CN106082994A - A kind of Mount Huang ballstone ceramic tile and preparation method thereof - Google Patents

A kind of Mount Huang ballstone ceramic tile and preparation method thereof Download PDF

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Publication number
CN106082994A
CN106082994A CN201610420684.XA CN201610420684A CN106082994A CN 106082994 A CN106082994 A CN 106082994A CN 201610420684 A CN201610420684 A CN 201610420684A CN 106082994 A CN106082994 A CN 106082994A
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Prior art keywords
slag
ballstone
mount huang
mine tailing
ceramic tile
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CN201610420684.XA
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郑辉
郭孝建
王俊武
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ANHUI YA'OU CERAMIC Co Ltd
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ANHUI YA'OU CERAMIC Co Ltd
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Publication of CN106082994A publication Critical patent/CN106082994A/en
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349—Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9669—Resistance against chemicals, e.g. against molten glass or molten salts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a kind of Mount Huang ballstone ceramic tile and preparation method thereof, it is made up of the raw material of following weight portion: Mount Huang ballstone 20 30, bentonite 10 20, ceramic polished waste residue 16 24, slag of coal gasification 15 25, brine sludge 7 14, fluorite ore mine tailing 11 19, low copper silicon mine tailing 14 22, electric furnace phosphoric slag 17 29, magnesium hydroxide 5 13, lithium slag 13 21, barite 18 32, ferronickel slag 15 25.By the present invention in that and be combined prepared ceramic tile excellent combination property with Mount Huang ballstone and ceramic polished waste residue, electric furnace phosphoric slag, lithium slag, slag of coal gasification, not only there is the mechanical property of excellence, also there is excellent weatherability, wearability, resistance to water, corrosion resistance and thermostability.

