CN106079783A - A kind of antibacterial resin plate and preparation method thereof - Google Patents

A kind of antibacterial resin plate and preparation method thereof Download PDF

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Publication number
CN106079783A
CN106079783A CN201610458130.9A CN201610458130A CN106079783A CN 106079783 A CN106079783 A CN 106079783A CN 201610458130 A CN201610458130 A CN 201610458130A CN 106079783 A CN106079783 A CN 106079783A
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parts
layer
resin plate
antibacterial
crashproof
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CN201610458130.9A
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CN106079783B (en
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李海平
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Guangzhou Ruibo New Materials Co., Ltd.
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Guangzhou Ruibo Plastic Hardware Products Co Ltd
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/04—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C09D7/60—Additives non-macromolecular
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • B32B2255/00—Coating on the layer surface
    • B32B2255/26—Polymeric coating
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
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    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
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    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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    • C08L2201/02—Flame or fire retardant/resistant
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    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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Abstract

The invention provides a kind of antibacterial resin plate, formed by from lower and outside upper substrate layer, crashproof layer, fireprotection layer, decorative layer, antibiotic layer and the anti-soil layer set gradually.The present invention also provides for the preparation method of a kind of above-mentioned antibacterial resin plate.The present invention uses soybean oil as partial synthesis raw material, beneficially environmental conservation and economic sustainable development, and the anti-bacterial and anti-fouling surface of the present invention has hardness height, good toughness, the features such as resistance to impact is strong.Simultaneously, the present invention uses Particular craft to make the multilager base plate that substrate layer, crashproof layer and fireprotection layer are combined, and reaches perfect adaptation between each layer, also has elasticity while ensure that the intensity of resin plate, external force collision can be absorbed, there is good anti-flammability simultaneously.Multi-layer substrate surface of the present invention is coated with the antibacterial and coating of anti-soil, and coating is difficult to be contaminated, it is easier to cleaning, moreover it is possible to effectively prevent from being scratched.

Description

A kind of antibacterial resin plate and preparation method thereof
Technical field
The invention belongs to decorate anti-biotic material field, relate to a kind of antibacterial environment protection sheet material, particularly a kind of antibacterial resin plate And preparation method thereof.
Background technology
The swift and violent Great War of China's green building body of wall environment-friendly materials in recent years, for development environmental protection decorative material for internal wall society Build consensus in meeting, along with management system and the progressively foundation of standards system, and environmental protection effect of new decorative material Enhancing, green building has welcome good development.Antibacterial plate, as a kind of environment friendly decorative material, is class basis in using environment Antibacterial, mycete, alcohol mother bacterium, algae even virus etc. is played suppression or the sheet material of killing action, by suppressing the numerous of microorganism by body Grow and keep itself clean.Antibacterial plate is mainly used in public place decoration use, especially medical treatment and clean place, and antibacterial plate first has to Meet the exclusive requirement to performances such as its physics, chemistry, machineries when stock uses, to consider possess this spy antibacterial simultaneously The requirement of distinguished service energy and consequent additive factors.At present, antibacterial plate mainly chooses density fiber cement plate as base material, Surface-coated antibiotic paint is made, and this antibacterial plate surface is harder, and crashworthiness is poor, and anti-microbial property is the best, and is easily scraped Flower, it is difficult to repair.In addition, the fire resistance of existing antibacterial plate is poor, and needs by modes such as cement steel nails when installing Just can be stably fixed on body of wall, it is more difficult to install.
Summary of the invention
In order to overcome the deficiencies in the prior art, the invention provides a kind of antibacterial resin plate and preparation method thereof, solve The problems such as the crashproof scratch resistant poor performance of existing antibacterial plate existence and installation inconvenience.
The technical solution adopted for the present invention to solve the technical problems is:
Present invention firstly provides a kind of antibacterial resin plate, by the substrate layer set gradually from lower and outside upper, crashproof layer, fire prevention Layer, decorative layer, antibiotic layer and anti-soil layer composition.
Preferably, described anti-soil layer is that anti-pollution paint is formed, and described anti-pollution paint comprises the raw material of following weight portion: saturated Three grades the last of the ten Heavenly stems vinyl carboxylates 3～5 parts, non-isocyanate polyurethane 10～20 parts.
