CN106082843B - The superior foam concrete compound external wall panel of stress performance - Google Patents

The superior foam concrete compound external wall panel of stress performance Download PDF

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CN106082843B
CN106082843B CN201610407308.7A CN201610407308A CN106082843B CN 106082843 B CN106082843 B CN 106082843B CN 201610407308 A CN201610407308 A CN 201610407308A CN 106082843 B CN106082843 B CN 106082843B
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layer
parts
concrete
composite layer
agent
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CN106082843A (en
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王亚波
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Jilin Jianzhu University
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Jilin Jianzhu University
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/049Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres completely or partially of insulating material, e.g. cellular concrete or foamed plaster
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/04Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres
    • E04C2/06Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials of concrete or other stone-like material; of asbestos cement; of cement and other mineral fibres reinforced
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/30Water reducers, plasticisers, air-entrainers, flow improvers
    • C04B2103/302Water reducers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a kind of superior foam concrete compound external wall panels of stress performance comprising first layer composite layer, second layer composite layer and third layer composite layer, the 4th layer of composite layer and the layer 5 composite layer set gradually from the inner to the outer;The first layer composite layer specifically includes the first fiber concrete layer, reinforcement net and framework of steel reinforcement;The second layer composite layer specifically includes defoaming agent carrier;The defoaming agent carrier is netted;The third layer composite layer specifically includes bubble concrete layer;The 4th layer of composite layer is identical as the second layer lamination layer structure;The layer 5 composite layer specifically includes the second fiber concrete layer.The invention discloses a kind of superior foam concrete compound external wall panels of stress performance, with all various technical advantages such as stress performance is remarkable, endurance quality is good, shock resistance is strong, fire line is more preferable, strong applicability, anti-seismic performance is superior, structural reliability and stable structure are strong.

Description

The superior foam concrete compound external wall panel of stress performance
Technical field
It is compound outer that the present invention relates to construction engineering technical fields more particularly to a kind of superior foam concrete of stress performance Wallboard.
Background technology
It is well known that foam concrete is to be built in China's architectural engineering using more and more extensive one kind is novel in recent years Energy-saving material is built, it has the advantages that lightweight, heat preservation, sound insulation, damping etc. are a variety of.
Conventional foam concrete slab Side fascia its mostly use using the organic materials such as styrofoam, extruded sheet plank as exterior wall Moderate soak interlayer, the form of outer layer monolithic reinforced concrete structure;
It is obvious that the Side fascia used in engineering at present still remains some technological deficiencies:Existing foam is mixed Solidifying soil Side fascia, stress performance and bearing capacity are relatively all poor, and anti-seismic performance is bad, easy to crack after floor piece.
In conclusion how to overcome, conventional foam concrete external wall panel stress performance in the prior art is poor, structural strength It is those skilled in the art's technical problem urgently to be resolved hurrily with the technological deficiency of structural stability difference.
Invention content
It is above-mentioned to solve the purpose of the present invention is to provide a kind of superior foam concrete compound external wall panel of stress performance Problem.
In order to achieve the above object, the technical proposal of the invention is realized in this way:
The present invention provides a kind of superior foam concrete compound external wall panels of stress performance, including from the inner to the outer according to First layer composite layer, second layer composite layer and the third layer composite layer of secondary setting, the 4th layer of composite layer and layer 5 composite layer;
The first layer composite layer specifically includes the first fiber concrete layer, reinforcement net and framework of steel reinforcement, the reinforcing bar Skeleton includes multigroup transversely arranged composition of framework of steel reinforcement component;Every group of framework of steel reinforcement component specifically includes and is arranged in concrete rib Four Reinforcements and Duo Gen stirrups and the bar-mat reinforcement being arranged inside concrete slab;
The second layer composite layer specifically includes defoaming agent carrier;The defoaming agent carrier is netted;
The third layer composite layer specifically includes bubble concrete layer;
The 4th layer of composite layer is identical as the second layer lamination layer structure;The i.e. described 4th layer of composite layer specifically includes Agent carrier is defoamed, and the defoaming agent carrier is netted;
The layer 5 composite layer specifically includes the second fiber concrete layer;
First fiber concrete layer specific formula of the first layer composite layer is as follows:
