CN106084995A - A kind of microwax ink and preparation method thereof - Google Patents
A kind of microwax ink and preparation method thereof Download PDFInfo
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- CN106084995A CN106084995A CN201610667717.0A CN201610667717A CN106084995A CN 106084995 A CN106084995 A CN 106084995A CN 201610667717 A CN201610667717 A CN 201610667717A CN 106084995 A CN106084995 A CN 106084995A
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- microwax
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
- C09D11/037—Printing inks characterised by features other than the chemical nature of the binder characterised by the pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to printing-ink field, concrete open a kind of microwax ink and preparation method thereof, is composed of the following components in parts by weight: Oleum Terebinthinae 4 10 parts, azo pigment 0.5 3 parts, ethyl cellulose 6 10 parts, ethanol 57 parts, binder 11 23 parts, polyethylene microwax 37 parts, aminating agent 15 parts, water soluble acrylic resin 15 parts, friction resistant auxiliary agent 27 parts, tridecanol 13 parts, additive 0.5 2 parts.The ink adhesion that the present invention provides is strong, good stability, and production efficiency is high.
Description
Technical field
The invention belongs to printing-ink field, concretely relate to a kind of microwax ink and preparation method thereof.
Background technology
Ink (ink, printing ink) is the important materials for printing, and pattern, word are showed by it by printing
On the substrate.For various printings such as books and periodicals, packing and decorating, building decoration and electronic circuit sheet materials.Along with social need increases
Greatly, ink kind and yield also respective extension and growth.Existing ink uses the inorganic pigment such as clay, silicon dioxide mostly, but
It is in terms of the stability of base material adhesive force and coefficient of friction, still can not reach promising result.And inorganic pigment mixes with binder
After, ability conformance with standard be need to repeatedly grind, mass energy and time, Printing ink producing inefficiency expended.
Summary of the invention
For solving above-mentioned technical problem, the present invention provides a kind of microwax ink and preparation method thereof.To improve existing oil
Ink poor adhesive force, the problems such as stability is low, production efficiency is low.
For reaching above-mentioned purpose, the technical solution used in the present invention is:
A kind of microwax ink, is composed of the following components in parts by weight: Oleum Terebinthinae 4-10 part, azo pigment 0.5-3 part, ethyl
Cellulose 6-10 part, ethanol 5-7 part, binder 11-23 part, polyethylene microwax 3-7 part, aminating agent 1-5 part, water solublity third
Olefin(e) acid resin 1-5 part, friction resistant auxiliary agent 2-7 part, tridecanol 1-3 part, additive 0.5-2 part.
Preferably, in the preferred embodiment, described binder is made up of the raw material of following weight portion: polyethylene
Polyvinyl butyral resin 15-19 part, acrylic monomers 5-9 part, rosin resin 3-5 part, Oleum Verniciae fordii 1-5 part, dehydrated alcohol 1-3 part, nitre
Change cotton liquid 5-7 part, polyethylene microwax 0.5-1.5 part and acrylic resin 0.5-1.5 part.
Preferably, in the preferred embodiment, described aminating agent is ammonia.
Preferably, in the preferred embodiment, described additive is dispersant, defoamer and surfactant.
Preferably, in the preferred embodiment, described surfactant is aryl sulfonic acid natrium surfactant.
It addition, present invention also offers the preparation method of a kind of microwax ink, comprise the following steps:
(1) each component raw material is weighed by weight；
(2) described Oleum Terebinthinae, described azo pigment, described ethyl cellulose and described ethanol are added in reactor, stirring
Uniformly；
(3) add described binder, stir 10-20min mix homogeneously with 400-600r/min, mixed material is ground and divides
Dissipate；
(4) described reactor is warming up to 40-50 DEG C, reacts 5-10min；
(5), after cooling to 5-10 DEG C, continue to add described polyethylene microwax, described aminating agent, described in described reactor
Water soluble acrylic resin, described friction resistant auxiliary agent, described tridecanol, described additive, stir；
(6) described reactor is warming up to 30-40 DEG C, after reaction 5-15min, filters, take filtrate.
Preferably, in the preferred embodiment, in step (2), the speed of stirring is 800-1200 r/min.
Preferably, in the preferred embodiment, in step (3), grinding distribution to fineness is 400-600 mesh.
Preferably, in the preferred embodiment, in step (5), the speed of stirring is 400-800r/min.
Beneficial effects of the present invention: the microwax ink that the present invention provides is provided without inorganic pigment, uses water-soluble during preparation
Property acrylic resin, polyethylene microwax and azo pigment, decrease the number of times of grinding step, improve production efficiency；Simultaneously
The use of polyethylene microwax, allows the adhesive force of ink and crocking resistance be greatly improved, and adaptability is wider.Binder is added
Polyvinyl butyral resin, acrylic monomers and Oleum Verniciae fordii, make ink form uniform thin layer after printing, formed after drying
Having the film layer of some strength, shield pigment so that it is be difficult to come off, ink is bright in colour, and glossiness is higher.