Preferably, described antibiotic layer is that antibiotic paint is formed, and described antibiotic paint is made up of the raw material of following weight portion: negative The silicon-dioxide powdery 7 of load high valency silver ion～8 parts, Tissuemat E 0.3-0.6 part, anti-impact modifier 2.5～3.5 parts, color Powder 5～8 parts, epoxy soybean oil 15～20 parts, ethyl acetate 30～35 parts, titanium dioxide 12-15 part, meerschaum 6-10 part, nanometer Zinc oxide 3-7 part, Corvic 25～45 parts, light trigger 3～5 parts, UV absorbers 0.02～0.05 part.
Preferably, described fireprotection layer is made up of the raw material of following weight portion: epoxy soybean oil 10～12 parts, polrvinyl chloride tree Fat 15～25 parts, bimaleimide resin 4～5 parts, 1,2-double (5,5-dimethyl-1,3-dioxa acyl phosphorus imido grpups in oneself) Ethane 3～4 parts, titanium dioxide 5～8 parts, nano-aluminum hydroxide 5～8 parts, dispersant 0.12～0.2 part.
Preferably, described crashproof layer includes the raw material of following weight portion: Corvic 40-55 part, epoxy resin 5- 10 parts, politef 5～6 parts, nano titanium oxide 2～3 parts, ceramic 6～8 parts, auxiliary agent is 0.5-1 part.
Preferably, described substrate layer is made up of the raw material of following weight portion: polrvinyl chloride 35～45 parts, chlorinated polyethylene 20 ～25 parts, processing aid 8～10 parts, reinforcing agent 10～15 parts, plasticizer 10～12 parts, stabilizer 5～8 parts.
The present invention also provides for the preparation method of a kind of above-mentioned antibacterial resin plate, comprises the steps:
(1) polrvinyl chloride is put in mixing facilities and heat, when temperature rises to 80-95 DEG C, add stabilizer, chlorinated polyethylene Alkene, is continuously heating to 120-130 DEG C, adds processing aid, reinforcing agent and plasticizer and carries out mixing, by compound after mixing end It is cooled to 65～75 DEG C, and machinery is mated formation on hot press, after hot pressing, make substrate layer；
(2) in extruder, add Corvic, epoxy resin, politef to stir 20 minutes at 200 DEG C, It is subsequently adding the mixture of the nano titanium oxide of mix homogeneously, ceramic and auxiliary agent, at 60 DEG C, is hot pressed into crashproof layer；
(3) at 60～70 DEG C by crashproof laminating above substrate layer, be then pressed into crashproof base material；
(4) take epoxy soybean oil, Corvic mechanical agitation 1～2h at 80～100 DEG C, be subsequently added titanium dioxide And ultrasonic disperse 1～2h, obtain resin adhesive liquid；By double for 1,2-(the own interior acyl phosphorus imido grpup of 5,5-dimethyl-1,3-dioxa) second Alkane adds in the resin adhesive liquid obtained, mechanical agitation 15～30min at 120～140 DEG C, is subsequently adding nano-aluminum hydroxide and divides The mixture of powder, continues stirring 15～30min, adds bimaleimide resin, machine at 130～140 DEG C after mix homogeneously Tool stirring 30～60min, finally directly waters it above described crashproof substrate layer, and substrate is suppressed to obtain in solidification；
(5) suppress smooth after upper surface of base plate paste the facing paper lamina that processed through antibacterial mildew inhibitor, then enter Row compacting；
(6) at facing paper lamina surface-coated antibiotic paint, after drying, antibiotic layer is formed；
(7) at antibiotic layer surface-coated anti-pollution paint, after drying, dirt resistant surfaces layer is formed.
Preferably, in step (1), the process of hot pressing includes precompressed and compacting, described precompressed temperature 60-65 DEG C, pressure 3- 4MPa, second time 20-30；Press temperature 100-110 DEG C, pressure is 4-5Mpa, second time 20-30；The temperature of hot pressing in step (2) Spending 140-145 DEG C, pressure is 3-4Mpa, second time 20-30；Press temperature 110-115 DEG C in step (3), pressure 6-8MPa, time Between 90-120 minute；Press temperature 120-125 DEG C, pressure 6-8MPa, 90-120 minute time in step (4).
