CN105419023A - Tire tread rubber special for shop truck - Google Patents

Tire tread rubber special for shop truck Download PDF

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Publication number
CN105419023A
CN105419023A CN201510947855.XA CN201510947855A CN105419023A CN 105419023 A CN105419023 A CN 105419023A CN 201510947855 A CN201510947855 A CN 201510947855A CN 105419023 A CN105419023 A CN 105419023A
Authority
CN
China
Prior art keywords
rubber
tread rubber
engineering truck
carbon black
tyre tread
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510947855.XA
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Chinese (zh)
Inventor
尤晓明
王显涛
张新平
曹佃波
冯小波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yongtai Shandong Group Co Ltd
Original Assignee
Yongtai Shandong Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yongtai Shandong Group Co Ltd filed Critical Yongtai Shandong Group Co Ltd
Priority to CN201510947855.XA priority Critical patent/CN105419023A/en
Publication of CN105419023A publication Critical patent/CN105419023A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06Copolymers with styrene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Tires In General (AREA)

Abstract

The invention relates to tire tread rubber special for a shop truck. According to the tire tread rubber, adopted high vinyl polybutadiene rubber can effectively improve the wear-resisting property of the tire tread rubber, in addition, under the synergistic effect of other components in the tire tread rubber, the wear-resisting property and ageing resistance of the rubber are further improved, the wear-resisting property of the rubber is improved while the requirements of tire tread cut resistance, chunking and falling resistance are met, and the service life of a tire is greatly prolonged.

Description

A kind of engineering truck special tyre tread rubber
Technical field
The invention belongs to tire manufacturing techniques field, be specifically related to a kind of engineering truck special tyre tread rubber.
Background technology
Because natural rubber has best bond properties, and synthetic rubber has outstanding abrasion resistance, thus all-steel radial tyre tread rubber generally adopt natural rubber and synthetic rubber and rubber system.
Off-the-road tyre travel speed is low, load is large, haul distance is short, turning is frequent, its tread rubber general requirement cut resistant, resistance to puncture, anti-collapse use up block, abrasion performance, good springiness, hardness high, be out of shape little, heat-dissipating is low.Based on the over-all properties that natural rubber is good, although the prices of raw and semifnished materials are high, traditional off-the-road tyre tread rubber composition majority still adopts All Pure Nature rubber, or with styrene-butadiene rubber(SBR) in 70/30 ratio and use.In fact, theoretical and test all shows, natural rubber for improving the abrasion performance of tread mix, cut resistant, resistance to puncture, anti-collapsing use up block performance and reduce the aspects such as distortion, contribute not remarkable, its advantage is mainly good processing characteristics and lower hysteresis loss, and these characteristics all by equipment and processing and manufacturing technology and reasonably Design of Tire Structure made up.Although adding of styrene-butadiene rubber(SBR) can provide good belt cutting-resisting property for tread rubber, its heat-dissipating is higher, and speed of response is slow, and wear resisting property is slightly poor.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of engineering truck special tyre tread rubber.By being optimized the raw material of tire tread glue and ratio and adjusting, meet tire tread cut resistant, anti-collapse use up block while, improve its wear resisting property, improve the work-ing life of tire dramatically.
A kind of engineering truck special tyre tread rubber of the present invention is realized by following technical scheme: described tread rubber comprises the component of following portions by weight:
Natural rubber 20-50 high vinyl polybutadiene rubber 20-80
Solution polymerized butadiene styrene rubber 20-80 silane coupling agent Si-691-4
Stearic acid 1-4 protection wax 1-3
Sulphur 1-4 amine-BSA1-5
Carbon black 10-50 white carbon black 7-15
Process oil 3-10 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4ISAF1-30
Altax 0.5-2 accelerant CZ 0.5-3.
Described high vinyl polybutadiene rubber Mooney viscosity 65-80, contents of ethylene 85-90%.
Described carbon black is N339.
Described anti-aging agent is antioxidant 4020.
Described white carbon black is the precipitated silica of particle diameter 20-100nm.
Described petroleum resin are coumarone petroleum resin.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
Described a kind of engineering truck special tyre tread rubber, is grouped into by following one-tenth by weight:
Natural rubber 30 high vinyl polybutadiene rubber 30
Solution polymerized butadiene styrene rubber 40 silane coupling agent Si-691.4
Stearic acid 1.2 protection wax 1.6
Sulphur 2.5 amine-BSA2
Carbon black 45 white carbon black 12
Process oil 6 resol resin 2
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011ISAF8
Altax 0.8 accelerant CZ 1.5.
Beneficial effect of the present invention is, tread rubber of the present invention, tire wear, resistance to deterioration are good, the mixing of the natural rubber adopted, high vinyl polybutadiene rubber, solution polymerized butadiene styrene rubber, effectively can improve the wear resisting property of tread rubber, high vinyl polybutadiene rubber, has good wet-sliding resistant performance, lower rolling resistance and heat-dissipating.
In addition, the interpolation of the interpolation of each ancillary component further increases wear resisting property and the ageing resistance of rubber.The present invention by rational proportion design, make the sizing material of gained meet tire resist collapse use up block while improve its wear resisting property, Using Life of Tyre is improved largely.
It is crown in two side three block structures or upper, middle level tread rubber part that sizing material provided by the invention only can be used as tyre surface working design, with have compared with low-heat-generation Tire shoulder rubber material with the use of, there is the defects such as early stage shoulder is empty to avoid tire.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
A kind of engineering truck special tyre tread rubber, is made up of following component by weight:
Natural rubber 30 high vinyl polybutadiene rubber 30
Solution polymerized butadiene styrene rubber 40 silane coupling agent Si-691.4
Stearic acid 1.2 protection wax 1.6
Sulphur 2.5 amine-BSA2
Carbon black 45 white carbon black 12
Process oil 6 resol resin 2
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011ISAF8
Altax 0.8 accelerant CZ 1.5.
Described high vinyl polybutadiene rubber Mooney viscosity 65-80, contents of ethylene 85-90%.
Described carbon black is N339.
Described anti-aging agent is antioxidant 4020.
Described white carbon black is the precipitated silica of particle diameter 20-100nm.。
Described petroleum resin are coumarone petroleum resin.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
After testing, 80 weeks abrasion performance (the Pico)/cm of the tread rubber sizing material in the present embodiment 3for 0.0010-0.0017;
300% stress at definite elongation reaches 31.2Mpa; Hardness is 75 Shao Er; Tensile strength at yield is 27.2MPa; Tensile yield is 590%; Compression heat generation is 37 DEG C; Cut resistant decrement is less than 1.4g.

