CN106084357A - A kind of oil-resistant wear-resistant rubber - Google Patents
A kind of oil-resistant wear-resistant rubber Download PDFInfo
- Publication number
- CN106084357A CN106084357A CN201610459671.3A CN201610459671A CN106084357A CN 106084357 A CN106084357 A CN 106084357A CN 201610459671 A CN201610459671 A CN 201610459671A CN 106084357 A CN106084357 A CN 106084357A
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- China
- Prior art keywords
- rubber
- resistant
- oil
- white carbon
- wear
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of oil-resistant wear-resistant rubber, it is added with natural rubber, there is the premium properties of natural rubber, additionally, it is added with butadiene-styrene rubber and bromination butene rubber, it is equipped with white carbon, white carbon black, magnesium oxide, zinc oxide again, hydrocarbon oil, plasticizer, urethanes and sodium pyrosulfite etc., can effectively improve its oil resistant anti-wear performance.Oil resistivity improves 41.5% less than 6.2%, compared with the anti-wear performance tire commercially available with present stage of automobile tire that prepare of the rubber of the present invention.
Description
Technical field
The invention belongs to field of rubber technology, be specifically related to a kind of oil-resistant wear-resistant rubber.
Background technology
So-called rubber, is the strong flexible polymer material with reversible deformation, and at room temperature high resilience, outside the least
Can produce relatively large deformation under power effect, remove resilient after external force, excellent high-performance tire material is except rubber itself
Have outside outstanding combination property, in addition it is also necessary to consider from the processing characteristics of rubber.
Along with expanding economy and the demand of the factor such as weather, environment, in tire industry, the demand for rubber also exists
Improving, security performance and the technical ability performance of tire are had higher requirement by people, and tire develops to high-performance direction, example
Wearability of wet-sliding resistant performance, low-rolling-resistance and excellence such as tire etc..
At present, although the abrasive rubber product category of market sale is various, but mostly there is wearability and oil resistivity not
The problem of foot.
How to improve the oil resistant anti-wear performance of rubber, be the technical issues that need to address of the present invention.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of oil-resistant wear-resistant rubber.The wear-resisting rubber of oil resistant of the present invention
Glue is added with natural rubber, has the premium properties of natural rubber, it addition, be added with butadiene-styrene rubber and bromination butene rubber, then
It is equipped with white carbon, white carbon black, magnesium oxide, zinc oxide, hydrocarbon oil, plasticizer, urethanes and sodium pyrosulfite etc., can have
Its oil resistant anti-wear performance of raising of effect.Oil resistivity less than 6%, the anti-wear performance of automobile tire for preparing of the rubber of the present invention with
Commercially available tire was compared and was improve 41.5% present stage.
The present invention is to be realized by following technical scheme:
A kind of oil-resistant wear-resistant rubber, is made up of following component by weight: natural rubber 20-40, butadiene-styrene rubber 20-60, bromine
Change butene rubber 20-40, white carbon 10-15, white carbon black 15-20, zinc oxide 1-8, magnesium oxide 2-10, softening agent 2-15, anti-old
Agent 5-10, microwax 1-4, accelerator 1-2, sulfur 2-5, plasticizer 3-10, urethanes 5-8, sodium pyrosulfite 3-
5。
Described a kind of oil-resistant wear-resistant rubber, it is preferred that natural rubber 30, butadiene-styrene rubber 40, bromination butene rubber 30, in vain
White carbon black 12, white carbon black 16, zinc oxide 4, magnesium oxide 5, softening agent 8, age resistor 6, microwax 2, accelerator 1, sulfur 3, plasticizer
5, urethanes 6, sodium pyrosulfite 4.
Described white carbon black is white carbon black N220.
Described age resistor is made up of anti-aging agent RD, age resistor 3100.
Anti-aging agent RD, the mass ratio of age resistor 3100 are 1:2.
Softening agent is hydrocarbon oil.
Accelerator is made up of Vulcanization accelerator TMTD and accelerant CZ, and the mass ratio of Vulcanization accelerator TMTD and accelerant CZ is 1:1.
Described plasticizer is tricresyl phosphate.
The beneficial effects of the present invention is: the oil-resistant wear-resistant rubber of the present invention is added with natural rubber, has natural rubber
Premium properties, it addition, be added with butadiene-styrene rubber and bromination butene rubber, then be equipped with white carbon, white carbon black, magnesium oxide, zinc oxide,
Hydrocarbon oil, plasticizer, urethanes and sodium pyrosulfite etc., can effectively improve its oil resistant anti-wear performance.Oil resistivity
Improve less than 6.2%, compared with the anti-wear performance tire commercially available with present stage of automobile tire that prepare of the rubber of the present invention
41.5%。
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is further described, in order to those skilled in the art knows more about
The present invention, but and it is not so limited the present invention.
Embodiment 1
A kind of oil-resistant wear-resistant rubber, natural rubber 30, butadiene-styrene rubber 40, bromination butene rubber 30, white carbon 12, white carbon black 16, oxygen
Change zinc 4, magnesium oxide 5, softening agent 8, age resistor 6, microwax 2, accelerator 1, sulfur 3, plasticizer 5, urethanes 6,
Sodium pyrosulfite 4.