Detailed description of the invention
Below in conjunction with specific embodiment, technical scheme of the present invention is further described.
Embodiment 1:
Embodiments of the invention 1 provide a kind of microwax ink, are composed of the following components in parts by weight: Oleum Terebinthinae 4 parts, azo
Series pigments 0.5 part, ethyl cellulose 6 parts, ethanol 5 parts, binder 11 parts, polyethylene microwax 3 parts, aminating agent 1 part, water-soluble
Property acrylic resin 1 part, friction resistant auxiliary agent 2 parts, tridecanol 1 part, additive 0.5 part.
Binder is made up of the raw material of following weight portion: polyvinyl butyral resin 15 parts, acrylic monomers 5 parts, pine
3 parts of balsam, Oleum Verniciae fordii 1 part, dehydrated alcohol 1 part, nitrocotton liquid 5 parts, polyethylene microwax 0.5 part and acrylic resin 0.5 part.
Aminating agent is ammonia.
Additive is dispersant, defoamer and surfactant.
Surfactant is aryl sulfonic acid natrium surfactant.
It addition, the present embodiment additionally provides the preparation method of a kind of microwax ink, comprise the following steps:
(1) each component raw material is weighed by weight；
(2) Oleum Terebinthinae, azo pigment, ethyl cellulose and ethanol are added in reactor, stir；
(3) add binder, stir 10min mix homogeneously with 400r/min, by mixed material grinding distribution；
(4) reactor is warming up to 40 DEG C, reacts 5min；
(5), after cooling to 5 DEG C, continue in reactor, to add polyethylene microwax, aminating agent, water soluble acrylic resin, resist
Friction auxiliary agent, tridecanol, additive, stir；
(6) reactor is warming up to 30 DEG C, after reaction 5min, filters, take filtrate.
In step (2), the speed of stirring is 800r/min.
In step (3), grinding distribution to fineness is 400 mesh.
In step (5), the speed of stirring is 400r/min.
Embodiment 2:
Embodiments of the invention 2 provide a kind of microwax ink, are composed of the following components in parts by weight: Oleum Terebinthinae 10 parts, idol
Nitrogen series pigments 3 parts, ethyl cellulose 10 parts, ethanol 7 parts, binder 23 parts, polyethylene microwax 7 parts, aminating agent 5 parts, water
Soluble acrylic resin 5 parts, friction resistant auxiliary agent 7 parts, tridecanol 3 parts, additive 2 parts.
Binder is made up of the raw material of following weight portion: polyvinyl butyral resin 19 parts, acrylic monomers 9 parts, pine
5 parts of balsam, Oleum Verniciae fordii 5 parts, dehydrated alcohol 3 parts, nitrocotton liquid 7 parts, polyethylene microwax 1.5 parts and acrylic resin 1.5 parts.
Aminating agent is ammonia.
Additive is dispersant, defoamer and surfactant.
Surfactant is aryl sulfonic acid natrium surfactant.
It addition, the present embodiment additionally provides the preparation method of a kind of microwax ink, comprise the following steps:
(1) each component raw material is weighed by weight；
(2) Oleum Terebinthinae, azo pigment, ethyl cellulose and ethanol are added in reactor, stir；
(3) add binder, stir 20min mix homogeneously with 600r/min, by mixed material grinding distribution；
(4) reactor is warming up to 50 DEG C, reacts 10min；
(5), after cooling to 10 DEG C, continue in reactor, to add polyethylene microwax, aminating agent, water soluble acrylic resin, resist
Friction auxiliary agent, tridecanol, additive, stir；
(6) reactor is warming up to 40 DEG C, after reaction 15min, filters, take filtrate.
In step (2), the speed of stirring is 1200 r/min.
In step (3), grinding distribution to fineness is 600 mesh.
In step (5), the speed of stirring is 800r/min.
Embodiment 3:
Embodiments of the invention 3 provide a kind of microwax ink, are composed of the following components in parts by weight: Oleum Terebinthinae 7 parts, azo
Series pigments 1.7 parts, ethyl cellulose 8 parts, ethanol 6 parts, binder 17 parts, polyethylene microwax 5 parts, aminating agent 3 parts, water-soluble
Property acrylic resin 3 parts, friction resistant auxiliary agent 4.5 parts, tridecanol 2 parts, additive 1.2 parts.
Binder is made up of the raw material of following weight portion: polyvinyl butyral resin 17 parts, acrylic monomers 7 parts, pine
4 parts of balsam, Oleum Verniciae fordii 3 parts, dehydrated alcohol 2 parts, nitrocotton liquid 6 parts, polyethylene microwax 1 part and acrylic resin 1 part.
Aminating agent is ammonia.
Additive is dispersant, defoamer and surfactant.
Surfactant is aryl sulfonic acid natrium surfactant.