The first fiber concrete layer is in terms of mass fraction:The first fiber concrete layer includes urban inorganic garbage 26-28 parts of powder, 25-30 parts of bastard coal mountain flour, 28-30 parts of Emathlite, 10-15 parts of land plaster, 3-5 parts of cement, quartz sand powder 3-5 Part, be chopped 1-2 parts of alkali-resistant glass fibre, nano-mineral modified mixed powder 2-4 parts, 0.01-0.09 parts of expanded perlite, waterproofing agent 0.7-1.9 parts, 0.02-0.08 parts of anti-cracking agent, 0.7-0.9 parts of concrete intensifier;
It is made of the concrete intensifier organic high molecular polymer and compounding agent, the organic high molecular polymer For polyacrylamide copolymer aqueous solution;The compounding agent is by colloidal silicon dioxide, triisopropanolamine, sodium tripolyphosphate and three second Hydramine forms;The reinforcing agent appearance is pink liquid, solid content 25wt%, pH value 8.9;
Each substance of concrete intensifier is specific as follows:Polyacrylamide copolymer aqueous solution 50g, colloidal silicon dioxide 2.5g, triisopropanolamine 1.5g, sodium tripolyphosphate 2.0g, triethanolamine 1.5g;Above-mentioned concrete intensifier is by with lower section What method was configured to, compounding agent raw material is first configured to cooperation agent solution with water in proportion, then under stiring in polyacrylamide Cooperation agent solution is added in aqueous copolymers solution, continues stirring 10 minutes or more after adding;
The nano-mineral modified mixed powder is by 1-2 parts by weight peridotite, 2-4 parts by weight phosphorus ores slag, 5-8 parts by weight fluorites After slag powders, 1-2 parts by weight sepiolite powder mixings, scaling loss 4-5 hours at 700-800 DEG C, after be ground into nanometer powder, admix The chlorinated paraffin agitating of the dibutyl maleate, 1-2% that are equivalent to powder weight 1-2% is uniform, and drying is ground into powder i.e. ;
The bubble concrete layer specific formula of the third layer composite layer is as follows:
The bubble concrete layer is mixed evenly by cementitious material, water and water-reducing agent, foaming agent;The gelling Material is made of portland cement and fine coal ashes;Wherein each component ratio range is as follows:Portland cement 300-500kg/ m3;Fine coal ashes 100-150kg/m3;Water 150-210kg/m3;Water-reducing agent 2-4kg/m3;The water-reducing agent is polycarboxylic-acid solid High efficiency water reducing agent;The foaming agent is specially the hydrogen peroxide solution of a concentration of 35-45%;The fine coal ashes is I grades of fine coal of F classes Ash.
Second fiber concrete layer specific formula of the layer 5 composite layer is as follows:
The second fiber concrete layer is in terms of mass fraction:The second fiber concrete layer includes industrial aluminum sulphate 7- 12 parts, high-strength imitative steel wire fibre 5-9 parts, 60-80 parts of sandstone, 3-8 parts of siderite, 90-150 parts of cement, 5-9 parts of diatom ooze, carbon Sour calcium 7-10 parts, 8-15 parts of blast-furnace cinder, 3-6 parts of soda ash, 0.5-2 parts of sodium hexametaphosphate, 2-4 parts of aluminium hydroxide, coal ash 2-6 Part, 6-10 parts of dicalcium silicate, 9-14 parts of lithium slag, completely new compound 4 parts of diminishing formula;The completely new compound diminishing formula is:Choosing is cloudy Ionic surface active agent dodecyl sodium sulfate or cationic surfactant brocide are that organic water-reducing agent is former Material, it is inorganic water-reducing agent raw material to select waterglass or sodium carbonate;By above-mentioned raw materials weight ratio respectively according to organic water-reducing agent: inorganic The proportioning that water-reducing agent is 1~3: 1~3 carries out configuration and, obtained completely new compound diminishing formula uniform by ball milling mixing.
It preferably, can embodiment as one kind;It is additionally provided with steel in the perpendicular concrete edge rib of the concrete rib Skeleton;The steel skeleton is made of multiple truss pieces, and multiple truss pieces, which are sequentially fixedly connected, constitutes the steel skeleton.
It preferably, can embodiment as one kind;The surface of the steel skeleton, which is coated with, is provided with corrosion-inhibiting coating.
It preferably, can embodiment as one kind;The surface of the Reinforcement, which is coated with, is provided with corrosion-inhibiting coating.
Compared with prior art, this have the advantage that:
The superior foam concrete compound external wall panel of a kind of stress performance provided by the invention, analyzing above-mentioned main contents can Know:
The first layer that the superior foam concrete compound external wall panel of the stress performance is mainly set gradually from the inner to the outer Composite layer, second layer composite layer and third layer composite layer, the 4th layer of composite layer and layer 5 lamination layer structure part composition;
The first layer composite layer specifically includes the first fiber concrete layer, reinforcement net and framework of steel reinforcement, the reinforcing bar Skeleton includes multigroup transversely arranged composition of framework of steel reinforcement component;Every group of framework of steel reinforcement component specifically includes and is arranged in concrete rib Four Reinforcements and Duo Gen stirrups and the bar-mat reinforcement being arranged inside concrete slab;The second layer composite layer tool Body includes defoaming agent carrier;The third layer composite layer specifically includes bubble concrete layer;The 4th layer of composite layer with it is described Second layer lamination layer structure is identical;The i.e. described 4th layer of composite layer specifically includes defoaming agent carrier;The layer 5 composite layer tool Body includes the second fiber concrete layer;
Generally speaking, the superior foam concrete compound external wall panel of a kind of stress performance provided by the invention, have by All various skills such as power performance is remarkable, endurance quality is good, shock resistance is strong, fire line is more preferable, strong applicability, anti-seismic performance are superior Art advantage.