Described white carbon black is white carbon black N220.
Described age resistor is made up of anti-aging agent RD, age resistor 3100.
Anti-aging agent RD, the mass ratio of age resistor 3100 are 1:2.
Softening agent is hydrocarbon oil.
Accelerator is made up of Vulcanization accelerator TMTD and accelerant CZ, and the mass ratio of Vulcanization accelerator TMTD and accelerant CZ is 1:1.
Described plasticizer is tricresyl phosphate.
The rubber produced by above-mentioned formula, oil resistance (expansion rate after oil immersion bubble) 6.2%, the rubber of the present invention prepares
Automobile tire anti-wear performance tire commercially available with present stage compared with improve 41.5%.
Claims (8)
1. an oil-resistant wear-resistant rubber, it is characterised in that be made up of following component by weight: natural rubber 20-40, butylbenzene
Rubber 20-60, bromination butene rubber 20-40, white carbon 10-15, white carbon black 15-20, zinc oxide 1-8, magnesium oxide 2-10, soften
Agent 2-15, age resistor 5-10, microwax 1-4, accelerator 1-2, sulfur 2-5, plasticizer 3-10, urethanes 5-8 are burnt
Sodium sulfite 3-5.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that natural rubber 30, butadiene-styrene rubber 40,
Bromination butene rubber 30, white carbon 12, white carbon black 16, zinc oxide 4, magnesium oxide 5, softening agent 8, age resistor 6, microwax 2, promote
Agent 1, sulfur 3, plasticizer 5, urethanes 6, sodium pyrosulfite 4.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that described white carbon black is white carbon black N220.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that described age resistor is by anti-aging agent RD, anti-
Old agent 3100 forms.
A kind of oil-resistant wear-resistant rubber the most according to claim 4, it is characterised in that anti-aging agent RD, the matter of age resistor 3100
Amount ratio is 1:2.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that softening agent is hydrocarbon oil.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that accelerator is by Vulcanization accelerator TMTD and promotion
Agent CZ forms, and the mass ratio of Vulcanization accelerator TMTD and accelerant CZ is 1:1.
A kind of oil-resistant wear-resistant rubber the most according to claim 1, it is characterised in that described plasticizer is phosphate trimethylbenzene
Ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610459671.3A CN106084357A (en) | 2016-06-23 | 2016-06-23 | A kind of oil-resistant wear-resistant rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610459671.3A CN106084357A (en) | 2016-06-23 | 2016-06-23 | A kind of oil-resistant wear-resistant rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106084357A true CN106084357A (en) | 2016-11-09 |
Family
ID=57252064
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610459671.3A Pending CN106084357A (en) | 2016-06-23 | 2016-06-23 | A kind of oil-resistant wear-resistant rubber |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106084357A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086290A (en) * | 2009-12-07 | 2011-06-08 | 四川轮胎橡胶（集团）股份有限公司 | Riding radial tire airtight layer calendering sizing compound |
| CN103435857A (en) * | 2013-08-07 | 2013-12-11 | 山东永泰化工有限公司 | Automobile tire tube rubber |
| EP2690136A1 (en) * | 2012-07-25 | 2014-01-29 | Lanxess Elastomers B.V. | Thermoplastic elastomer compositions and process for preparing them |
| CN105131357A (en) * | 2015-09-02 | 2015-12-09 | 苏州国泰科技发展有限公司 | Fatigue-resistant tread rubber and preparation method thereof |
| CN105273255A (en) * | 2015-09-09 | 2016-01-27 | 苏州国泰科技发展有限公司 | Automobile tire wear-resistant rubber |
| CN105315524A (en) * | 2015-09-09 | 2016-02-10 | 苏州国泰科技发展有限公司 | Preparation method of abrasion-resistant rubber for automobile tire |
-
2016
- 2016-06-23 CN CN201610459671.3A patent/CN106084357A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086290A (en) * | 2009-12-07 | 2011-06-08 | 四川轮胎橡胶（集团）股份有限公司 | Riding radial tire airtight layer calendering sizing compound |
| EP2690136A1 (en) * | 2012-07-25 | 2014-01-29 | Lanxess Elastomers B.V. | Thermoplastic elastomer compositions and process for preparing them |
| CN103435857A (en) * | 2013-08-07 | 2013-12-11 | 山东永泰化工有限公司 | Automobile tire tube rubber |
| CN105131357A (en) * | 2015-09-02 | 2015-12-09 | 苏州国泰科技发展有限公司 | Fatigue-resistant tread rubber and preparation method thereof |
| CN105273255A (en) * | 2015-09-09 | 2016-01-27 | 苏州国泰科技发展有限公司 | Automobile tire wear-resistant rubber |
| CN105315524A (en) * | 2015-09-09 | 2016-02-10 | 苏州国泰科技发展有限公司 | Preparation method of abrasion-resistant rubber for automobile tire |
Non-Patent Citations (1)
| Title |
|---|
| 赵晨阳主编: "《化工产品手册 精细无机化工产品》", 31 July 2008, 化学工业出版社 * |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161109 |
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| RJ01 | Rejection of invention patent application after publication |