obtain the first slurry 3) prepare the second slurry;4) toward described second slurry being sequentially added into hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, propolis rubber powder under stirring and stirring and i.e. obtain diatomite inner wall coating;The present invention can prepare ecological environment function such as not only having green, environmental protection, ventilative, homoiothermic, damping, microcirculation, air cleaning, and possesses coating property and the diatomite inner wall coating in high service life of excellence.

Description

A kind of preparation method of diatomite inner wall coating
Technical field
The present invention relates to the preparation method of a kind of diatomite inner wall coating.
Background technology
From the point of view of new green building evaluation standard, interior wall coating, it is necessary to have good breathability, it is possible to conditioning, Purify air, keep the building ecological microcirculation with environment.
From environmental protection and healthy needs, raw materials in coating for internal and external wall, few as much as possible use or not use Learn adhesive, chemical assistant, chemistry mill base, use more preferable, more stable, the more environmentally friendly inorganic coagulation material of performance, inorganic pigment With ecological functions material etc..Improve the natural functions such as automatically ventilative, the homoiothermic of construction wall, damping, microcirculation, air cleaning, Improve the air quality of indoor living environment, the comfort level of inhabitation, safety and dicoration.
Interior wall coating in the market mostly is interiro wall latex paint, containing substantial amounts of chemical noxious composition.How to close with chemistry Resin emulsion, auxiliary agent, filler, pigment, use the technique such as high speed dispersion, sand milling etc. to make, be main film forming matter with emulsion, but The molecular structure of latex is not the most stable, during dope viscosity instability, needs to add thickening agent, anti-settling agent;Application property is bad, also Thixotropic agent to be added, levelling agent, additionally, also anti-skinning agent, optical brightener, delustering agent, Hardening agent, water-repelling agent, hydrophober, urge dry Agent, slipping agent, emulsifying agent, anti-blocking agent, anticrater agent, anti-grow dim agent, anti-flooding agent, anti-gelling agent, viscosity stabiliser, antioxygen Hundreds of auxiliary agents such as agent, eliminating smell agent, mallear stria agent, conductive agent, antistatic agent, brightening agent.Make with so many chemicals Emulsion paint, is but difficult to make the performance and used life of coating reach perfect condition.
Therefore, develop one and not only there is the ecologies such as green, environmental protection, ventilative, homoiothermic, damping, microcirculation, air cleaning Environmental functional, and possess coating property and the diatomite inner wall coating in high service life of excellence, to promoting living environment Air quality, the comfort level of inhabitation, safety be significant.
Summary of the invention
The technical problem to be solved is, the shortcoming overcoming above prior art: provide one not only to have green The ecological environment function such as color, environmental protection, ventilative, homoiothermic, damping, microcirculation, air cleaning, and possess the coating property of excellence with And the diatomite inner wall coating in high service life.
The technical solution of the present invention is as follows: the preparation method of a kind of diatomite inner wall coating, including walking in detail below Rapid:
1) raw material of following parts by weight is weighed: kieselguhr 100-160 part;Wood fibre 50-60 part;Anatase thpe white powder 60-120 part;Hydroxyethyl cellulose 3-8 part;Attapulgite 2-5 part;Precipitated calcium carbonate 375-420 part;Propylene glycol 6-12 Part;Styrene-acrylic emulsion 80-120 part;Propolis rubber powder 5-8 part;Ethylene glycol phenyl ether 3-5 part;Antibacterial 1-1.5 part;Point Powder 4-7 part;Defoamer 0.5-1.2 part;Wetting agent 1-2 part;Water 350-450 part;
2) first the ethylene glycol phenyl ether of step 1), antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, stir The effect of mixing is lower to add attapulgite and stirs evenly and obtain the first slurry;
3) being ground to mean diameter with wood fibre after being mixed by kieselguhr is 15-50 μm;Anatase thpe white powder and lightweight carbonic acid Being ground to mean diameter after calcium mixing is 100-200nm;Compound after above two being ground successively adds step 2) middle system The first standby slurry stirs evenly and obtains the second slurry;
4) in described second slurry, hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, plant tree it are sequentially added under stirring Fat rubber powder also stirs and i.e. obtains diatomite inner wall coating.
Described antibacterial is ROCIMA-640.
Described dispersant is sp-740.
Described defoamer is sp-800.
Described wetting agent is sp-994.
Described propolis rubber powder is the HYM-21 rubber powder of Beijing ring benefit U.S. high molecular polymer Research Institute.
It is to use after 1:8-9 mixing and stirring according to the weight ratio of coating Yu water when the present invention uses.