It addition, the present embodiment additionally provides the preparation method of a kind of microwax ink, comprise the following steps:
(1) each component raw material is weighed by weight；
(2) Oleum Terebinthinae, azo pigment, ethyl cellulose and ethanol are added in reactor, stir；
(3) add binder, stir 15min mix homogeneously with 500r/min, by mixed material grinding distribution；
(4) reactor is warming up to 45 DEG C, reacts 7min；
(5), after cooling to 7 DEG C, continue in reactor, to add polyethylene microwax, aminating agent, water soluble acrylic resin, resist
Friction auxiliary agent, tridecanol, additive, stir；
(6) reactor is warming up to 35 DEG C, after reaction 10min, filters, take filtrate.
In step (2), the speed of stirring is 1000 r/min.
In step (3), grinding distribution to fineness is 500 mesh.
In step (5), the speed of stirring is 600r/min.
The product quality preparing embodiment 1-3 has carried out reliability inspection, is tested by adhesive force and 24 hours salt fogs
Test, salt spray test effect is accounted for the percent of the gross area by defect area A(sample surfaces defect) represent.Testing result such as table 1
Shown in:
Table 1: a kind of microwax ink assay
| Embodiment | Adhesive force (come off degree) | Defect area A(%) |
| Embodiment 1 | 8.2% | 0.14 |
| Embodiment 2 | 9.0% | 0.13 |
| Embodiment 3 | 6.6% | 0.11 |
By test it can be seen that microwax ink prepared by the present invention generally has preferable adhesive force and higher stablizing
Property.Being found by contrast, the product adhesive force that embodiment 3 prepares is higher, and the area that is corroded is less, has more preferable stability.
Claims (9)
1. a microwax ink, it is characterised in that be composed of the following components in parts by weight: Oleum Terebinthinae 4-10 part, azo system face
Material 0.5-3 part, ethyl cellulose 6-10 part, ethanol 5-7 part, binder 11-23 part, polyethylene microwax 3-7 part, aminating agent
1-5 part, water soluble acrylic resin's 1-5 part, friction resistant auxiliary agent 2-7 part, tridecanol 1-3 part, additive 0.5-2 part.
Microwax ink the most according to claim 1, it is characterised in that: described binder is by the raw material group of following weight portion
Become: polyvinyl butyral resin 15-19 part, acrylic monomers 5-9 part, rosin resin 3-5 part, Oleum Verniciae fordii 1-5 part, dehydrated alcohol
1-3 part, nitrocotton liquid 5-7 part, polyethylene microwax 0.5-1.5 part and acrylic resin 0.5-1.5 part.
Microwax ink the most according to claim 1, it is characterised in that: described aminating agent is ammonia.
Microwax ink the most according to claim 1, it is characterised in that: described additive is dispersant, defoamer and table
Face activating agent.
Microwax ink the most according to claim 1, it is characterised in that: described surfactant is aryl sulfonic acid sodium surface
Activating agent.
6. the preparation method of the microwax ink as described in any one of claim 1-5, it is characterised in that include following step
Rapid:
(1) each component raw material is weighed by weight；
(2) described Oleum Terebinthinae, described azo pigment, described ethyl cellulose and described ethanol are added in reactor, stirring
Uniformly；
(3) add described binder, stir 10-20min mix homogeneously with 400-600r/min, mixed material is ground and divides
Dissipate；
(4) described reactor is warming up to 40-50 DEG C, reacts 5-10min；
(5), after cooling to 5-10 DEG C, continue to add described polyethylene microwax, described aminating agent, described in described reactor
Water soluble acrylic resin, described friction resistant auxiliary agent, described tridecanol, described additive, stir；
(6) described reactor is warming up to 30-40 DEG C, after reaction 5-15min, filters, take filtrate.
The preparation method of a kind of microwax ink the most according to claim 6, it is characterised in that: stirring in step (2)
Speed be 800-1200 r/min.
The preparation method of a kind of microwax ink the most according to claim 6, it is characterised in that: step (3) is ground
Being dispersed to fineness is 400-600 mesh.
The preparation method of a kind of microwax ink the most according to claim 6, it is characterised in that: stirring in step (5)
Speed be 400-800r/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610667717.0A CN106084995A (en) | 2016-08-15 | 2016-08-15 | A kind of microwax ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610667717.0A CN106084995A (en) | 2016-08-15 | 2016-08-15 | A kind of microwax ink and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN106084995A true CN106084995A (en) | 2016-11-09 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610667717.0A Pending CN106084995A (en) | 2016-08-15 | 2016-08-15 | A kind of microwax ink and preparation method thereof |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666019A (en) * | 2013-12-11 | 2014-03-26 | 苏州谊恒印务有限公司 | Alcohol-soluble letterpress ink |
| CN104817875A (en) * | 2015-04-24 | 2015-08-05 | 郭小曼 | Microcrystalline wax printing ink and preparation method thereof |
-
2016
- 2016-08-15 CN CN201610667717.0A patent/CN106084995A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103666019A (en) * | 2013-12-11 | 2014-03-26 | 苏州谊恒印务有限公司 | Alcohol-soluble letterpress ink |
| CN104817875A (en) * | 2015-04-24 | 2015-08-05 | 郭小曼 | Microcrystalline wax printing ink and preparation method thereof |
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Application publication date: 20161109 |