Description of the drawings
It, below will be to specific in order to illustrate more clearly of the specific embodiment of the invention or technical solution in the prior art Embodiment or attached drawing needed to be used in the description of the prior art are briefly described, it should be apparent that, in being described below Attached drawing is some embodiments of the present invention, for those of ordinary skill in the art, before not making the creative labor It puts, other drawings may also be obtained based on these drawings.
Fig. 1 is the superior foam concrete compound external wall panel principle of stratification signal of stress performance provided in an embodiment of the present invention Figure;
Fig. 2 is that the first layer in the superior foam concrete compound external wall panel of stress performance provided in an embodiment of the present invention is multiple Close the dimensional structure diagram of layer;
Fig. 3 is the bottom plate skeleton in the superior foam concrete compound external wall panel of stress performance provided in an embodiment of the present invention Main structure diagram;
Fig. 4 is that the second layer in the superior foam concrete compound external wall panel of stress performance provided in an embodiment of the present invention is multiple Close the main structure diagram of layer;
Reference sign:
First layer composite layer 1;First fiber concrete layer 12;Framework of steel reinforcement 13;Bar-mat reinforcement 14;Truss piece 15;
Second layer composite layer 2;Defoam agent carrier 21;
Third layer composite layer 3;
4th layer of composite layer 4;
Layer 5 composite layer 5.
Specific implementation mode
Technical scheme of the present invention is clearly and completely described below in conjunction with attached drawing, it is clear that described implementation Example is a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, ordinary skill The every other embodiment that personnel are obtained without making creative work, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that term "center", "upper", "lower", "left", "right", "vertical", The orientation or positional relationship of the instructions such as "horizontal", "inner", "outside" be based on the orientation or positional relationship shown in the drawings, merely to Convenient for the description present invention and simplify description, do not indicate or imply the indicated device or element must have a particular orientation, With specific azimuth configuration and operation, therefore it is not considered as limiting the invention.In addition, term " first ", " second ", " third " is used for description purposes only, and is not understood to indicate or imply relative importance.
In the description of the present invention, it should be noted that unless otherwise clearly defined and limited, term " installation ", " phase Even ", " connection " shall be understood in a broad sense, for example, it may be being fixedly connected, may be a detachable connection, or be integrally connected;It can Can also be electrical connection to be mechanical connection;It can be directly connected, can also indirectly connected through an intermediary, Ke Yishi Connection inside two elements.For the ordinary skill in the art, above-mentioned term can be understood at this with concrete condition Concrete meaning in invention.
The present invention is described in further detail below through specific implementation examples and in conjunction with the accompanying drawings.
Referring to Fig. 1, a kind of superior foam concrete compound external wall panel of stress performance provided in an embodiment of the present invention, including First layer composite layer 1, second layer composite layer 2 and third layer composite layer 3, the 4th layer of composite layer set gradually from the inner to the outer 4 and layer 5 composite layer 5;
The first layer composite layer 1 specifically includes the first fiber concrete layer 12, framework of steel reinforcement 13 and reinforcement net 14, institute It includes multigroup transversely arranged composition of framework of steel reinforcement component to state framework of steel reinforcement;Every group of framework of steel reinforcement component, which specifically includes, to be arranged in coagulation Four Reinforcements and Duo Gen stirrups of native rib and the bar-mat reinforcement being arranged inside concrete slab;It (needs to illustrate It is, along more stirrups of four Reinforcement sockets)
The second layer composite layer 2 specifically includes defoaming agent carrier 21;The defoaming agent carrier 21 is netted;
The third layer composite layer 3 specifically includes bubble concrete layer;
The 4th layer of composite layer 4 is identical as the second layer lamination layer structure;The i.e. described 4th layer of composite layer specifically wraps Defoaming agent carrier is included, and the defoaming agent carrier is netted;
The layer 5 composite layer 5 specifically includes the second fiber concrete layer;
First fiber concrete layer specific formula of the first layer composite layer is as follows:
The first fiber concrete layer is in terms of mass fraction:The first fiber concrete layer includes urban inorganic garbage 26-28 parts of powder, 25-30 parts of bastard coal mountain flour, 28-30 parts of Emathlite, 10-15 parts of land plaster, 3-5 parts of cement, quartz sand powder 3-5 Part, be chopped 1-2 parts of alkali-resistant glass fibre, nano-mineral modified mixed powder 2-4 parts, 0.01-0.09 parts of expanded perlite, waterproofing agent 0.7-1.9 parts, 0.02-0.08 parts of anti-cracking agent, 0.7-0.9 parts of concrete intensifier;
