CN105418993A - Tread rubber of radial tire - Google Patents

Tread rubber of radial tire Download PDF

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Publication number
CN105418993A
CN105418993A CN201510947843.7A CN201510947843A CN105418993A CN 105418993 A CN105418993 A CN 105418993A CN 201510947843 A CN201510947843 A CN 201510947843A CN 105418993 A CN105418993 A CN 105418993A
Authority
CN
China
Prior art keywords
rubber
carbon black
meridian tyre
resistance
tyre according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510947843.7A
Other languages
Chinese (zh)
Inventor
尤晓明
王显涛
张新平
曹佃波
冯小波
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yongtai Shandong Group Co Ltd
Original Assignee
Yongtai Shandong Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yongtai Shandong Group Co Ltd filed Critical Yongtai Shandong Group Co Ltd
Priority to CN201510947843.7A priority Critical patent/CN105418993A/en
Publication of CN105418993A publication Critical patent/CN105418993A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention relates to tread rubber of a radial tire. The tread rubber disclosed by the invention is prepared by mixing natural rubber, butadiene styrene rubber and cis-1,4-polyisoprene rubber; due to the matching of other auxiliary materials, the tread rubber not only has good properties of cutting resistance, prickling resistance, crack extension resistance and tear and chipping resistance, but also has the characteristics of lower dynamic heat generation and better heat resistance; the tread rubber can be used for a long time and is not easy to age, and a prepared tire is good in abrasion resistance and aging resistance.

Description

A kind of meridian tyre
Technical field
The invention belongs to tread rubber technical field, be specifically related to a kind of meridian tyre.
Background technology
Radial is widely used in engineering transportation equipment now, and in use, because working conditions is relatively harsh, not cut resistant when using such as have sharp-pointed ore pavement conditions under more bad pavement conditions under, easily collapses and use up block; The existing tread rubber that can adapt to more bad pavement conditions, when using under fair speed condition, dynamic heat build up is high, easy delamination, bulge.Existingly can adapt to that more bad pavement conditions can use again under fair speed condition, under the natural condition such as daylight long-term to place easily aging.
Though TBR tire tread formula lays particular emphasis on the compound physical performance need solving certain aspect in prior art.But fail the relation of the every physical and mechanical properties of overall equilbrium tread mix.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides a kind of meridian tyre.The natural rubber that tread rubber of the present invention adopts, styrene-butadiene rubber(SBR), suitable 1,4-polyisoprene rubber mixes, coordinate other auxiliary materials not only to have good cut resistant, resistance to puncture, the expansion of cracking resistance mouth and anti tear and fall block performance, but also have that dynamic heat build up is lower, the good feature of resistance toheat, and can life-time service, not easily aging, tire wear, the resistance to deterioration of preparation are good.
A kind of meridian tyre of the present invention is realized by following technical scheme:
Described tread rubber comprises the component of following portions by weight:
Natural rubber 70-90 styrene-butadiene rubber(SBR) 10-50
Along Isosorbide-5-Nitrae-polyisoprene rubber 10-50 silane coupling agent Si-691-4
Stearic acid 1-4 sulphur 2-4
Carbon black 10-50 white carbon black 7-15
Plasticizer A 1-4 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4 altax 0.5-2
Accelerant CZ 0.5-3 aromatic hydrocarbon oil 10-40.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
Described carbon black is N220 and N234.
Carbon black N220 and N234 mixes according to the ratio of weight ratio 1:1,
Described described anti-aging agent is Microcrystalline Wax and anti-aging agent RD.
Microcrystalline Wax and anti-aging agent RD mix according to the ratio of weight ratio 1:1.
Described described white carbon black is the precipitated silica of particle diameter 20-100nm.
Described a kind of meridian tyre, is grouped into by following one-tenth by weight:
Natural rubber 50 styrene-butadiene rubber(SBR) 40
Along Isosorbide-5-Nitrae-polyisoprene rubber 10 silane coupling agent Si-692
Stearic acid 2 sulphur 2.5
Carbon black 45 white carbon black 10
Plasticizer A 2 resol resin 2
Zinc oxide 4 anti-aging agent 3
Anti-recovery agent WK-9012 altax 1.2
Accelerant CZ 1 aromatic hydrocarbon oil 12.
Beneficial effect of the present invention is, the natural rubber that tread rubber of the present invention adopts, styrene-butadiene rubber(SBR), suitable 1,4-polyisoprene rubber mixes, coordinate other auxiliary materials not only to have good cut resistant, resistance to puncture, the expansion of cracking resistance mouth and anti tear and fall block performance, but also have that dynamic heat build up is lower, the good feature of resistance toheat, and can life-time service, not easily aging, tire wear, the resistance to deterioration of preparation are good.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
A kind of meridian tyre is grouped into by following one-tenth by weight:
Natural rubber 50 styrene-butadiene rubber(SBR) 40
Along Isosorbide-5-Nitrae-polyisoprene rubber 10 silane coupling agent Si-692
Stearic acid 2 sulphur 2.5
Carbon black 45 white carbon black 10
Plasticizer A 2 resol resin 2
Zinc oxide 4 anti-aging agent 3
Anti-recovery agent WK-9012 altax 1.2
Accelerant CZ 1 aromatic hydrocarbon oil 12.
Described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
Described carbon black is that N220 and N234 mixes according to the ratio of weight ratio 1:1,
Described described anti-aging agent is that Microcrystalline Wax and anti-aging agent RD mix according to the ratio of weight ratio 1:1.
Described described white carbon black is the precipitated silica of particle diameter 20-100nm.
After testing, 80 weeks abrasion performance (the Pico)/cm of the tread rubber sizing material in the present embodiment 3for 0.00010-0.0020;
300% stress at definite elongation reaches 33.5Mpa; Hardness is 75 Shao Er; Tensile strength at yield is 25.3MPa; Tensile yield is 580%; Compression heat generation is 35 DEG C; Cut resistant decrement is less than 1.4g.

