CN106082957A - A kind of wear-resisting antidetonation ceramic tile and preparation method thereof - Google Patents

A kind of wear-resisting antidetonation ceramic tile and preparation method thereof Download PDF

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CN106082957A
CN106082957A CN201610420924.6A CN201610420924A CN106082957A CN 106082957 A CN106082957 A CN 106082957A CN 201610420924 A CN201610420924 A CN 201610420924A CN 106082957 A CN106082957 A CN 106082957A
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slag
ceramic tile
wear
rotating speed
under
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郑辉
郭孝建
王俊武
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ANHUI YA'OU CERAMIC Co Ltd
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ANHUI YA'OU CERAMIC Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/1324—Recycled material, e.g. tile dust, stone waste, spent refractory material
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/135—Combustion residues, e.g. fly ash, incineration waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/02—Preparing or treating the raw materials individually or as batches
    • C04B33/13—Compounding ingredients
    • C04B33/132—Waste materials; Refuse; Residues
    • C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3206—Magnesium oxides or oxide-forming salts thereof
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    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208—Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427—Silicates other than clay, e.g. water glass
    • C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
    • C—CHEMISTRY; METALLURGY
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    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/38—Non-oxide ceramic constituents or additives
    • C04B2235/3804—Borides
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

Abstract

The invention discloses a kind of wear-resisting antidetonation ceramic tile and preparation method thereof, it is made up of the raw material of following weight portion: discarded clay brick 25 35, prepared by ocean dredged sludge 22 33, Yellow Phosphorous Slag 19 31, galapectite 14 26, this mountain green mud 18 30, leucite 23 34, pelelith 16 28, metallurgical slag 24 36, periclase 27 39, Brown Alundum slag 17 29, aluminium diboride 8 16, dihydrate gypsum 15 25, skive waste material 18 26.The raw materials such as the skive waste material that the present invention adds, discarded clay brick, can improve wearability and the weatherability of ceramic tile, the raw material such as the Brown Alundum slag of interpolation, aluminium diboride, can improve shock resistance and the heat stability of ceramic tile.The advantages such as it is high that the ceramic tile that the present invention prepares has mechanical strength, and wear-resisting antidetonation is high temperature resistant, weather-proof, aging resistance, service life length, good environmental adaptability.