It is made of the concrete intensifier organic high molecular polymer and compounding agent, the organic high molecular polymer For polyacrylamide copolymer aqueous solution;The compounding agent is by colloidal silicon dioxide, triisopropanolamine, sodium tripolyphosphate and three second Hydramine forms;The reinforcing agent appearance is pink liquid, solid content 25wt%, pH value 8.9;
Each substance of concrete intensifier is specific as follows:Polyacrylamide copolymer aqueous solution 50g, colloidal silicon dioxide 2.5g, triisopropanolamine 1.5g, sodium tripolyphosphate 2.0g, triethanolamine 1.5g;Above-mentioned concrete intensifier is by with lower section What method was configured to, compounding agent raw material is first configured to cooperation agent solution with water in proportion, then under stiring in polyacrylamide Cooperation agent solution is added in aqueous copolymers solution, continues stirring 10 minutes or more after adding;
The nano-mineral modified mixed powder is by 1-2 parts by weight peridotite, 2-4 parts by weight phosphorus ores slag, 5-8 parts by weight fluorites After slag powders, 1-2 parts by weight sepiolite powder mixings, scaling loss 4-5 hours at 700-800 DEG C, after be ground into nanometer powder, admix The chlorinated paraffin agitating of the dibutyl maleate, 1-2% that are equivalent to powder weight 1-2% is uniform, and drying is ground into powder i.e. ;
It should be noted that the above-mentioned specific first fiber concrete layer of first layer composite layer is set in addition to containing innovation ratio The cement of meter, expanded perlite, waterproofing agent, anti-cracking agent, concrete intensifier are prepared outer;It is also special to devise completely new coagulation Native reinforcing agent, the concrete intensifier are made of polyacrylamide copolymer aqueous solution and compounding agent, and the polyacrylamide is total Polymers aqueous solution account for the reinforcing agent mass ratio be 80~95%, the compounding agent account for the reinforcing agent mass ratio be 5~ 20%;The compounding agent is made of colloidal silicon dioxide, triisopropanolamine, sodium tripolyphosphate and triethanolamine, wherein accounting for described The weight ratio of reinforcing agent is 1~5%, and the weight ratio that triisopropanolamine accounts for the reinforcing agent is 0.5~3%, and sodium tripolyphosphate accounts for The weight ratio of the reinforcing agent is 0.1~5%, and the weight ratio that triethanolamine accounts for the reinforcing agent is 0.1~3%;And coagulation Native reinforcing agent is configured to by the following method, compounding agent raw material is first configured to cooperation agent solution with water in proportion, then The solution of compounding agent is added in polyacrylamide copolymer aqueous solution under stiring, continues stirring 10 minutes or more after adding.
It is had the following technical effects about the first fiber concrete layer:1. appropriate special concrete is added in concrete After reinforcing agent, the strength grade of concrete can be improved;2. above-mentioned concrete intensifier and all kinds of cement well adapting to property, Reinforcing bar non-corroding is endangered, various prefabricated and cast-in-place concrete is can be used for;3. above-mentioned concrete intensifier is common outer to other Add the adaptability of agent good;4. above-mentioned concrete intensifier is liquid, there is polymolecularity, mobility pumpability in concrete It is splendid, and to anti-permeability performance, endurance quality plays positive effect;5. above-mentioned concrete intensifier is by organic and inorganic equal more Kind of material is prepared, and various composition complementation of making the most of the advantage significantly improves the intensity of concrete after concrete is added.
The nano-mineral modified mixed powder is by 1-2 parts by weight peridotite, 2-4 parts by weight phosphorus ores slag, 5-8 parts by weight fluorites After slag powders, 1-2 parts by weight sepiolite powder mixings, scaling loss 4-5 hours at 700-800 DEG C, after be ground into nanometer powder, admix The chlorinated paraffin agitating of the dibutyl maleate, 1-2% that are equivalent to powder weight 1-2% is uniform, and drying is ground into powder i.e. ;
It should be noted that its design of formula with innovation formula of above-mentioned first fiber concrete layer, in addition to using coal Spoil powder, Emathlite, land plaster, cement, quartz sand powder, the formula such as alkali-resistant glass fibre that is chopped (pay attention to the alkaline-resisting glass that is chopped Glass fiber can also pass through steel fibre or carbon fiber or chrysotile asbestos fibre, green stone cotton fiber, iron-stone cotton fiber, alkali resistant glass fibers Carbon fibers such as dimension and alkali resistant mineral wool etc. are replaced), additionally using urban inorganic garbage powder, it clearly enhances construction material Environmental-protection function;It also added brand-new design formula as nano-mineral modified mixed powder simultaneously, this is nano-mineral modified mixed Can significantly the first fiber concrete layer progress performances such as intensity and anti-impact force, stress performance be improved by closing powder;It is above-mentioned First fiber concrete layer shock resistance is good, and has many advantages, such as sound insulation, heat preservation, waterproof;Meanwhile aluminium hydroxide plays centainly The fire retardation of degree.