Claims (8)

1. a meridian tyre, is characterized in that, described tread rubber comprises the component of following portions by weight:
Natural rubber 70-90 styrene-butadiene rubber(SBR) 10-50
Along Isosorbide-5-Nitrae-polyisoprene rubber 10-50 silane coupling agent Si-691-4
Stearic acid 1-4 sulphur 2-4
Carbon black 10-50 white carbon black 7-15
Plasticizer A 1-4 resol resin 1-4
Zinc oxide 1-8 anti-aging agent 1-10
Anti-recovery agent WK-9011-4 altax 0.5-2
Accelerant CZ 0.5-3 aromatic hydrocarbon oil 10-40.
2. a kind of meridian tyre according to claim 1, is characterized in that, described natural rubber is 1# smoke sheet rubber or 3# smoke sheet rubber.
3. a kind of meridian tyre according to claim 2, is characterized in that, described carbon black is N220 and N234.
4. a kind of meridian tyre according to claim 3, is characterized in that, carbon black N220 and N234 mixes according to the ratio of weight ratio 1:1.
5. a kind of meridian tyre according to claim 4, is characterized in that, described described anti-aging agent is Microcrystalline Wax and anti-aging agent RD.
6. a kind of meridian tyre according to claim 5, is characterized in that, Microcrystalline Wax and anti-aging agent RD mix according to the ratio of weight ratio 1:1.
7. a kind of meridian tyre according to claim 6, is characterized in that, described described white carbon black is the precipitated silica of particle diameter 20-100nm.
8. a kind of meridian tyre according to claim 7, is characterized in that, is grouped into by following one-tenth by weight:
Natural rubber 50 styrene-butadiene rubber(SBR) 40
Along Isosorbide-5-Nitrae-polyisoprene rubber 10 silane coupling agent Si-692
Stearic acid 2 sulphur 2.5
Carbon black 45 white carbon black 10
Plasticizer A 2 resol resin 2
Zinc oxide 4 anti-aging agent 3
Anti-recovery agent WK-9012 altax 1.2
Accelerant CZ 1 aromatic hydrocarbon oil 12.
CN201510947843.7A 2015-12-17 2015-12-17 Tread rubber of radial tire Pending CN105418993A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510947843.7A CN105418993A (en) 2015-12-17 2015-12-17 Tread rubber of radial tire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510947843.7A CN105418993A (en) 2015-12-17 2015-12-17 Tread rubber of radial tire