The present invention compared with the existing technology provides the benefit that: owing to kieselguhr surface distributed is the most nanometer level microporous, be Natural nano material, have uniqueness molecular sieve structure, porous, relatively low density, bigger specific surface area, relative not Compressibility and chemical stability, have metastable heat-insulating flame-retardant, non-conductive property, particularly has extremely strong physics and inhales Attached performance and ion exchanging function, its absorption property, up to 3000-5000 times of activated carbon, can adsorb the dirt in air effectively Dye thing, with under the compounding combination of corresponding function material, the harmful substance of absorption of effectively degrading also produces the waterfall of negative oxygen ion Cloth effect, makes interior wall coating have ecological functions.Meanwhile, ecological vegetable resin glue gel material is used to substitute ordinary resin emulsion, Interior wall coating is allowed not contain chemical harmful substance.The present invention uses corresponding functional material to combine with kieselguhr the interior wall prepared Coating, has good moistureproof and mildewproof, humidity, purifies air, fire resistance has had and is greatly improved;Use ecological vegetable Resin gel material substitution ordinary resin emulsion, reduces again corresponding auxiliary agent usage amount, is greatly improved the ecological, environmental protective of coating Performance.
Detailed description of the invention
With specific embodiment, the present invention is described in further details below, but the present invention is not only limited to real in detail below Execute example.
Embodiment one
A kind of preparation method of diatomite inner wall coating, including step in detail below:
1) raw material of following parts by weight is weighed: kieselguhr 100-160 part;Wood fibre 50-60 part;Anatase thpe white powder 60-120 part;Hydroxyethyl cellulose 3-8 part;Attapulgite 2-5 part;Precipitated calcium carbonate 375-420 part;Propylene glycol 6-12 Part;Styrene-acrylic emulsion 80-120 part;Propolis rubber powder 5-8 part;Ethylene glycol phenyl ether 3-5 part;Antibacterial 1-1.5 part;Point Powder 4-7 part;Defoamer 0.5-1.2 part;Wetting agent 1-2 part;Water 350-450 part;
2) first the ethylene glycol phenyl ether of step 1), antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, stir The effect of mixing is lower to add attapulgite and stirs evenly and obtain the first slurry;
3) being ground to mean diameter with wood fibre after being mixed by kieselguhr is 15-50 μm;Anatase thpe white powder and lightweight carbonic acid Being ground to mean diameter after calcium mixing is 100-200nm;Compound after above two being ground successively adds step 2) middle system The first standby slurry stirs evenly and obtains the second slurry;
4) in described second slurry, hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, plant tree it are sequentially added under stirring Fat rubber powder also stirs and i.e. obtains diatomite inner wall coating.
Described antibacterial is ROCIMA-640.
Described dispersant is sp-740.
Described defoamer is sp-800.
Described wetting agent is sp-994.
Described propolis rubber powder is the HYM-21 rubber powder of Beijing ring benefit U.S. high molecular polymer Research Institute.
Embodiment two
A kind of preparation method of diatomite inner wall coating, including step in detail below:
1) raw material of following parts by weight is weighed: 160 parts of kieselguhr;Wood fibre 60 parts;Anatase thpe white powder 60 parts;Hydroxyl Ethyl cellulose 8 parts;Attapulgite 5 parts;Precipitated calcium carbonate 420 parts;Propylene glycol 6 parts;Styrene-acrylic emulsion 120 parts;Plant tree Fat rubber powder 8 parts;Ethylene glycol phenyl ether 5 parts;Antibacterial 1.5 parts;Dispersant 4 parts;Defoamer 0.5 part;Wetting agent 1 part; 350 parts of water;
2) first the ethylene glycol phenyl ether of step 1), antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, stir The effect of mixing is lower to add attapulgite and stirs evenly and obtain the first slurry;
3) being ground to mean diameter with wood fibre after being mixed by kieselguhr is 50 μm;Anatase thpe white powder mixes with precipitated calcium carbonate Being ground to mean diameter after conjunction is 200nm;Successively by above two grind after compound add step 2) in preparation first Slurry stirs evenly and obtains the second slurry;
4) in described second slurry, hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, plant tree it are sequentially added under stirring Fat rubber powder also stirs and i.e. obtains diatomite inner wall coating.Described antibacterial is ROCIMA-640, and described dispersant is sp-740, Described defoamer is sp-800, and described wetting agent is sp-994, and described propolis rubber powder is Beijing ring benefit U.S. high molecular polymerization The HYM-21 rubber powder of thing Research Institute.
Embodiment three
A kind of preparation method of diatomite inner wall coating, including step in detail below:
1) raw material of following parts by weight is weighed: 100 parts of kieselguhr;Wood fibre 50 parts;Anatase thpe white powder 120 parts;Hydroxyl Ethyl cellulose 8 parts;Attapulgite 5 parts;Precipitated calcium carbonate 375 parts;Propylene glycol 6 parts;Styrene-acrylic emulsion 80 parts;Plant tree Fat rubber powder 8 parts;Ethylene glycol phenyl ether 5 parts;Antibacterial 1 part;Dispersant 4 parts;Defoamer 1.2 parts;Wetting agent 2 parts;Water 380 parts;
2) first the ethylene glycol phenyl ether of step 1), antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, stir The effect of mixing is lower to add attapulgite and stirs evenly and obtain the first slurry;
3) being ground to mean diameter with wood fibre after being mixed by kieselguhr is 20 μm;Anatase thpe white powder mixes with precipitated calcium carbonate Being ground to mean diameter after conjunction is 150nm;Successively by above two grind after compound add step 2) in preparation first Slurry stirs evenly and obtains the second slurry;
4) in described second slurry, hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, plant tree it are sequentially added under stirring Fat rubber powder also stirs and i.e. obtains diatomite inner wall coating;Described propolis rubber powder is that Beijing ring benefit U.S. high molecular polymer grinds Study carefully developed HYM-21 rubber powder.
Below it is only that inventive feature implements example, scope is not constituted any limitation.All employings are same The technical scheme replaced Deng exchange or equivalence and formed, within the scope of all falling within rights protection of the present invention.