It needs to be emphasized that urban inorganic garbage refers to the waste of inorganic constituents in domestic waste.This is useless Gurry further includes some lightweight slag, clinkers etc. essentially from bottle, jar and other old metal and cullet for being packed for.City City's inorganic refuse powder is then the floury structure substance being manufactured by the inorganic rubbish in city.Emathlite is also known as natural bleaching soil, i.e., The inherently carclazyte with bleachability of natural output is with montmorillonite, albite, quartz for the white, white of key component Gray clay is bentonitic one kind.Emathlite is mainly the product after nature of glass volcanic rock decomposes, it is not swollen after absorbing water It is swollen, find that the structural formulation as fiber concrete layer has the technique effect for being obviously improved water resistance by research.
The bubble concrete layer specific formula of the third layer composite layer is as follows:
The bubble concrete layer is mixed evenly by cementitious material, water and water-reducing agent, foaming agent;The gelling Material is made of portland cement and fine coal ashes;Wherein each component ratio range is as follows:Portland cement 300-500kg/ m3;Fine coal ashes 100-150kg/m3;Water 150-210kg/m3;Water-reducing agent 2-4kg/m3;The water-reducing agent is polycarboxylic-acid solid High efficiency water reducing agent;The foaming agent is specially the hydrogen peroxide solution of a concentration of 35-45%;The fine coal ashes is I grades of fine coal of F classes Ash;
It should be noted that the second layer composite layer specifically includes defoaming agent carrier 21 (i.e. with the 4th layer of composite layer); The defoaming agent carrier 21 is netted (referring to Fig. 4);
It should be noted that antifoaming agent good dispersion, defoaming in cement mortar system is rapid;It can effectively control water Foam generates in silt particle slurry system, and alloing the finer and close light of concrete layer, (i.e. antifoaming agent changes foam surface tension and makes Bubbles burst, to achieve the purpose that defoaming).It pours into a mould in the forming process after concrete grout, and impregnated in shaping mold cavity The bubble overwhelming majority that the defoaming agent carrier of antifoaming agent is in direct contact is eliminated, and concrete grout is close at left and right sides of defoaming agent carrier It spends larger, has been here formed as the fine and close hard thin layer with some strength, i.e. surface dense layer.Due near defoaming agent carrier A part of bubble be also eliminated, therefore the density of concrete grout is also opposite improves.
Because being provided with defoaming agent carrier in concrete layer, and defoam agent carrier be it is netted (i.e. its substantially be exactly a piece of Reticular structure), effect is adherency antifoaming agent;It will be fixed in shaping mold cavity, defoam immersed with the defoaming agent carrier of antifoaming agent Agent can change foam surface tension and make bubbles burst, to achieve the purpose that defoaming.Then when concrete layer is molded The both sides bubble overwhelming majority of defoaming agent carrier is eliminated and forms a thin layer of, the higher surface dense layer of intensity.
It when making, will be fixed in shaping mold cavity immersed with the defoaming agent carrier of antifoaming agent, after pouring into a mould concrete grout In forming process, the bubble overwhelming majority being in direct contact with the defoaming agent carrier for impregnating antifoaming agent is eliminated, therefore is defoamed The both sides of agent carrier just form the fine and close hard thin layer with some strength, i.e. surface dense layer.(in this way in foam concrete plate It when moulding by casting, is eliminated with the bubble overwhelming majority for the forming panel face layer contacts for smearing antifoaming agent, the gas near the layer of face A bubble part is eliminated, and has then just been formed about compacted zone on the surface of foam concrete.) therefore antifoaming agent combination antifoaming agent The design of carrier will significantly play the role of defoaming, significantly promote the compactness of concrete layer, and it is strong to promote concrete layer Spend index and quick-drying index.