Description

A kind of wear-resisting antidetonation ceramic tile and preparation method thereof
Technical field
The present invention relates to a kind of ceramic tile and preparation method thereof, be specifically related to a kind of wear-resisting antidetonation ceramic tile and preparation method thereof.
Background technology
The development of China's modem ceramic tile industry originated from for 20th century, and originally the kind of Ceramic Tiles product is single, only interior wall A kind of product of brick (being commonly called as ceramics), yield is less, and automaticity is the lowest, engenders mosaic tile, acidproof brick, color glazed brick etc. later Product.From the eighties in 20th century, tile industry starts fast development, and existing the sector has become in construction material Main force, tile product has been widely used in family, commercial building and communal facility, product also present multi-functional, Multi-color kind, the development trend of many decorative effects.Along with the fast development of China's building trade and people's living standard Improving constantly, people are the harshest to the performance requirement of ceramic tile, and the wearability of existing ceramic tile and shock resistance increasingly cannot meet The demand of existing market.
Summary of the invention
Present invention aims to the deficiencies in the prior art, it is provided that a kind of wear-resisting antidetonation ceramic tile and preparation method thereof.
For achieving the above object, the present invention adopts the following technical scheme that:
A kind of wear-resisting antidetonation ceramic tile, is made up of the raw material of following weight portion: discarded clay brick 25-35, prepared by ocean dredged sludge 22- 33, Yellow Phosphorous Slag 19-31, galapectite 14-26, this mountain green mud 18-30, leucite 23-34, pelelith 16-28, metallurgical slag 24-36, periclase 27-39, Brown Alundum slag 17-29, aluminium diboride 8-16, dihydrate gypsum 15-25, skive waste material 18- 26。
The preparation method of a kind of wear-resisting antidetonation ceramic tile, comprises the following steps:
(1) by Yellow Phosphorous Slag, galapectite, Brown Alundum slag, pelelith mixing, pulverize, cross 100-150 mesh sieve, add appropriate Water stirring make the serosity of 50-60%, under the rotating speed of 3500-4500r/min, grind 15-25min, then by after ball milling Slurry sends into mist projection granulating in spray drying granulation machine with the pressure of 0.2-0.3Mpa, and centrifugal turntable rotating speed is 5000-6000r/ Min, the inlet temperature of spray drying granulation machine is 230-280 DEG C, outlet temperature 100-150 DEG C, finally by the granule mistake of gained 100-150 mesh sieve, then at 870-930 DEG C of roasting temperature 2.5-3.5h, be cooled to room temperature, obtain material A；
(2) taking leucite, metallurgical slag, periclase mix homogeneously, heating is fused into fused solution, and then employing pressure is 1.5-2.5MPa, air velocity are that fused solution is jetted into wadding fibrous by the high-voltage high-speed air of 10-20m/s, obtain material B；
(3) by discarded clay brick, dihydrate gypsum, skive waste material mix homogeneously, pulverize, cross 80-120 mesh sieve, so The raw materials such as rear addition prepared by ocean dredged sludge, this mountain green mud, aluminium diboride, ball milling 15-under the rotating speed of 4000-5000r/min 25min, obtains material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 600-1200r/min, 10-is stirred 15min, is subsequently adding the waterglass that solid content is 35% being equivalent to compound weight 10-15%, at 1500-2500r/min Rotating speed under stir 10-15min, stand that to be sent to forming machine after 14-18h compressing under the pressure of 50-60MPa, then The adobe suppressed is dried at a temperature of 70-80 DEG C to water content less than 3%；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 7-9 DEG C/min to 770- 820 DEG C, it is incubated 1-2h, then with the ramp of 3-5 DEG C/min to 1050-1100 DEG C, is incubated 2-3h, then with 4-6 DEG C/min Speed be cooled to 660-710 DEG C, be incubated 1-2h, then be cooled to 410-460 DEG C with the speed of 1-3 DEG C/min, be incubated 0.5-1h； Calcine in being placed in microwave calcination stove again: first control microwave power is at 800-1000W, calcines 15-35min, then controls microwave Power, at 400-600W, is calcined 30-50min, is cooled to room temperature with the furnace, get product.