The positive effect of the present invention: the present invention uses soybean oil as partial synthesis raw material, beneficially environmental conservation and warp The sustainable development of Ji, the features such as it is high that the anti-bacterial and anti-fouling surface of the present invention has hardness, good toughness, and resistance to impact is strong.Meanwhile, originally Invention uses Particular craft to make the multilager base plate that substrate layer, crashproof layer and fireprotection layer are combined, and has reached between each layer U.S. combination, also has elasticity while ensure that the intensity of resin plate, can absorb external force collision, have the most fire-retardant simultaneously Property.Multi-layer substrate surface of the present invention is coated with the antibacterial and coating of anti-soil, and coating is difficult to be contaminated, it is easier to cleaning, moreover it is possible to have Effect prevents from being scratched.Additionally, product of the present invention can be directly installed on body of wall by adhesive means, the fire prevention meeting building is wanted Ask, convenient and quick construction.
Detailed description of the invention
Below to a preferred embodiment of the present invention will be described in detail.
Embodiment 1
The preferred embodiment of the present invention 1 provides a kind of antibacterial resin plate, by the substrate layer set gradually from lower and outside upper, crashproof Layer, fireprotection layer, decorative layer, antibiotic layer and anti-soil layer composition.
Described anti-soil layer is that anti-pollution paint is formed, and described anti-pollution paint comprises the raw material of following weight portion: saturated three grades of last of the ten Heavenly stems Vinyl carboxylates 4 parts, non-isocyanate polyurethane 12 parts.Described anti-pollution paint can be by any of which system well known in the art Standby, such as at applicable temperature by saturated three grades the last of the ten Heavenly stems vinyl carboxylates, non-isocyanate polyurethane and acrylic monomer be with suitable Close solvent and the most suitable initiator mix homogeneously, in proper temperature and carry out under conditions of the response time polymerization make With, then can add the auxiliary agent such as the levelling agent known to the art personage or surface light lubrication prescription, described anti-pollution paint can be obtained. Anti-pollution paint the most of the present invention, based on non-isocyanate polyurethane, does not contains the harmful substances such as isocyanates, keeps away Having exempted from the pollution to air during coating uses, formulation green environment-protecting asepsis, the present invention uses the poly-ammonia of non-isocyanate simultaneously Ester arrange in pairs or groups this area conventional must raw material propylene acids activated monomer, in conjunction with saturated three grades the last of the ten Heavenly stems vinyl carboxylates addition, make Coating has a preferable scratch resistance, and collect hardness is good, wearability is good, adhesion is good, solvent resistance is good advantage in one Body, can effectively be combined with each other with following antimicrobial coating, achieves good effect on product of the present invention.
Described antibiotic layer is that antibiotic paint is formed, and described antibiotic paint is made up of the raw material of following weight portion: load high price The silicon-dioxide powdery of silver ion 7 parts, Tissuemat E 0.4 part, anti-impact modifier 3.2 parts, toner 6 parts, epoxy soybean oil 18 Part, ethyl acetate 33 parts, titanium dioxide 13 parts, meerschaum 7 parts, nano zine oxide 4 parts, Corvic 30 parts, light trigger 4 Part, UV absorbers 0.04 part.Described antibiotic paint can be prepared by any of which well known in the art, such as by acetic acid The silicon-dioxide powdery of ethyl ester, Corvic, meerschaum, nano zine oxide and load high valency silver ion joins mixing and stirs Mix in machine and be uniformly mixed, add epoxy soybean oil, titanium dioxide, Tissuemat E and anti-impact the most at a suitable temperature and click to change Property agent, in proper temperature and carry out polymerization under conditions of the time, is eventually adding light trigger, UV absorbers, toner Deng auxiliary agent, described antibiotic paint can be obtained.Antibiotic paint of the present invention is free from environmental pollution, can be mutual at contact surface with above-mentioned anti-pollution paint Infiltration combines, and curing rate is fast, in normal temperature cure, can be particularly suitable for the covering with paint of substrate surface of the present invention, will not be right Final products adversely affect, and the hardness of coating is high, and wearability is good, and resistance to hard thing scratches, and can not only meet antibacterial wanting Ask, and with photocuring system, there is the good compatibility, improve by the use of the silicon-dioxide powdery of load silver ion The activity of photocatalysis antibacterial and range of application, have stronger antibacterial effect, and the persistent period be long.
Described fireprotection layer is made up of the raw material of following weight portion: epoxy soybean oil 11 parts, Corvic 18 parts, span Bismaleimide resin 4 parts, 1,2-double (5,5-dimethyl-1, acyl phosphorus imido grpup in 3-dioxa is own) 3 parts of ethane, titanium dioxide 6 parts, Nano-aluminum hydroxide 5 parts, dispersant 0.15 part.