Second fiber concrete layer specific formula of the layer 5 composite layer is as follows:
The second fiber concrete layer is in terms of mass fraction:The second fiber concrete layer includes industrial aluminum sulphate 7- 12 parts, high-strength imitative steel wire fibre 5-9 parts, 60-80 parts of sandstone, 3-8 parts of siderite, 90-150 parts of cement, 5-9 parts of diatom ooze, carbon Sour calcium 7-10 parts, 8-15 parts of blast-furnace cinder, 3-6 parts of soda ash, 0.5-2 parts of sodium hexametaphosphate, 2-4 parts of aluminium hydroxide, coal ash 2-6 Part, 6-10 parts of dicalcium silicate, 9-14 parts of lithium slag, completely new compound 4 parts of diminishing formula;The completely new compound diminishing formula is:Choosing is cloudy Ionic surface active agent dodecyl sodium sulfate or cationic surfactant brocide are that organic water-reducing agent is former Material, it is inorganic water-reducing agent raw material to select waterglass or sodium carbonate;By above-mentioned raw materials weight ratio respectively according to organic water-reducing agent: inorganic The proportioning that water-reducing agent is 1~3: 1~3 carries out configuration and, obtained completely new compound diminishing formula uniform by ball milling mixing.
It should be noted that the second fiber concrete layer of above-mentioned layer 5 composite layer uses completely new formula design, The second fiber concrete layer has apparent structure stress specific aim;Second fiber concrete layer of the layer 5 composite layer, With good anticracking ability, at the same it is few with water, the wasting of resources, and good fluidity are reduced, deformation is small.The work of above-mentioned blast-furnace cinder With the load-bearing capacity for the second fiber concrete layer that can further enhance layer 5 composite layer;So-called blast-furnace cinder, i.e., it is all When the blast furnace process pig iron, be able to silicate is as granulated with alumino-silicate fusant as main component after quenching granulating Blast-furnace cinder (hereinafter referred to as slag);It is fine that second fiber concrete layer of above-mentioned layer 5 composite layer is also mixed with high-strength imitative steel wire Dimension, siderite, the formulas such as diatom ooze;Wherein high-strength imitative steel wire fibre and siderite can further enhance layer 5 composite layer The second fiber concrete layer structural strength;Wherein, diatom ooze can promote the cracking resistance change performance of the second fiber concrete layer. The main raw material(s) of diatom ooze be after 1 years formed diatom mineral --- diatomite, diatom be one kind live in ocean, Algae in lake.Diatom ooze takes the aquatic class biology that swims before living in millions of years --- and it is natural made of diatom deposition Substance, main component are opal, are rich in multiple beneficial minerals, and quality is light and soft, and electron microscope shows that its particle surface has There are countless small holes, for porosity up to 90% or more, specific surface area is up to 65 ㎡/g.Exactly this molecular sieve knot outstanding Structure determines that its unique function has extremely strong physical adsorption property and ion-exchange performance, sprays water in metope large area, energy A large amount of water are absorbed, illustrate that adsorptivity is extremely strong, and slowly sustained release negative oxygen ion, energy effectively decomposing formaldehyde, benzene, radon gas etc. are harmful Carcinogen.
It is well known that water-reducing agent can mainly improve the intensity of mortar, its definition is not influence concrete construction and easily Property under conditions of, the additive with diminishing and humidification is known as water-reducing agent.The type of traditional water-reducing agent has sulfomethylated lignin Hydrochlorate, naphthalene water reducer, melamine based water reducer, polycarboxylate dehydragent, casein water-reducing agent, sulfamate water reducer, third Olefin(e) acid based water reducer etc..It is small but the solidifying effect of its solution of conventional water reducing agents is poor, solution coagulates range.However the layer 5 in the present invention is compound Completely new compound diminishing formula used by second fiber concrete layer of layer, there is solution to coagulate, and effect is good, solution coagulates that range is wide, energy saving increasing The advantages that imitating and be easy to use.Second fiber concrete layer of above-mentioned layer 5 composite layer can be such that cement granules disperse, improve and Yi Xing reduces water consumption, to improve the compactness and hardness of cement-based material.
To sum up, the superior foam concrete compound external wall panel of stress performance of the present invention relates to first layer composite layer, Two layers of composite layer and third layer composite layer, the 4th layer of composite layer and layer 5 composite layer etc. complex composite design, wherein each Specific various innovative designs such as individual fiber concrete layer, bubble concrete layer and defoaming agent carrier, to this Invention no longer repeats one by one.