Publications (1)

Publication Number Publication Date
CN105418993A true CN105418993A (en) 2016-03-23

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
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Country Status (1)

Country Link
CN (1) CN105418993A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009096A (en) * 2016-06-24 2016-10-12 山东永泰集团有限公司 Rubber for improving wet slip resistance of tires
CN106118081A (en) * 2016-08-18 2016-11-16 四川远星橡胶有限责任公司 A kind of low rolling resistance tire tread compound
CN106496666A (en) * 2016-11-22 2017-03-15 正新橡胶(中国)有限公司 A kind of rubber composition and tire for tire tread
CN107082922A (en) * 2017-05-27 2017-08-22 安徽誉林汽车部件有限公司 A kind of automobile tire abrasion-resistant rubber material
CN108424552A (en) * 2018-04-08 2018-08-21 贾中将 A kind of rubber absorbers of high anti-reversion behaviour
CN115216066A (en) * 2022-07-15 2022-10-21 山东玲珑轮胎股份有限公司 High-strength aviation radial tire tread rubber material and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101228223A (en) * 2005-05-26 2008-07-23 米其林技术公司 Rubber composition for tyre comprising an organosilicium coupling agent and an inorganic filler covering agent
CN101233181A (en) * 2005-05-26 2008-07-30 米其林技术公司 Rubber composition for tyre comprising an organosiloxane coupling agent
CN101735492A (en) * 2010-01-22 2010-06-16 中国化工橡胶桂林有限公司 Engineering tire tread rubber

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101228223A (en) * 2005-05-26 2008-07-23 米其林技术公司 Rubber composition for tyre comprising an organosilicium coupling agent and an inorganic filler covering agent
CN101233181A (en) * 2005-05-26 2008-07-30 米其林技术公司 Rubber composition for tyre comprising an organosiloxane coupling agent
CN101735492A (en) * 2010-01-22 2010-06-16 中国化工橡胶桂林有限公司 Engineering tire tread rubber

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
吴明生等: "提高工程轮胎使用寿命的措施", 《特种橡胶制品》 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009096A (en) * 2016-06-24 2016-10-12 山东永泰集团有限公司 Rubber for improving wet slip resistance of tires
CN106118081A (en) * 2016-08-18 2016-11-16 四川远星橡胶有限责任公司 A kind of low rolling resistance tire tread compound
CN106496666A (en) * 2016-11-22 2017-03-15 正新橡胶(中国)有限公司 A kind of rubber composition and tire for tire tread
CN106496666B (en) * 2016-11-22 2019-02-12 正新橡胶(中国)有限公司 A kind of rubber composition and tire for tire tread
CN107082922A (en) * 2017-05-27 2017-08-22 安徽誉林汽车部件有限公司 A kind of automobile tire abrasion-resistant rubber material
CN108424552A (en) * 2018-04-08 2018-08-21 贾中将 A kind of rubber absorbers of high anti-reversion behaviour
CN108424552B (en) * 2018-04-08 2020-05-12 贾中将 Rubber shock absorber with high reversion resistance
CN115216066A (en) * 2022-07-15 2022-10-21 山东玲珑轮胎股份有限公司 High-strength aviation radial tire tread rubber material and preparation method and application thereof

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Application publication date: 20160323