Beneficial effects of the present invention:
The raw materials such as the skive waste material that the present invention adds, discarded clay brick, can improve the wearability of ceramic tile and resistance to Hou Xing, the raw material such as the Brown Alundum slag of interpolation, aluminium diboride, can improve shock resistance and the heat stability of ceramic tile.The present invention prepares Ceramic tile to have mechanical strength high, wear-resisting antidetonation, high temperature resistant, weather-proof, the advantage such as aging resistance, service life length, environmental suitability Good.
Detailed description of the invention
A kind of wear-resisting antidetonation ceramic tile, is made up of the raw material of following weight (kg): discarded clay brick 30, prepared by ocean dredged sludge 27, Yellow Phosphorous Slag 26, galapectite 22, this mountain green mud 24, leucite 29, pelelith 25, metallurgical slag 32, periclase 34, Brown Alundum slag 24, aluminium diboride 13, dihydrate gypsum 20, skive waste material 22.
The preparation method of a kind of wear-resisting antidetonation ceramic tile, comprises the following steps:
(1) by Yellow Phosphorous Slag, galapectite, Brown Alundum slag, pelelith mixing, pulverize, cross 150 mesh sieves, add appropriate water The serosity of 55% is made in stirring, grinds 20min, then by the slurry after ball milling with 0.25Mpa's under the rotating speed of 4000r/min Pressure sends into mist projection granulating in spray drying granulation machine, and centrifugal turntable rotating speed is 5500r/min, the import of spray drying granulation machine Temperature is 260 DEG C, outlet temperature 130 DEG C, and the granule of gained finally crosses 150 mesh sieves, then at 905 DEG C of roasting temperature 3h, cold But to room temperature, material A is obtained；
(2) taking leucite, metallurgical slag, periclase mix homogeneously, heating is fused into fused solution, and then employing pressure is 2MPa, air velocity are that fused solution is jetted into wadding fibrous by the high-voltage high-speed air of 15m/s, obtain material B；
(3) by discarded clay brick, dihydrate gypsum, skive waste material mix homogeneously, pulverize, cross 100 mesh sieves, then add Enter the raw material such as prepared by ocean dredged sludge, this mountain green mud, aluminium diboride, ball milling 20min under the rotating speed of 4500r/min, obtain material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 800r/min, 12min is stirred, then Add the waterglass that solid content is 35% being equivalent to compound weight 12%, under the rotating speed of 2000r/min, stir 12min, Stand that to be sent to forming machine after 16h compressing under the pressure of 55MPa, then by the adobe that suppresses at a temperature of 75 DEG C It is dried to water content less than 3%；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 8 DEG C/min to 790 DEG C, protect Temperature 1.5h, then with the ramp of 4 DEG C/min to 1070 DEG C, be incubated 2.5h, be then cooled to 690 DEG C with the speed of 5 DEG C/min, Insulation 1.5h, then it is cooled to 440 DEG C with the speed of 2 DEG C/min, it is incubated 0.5h；Calcine in being placed in microwave calcination stove again: first Control microwave power at 900W, calcine 25min, then control microwave power at 500W, calcine 40min, cool to room temperature with the furnace, i.e. Obtain finished product.
The performance test results of the ceramic tile that above-described embodiment is produced is as shown in the table:
Project Unit Testing result
Breakdown strength N 2045
The modulus of rupture MPa 36
Water absorption rate % 0.21
Thermal coefficient of expansion m/m·k 6.5×10<sup>-6</sup>
Wear extent cm<sup>3</sup> 2.2
Thermal shock resistance (1100 DEG C of water-cooleds) Secondary 191