It should be noted that the above-mentioned superior foam concrete compound external wall panel of stress performance, intensity is high, anti-seismic performance It is good so that wall has excellent insulation, sound insulation, fireproof excellent results.The superior foam of stress performance of the present invention is mixed Solidifying soil compound external wall panel, outer layer intensity is high, and water resistance is superior, and inside has preferable elasticity and do not absorb water.The present invention The superior foam concrete compound external wall panel of stress performance also has otherwise many technical advantages:1, durability, having can The quality assurance leaned on, it is integrated with building structure.2, fire line can reach A grades of fire protection requirements, absolutely non-ignitable.3, shock resistance is strong, Exterior wall shock resistance requirement is fully achieved.4, range of applicability is extensive, can be used for public building, residential housing, industrial building and its His various buildings.5, economy, wall cost are less than existing wall way 10-30%, have great cost advantage, are conducive to It is widely applied.6, shock resistance, wall body structure intensity superelevation, can be improved antidetonation earthquake intensity.
It preferably, can embodiment as one kind;It is additionally provided with steel in the perpendicular concrete edge rib of the concrete rib Skeleton;The steel skeleton is made of multiple truss pieces, and multiple truss pieces, which are sequentially fixedly connected, constitutes the steel skeleton.
It should be noted that above-mentioned truss chip architecture can further enhance the intensity and toughness of concrete layer.
It preferably, can embodiment as one kind;The surface of the steel skeleton, which is coated with, is provided with corrosion-inhibiting coating.In order into The antidetonation and crack resistence performance of one step the first fiber concrete layer, it is above-mentioned be arranged concrete rib Reinforcement and set The bar-mat reinforcement inside concrete slab is set, better effect is can act as, can preferably increase by the first fiber concrete layer Intensity, toughness, shock resistance and crack resistence.
It preferably, can embodiment as one kind;The surface of the steel skeleton, which is coated with, is provided with corrosion-inhibiting coating.
It preferably, can embodiment as one kind;The surface of the Reinforcement, which is coated with, is provided with corrosion-inhibiting coating.
It should be noted that the structure of reinforcing bar or steel skeleton involved in above structure, it may indicate that coating anti-corrosion applies Layer, and then avoid the influence structural strength that is corroded;Simultaneously, it might even be possible to selection addition corrosion inhibitor;It should be noted that above-mentioned resistance Rust agent (i.e. reinforcing steel bar corrosion inhibitor) has no adverse effect to concrete strength, to the mobility of concrete mix without ill-effect, very Some plasticizing effects may be extremely gone back, with other type additives simultaneously using with good intermiscibility.The corrosion inhibitor can drop The corrosion current and corrosion rate of reinforcing bar in low concrete.
The present invention implements the superior foam concrete compound external wall panel of stress performance provided, mixed compared to more traditional foam Solidifying soil Side fascia, operates more convenient, simplifies technological operation step, improve production efficiency, and saves more Labour cost and labour.Simultaneously most importantly, the present invention implements the superior foam concrete of stress performance provided Compound external wall panel, with stress performance is remarkable, endurance quality is good, shock resistance is strong, fire line is more preferable, strong applicability, shock resistance All various technical advantages such as the superior, structural reliability of energy and stable structure are strong.
In conclusion the superior foam concrete compound external wall panel of stress performance of the present invention, specific all various technologies Advantage, therefore it will bring good market prospects and economic benefit.
Finally it should be noted that:The above embodiments are only used to illustrate the technical solution of the present invention., rather than its limitations;To the greatest extent Present invention has been described in detail with reference to the aforementioned embodiments for pipe, it will be understood by those of ordinary skill in the art that:Its according to So can with technical scheme described in the above embodiments is modified, either to which part or all technical features into Row equivalent replacement;And these modifications or replacements, various embodiments of the present invention technology that it does not separate the essence of the corresponding technical solution The range of scheme.