Described crashproof layer includes the raw material of following weight portion: Corvic 45 parts, epoxy resin 6 parts, polytetrafluoroethyl-ne 6 parts of alkene, nano titanium oxide 3 parts, ceramic 6 parts, auxiliary agent is 1 part.
Described substrate layer is made up of the raw material of following weight portion: polrvinyl chloride 37 parts, chlorinated polyethylene 22 parts, processing aid 9 parts, reinforcing agent 12 parts, plasticizer 11 parts, stabilizer 6 parts.
The preparation method of above-mentioned antibacterial resin plate, comprises the steps:
(1) polrvinyl chloride is put in mixing facilities and heat, when temperature rises to 80-95 DEG C, add stabilizer, chlorinated polyethylene Alkene, is continuously heating to 120-130 DEG C, adds processing aid, reinforcing agent and plasticizer and carries out mixing, by compound after mixing end It is cooled to 65～75 DEG C, and machinery is mated formation on hot press, after hot pressing, make substrate layer；
(2) in extruder, add Corvic, epoxy resin, politef to stir 20 minutes at 200 DEG C, It is subsequently adding the mixture of the nano titanium oxide of mix homogeneously, ceramic and auxiliary agent, at 60 DEG C, is hot pressed into crashproof layer；
(3) at 60～70 DEG C by crashproof laminating above substrate layer, be then pressed into crashproof base material；
(4) take epoxy soybean oil, Corvic mechanical agitation 1～2h at 80～100 DEG C, be subsequently added titanium dioxide And ultrasonic disperse 1～2h, obtain resin adhesive liquid；By double for 1,2-(the own interior acyl phosphorus imido grpup of 5,5-dimethyl-1,3-dioxa) second Alkane adds in the resin adhesive liquid obtained, mechanical agitation 15～30min at 120～140 DEG C, is subsequently adding nano-aluminum hydroxide and divides The mixture of powder, continues stirring 15～30min, adds bimaleimide resin, machine at 130～140 DEG C after mix homogeneously Tool stirring 30～60min, finally directly waters it above described crashproof substrate layer, and substrate is suppressed to obtain in solidification；
(5) suppress smooth after upper surface of base plate paste the facing paper lamina that processed through antibacterial mildew inhibitor, then enter Row compacting；
(6) at facing paper lamina surface-coated antibiotic paint, after drying, antibiotic layer is formed；
(7) at antibiotic layer surface-coated anti-pollution paint, after drying, dirt resistant surfaces layer is formed.
In step (1), the process of hot pressing includes precompressed and compacting, described precompressed temperature 60-65 DEG C, pressure 3-4MPa, time Between the 20-30 second；Press temperature 100-110 DEG C, pressure is 4-5Mpa, second time 20-30；Temperature 140-of hot pressing in step (2) 145 DEG C, pressure is 3-4Mpa, second time 20-30；Press temperature 110-115 DEG C, pressure 6-8MPa, time 90-in step (3) 120 minutes；Press temperature 120-125 DEG C, pressure 6-8MPa, 90-120 minute time in step (4).
The present invention may also include step (8): by whole resin plate in the temperature environment of 40～45 DEG C after anti-soil layer solidifies Lower standing 3～4 hours, this not only makes each interlayer can carry out more favourable combination, crucial, anti-soil layer tool after this step The effect that cooperates of antibiotic layer is higher, and its anti-bacterial and anti-fouling effect becomes apparent from, the resin board surface installed in painting with the black pen of oiliness Upper standardized pen, with the toilet paper wiping back and forth being dried, the number of times of pen touch be completely eliminated as the foundation judging that pollution resistance is fine or not, Product of the present invention only needs wiping 2～3 times, compares and 5～10 times of existing anti-bacterial and anti-fouling sheet material, and the present invention has extremely excellent anti- Dirty performance, and the antibiotic rate of escherichia coli and staphylococcus aureus is 100%, meet or exceed international standard.
The performance of the antibacterial resin plate of preparation contrasts such as following table with existing each like product:
Product of the present invention completes escherichia coli, golden yellow in Prevention & Control Station of Parasitic Disease, China Diseases Prevention & C In staphylococcus and standard, escherichia coli and staphylococcus aureus are wherein resisted by the antibacterial test of contained mycete totally 8 strains Bacterium rate is 100%, is the fungi-growth grade of 6 kinds of test mycetes " 0 ", according to international standard QB/T2591-2003, the present invention Product has strong antibacterial actions and strong Antifungal activities.