Claims (2)

1. a wear-resisting antidetonation ceramic tile, it is characterised in that be made up of the raw material of following weight portion: discarded clay brick 25-35, ocean Dredged mud 22-33, Yellow Phosphorous Slag 19-31, galapectite 14-26, this mountain green mud 18-30, leucite 23-34, pelelith 16-28, Metallurgical slag 24-36, periclase 27-39, Brown Alundum slag 17-29, aluminium diboride 8-16, dihydrate gypsum 15-25, skive Waste material 18-26.
2. the preparation method of a wear-resisting antidetonation ceramic tile as claimed in claim 1, it is characterised in that comprise the following steps:
(1) by Yellow Phosphorous Slag, galapectite, Brown Alundum slag, pelelith mixing, pulverize, cross 100-150 mesh sieve, add appropriate water The serosity of 50-60% is made in stirring, grinds 15-25min, then by the slurry after ball milling under the rotating speed of 3500-4500r/min Sending into mist projection granulating in spray drying granulation machine with the pressure of 0.2-0.3Mpa, centrifugal turntable rotating speed is 5000-6000r/min, The inlet temperature of spray drying granulation machine is 230-280 DEG C, outlet temperature 100-150 DEG C, finally the granule of gained is crossed 100- 150 mesh sieves, then at 870-930 DEG C of roasting temperature 2.5-3.5h, be cooled to room temperature, obtain material A；
(2) taking leucite, metallurgical slag, periclase mix homogeneously, heating is fused into fused solution, and then using pressure is 1.5- 2.5MPa, air velocity are that fused solution is jetted into wadding fibrous by the high-voltage high-speed air of 10-20m/s, obtain material B；
(3) by discarded clay brick, dihydrate gypsum, skive waste material mix homogeneously, pulverize, cross 80-120 mesh sieve, then add Enter the raw material such as prepared by ocean dredged sludge, this mountain green mud, aluminium diboride, ball milling 15-25min under the rotating speed of 4000-5000r/min, obtain Material C；
(4) by above-mentioned prepared material A, material B, material C mixing, under the rotating speed of 600-1200r/min, 10-15min is stirred, It is subsequently adding the waterglass that solid content is 35% being equivalent to compound weight 10-15%, under the rotating speed of 1500-2500r/min Stirring 10-15min, is sent to forming machine after standing 14-18h compressing under the pressure of 50-60MPa, then will suppress Adobe be dried at a temperature of 70-80 DEG C to water content less than 3%；
(5) adobe after drying is calcined in being placed in Muffle furnace: first with the ramp of 7-9 DEG C/min to 770-820 DEG C, Insulation 1-2h, then with the ramp of 3-5 DEG C/min to 1050-1100 DEG C, it is incubated 2-3h, then with the speed of 4-6 DEG C/min It is cooled to 660-710 DEG C, is incubated 1-2h, then is cooled to 410-460 DEG C with the speed of 1-3 DEG C/min, be incubated 0.5-1h；It is placed in again Calcine in microwave calcination stove: first control microwave power at 800-1000W, calcine 15-35min, then control microwave power and exist 400-600W, calcines 30-50min, cools to room temperature with the furnace, get product.
CN201610420924.6A 2016-06-12 2016-06-12 A kind of wear-resisting antidetonation ceramic tile and preparation method thereof Withdrawn CN106082957A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630942A (en) * 2016-12-27 2017-05-10 定远县明友墙体材料有限责任公司 Preparation method of high-hardness wear-resistant sintered brick
CN107056234A (en) * 2017-04-28 2017-08-18 福建省德化县艺韵陶瓷有限公司 Health ceramic is formulated
CN108503279A (en) * 2017-02-28 2018-09-07 北京城泰混凝土制品有限公司 Frost-resistant concrete and preparation method thereof

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CN103951383A (en) * 2014-04-08 2014-07-30 安徽省亚欧陶瓷有限责任公司 Ceramic tile with low water absorption rate and preparation method thereof
CN104944921A (en) * 2015-05-29 2015-09-30 方堃 Slag-doped wear-resistant ceramic floor tile
CN105272133A (en) * 2015-09-29 2016-01-27 马鞍山杰创塑胶科技有限公司 High-shock resistance aerated building block and making method thereof
CN105367041A (en) * 2015-10-29 2016-03-02 合肥正拓装饰材料有限公司 Abrasion-resistant and anti-fracturing sintered water-permeable floor tile

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Publication number Priority date Publication date Assignee Title
CN103951383A (en) * 2014-04-08 2014-07-30 安徽省亚欧陶瓷有限责任公司 Ceramic tile with low water absorption rate and preparation method thereof
CN104944921A (en) * 2015-05-29 2015-09-30 方堃 Slag-doped wear-resistant ceramic floor tile
CN105272133A (en) * 2015-09-29 2016-01-27 马鞍山杰创塑胶科技有限公司 High-shock resistance aerated building block and making method thereof
CN105367041A (en) * 2015-10-29 2016-03-02 合肥正拓装饰材料有限公司 Abrasion-resistant and anti-fracturing sintered water-permeable floor tile

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630942A (en) * 2016-12-27 2017-05-10 定远县明友墙体材料有限责任公司 Preparation method of high-hardness wear-resistant sintered brick
CN108503279A (en) * 2017-02-28 2018-09-07 北京城泰混凝土制品有限公司 Frost-resistant concrete and preparation method thereof
CN108503279B (en) * 2017-02-28 2021-02-23 北京城泰混凝土制品有限公司 Antifreezing concrete and preparation method thereof
CN107056234A (en) * 2017-04-28 2017-08-18 福建省德化县艺韵陶瓷有限公司 Health ceramic is formulated

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Application publication date: 20161109