Description

A kind of Mount Huang ballstone ceramic tile and preparation method thereof
Technical field
The present invention relates to a kind of ceramic tile and preparation method thereof, be specifically related to a kind of Mount Huang ballstone ceramic tile and preparation method thereof.
Background technology
The development of China's modem ceramic tile industry originated from for 20th century, and originally the kind of Ceramic Tiles product is single, only interior wall A kind of product of brick (being commonly called as ceramics), yield is less, and automaticity is the lowest, engenders mosaic tile, acidproof brick, color glazed brick etc. later Product.From the eighties in 20th century, tile industry starts fast development, and existing the sector has become in construction material Main force, tile product has been widely used in family, commercial building and communal facility, product also present multi-functional, Multi-color kind, the development trend of many decorative effects.Along with the fast development of China's building trade and people's living standard Improving constantly, people are the harshest to the performance requirement of ceramic tile, and the combination property of existing ceramic tile increasingly cannot meet existing city The demand of field.
Summary of the invention
Present invention aims to the deficiencies in the prior art, it is provided that the Mount Huang ballstone ceramic tile of a kind of excellent combination property And preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that:
A kind of Mount Huang ballstone ceramic tile, it is made up of the raw material of following weight portion: Mount Huang ballstone 20-30, bentonite 10-20, pottery Porcelain polishing slag 16-24, slag of coal gasification 15-25, brine sludge 7-14, fluorite ore mine tailing 11-19, low copper silicon mine tailing 14-22, electric furnace Phosphorus slag 17-29, magnesium hydroxide 5-13, lithium slag 13-21, barite 18-32, ferronickel slag 15-25.
The preparation method of a kind of Mount Huang ballstone ceramic tile, comprises the following steps:
(1) by ceramic polished waste residue, electric furnace phosphoric slag, the mixing of lithium slag, pulverize, cross 70-90 mesh sieve, add appropriate water stirring Make the serosity of 40-50%, under the rotating speed of 1500-2500r/min grind 30-50min, then by the slurry after ball milling with The pressure of 0.2-0.4Mpa sends into mist projection granulating in spray drying granulation machine, and centrifugal turntable rotating speed is 2000-3000r/min, spray The inlet temperature of mist drying-granulating machine is 240-280 DEG C, and the granule of gained is finally crossed 80-120 by outlet temperature 120-150 DEG C Mesh sieve, then at 855-925 DEG C of roasting temperature 2-4h, be cooled to room temperature, obtain material A；
(2) taking fluorite ore mine tailing, low copper silicon mine tailing, barite, ferronickel slag mix homogeneously, heating is fused into fused solution, so Fused solution is jetted into wadding fibrous by the high-voltage high-speed air that rear employing pressure is 2-3MPa, air velocity is 5-10m/s, obtains thing Material B；
(3) by Mount Huang ballstone, slag of coal gasification mix homogeneously, pulverize, cross 60-80 mesh sieve, be subsequently adding bentonite, salt The raw material such as mud, magnesium hydroxide, ball milling 25-40min under the rotating speed of 1500-2000r/min, obtain material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 1000-1500r/min, 12-is stirred 16min, is subsequently adding the waterglass that solid content is 42% being equivalent to compound weight 5-10%, 800-1200r/min's Stir 14-18min under rotating speed, be sent to forming machine after standing 15-20h compressing under the pressure of 65-75MPa, then will The adobe suppressed is dried to water content less than 3% at a temperature of 60-70 DEG C；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 5-9 DEG C/min to 860- 890 DEG C, be incubated 1.5-2.5h, then be cooled to 370-430 DEG C with the speed of 2-5 DEG C/min, be incubated 0.5-1h, then with 3-6 DEG C/ The ramp of min, to 1050-1150 DEG C, is incubated 3-4h, then is cooled to 620-680 DEG C with the speed of 1-3 DEG C/min, is incubated 1- 2h；Calcine in being placed in microwave calcination stove again: first control microwave power is at 400-500W, calcines 40-50min, then controls micro- Wave power, at 700-800W, is calcined 20-30min, then is controlled microwave power at 300-400W, calcining 55-65min, furnace cooling To room temperature, get product.
Beneficial effects of the present invention:
By the present invention in that and be combined prepared with Mount Huang ballstone with ceramic polished waste residue, electric furnace phosphoric slag, lithium slag, slag of coal gasification Ceramic tile excellent combination property, not only there is the mechanical property of excellence, also there is excellent weatherability, wearability, resistance to water, resistance to Corrosivity and thermostability.
Detailed description of the invention
A kind of Mount Huang ballstone ceramic tile, it is made up of the raw material of following weight (kg): Mount Huang ballstone 25, bentonite 15, pottery are thrown Light waste residue 20, slag of coal gasification 20, brine sludge 11, fluorite ore mine tailing 14, low copper silicon mine tailing 16, electric furnace phosphoric slag 23, magnesium hydroxide 10, Lithium slag 17, barite 28, ferronickel slag 20.
The preparation method of a kind of Mount Huang ballstone ceramic tile, comprises the following steps:
(1) by ceramic polished waste residue, electric furnace phosphoric slag, the mixing of lithium slag, pulverize, cross 80 mesh sieves, add appropriate water stirring system Become the serosity of 45%, under the rotating speed of 2000r/min, grind 40min, then the slurry after ball milling is sent with the pressure of 0.3Mpa Entering mist projection granulating in spray drying granulation machine, centrifugal turntable rotating speed is 2500r/min, and the inlet temperature of spray drying granulation machine is 260 DEG C, outlet temperature 140 DEG C, finally the granule of gained is crossed 100 mesh sieves, then at 895 DEG C of roasting temperature 3h, is cooled to room Temperature, obtains material A；
(2) taking fluorite ore mine tailing, low copper silicon mine tailing, barite, ferronickel slag mix homogeneously, heating is fused into fused solution, so Fused solution is jetted into wadding fibrous by the high-voltage high-speed air that rear employing pressure is 2.5MPa, air velocity is 8m/s, obtains material B；
(3) by Mount Huang ballstone, slag of coal gasification mix homogeneously, pulverize, cross 70 mesh sieves, be subsequently adding bentonite, brine sludge, hydrogen The raw materials such as magnesium oxide, ball milling 35min under the rotating speed of 1800r/min, obtain material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 1200r/min, 14min is stirred, so Rear addition is equivalent to the waterglass that solid content is 42% of compound weight 8%, stirs 16min under the rotating speed of 1000r/min, Stand that to be sent to forming machine after 18h compressing under the pressure of 70MPa, then by the adobe that suppresses at a temperature of 65 DEG C It is dried to water content less than 3%；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 7 DEG C/min to 870 DEG C, protect Temperature 2h, then is cooled to 400 DEG C with the speed of 3 DEG C/min, is incubated 0.5h, then with the ramp of 4 DEG C/min to 1110 DEG C, protects Temperature 3.5h, then it is cooled to 660 DEG C with the speed of 2 DEG C/min, it is incubated 1.5h；Calcine in being placed in microwave calcination stove again: first control Microwave power processed at 450W, calcines 45min, then controls microwave power at 750W, calcines 25min, then controls microwave power and exist 350W, calcines 60min, cools to room temperature with the furnace, get product.
The performance test results of the ceramic tile that above-described embodiment is produced is as shown in the table:
Project Unit Testing result
Breakdown strength N 2104
The modulus of rupture MPa 37
Water absorption rate % 0.19
Thermal coefficient of expansion m/m·k 5.8×10<sup>-6</sup>