Meanwhile, product of the present invention has passed through " country's fixed fire extinguishing system and fire-resistant structure quality surveillance inspection center " Detection, fire protecting performance reaches B1 level, and at product smoke density, cigarette cusp height, smoke moisture and burning residue length meansigma methods etc. refer to Mark has met or exceeded A level composite material standard the most, and overall technology of the present invention is safe and reliable, leads far away at home in building material industry First.
Surface of the present invention anti-pollution layer has excellent properties non-maintaining, self-cleaning.Extremely low surface energy, surface dirt can Directly cleaned by clear water.Fabulous hydrophobicity (maximum water absorption rate is less than 5%) and scold oil.Minimum coefficient of friction (0.15～ 0.17), will not non-dust absorption and non-fouling, soil resistance is good.
The silver ion of the present invention purifies coating, has good antibiotic property, and opposing multiple infectious disease bacterium is at plate surface Survival, reduces the probability of disease propagation, it is possible to keeps clean for a long time, and has anti-ultraviolet function.
Interiors of products compact texture of the present invention possesses certain soundproof effect, can effectively prevent outdoor noise from entering indoor, Keep indoor environment peace and quiet comfortable.Product the most of the present invention is attractive in appearance, cleaning, comfortable, on-the-spot completion can be moved into office, does not pollutes Environment, do not produce a large amount of waste material, there is environmental protection and the effect economized on resources, and easy construction, decrease by construction activities doctor The inconvenience that treatment or clean environment cause.
Above-described only the preferred embodiments of the present invention, the explanation of it should be understood that above example is simply used In helping to understand method and the core concept thereof of the present invention, the protection domain being not intended to limit the present invention, all the present invention's Any amendment of being made within thought and principle, equivalent etc., should be included within the scope of the present invention.

Claims (8)

1. an antibacterial resin plate, it is characterised in that: by the substrate layer set gradually from lower and outside upper, crashproof layer, fireprotection layer, dress Decorations layer, antibiotic layer and anti-soil layer composition.
A kind of antibacterial resin plate the most according to claim 1, it is characterised in that: described anti-soil layer is that anti-pollution paint is formed, Described anti-pollution paint comprises the raw material of following weight portion: saturated three grades the last of the ten Heavenly stems vinyl carboxylates 3～5 parts, non-isocyanate polyurethane 10～20 parts.
A kind of antibacterial resin plate the most according to claim 1, it is characterised in that: described antibiotic layer is that antibiotic paint is formed, Described antibiotic paint is made up of the raw material of following weight portion: the silicon-dioxide powdery 7 of load high valency silver ion～8 parts, polyethylene Wax 0.3-0.6 part, anti-impact modifier 2.5～3.5 parts, toner 5～8 parts, epoxy soybean oil 15～20 parts, ethyl acetate 30～ 35 parts, titanium dioxide 12-15 part, meerschaum 6-10 part, nano zine oxide 3-7 part, Corvic 25～45 parts, light trigger 3～5 parts, UV absorbers 0.02～0.05 part.
A kind of antibacterial resin plate the most according to claim 1, it is characterised in that: described fireprotection layer is former by following weight portion Material composition: epoxy soybean oil 10～12 parts, Corvic 15～25 parts, bimaleimide resin 4～5 parts, 1,2-is double (5,5-dimethyl-1,3-dioxa acyl phosphorus imido grpup in oneself) ethane 3～4 parts, titanium dioxide 5～8 parts, nano-aluminum hydroxide 5～8 Part, dispersant 0.12～0.2 part.
A kind of antibacterial resin plate the most according to claim 1, it is characterised in that: described crashproof layer includes following weight portion Raw material: Corvic 40-55 part, epoxy resin 5-10 part, politef 5～6 parts, nano titanium oxide 2～3 parts, Ceramic 6～8 parts, auxiliary agent is 0.5-1 part.
A kind of antibacterial resin plate the most according to claim 1, it is characterised in that: described substrate layer is former by following weight portion Material composition: polrvinyl chloride 35～45 parts, chlorinated polyethylene 20～25 parts, processing aid 8～10 parts, reinforcing agent 10～15 parts, increasing Mould agent 10～12 parts, stabilizer 5～8 parts.