Claims (4)

1. a kind of superior foam concrete compound external wall panel of stress performance, which is characterized in that including from the inner to the outer successively First layer composite layer, second layer composite layer and the third layer composite layer of setting, the 4th layer of composite layer and layer 5 composite layer;
The first layer composite layer specifically includes the first fiber concrete layer, reinforcement net and framework of steel reinforcement, the framework of steel reinforcement Including multigroup transversely arranged composition of framework of steel reinforcement component;Every group of framework of steel reinforcement component specifically includes four be arranged in concrete rib Reinforcement and Duo Gen stirrups and the bar-mat reinforcement being arranged inside concrete slab;
The second layer composite layer specifically includes defoaming agent carrier;The defoaming agent carrier is netted;
The third layer composite layer specifically includes bubble concrete layer;
The 4th layer of composite layer is identical as the second layer lamination layer structure;The i.e. described 4th layer of composite layer specifically includes defoaming Agent carrier, and the defoaming agent carrier is netted;
The layer 5 composite layer specifically includes the second fiber concrete layer;
First fiber concrete layer specific formula of the first layer composite layer is as follows:
The first fiber concrete layer is in terms of mass fraction:The first fiber concrete layer includes urban inorganic garbage powder 26-28 parts, 25-30 parts of bastard coal mountain flour, 28-30 parts of Emathlite, 10-15 parts of land plaster, 3-5 parts of cement, quartz sand powder 3-5 Part, be chopped 1-2 parts of alkali-resistant glass fibre, nano-mineral modified mixed powder 2-4 parts, 0.01-0.09 parts of expanded perlite, waterproofing agent 0.7-1.9 parts, 0.02-0.08 parts of anti-cracking agent, 0.7-0.9 parts of concrete intensifier;
It is made of the concrete intensifier organic high molecular polymer and compounding agent, and the organic high molecular polymer is poly- Acrylamide copolymer aqueous solution;The compounding agent is by colloidal silicon dioxide, triisopropanolamine, sodium tripolyphosphate and triethanolamine Composition;The reinforcing agent appearance is pink liquid, solid content 25wt%, pH value 8.9;
Each substance of concrete intensifier is specific as follows:Polyacrylamide copolymer aqueous solution 50g, colloidal silicon dioxide 2.5g, triisopropanolamine 1.5g, sodium tripolyphosphate 2.0g, triethanolamine 1.5g;Above-mentioned concrete intensifier is by with lower section What method was configured to, compounding agent raw material is first configured to cooperation agent solution with water in proportion, then under stiring in polyacrylamide Cooperation agent solution is added in aqueous copolymers solution, continues stirring 10 minutes or more after adding;
The nano-mineral modified mixed powder is by 1-2 parts by weight peridotite, 2-4 parts by weight phosphorus ores slag, 5-8 parts by weight Fluorite slags After powder, 1-2 parts by weight sepiolite powder mixings, scaling loss 4-5 hours at 700-800 DEG C, after be ground into nanometer powder, admix quite Uniform in the dibutyl maleate of powder weight 1-2%, the chlorinated paraffin agitating of 1-2%, drying is ground into powder to obtain the final product;
The bubble concrete layer specific formula of the third layer composite layer is as follows:
The bubble concrete layer is mixed evenly by cementitious material, water and water-reducing agent, foaming agent;The cementitious material It is made of portland cement and fine coal ashes;Wherein each component ratio range is as follows:Portland cement 300-500kg/m3;Powder Coal ash powder 100-150kg/m3;Water 150-210kg/m3;Water-reducing agent 2-4kg/m3;The water-reducing agent is polycarboxylic-acid solid high-efficiency Water-reducing agent;The foaming agent is specially the hydrogen peroxide solution of a concentration of 35-45%;The fine coal ashes is I grades of flyash of F classes;
Second fiber concrete layer specific formula of the layer 5 composite layer is as follows:
The second fiber concrete layer is in terms of mass fraction:The second fiber concrete layer includes industrial aluminum sulphate 7-12 Part, high-strength imitative steel wire fibre 5-9 parts, 60-80 parts of sandstone, 3-8 parts of siderite, 90-150 parts of cement, 5-9 parts of diatom ooze, carbonic acid 7-10 parts of calcium, 8-15 parts of blast-furnace cinder, 3-6 parts of soda ash, 0.5-2 parts of calgon, 2-4 parts of aluminium hydroxide, coal ash 2-6 Part, 6-10 parts of dicalcium silicate, 9-14 parts of lithium slag, compound 4 parts of diminishing formula;The compound diminishing formula is:Select anionic surface Activating agent dodecyl sodium sulfate or cationic surfactant brocide are organic water-reducing agent raw material, select water Glass or sodium carbonate are inorganic water-reducing agent raw material;By above-mentioned raw materials weight ratio respectively according to organic water-reducing agent: inorganic water-reducing agent is 1 ~3: 1~3 proportioning carries out configuration and, obtained compound diminishing formula uniform by ball milling mixing.
2. the superior foam concrete compound external wall panel of stress performance as described in claim 1, which is characterized in that
It is additionally provided with steel skeleton in the perpendicular concrete edge rib of the concrete rib;The steel skeleton is by multiple truss piece groups At multiple truss pieces, which are sequentially fixedly connected, constitutes the steel skeleton.
3. the superior foam concrete compound external wall panel of stress performance as claimed in claim 2, which is characterized in that
The surface of the steel skeleton, which is coated with, is provided with corrosion-inhibiting coating.
4. the superior foam concrete compound external wall panel of stress performance as claimed in claim 3, which is characterized in that
The surface of the Reinforcement, which is coated with, is provided with corrosion-inhibiting coating.
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CN107417181B (en) * 2017-07-13 2020-04-28 山西恒久安建筑科技有限公司 Spontaneous combustion coal gangue concrete sandwich floor slab
CN108373340A (en) * 2018-05-03 2018-08-07 合肥宸翊商贸有限公司 A kind of preparation method of the compound precast concrete wall of sound-insulating
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