Claims (2)

1. a Mount Huang ballstone ceramic tile, it is characterised in that be made up of the raw material of following weight portion: Mount Huang ballstone 20-30, bentonite 10-20, ceramic polished waste residue 16-24, slag of coal gasification 15-25, brine sludge 7-14, fluorite ore mine tailing 11-19, low copper silicon mine tailing 14-22, electric furnace phosphoric slag 17-29, magnesium hydroxide 5-13, lithium slag 13-21, barite 18-32, ferronickel slag 15-25.
2. the preparation method of a Mount Huang as claimed in claim 1 ballstone ceramic tile, it is characterised in that comprise the following steps:
(1) by ceramic polished waste residue, electric furnace phosphoric slag, the mixing of lithium slag, pulverize, cross 70-90 mesh sieve, add appropriate water stirring and make The serosity of 40-50%, grinds 30-50min, then by the slurry after ball milling with 0.2-under the rotating speed of 1500-2500r/min The pressure of 0.4Mpa sends into mist projection granulating in spray drying granulation machine, and centrifugal turntable rotating speed is 2000-3000r/min, spray dried The inlet temperature of dry comminutor is 240-280 DEG C, outlet temperature 120-150 DEG C, finally the granule of gained is crossed 80-120 mesh sieve, Again at 855-925 DEG C of roasting temperature 2-4h, it is cooled to room temperature, obtains material A；
(2) taking fluorite ore mine tailing, low copper silicon mine tailing, barite, ferronickel slag mix homogeneously, heating is fused into fused solution, then adopts With pressure be 2-3MPa, air velocity be that fused solution is jetted into wadding fibrous by the high-voltage high-speed air of 5-10m/s, obtain material B；
(3) by Mount Huang ballstone, slag of coal gasification mix homogeneously, pulverize, cross 60-80 mesh sieve, be subsequently adding bentonite, brine sludge, hydrogen The raw materials such as magnesium oxide, ball milling 25-40min under the rotating speed of 1500-2000r/min, obtain material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 1000-1500r/min, 12-is stirred 16min, is subsequently adding the waterglass that solid content is 42% being equivalent to compound weight 5-10%, turning at 800-1200r/min Stir 14-18min under speed, be sent to forming machine after standing 15-20h compressing under the pressure of 65-75MPa, then will pressure The adobe made is dried to water content less than 3% at a temperature of 60-70 DEG C；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 5-9 DEG C/min to 860-890 DEG C, Insulation 1.5-2.5h, then it is cooled to 370-430 DEG C with the speed of 2-5 DEG C/min, it is incubated 0.5-1h, then with 3-6 DEG C/min's Ramp, to 1050-1150 DEG C, is incubated 3-4h, then is cooled to 620-680 DEG C with the speed of 1-3 DEG C/min, is incubated 1-2h；Again Calcine in being placed in microwave calcination stove: first control microwave power is at 400-500W, calcines 40-50min, then controls microwave power At 700-800W, calcine 20-30min, then control microwave power at 300-400W, calcine 55-65min, cool to room temperature with the furnace, Get product.
CN201610420684.XA 2016-06-12 2016-06-12 A kind of Mount Huang ballstone ceramic tile and preparation method thereof Withdrawn CN106082994A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112723746A (en) * 2021-01-22 2021-04-30 福建省德化县宝瑞陶瓷有限公司 Low-temperature fancy glaze prepared from high-barium copper ore tailings and preparation method thereof
CN114014687A (en) * 2021-11-11 2022-02-08 河南心连心化学工业集团股份有限公司 Aerated concrete block prepared from gasified ash and slag and preparation method thereof

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104860654A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Acid and alkali resistance ceramic tile and production method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104860654A (en) * 2015-05-04 2015-08-26 安徽省亚欧陶瓷有限责任公司 Acid and alkali resistance ceramic tile and production method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112723746A (en) * 2021-01-22 2021-04-30 福建省德化县宝瑞陶瓷有限公司 Low-temperature fancy glaze prepared from high-barium copper ore tailings and preparation method thereof
CN114014687A (en) * 2021-11-11 2022-02-08 河南心连心化学工业集团股份有限公司 Aerated concrete block prepared from gasified ash and slag and preparation method thereof

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