Claims (8)

1. an engineering truck special tyre tread rubber, is characterized in that, described tread rubber comprises the component of following portions by weight:
Natural rubber 20-50 high vinyl polybutadiene rubber 20-80
Solution polymerized butadiene styrene rubber 20-80 silane coupling agent Si-691-4
Stearic acid 1-4 protection wax 1-3
Sulphur 1-4 amine-BSA1-5
Carbon black 10-50 white carbon black 7-15
Process oil 3-10 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4ISAF1-30
Altax 0.5-2 accelerant CZ 0.5-3.
2. a kind of engineering truck special tyre tread rubber according to claim 1, is characterized in that, described high vinyl polybutadiene rubber Mooney viscosity 65-80, contents of ethylene 85-90%.
3. a kind of engineering truck special tyre tread rubber according to claim 2, it is characterized in that, described carbon black is N339.
4. a kind of engineering truck special tyre tread rubber according to claim 3, it is characterized in that, described anti-aging agent is antioxidant 4020.
5. a kind of engineering truck special tyre tread rubber according to claim 4, it is characterized in that, described white carbon black is the precipitated silica of particle diameter 20-100nm.
6. a kind of engineering truck special tyre tread rubber according to claim 5, it is characterized in that, described petroleum resin are coumarone petroleum resin.
7. a kind of engineering truck special tyre tread rubber according to claim 6, is characterized in that, described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
8. a kind of engineering truck special tyre tread rubber according to claim 7, is characterized in that, be grouped into by following one-tenth by weight:
Natural rubber 30 high vinyl polybutadiene rubber 30
Solution polymerized butadiene styrene rubber 40 silane coupling agent Si-691.4
Stearic acid 1.2 protection wax 1.6
Sulphur 2.5 amine-BSA2
Carbon black 45 white carbon black 12
Process oil 6 resol resin 2
Zinc oxide 4 anti-aging agent 1.5
Anti-recovery agent WK-9011ISAF8
Altax 0.8 accelerant CZ 1.5.
CN201510947855.XA 2015-12-17 2015-12-17 Tire tread rubber special for shop truck Pending CN105419023A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510947855.XA CN105419023A (en) 2015-12-17 2015-12-17 Tire tread rubber special for shop truck