7. the preparation method of an antibacterial resin plate as claimed in claim 1, it is characterised in that comprise the steps:
(1) polrvinyl chloride is put in mixing facilities and heats, when temperature rises to 80-95 DEG C, add stabilizer, chlorinated polyethylene, It is continuously heating to 120-130 DEG C, adds processing aid, reinforcing agent and plasticizer and carry out mixing, after mixing end, compound is dropped Temperature is to 65～75 DEG C, and on hot press, machinery is mated formation, and makes substrate layer after hot pressing；
(2) in extruder, add Corvic, epoxy resin, politef and at 200 DEG C, stir 20 minutes, then Add the nano titanium oxide of mix homogeneously, ceramic and the mixture of auxiliary agent, at 60 DEG C, be hot pressed into crashproof layer；
(3) at 60～70 DEG C by crashproof laminating above substrate layer, be then pressed into crashproof base material；
(4) take epoxy soybean oil, Corvic mechanical agitation 1～2h at 80～100 DEG C, be subsequently added titanium dioxide and surpass Sound dispersion 1～2h, obtains resin adhesive liquid；Double for 1,2-(the own interior acyl phosphorus imido grpup of 5,5-dimethyl-1,3-dioxa) ethane is added Enter in the resin adhesive liquid obtained, mechanical agitation 15～30min at 120～140 DEG C, it is subsequently adding nano-aluminum hydroxide and dispersant Mixture, continue stirring 15～30min, after mix homogeneously add bimaleimide resin, at 130～140 DEG C, machinery stirs Mix 30～60min, finally it is directly watered above described crashproof substrate layer, solidification, suppress to obtain substrate；
(5) suppress smooth after upper surface of base plate paste the facing paper lamina that processed through antibacterial mildew inhibitor, then press System；
(6) at facing paper lamina surface-coated antibiotic paint, after drying, antibiotic layer is formed；
(7) at antibiotic layer surface-coated anti-pollution paint, after drying, dirt resistant surfaces layer is formed.
The preparation method of a kind of antibacterial resin plate the most according to claim 7, it is characterised in that: hot pressing in step (1) Process includes precompressed and compacting, described precompressed temperature 60-65 DEG C, pressure 3-4MPa, second time 20-30；Press temperature 100- 110 DEG C, pressure is 4-5Mpa, second time 20-30；Temperature 140-145 DEG C of hot pressing in step (2), pressure is 3-4Mpa, the time The 20-30 second；Press temperature 110-115 DEG C, pressure 6-8MPa, 90-120 minute time in step (3)；Compacting temperature in step (4) Spend 120-125 DEG C, pressure 6-8MPa, 90-120 minute time.
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CN106806922A (en) * 2016-12-09 2017-06-09 安徽宏翔自动化科技有限公司 A kind of antibacterial treatment process of sunlight board
CN107082900A (en) * 2017-05-11 2017-08-22 安徽大德中电科技发展股份有限公司 Fungi-proofing switch on wall shell and its preparation technology
CN107129728A (en) * 2017-05-19 2017-09-05 浙江伟星新型建材股份有限公司 A kind of antibiotic fungus-resisting paint and preparation method thereof
CN108312674A (en) * 2018-03-02 2018-07-24 王平 A kind of green structural material decorative panel and preparation method thereof
CN108441064A (en) * 2018-01-30 2018-08-24 东莞市佳乾新材料科技有限公司 A kind of inner wall of building fire retarding epoxide resin coating and preparation method thereof
CN113604086A (en) * 2021-08-18 2021-11-05 沈阳浩丰科技有限公司 Preparation method of heat-insulating fireproof coating

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106806922A (en) * 2016-12-09 2017-06-09 安徽宏翔自动化科技有限公司 A kind of antibacterial treatment process of sunlight board
CN107082900A (en) * 2017-05-11 2017-08-22 安徽大德中电科技发展股份有限公司 Fungi-proofing switch on wall shell and its preparation technology
CN107129728A (en) * 2017-05-19 2017-09-05 浙江伟星新型建材股份有限公司 A kind of antibiotic fungus-resisting paint and preparation method thereof
CN108441064A (en) * 2018-01-30 2018-08-24 东莞市佳乾新材料科技有限公司 A kind of inner wall of building fire retarding epoxide resin coating and preparation method thereof
CN108312674A (en) * 2018-03-02 2018-07-24 王平 A kind of green structural material decorative panel and preparation method thereof
CN113604086A (en) * 2021-08-18 2021-11-05 沈阳浩丰科技有限公司 Preparation method of heat-insulating fireproof coating

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