Claims (6)

1. the preparation method of a diatomite inner wall coating, it is characterised in that: include step in detail below:
1) raw material of following parts by weight is weighed: kieselguhr 100-160 part;Wood fibre 50-60 part;Anatase thpe white powder 60-120 part;Hydroxyethyl cellulose 3-8 part;Attapulgite 2-5 part;Precipitated calcium carbonate 375-420 part;Propylene glycol 6-12 Part;Styrene-acrylic emulsion 80-120 part;Propolis rubber powder 5-8 part;Ethylene glycol phenyl ether 3-5 part;Antibacterial 1-1.5 part;Point Powder 4-7 part;Defoamer 0.5-1.2 part;Wetting agent 1-2 part;Water 350-450 part;
2) first the ethylene glycol phenyl ether of step 1), antibacterial, dispersant, defoamer and wetting agent are mixed homogeneously with water, stir The effect of mixing is lower to add attapulgite and stirs evenly and obtain the first slurry;
3) being ground to mean diameter with wood fibre after being mixed by kieselguhr is 15-50 μm;Anatase thpe white powder and lightweight carbonic acid Being ground to mean diameter after calcium mixing is 100-200nm;Compound after above two being ground successively adds step 2) middle system The first standby slurry stirs evenly and obtains the second slurry;
4) in described second slurry, hydroxyethyl cellulose, propylene glycol, styrene-acrylic emulsion, plant tree it are sequentially added under stirring Fat rubber powder also stirs and i.e. obtains diatomite inner wall coating.
The preparation method of diatomite inner wall coating the most according to claim 1, it is characterised in that: described antibacterial is ROCIMA-640。
The preparation method of diatomite inner wall coating the most according to claim 1, it is characterised in that: described dispersant is sp- 740。
The preparation method of diatomite inner wall coating the most according to claim 1, it is characterised in that: described defoamer is sp- 800。
The preparation method of diatomite inner wall coating the most according to claim 1, it is characterised in that: described wetting agent is sp- 994。
The preparation method of diatomite inner wall coating the most according to claim 1, it is characterised in that: described propolis rubber powder HYM-21 rubber powder for Beijing ring benefit U.S. high molecular polymer Research Institute.
CN201610693917.3A 2016-08-22 2016-08-22 A kind of preparation method of diatomite inner wall coating Pending CN106085030A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111072324A (en) * 2019-12-11 2020-04-28 江门市壹家美环境工程有限公司 Bactericidal environment-friendly coating
CN112608651A (en) * 2020-12-26 2021-04-06 成都拓凝舟涂料科技有限公司 Preparation method of fireproof coating for wall

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CN105778637A (en) * 2016-03-09 2016-07-20 佛山市恒学科技服务有限公司 Interior wall coating capable of adjusting humidity

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111072324A (en) * 2019-12-11 2020-04-28 江门市壹家美环境工程有限公司 Bactericidal environment-friendly coating
CN112608651A (en) * 2020-12-26 2021-04-06 成都拓凝舟涂料科技有限公司 Preparation method of fireproof coating for wall

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Application publication date: 20161109