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510947855.XA CN105419023A (en) 2015-12-17 2015-12-17 Tire tread rubber special for shop truck

Publications (1)

Publication Number Publication Date
CN105419023A true CN105419023A (en) 2016-03-23

Family

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Family Applications (1)

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CN201510947855.XA Pending CN105419023A (en) 2015-12-17 2015-12-17 Tire tread rubber special for shop truck

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009096A (en) * 2016-06-24 2016-10-12 山东永泰集团有限公司 Rubber for improving wet slip resistance of tires
CN106188661A (en) * 2016-07-15 2016-12-07 山东永泰集团有限公司 A kind of magnetic suspension train tire tread glue and preparation method thereof
CN106832448A (en) * 2017-02-22 2017-06-13 双钱集团上海轮胎研究所有限公司 A kind of tread rubber for preparing high-performance tire
CN107141538A (en) * 2017-07-11 2017-09-08 合肥康之恒机械科技有限公司 A kind of wear-resisting tread rubber of bull dozer tire and preparation method thereof
CN107163329A (en) * 2017-07-11 2017-09-15 合肥康之恒机械科技有限公司 A kind of excavator tyre rubber material and preparation method thereof
CN107722403A (en) * 2017-10-27 2018-02-23 山东通泰橡胶股份有限公司 A kind of elastomeric material of wear-resisting cut resistant and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792545A (en) * 2010-03-04 2010-08-04 杭州中策橡胶有限公司 Tread rubber glue stock of tyre with low rolling resistance and tyre adopting tread rubber
CN102863656A (en) * 2011-07-06 2013-01-09 中国石油化工股份有限公司 Tread rubber material for preparing high-performance tyre
CN103483627A (en) * 2013-08-02 2014-01-01 山东永泰化工有限公司 Automobile tire tread rubber
CN103756024A (en) * 2013-11-27 2014-04-30 山东龙跃橡胶有限公司 Tread rubber for high thermal diffusivity semisteel car tire and tire

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792545A (en) * 2010-03-04 2010-08-04 杭州中策橡胶有限公司 Tread rubber glue stock of tyre with low rolling resistance and tyre adopting tread rubber
CN102863656A (en) * 2011-07-06 2013-01-09 中国石油化工股份有限公司 Tread rubber material for preparing high-performance tyre
CN103483627A (en) * 2013-08-02 2014-01-01 山东永泰化工有限公司 Automobile tire tread rubber
CN103756024A (en) * 2013-11-27 2014-04-30 山东龙跃橡胶有限公司 Tread rubber for high thermal diffusivity semisteel car tire and tire

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
(美)约翰S.迪克主编: "《提高橡胶胶料性能实用方案1500例》", 31 March 2013, 机械工业出版社 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009096A (en) * 2016-06-24 2016-10-12 山东永泰集团有限公司 Rubber for improving wet slip resistance of tires
CN106188661A (en) * 2016-07-15 2016-12-07 山东永泰集团有限公司 A kind of magnetic suspension train tire tread glue and preparation method thereof
CN106832448A (en) * 2017-02-22 2017-06-13 双钱集团上海轮胎研究所有限公司 A kind of tread rubber for preparing high-performance tire
CN106832448B (en) * 2017-02-22 2019-02-26 双钱集团上海轮胎研究所有限公司 A kind of tread rubber being used to prepare high-performance tire
CN107141538A (en) * 2017-07-11 2017-09-08 合肥康之恒机械科技有限公司 A kind of wear-resisting tread rubber of bull dozer tire and preparation method thereof
CN107163329A (en) * 2017-07-11 2017-09-15 合肥康之恒机械科技有限公司 A kind of excavator tyre rubber material and preparation method thereof
CN107722403A (en) * 2017-10-27 2018-02-23 山东通泰橡胶股份有限公司 A kind of elastomeric material of wear-resisting cut resistant and preparation method thereof

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Application publication date: 20160323